Novel pyrolinone derivative and pharmaceutical composition comprising the same

ABSTRACT

The present invention provides a novel P2X 3  and/or P2X 2 / 3  receptor antagonist. 
     A compound represented by the formula (I); 
     
       
         
         
             
             
         
       
     
     wherein Z 1  is optionally protected hydroxy, etc.; Z 2  is —C(═O)—, etc.; Z 3a  and Z 3b  are taken together ═O or ═S; t is an integer of 0 to 4; R 4a  and R 4b  are each independently, hydrogen or substituted or unsubstituted lower alkyl, etc.; m and n are each independently an integer of 0 to 2; k is an integer of 0 or 1; Ring A is an aromatic carbocyclic ring or a heterocyclic ring, etc.; B is aromatic carbocyclic ring-diyl or heterocyclic ring-diyl, etc.; R 1a  and R 1b  are each independently halogen, hydroxy, substituted or unsubstituted lower alkyl, etc.; R 2  is substituted or unsubstituted alkyl, etc.; R 3  is substituted or unsubstituted alkyl, substituted or unsubstituted aryl or a substituted or unsubstituted heterocyclic group, etc.; or its pharmaceutically acceptable salt, or a solvate thereof is provided.

TECHNICAL FIELD

The invention relates to P2X receptor, specifically to a compound usefulfor the treatment of diseases or conditions associated with a P2X₃receptor, specifically to a P2X₃ and/or P2X₂/₃ receptor, and apharmaceutical composition comprising such compound.

BACKGROUND ART

ATP (adenosine triphosphate) is known to serve as a source of energy incells and a substrate of phosphorylation, as well as an extracellularmessenger. It is known that ATP is released from a cell by variousstimulation such as cellular injury, inflammation, nociceptive stimulus,reduced blood oxygen level, and also known to be released together withanother messenger from a primary sensory nerve terminal. ATP thusreleased mediates various extracellular signal transductions through anATP receptor (Non-Patent Document 6, Non-Patent Document 7).

ATP receptor is categorized into ionotropic P2X family and Gprotein-coupled P2Y family. For P2X family, seven subtypes have beenreported, and a member of this family forms a homo-trimeric structure ora hetero-trimeric structure together with another member of this subtypeand functions as a non-specific cation channel (Non-Patent Document 8).

ATP is known to cause pain, and studies with P2X₃ knockout and knockdownmethodologies have shown that P2X₃ receptor mediates transmission ofchronic pain. P2X₃ receptors are expressed in a specific manner onperipheral sensory nerve to form a homo-complex or hetero-complex withP2X₂ (P2X₂/₃) (Non-Patent Document 1).

Later, the compound A-317491 was reported as a specific antagonist toP2X₃ and P2X₂/₃ receptors. A-317491 istri-substituted-N-[(1S)-1,2,3,4-tetrahydro-1-naphthalenyl]benzamidederivative represented by the formula:

(Patent Document 1). It was reported to exhibit an antagonist activityto P2X₃ and P2X₂/₃ receptors and analgesic action in neuropathic painmodel and inflammatory pain model (Non-Patent Document 9). Thisindicates that pain sensation is transmitted via P2X₃ or P2X₂/₃ receptorand that a P2X₃ or P2X₂/₃ receptor antagonist is useful as an analgesic.Also, compounds that exhibit P2X₃ or P2X₂/₃ receptor antagonizing effectare described in Patent Documents 2-7.

Additionally, it was recently reported that vesical reflex was stronglyreduced in P2X₃ knockout mouse (Non-Patent Document 2), suggesting thata P2X₃ antagonist is useful in the treatment of diseases caused byoveractive bladder.

Patent document 12 discloses that the compounds having similar chemicalstructures to the compound of the invention, however, does not disclosethat the compounds having an analgesic effect and a P2X₃ or P2X₂/₃receptor antagonizing effect. Non-Patent documents 3, 4, 10, and 11disclose that the compounds having similar chemical structures to thecompound of the invention and an analgesic effect, however, does notdisclose that the compound having a P2X₃ or P2X₂/₃ receptor antagonizingeffect.

-   [Patent Document 1] WO02/094767-   [Patent Document 2] WO2005/095359-   [Patent Document 3] US20070037974-   [Patent Document 4] US20070049758-   [Patent Document 5] US20070049610-   [Patent Document 6] US20070049609-   [Patent Document 7] US20070049534-   [Non-Patent Document 1] Neuroscientist 11 (2005) pp. 345-356-   [Non-Patent Document 2] J. Physiol. 567.2 (2005) pp. 621-639-   [Non-Patent Document 3] Pharmaceutical Chemistry Journal Vol. 39,    No. 9, (2005), pp 484-487-   [Non-Patent Document 4] Pharmaceutical Chemistry Journal Vol. 31,    No. 5, (1997), pp 251-254-   [Non-Patent Document 5] Expert Opin. Ther. Patens (2006) 16(8)    113-1127.-   [Non-Patent Document 6] J. Physiology (2003), 554(2), 301-308-   [Non-Patent Document 7] J. Physiology (2003), 553(3), 683-694-   [Non-Patent Document 8] Pflungers Arch Eur J physiol (2006), 452,    513-537-   [Non-Patent Document 9] PNAS (2002), 99(26), 17179-17184-   [Non-Patent Document 10] Khimiko-Farmatsevticheskii Zhurnal, Vol 31,    No. 11, (1997) 35-36-   [Non-Patent Document 11] Pharmaceutical Chemistry Journal Vol 36,    No. 4, (2002), 188-191-   [Non-Patent Document 12] Phosphorus, Sulfur and Silicon and the    Related Elements (2006), 181(4), 771-777

DISCLOSURE OF INVENTION Problems to be Resolved by the Invention

The present invention provides a novel P2X₃ and/or P2X₂/₃ receptorantagonist.

Means of Solving the Problems

During studies to solve the problems described above, the inventors havediscovered novel compounds that bind specifically to P2X₃ and/or P2X₂/₃receptor and exhibit an antagonizing effect, and thus, achieved theinventions described bellow.

(1) A compound represented by the formula (I):

whereinZ¹ is optionally protected hydroxy or optionally protected mercapto;

Z² is —C(═O)—, —C(═S)— or —S(O)v-, or

wherein R^(5a) and R^(5b) are each independently hydrogen or loweralkyl;R⁶ is hydrogen, substituted or unsubstituted lower alkyl, substituted orunsubstituted acyl or substituted or unsubstituted lower alkoxycarbonyl;p is an integer of 0 to 2;v is an integer of 0 to 2;Z^(3a) and Z^(3b) are each independently hydrogen, substituted orunsubstituted lower alkyl, or taken together ═O or ═S;t is an integer of 0 to 4;R^(4a) and R^(4b) are each independently, hydrogen or substituted orunsubstituted lower alkyl;m and n are each independently an integer of 0 to 2;k is an integer of 0 or 1;Ring A is cycloalkane, cycloalkene, an aromatic carbocyclic ring or aheterocyclic ring;B is cycloalkene-diyl, cycloalkene-diyl, aromatic carbocyclic ring-diylor heterocyclic ring-diyl;R^(1a) and R^(1b) are each independently halogen, hydroxy, substitutedor unsubstituted lower alkyl, substituted or unsubstituted loweralkenyl, substituted or unsubstituted lower alkynyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkylthio, substituted or unsubstituted acyl, carboxy, substituted orunsubstituted lower alkoxycarbonyl, substituted or unsubstitutedcarbamoyl, substituted or unsubstituted thiocarbamoyl, substituted orunsubstituted amino, substituted sulfinyl, substituted sulfonyl,substituted or unsubstituted sulfamoyl, cyano, nitro or—C(R^(7a))═N—O—R^(7b);R^(7a) and R^(7b) are each independently hydrogen or substituted orunsubstituted lower alkyl;R² is substituted or unsubstituted alkyl, substituted or unsubstitutedalkenyl, substituted or unsubstituted alkynyl, substituted orunsubstituted alkoxy, substituted or unsubstituted aryloxy, hydroxy,substituted or unsubstituted amino, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group;R³ is substituted or unsubstituted alkyl, substituted or unsubstitutedalkoxycarbonyl, substituted or unsubstituted aryloxycarbonyl, carboxy,substituted or unsubstituted carbamoyl, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group;provided that a compound of the following (i) to (viii) is excluded;(i) a compound wherein Ring A is thiadiazole, k is 0 and R^(1a) ismethylthio;(ii) a compound wherein Ring A is benzothiophene, k is 0, R^(1a) ismethylsulfonyl and R² is substituted or unsubstituted furyl orsubstituted or unsubstituted phenyl;(iii) a compound wherein Ring A is thiazole or 7H-purine, and R² issubstituted or unsubstituted furyl;(iv) a compound wherein R³ is a group represented by the formula:

t is an integer of 1 to 2 and Ring A is furan or benzene;(v) a compound wherein R² is t-butyl or 4-methyloxyphenyl;(vi) a compound wherein R² is substituted or unsubstituted alkylprovided that substituted or unsubstituted i-propyl and substituted orunsubstituted i-butyl are excluded, R³ is a substituted or unsubstitutedcarbocyclic ring or a substituted or unsubstituted heterocyclic ring,and k is 0;(vii) a compound wherein R² is substituted or unsubstituted cycloalkyl,substituted or unsubstituted cycloalkenyl, substituted or unsubstitutedaryl or a substituted or unsubstituted heterocyclic group, and R³ ispentane-3-yl; and(viii) a compound represented by the formula:

or its pharmaceutically acceptable salt, or a solvate thereof.

(2) The compound according to the above (1), wherein R² is a grouprepresented by the formula:

wherein Me is methyl, q is an integer of 0 to 4; andR³ is a group represented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group, or Y andR¹⁴ may form a substituted or unsubstituted heterocyclic group withadjacent carbon atom;R¹⁴ is halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano or nitro; andr is an integer of 0 to 2, or its pharmaceutically acceptable salt, or asolvate thereof.

(2′) A compound represented by the formula (I);

whereinZ¹ is optionally protected hydroxy or optionally protected mercapto;

Z² is —C(═O)—, —C(═S)— or —S(O)v-, or

wherein R^(5a) and R^(5b) are each independently hydrogen or loweralkyl;R⁶ is hydrogen, substituted or unsubstituted lower alkyl, substituted orunsubstituted acyl or substituted or unsubstituted lower alkoxycarbonyl;p is an integer of 0 to 2;v is an integer of 0 to 2;Z^(3a) and Z^(3b) are each independently hydrogen, substituted orunsubstituted lower alkyl, or taken together ═O or ═S;Z^(3a) and Z^(3b) are each independently hydrogen, substituted orunsubstituted lower alkyl, or taken together ═O or ═S;t is an integer of 0 to 4;R^(4a) and R^(4b) are each independently, hydrogen or substituted orunsubstituted lower alkyl;m and n are each independently an integer of 0 to 2;k is an integer of 0 or 1;Ring A is cycloalkane, cycloalkene, an aromatic carbocyclic ring or aheterocyclic ring;B is cycloalkane-diyl, cycloalkene-diyl, aromatic carbocyclic ring-diylor heterocyclic ring-diyl;R^(1a) and R^(1b) are each independently halogen, hydroxy, substitutedor unsubstituted lower alkyl, substituted or unsubstituted loweralkenyl, substituted or unsubstituted lower alkynyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkylthio, substituted or unsubstituted acyl, carboxy, substituted orunsubstituted lower alkoxycarbonyl, substituted or unsubstitutedcarbamoyl, substituted or unsubstituted thiocarbamoyl, substituted orunsubstituted amino, substituted sulfinyl, substituted sulfonyl,substituted or unsubstituted sulfamoyl, cyano, nitro or—C(R^(7a))═N—O—R^(7b);R^(7a) and R^(7b) are each independently hydrogen or substituted orunsubstituted lower alkyl;R² is a group represented by the formula:

wherein Me is methyl, q is an integer of 0 to 4;R³ is a group represented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group, or Y andR¹⁴ may form a substituted or unsubstituted heterocyclic group withadjacent carbon atom;R¹⁴ is halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano or nitro; andr is an integer of 0 to 2;provided that the following compounds are excluded:

or its pharmaceutically acceptable salt, or a solvate thereof.

(3) The compound according to the above (2) or (2′), wherein Z^(3a) andZ^(3b) are taken together ═O, or its pharmaceutically acceptable salt,or a solvate thereof.

(4) The compound according to any one of the above (2), (2′) or (3),wherein t is 0, or its pharmaceutically acceptable salt, or a solvatethereof.

(5) The compound according to any one of the above (2) to (4) or (2′),wherein Z² is —C(═O)—, —C(═S)— or —S(O)₂—, or its pharmaceuticallyacceptable salt, or a solvate thereof.

(6) The compound according to any one of the above (2) to (5) or (2′),wherein Z² is —C(═O)—, or its pharmaceutically acceptable salt, or asolvate thereof.

(7) The compound according to any one of the above (2) to (6) or (2′),wherein the group represented by the formula:

wherein Z¹, Z² and R² are as defined in the above (1), is a grouprepresented by the formula:

wherein. R², R^(5a), R^(5b), R⁶, and p are as defined in the above (1),or its pharmaceutically acceptable salt, or a solvate thereof.

(8) The compound according to any one of the above (2) to (6) or (2′),wherein the group represented by the formula:

wherein Z¹, Z², Z^(3a), Z^(3b), R², and R³ are as defined in the above(1), is a group represented by the formula:

wherein Z¹, Z², Z^(3a), Z^(3b), R² and R³ are as defined in the above(1), or its pharmaceutically acceptable salt, or a solvate thereof.

(9) A compound represented by the formula (I):

wherein Z¹, Z², Z^(3a), Z^(3b), R^(1a), R^(1b), R², R³, R^(4a), R^(4b),Ring A, B, h, m, n, and t are as defined in the above (1), or itspharmaceutically acceptable salt, or a solvate thereof; isa compound represented by the formula (I′);

whereinZ¹′ is optionally protected hydroxy or optionally protected mercapto;

Z²′ is O or S, or

wherein R^(5a)′ and R^(5b)′ are each independently hydrogen or loweralkyl;R⁶ is hydrogen, substituted or unsubstituted lower alkyl, substituted orunsubstituted acyl or substituted or unsubstituted lower alkoxycarbonyl;p′ is an integer of 0 to 2;t′ is an integer of 0 to 4;R^(4a)′ and R^(4b)′ are each independently hydrogen or lower alkyl;m′ and n′ are each independently an integer of 0 to 2;Ring A′ is cycloalkane, cycloalkene, an aromatic carbocyclic ring or aheterocyclic ring;B′ is cycloalkane-diyl, cycloalkene-diyl, aromatic carbocyclic ring-diylor heterocyclic ring-diyl;when n′ is 0, B′ may be methylthio, trifluoromethylthio, or—C(R^(7a)′)═N—O—R^(7b)′;R^(1a)′ and R^(1b)′ are each independently halogen, hydroxy, substitutedor unsubstituted lower alkyl, substituted or unsubstituted loweralkenyl, substituted or unsubstituted lower alkynyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkylthio, substituted or unsubstituted acyl, carboxy, substituted orunsubstituted lower alkoxycarbonyl, substituted or unsubstitutedcarbamoyl, substituted or unsubstituted amino, substituted orunsubstituted sulfamoyl, cyano, or nitro;R²′ and R³′ are each independently substituted or unsubstituted alkyl,substituted or unsubstituted cycloalkyl, substituted or unsubstitutedcycloalkenyl, substituted or unsubstituted aryl or a substituted orunsubstituted heterocyclic group;R^(7a)′ and R^(7b)′ are each independently hydrogen or substituted orunsubstituted lower alkyl;provided that a compound wherein Ring A′ is thiadiazole and B′ ismethylthio is excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

(10) The compound according to the above (9), wherein R³′ is a grouprepresented by the formula:

wherein Ring C′ is a substituted or unsubstituted aromatic carbocyclicring or a substituted or unsubstituted aromatic heterocyclic ring;

Y′ is —O—, —S—, or —NR⁹′—;

R⁹′ is hydrogen or lower alkyl;Z′ is hydroxy, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted lower alkylsulfinyl, substituted orunsubstituted alkylsulfamoyl or cyano;R^(8a)′ and R^(8b)′ are each independently hydrogen or substituted orunsubstituted lower alkyl;s′ is an integer of 1 to 4,or its pharmaceutically acceptable salt, or a solvate thereof.

(11) The compound according to the above (9) or (10), wherein Y′ is —O—,or its pharmaceutically acceptable salt, or a solvate thereof.

(12) The compound according to any one of the above (9) to (11), whereint′ is 0, or its pharmaceutically acceptable salt, or a solvate thereof.

(13) The compound according to any one of the above (9) to (12), whereina group represented by the formula:

t′ and p′ are 0;R² is a group represented by the formula:

wherein R^(10a)′ and R^(10b)′ are each independently hydroxy, halogen,substituted or unsubstituted alkyl, substituted or unsubstituted loweralkoxy, substituted or unsubstituted lower alkoxycarbonyl, carboxy,substituted or unsubstituted carbamoyl, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl, a substituted or unsubstituted heterocyclic group,or R^(10a)′ and R^(10b)′ are taken together may form a substituted orunsubstituted non-aromatic carbocyclic ring or a substituted orunsubstituted non-aromatic heterocyclic ring with an adjacent carbonatom;R^(10c)′ is hydrogen, hydroxy, halogen, substituted or unsubstitutedalkyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkoxycarbonyl, carboxy, substituted orunsubstituted lower alkylcarbamoyl, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group;R^(11a)′ and R^(11b)′ are each independently hydrogen or lower alkyl, ortaken together ═O;r′ is an integer of 0 to 4;provided that a compound wherein all of R^(10a)′, R^(10b)′ and R^(10c)′are methyl; and the following compounds;

are excluded, or its pharmaceutically acceptable salt, or a solvatethereof.

(14) The compound according to the above (13), wherein R^(10a)′ andR^(10b)′ are lower alkyl, and R^(10c)′ is carboxy, hydroxyalkyl,substituted or unsubstituted aryl, substituted or unsubstitutedheteroaryl, or substituted or unsubstituted lower alkylcarbamoyl, or itspharmaceutically acceptable salt, or a solvate thereof.

(15) The compound according to any one of the above (10) to (12),wherein is optionally protected hydroxy;

Z²′ is O;

R²′ is a group represented by the formula:

wherein R^(10a)′ and R^(10b)′ are each independently hydroxy, halogen,substituted or unsubstituted alkyl, substituted or unsubstituted loweralkoxy, substituted or unsubstituted lower alkoxycarbonyl, carboxy,substituted or unsubstituted lower alkylcarbamoyl, substituted orunsubstituted cycloalkyl, substituted or unsubstituted cycloalkenyl,substituted or unsubstituted aryl, a substituted or unsubstitutedheterocyclic group, or R^(10a)′ and R^(10b)′ are taken together may forma substituted or unsubstituted non-aromatic carbocyclic ring or asubstituted or unsubstituted non-aromatic heterocyclic ring with anadjacent carbon atom;R^(10c)′ is hydrogen, hydroxy, halogen, substituted or unsubstitutedalkyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkoxycarbonyl, carboxy, substituted orunsubstituted lower alkylcarbamoyl, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group;R^(11a)′ and R^(11b)′ are each independently hydrogen or lower alkyl;r′ is an integer of 0 to 4, or its pharmaceutically acceptable salt, ora solvate thereof.

(16) The compound according to any one of the above (10) to (12),wherein

Z¹′ is optionally protected hydroxy;

Z²′ is O;

R²′ is a group represented by the formula:

wherein Ring D′ is a substituted or unsubstituted aromatic carbocyclicring or a substituted or unsubstituted aromatic heterocyclic ring;

V′ is —C(═O)—, —O—C(═O)—, —NR¹³′—C(═O)—NR¹³′—, —NR¹³′—C(═O)—,—C(═O)—NR¹³′—, —O—, —S— or —NR¹³′—;

R¹³′ is hydrogen or lower alkyl;W′ is hydroxy, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted lower alkylsulfinyl, substituted orunsubstituted sulfamoyl, or cyano;R^(12a)′ and R^(12b)′ are each independently hydrogen or substituted orunsubstituted lower alkyl;u′ is an integer of 1 to 4;provided that the following compounds:

are excluded, or its pharmaceutically acceptable salt, or a solvatethereof.

(17) The compound according to the above (15) or (16), wherein t′ is 0,or its pharmaceutically acceptable salt, or a solvate thereof.

(18) A pharmaceutical composition comprising the compound according toany one of the above (1) to (17) or (2′), or its pharmaceuticallyacceptable salt, or a solvate thereof.

(19) A pharmaceutical composition having an antagonistic activity forP2X₃ and/or P2X_(2/3) receptor, comprising the compound according to anyone of the above (1) to (17) or (2′), or its pharmaceutically acceptablesalt, or a solvate thereof.

(20) A method for preventing or treating a disease related to P2X₃and/or P2X_(2/3) receptor characterized by administration of thecompound according to any one of the above (1) to (17) or (2′), or itspharmaceutically acceptable salt, or a solvate thereof.

(21) Use of the compound according to any one of the above (1) to (17)or (2′), or its pharmaceutically acceptable salt, or a solvate thereoffor treating and/or preventing a disease related to P2X₃ and/orP2X_(2/3) receptor.

(22) Use of the compound according to any one of the above (1) to (17)or (2′), or its pharmaceutically acceptable salt, or a solvate thereofin the manufacturing of an agent for treating and/or preventing adisease related to P2X₃ and/or P2X_(2/3) receptor.

BEST MODE FOR CARRYING OUT THE INVENTION

As used throughout the specification, the following terms have thefollowing meaning unless specifically indicated.

The term “alkyl” includes a straight or branched chain monovalenthydrocarbon group containing from 1 to 10, preferably from 1 to 8, morepreferably from 1 to 6 carbons, such as methyl, ethyl, n-propyl,isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl,isopentyl, neo-pentyl, n-hexyl, isohexyl, n-heptyl, isoheptyl, n-octyl,isooctyl, n-nonyl and n-decyl, and the like.

Preferable “alkyl” for R² is isopropyl, isobutyl, and the like.

The term “lower alkyl” includes a straight or branched chain monovalenthydrocarbon group containing from 1 to 6, preferably from 1 to 3carbons, such as, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl,sec-butyl, tert-butyl, n-pentyl, isopentyl, neo-pentyl, n-hexyl,isohexyl, and the like.

Preferable “lower alkyl” for R^(1a) is C1-C4 alkyl such as methyl,ethyl, n-propyl, isopropyl, terl-butyl, and the like.

Preferable “lower alkyl” for R^(1b) is C1-C3 alkyl such as methyl,ethyl, and the like.

Preferable “lower alkyl” for Y is C1-C3 alkyl such as methyl, ethyl,n-propyl, isopropyl, and the like.

The term “acyl” includes a group of the formula R—CO—, wherein R is, forexample, “lower alkyl” as defined above or “lower alkenyl”, “aryl”, “aheterocyclic group”, “cycloalkyl” or “cycloalkenyl” as defined bellow.

Preferable “acyl” for R^(1a) is C1-C3 alkylcarbonyl such as acetyl andthe like.

The term “cycloalkane” includes a monocyclic or polycyclic saturatedcyclic carbocyclic ring containing from 3 to 10 carbons. Monocycliccycloalkane includes, for example, cyclopropane, cyclobutane,cyclopentane, cyclohexane, cycloheptane, cyclooctane, cyclononane,cyclodecane, etc. Polycyclic cycloalkane includes norbornanane,tetrahydronaphthalene, etc.

Preferable “cycloalkane” for Ring A is C3-C6 monocyclic cycloalkane suchas cyclohexane and the like.

The term “cycloalkyl” includes a monovalent group derived from“cycloalkane” as defined above.

Monocyclic cycloalkyl includes, for example, cyclopropyl, cyclobutyl,cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl,cyclodecyl, etc. Polycyclic cycloalkyl includes norbornanyl,tetrahydronaphthalene-5-yl, tetrahydronaphthalene-6-yl, etc.

Preferable “cycloalkyl” for Ring R² is C3-C6 monocyclic cycloalkyl suchas cyclopentyl, cyclohexyl, and the like.

The term “cycloalkane-diyl” includes a divalent group derived from“cycloalkane” as defined above. Monocyclic cycloalkane-diyl includes,for example, cyclopropane-diyl, cyclobutane-diyl, cyclopentane-diyl,cyclohexane-diyl, cycloheptane-diyl, cyclooctane-diyl, cyclonone-diyl,cyclodecane-diyl, etc. Polycyclic cycloalkane-diyl includesnorbornane-diyl, etc.

Preferable “cycloalkane-diyl” for B is C3-C6 monocyclic cycloalkane-diylsuch as cyclopentane-diyl, cyclohexane-diyl, and the like.

The term “cycloalkene” includes a non-aromatic monocyclic or polycyclicring of 3 to 10 carbons containing at least one carbon-carbon doublebond. Monocyclic cycloalkene includes, for example, cyclopentene,cyclohexene, etc. Polycyclic cycloalkene includes norborne, indene, etc.

The term “cycloalkenyl” includes a monovalent group derived from“cycloalkene” as defined above. Monocyclic cycloalkenyl includescyclopentenyl, cyclohexenyl, etc. Polycyclic cycloalkenyl includesnorbornyl, indene-1-yl, indene-2-yl, indene-3-yl, etc.

The term “cycloalkene-diyl” includes a divalent group derived from“cycloalkene” as defined above. Monocyclic cycloalkene-diyl includescyclopentene-diyl, cyclohexene-diyl, etc. Polycyclic cycloalkene-diylincludes norbornene-diyl, etc.

Preferable “cycloalkene-diyl” for B is C3-C6 monocyclic cycloalkene-diylsuch as cyclopentene-diyl, cyclohexene-diyl, and the like.

The term “aromatic carbocyclic ring” includes an aromatichydrocarbocyclic ring which is monocyclic or fused-cyclic, such asbenzene ring, naphthalene ring, anthracene ring, phenanthrene ring, etc.

Benzene ring is preferable as “aromatic carbocyclic ring” for ring A.

The term “aryl” includes a monovalent group derived from “aromaticcarbocyclic ring” as defined above. For example, phenyl, 1-naphthyl,2-naphthyl, anthryl, phenanthryl, etc. are exemplified.

Preferable “aryl” for R³ is phenyl.

The term “aromatic carbocyclic ring-diyl” includes a divalent groupderived from “aromatic carbocyclic ring” as defined above. For example,1,2-phenylene, 1,3-phenylene, 1,4-phenylene, 1,2-naphthalene etc.

Preferable “aromatic carbocyclic ring-diyl” for B is 1,2-phenylene,1,3-phenylene, 1,4-phenylene, and the like. More preferably,1,4-phenylene and the like are exemplified.

The term “heterocyclic ring” includes an aromatic or a non-aromaticmonocyclic or fused-cyclic ring, which includes a five- toseven-membered ring having at least one nitrogen atom, oxygen atom,and/or sulphur atom in the ring; a fused ring consisting of two or moresaid five- to seven-membered rings; or a fused ring consisting of saidfive- to seven-membered ring having at least one nitrogen atom, oxygenatom, and/or sulphur atom in the ring fused to one or more “aromaticcarbocyclic ring”,“cycloalkane” or “cycloalkene” as defined above.

For example, a non-aromatic heterocyclic ring such as pyrroline,pyrrolidine, imidazole, pyrazole, piperidine, piperazine, morpholine,thiomorpholine, tetrahydropyrane, dihydropyridine, dihydropyridazine,dioxane, oxathiolane, thiane, tetrahydrofuran, tetrahydropyran,tetrahydrothiazole, tetrahydroisothiazole, etc.;

a monocyclic aromatic heterocyclic ring such as pyrrole, pyrazine,pyrazole, tetrazole, furan, thiophene, pyridine, imidazole, triazole,tetrazole, triazine, pyridazine, pyrimidine, isoxazole, thiazole,isothiazole, thiadiazole, oxazole, oxadiazole, etc; and

a fused heterocyclic ring such as indole, isoindole, indazole,indolizine, indoline, isoindoline, quinoline, isoquinoline, cinnoline,phthalazine, quinazoline, naphthyridine, quinoxaline, purine, pteridine,benzopyrane, benzimidazole, benzisoxazole, benzoxazole, benzoxadiazole,benzisothiazole, benzothiazole, benzothiadiazole, benzofuran,isobenzofuran, benzothiophene, benzotriazole, imidazopyridine,triazolopyridine, imidazothiazole, pyrazinopyridazine, benzimidazole,benzodioxane, tetrahydroquinoline, tetrahydrobenzothiophene, etc. areexemplified.

Preferable “heterocyclic ring” for Ring A is piperidine, thiophene,furan, pyridine, benzothiophene, benzothiazole, benzoxazole, and thelike.

The term “heterocyclic group” includes a monovalent group derived from“heterocyclic ring” as defined above. For example, non-aromaticheterocyclic groups such as pyrrolinyl, pyrrolidino, pyrrolidinyl,imidazolynyl, imidazolidinyl, pyrazolinyl, pyrazolidinyl, piperidino,piperidyl, piperidino, piperazinyl, morpholinyl, morpholino,thiomorpholinyl, thiomorpholino, tetrahydropyranyl, dihydropyridyl,dihydropyridazinyl, dihydropyrazinyl, dioxanyl, oxathiolanyl, thianyl,tetrahydrofuryl, tetrahydropyranyl, tetrahydrothiazolinyl,tetrahydroisothiazolinyl, etc.;

monocyclic aromatic heterocyclic groups such as pyrrolyl, pyrazinyl,pyrazolyl, tetrazolyl, furyl, thienyl, pyridyl, imidazolyl, triazolyl,tetrazolyl, triazinyl, pyridazinyl, pyrimidinyl, pyrazinyl, isoxazolyl,thiazolyl, isothiazolyl, thiadiazolyl, oxazolyl and oxadiazolyl, etc;and

fused heterocyclic groups such as indolyl, isoindolyl, indazolyl,indolizinyl, indolinyl, isoindolinyl, quinolyl, isoquinolyl, cinnolinyl,phthalazinyl, quinazolinyl, naphthyridinyl, quinoxalinyl, purinyl,pteridinyl, benzopyranyl, benzimidazolyl, benzisoxazolyl, benzoxazolyl,benzoxadiazolyl, benzisothiazolyl, benzothiazolyl, benzothiadiazolyl,benzofuryl, isobenzofuryl, benzothienyl, benzotriazolyl, imidazopyridyl,triazolopyridyl, imidazothiazolyl, pyrazinopyridazinyl,benzimidazolynyl, benzodioxanyl, tetrahydroquinoline,tetrahydrobenzothienyl, etc. are exemplified.

Preferable “heterocyclic group” for Y is pyperidino, morpholino, and thelike.

The term “heterocyclic ring-diyl” includes a divalent group derived from“heterocyclic ring” as defined above. For example, non-aromaticheterocyclic ring-diyl such as pyrrolin-diyl, pyrrolidin-diyl,imidazole-diyl, imidazolidin-diyl, pyrazolin-diyl, pyrazolidin-diyl,piperidin-diyl, piperazine-diyl, morpholin-diyl, thiomorpholin-diyl,tetrahydropyran-diyl, dihydropyridine-diyl, dihydropyridazin-diyl,dihydropyrazin-diyl, dioxan-diyl, oxathiolan-diyl, thian-diyl,tetrahydrofuran-diyl, tetrahydropyran-diyl, tetrahydrothiazol-diyl,tetrahydroisothiazol-diyl, etc.;

a monocyclic aromatic heterocyclic ring-diyl such as pyrrole-diyl,pyrazine-diyl, pyrazole-diyl, tetrazole-diyl, furan-diyl,thiophene-diyl, pyridine-diyl, imidazole-diyl, triazole-diyl,tetrazole-diyl, triazine-diyl, pyridazine-diyl, pyrimidine-diyl,pyrazine-diyl, isoxazole-diyl, thiazole-diyl, isothiazole-diyl,thiadiazole-diyl, oxazole-diyl, oxadiazole-diyl, etc; and

a fused heterocyclic ring-diyl such as indole-diyl, isoindole-diyl,indazole-diyl, indolizine-diyl, indoline-diyl, isoindoline-diyl,quinoline-diyl, isoquinoline-diyl, cinnoline-diyl, phthalazine-diyl,quinazoline-diyl, naphthyridine-diyl, quinoxaline-diyl, purine-diyl,pteridine-diyl, benzopyrane-diyl, benzimidazole-diyl,benzisoxazole-diyl, benzoxazole-diyl, benzoxadiazole-diyl,benzisothiazole-diyl, benzothiazole-diyl, benzothiadiazole-diyl,benzofuran-diyl, isobenzofuran-diyl, benzothiophene-diyl,benzotriazole-diyl, imidazopyridine-diyl, triazolopyridine-diyl,imidazothiazole-diyl, pyrazinopyridazine-diyl, benzimidazole-diyl,benzodioxane-diyl, tetrahydroquinoline-diyl,tetrahydrobenzothiophene-diyl, etc. are exemplified.

Preferable “heterocyclic ring-diyl” for B is pyrole-diyl, pyrazine-diyl,pyrazole-diyl, tetrazole-diyl, furan-diyl, thiophene-diyl,pyridine-diyl, imidazole-diyl, triazole-diyl, tetrazole-diyl,triazine-diyl, pyridazine-diyl, pyrimidine-diyl, pyrazine-diyl,isoxazole-diyl, thiazole-diyl, isothiazole-diyl, thiadiazole-diyl,oxazole-diyl, oxadiazole-diyl, and the like.

More preferably, dihydrothiazole-diyl, pyroridine-diyl, thiazole-diyl,thiophene-diyl, pyrrol-diyl, furan-diyl, isoxazole-diyl,thiadiazole-diyl, and the like are exemplified.

The term “non-aromatic carbocyclic ring” includes “cycloalkane” asdefined above, “cycloalkene” as defined above, a fused ring consistingof “aromatic carbocyclic ring” as defined above fused to “cycloalkane”as defined above, and a fused ring consisting of “aromatic carbocyclicring” as defined above fused to “cycloalkene” as defined above. As afused ring, indene and the like are exemplified.

The term “aromatic heterocyclic ring” includes aromatic rings of“heterocyclic ring” as defined above. “Aromatic heterocyclic ring”includes a five- to seven-membered aromatic ring having at least onenitrogen atom, oxygen atom, and/or sulphur atom in the ring; a fusedaromatic ring consisting of two or more said rings; and a fused ringconsisting of a five- to seven-membered aromatic ring having at leastone nitrogen atom, oxygen atom, and/or sulphur atom in the ring fused toone or more “aromatic carbocyclic ring” as defined above.

For example, a monocyclic aromatic heterocyclic ring such as pyrazine,pyrazole, tetrazole, furan, thiophene, pyridine, imidazole, triazole,triazine, pyridazine, pyrimidine, pyrazine, isoxazole, thiazole,isothiazole, thiadiazole, oxazole, oxadiazole, etc; and

a fused aromatic heterocyclic ring such as indole, isoindole, indazole,indolizine, quinoline, isoquinoline, cinnoline, phthalazine,quinazoline, naphthyridine, quinoxaline, purine, pteridine,benzimidazole, benzisoxazole, benzoxazole, benzoxadiazole,benzisothiazole, benzothiazole, benzothiadiazole, benzofuran,isobenzofuran, benzothiophene, benzotriazole, imidazopyridine,triazolopyridine, imidazothiazole, pyrazinopyridazine, benzimidazoline,etc. are exemplified.

The term “heteroaryl” includes a monovalent group derived from “aromaticheterocyclic ring” as defined above. “Heteroaryl” includes a five- toseven-membered aromatic group having at least one nitrogen atom, oxygenatom, and/or sulphur atom in the ring; a fused aromatic group consistingof two or more said rings; and a fused ring consisting of a five- toseven-membered aromatic group having at least one nitrogen atom, oxygenatom, and/or sulphur atom in the ring fused to one or more “aromaticcarbocyclic ring” as defined above.

For example, monocyclic aromatic heterocyclic groups such as pyrrolyl,pyrazinyl, pyrazolyl, tetrazolyl, furyl, thienyl, pyridyl, imidazolyl,triazolyl, tetrazolyl, triazinyl, pyridazinyl, pyrimidinyl, pyrazinyl,isoxazolyl, thiazolyl, isothiazolyl, thiadiazolyl, oxazolyl,oxadiazolyl, etc; and

fused heterocyclic aromatic groups such as indolyl, isoindolyl,indazolyl, indolizinyl, isoindolinyl, quinolyl, isoquinolyl, cinnolinyl,phthalazinyl, quinazolinyl, naphthyridinyl, quinoxalinyl, purinyl,pteridinyl, benzimidazolyl, benzisoxazolyl, benzoxazolyl,benzoxadiazolyl, benzisothiazolyl, benzothiazolyl, benzothiadiazolyl,benzofuryl, isobenzofuryl, benzothienyl, benzotriazolyl, imidazopyridyl,triazolopyridyl, imidazothiazolyl, pyrazinopyridazinyl,benzimidazolynyl, etc. are exemplified.

The term “non-Aromatic heterocyclic ring” includes non-aromatic rings of“heterocyclic ring” as defined above. “Non-aromatic heterocyclic ring”includes, a five- to seven-membered non-aromatic ring having at leastone nitrogen atom, oxygen atom, and/or sulphur atom in the ring; a fusednon-aromatic ring consisting of two or more said rings; a fused ringconsisting of a five- to seven-membered aromatic ring having at leastone nitrogen atom, oxygen atom, and/or sulphur atom in the ring fused toone or more “cycloalkane” as defined above or “cycloalkene” as definedabove; or a fused ring consisting of a five- to seven-memberednon-aromatic heterocyclic ring having at least one nitrogen atom, oxygenatom, and/or sulphur atom in the ring fused to one or more “aromaticcarbocyclic ring” as defined above or “non-aromatic carbocyclic ring” asdefined above

For example, non-aromatic heterocyclic ring such as pyrroline,pyrrolidine, imidazoline, imidazolidine, pyrazoline, pyrazolidine,piperidine, piperazine, morpholine, thiomorpholine, thiomorpholine,tetrahydropyrane, dihydropyridine, dihydropyridazine, dihydropyrazine,dioxane, oxathiolane, thiane, tetrahydrofuran, tetrahydropyran,tetrahydrothiazolin, tetrahydroisothiazole, etc.;

a fused non-aromatic heterocyclic ring such as indoline, isoindoline,benzopyrane, benzodioxane, tetrahydroquinoline,tetrahydrobenzothiophene, etc. are exemplified.

The term “halogen” means fluorine, chlorine, bromine and iodine.

The term “lower alkoxy” includes a group of the formula RO— wherein R isas defined above for lower alkyl, such as methoxy, ethoxy, propoxy,isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentoxy,isopentoxy, neopentoxy, hexoxy, etc.

Preferable “lower alkoxy” for Y is C1-C4 alkoxy such as methoxy, ethoxy,propoxy, isopropoxy, butoxy, and the like.

The term “lower alkylthio” includes a group of the formula RS— wherein Ris as defined above for lower alkyl, such as methylthio, ethylthio,propylthio, isopropylthio, butylthio, isobutylthio, sec-butylthio,tert-butylthio, pentylthio, isopentylthio, neopentylthio, hexylthio,etc.

Preferable “lower alkylthio” for R^(1a) is C1-C4 alkylthio such asmethylthio and the like.

The term “lower alkoxycarbonyl” includes a group of the formulaR—O—C(═O)— wherein R is as defined above for lower alkyl, such asmethyloxycarbonyl, ethyloxycarbonyl, n-propyloxycarbonyl,isopropyloxycarbonyl, n-butyloxycarbonyl, tert-butyloxycarbonyl,n-pentyloxycarbonyl, etc.

Preferable “lower alkoxycarbonyl” for R^(1a), R³ and Y is C1-C4alkoxycarbonyl such as methyloxycarbonyl, ethyloxycarbonyl, and thelike.

The term “lower alkylcarbamoyl” includes mono- or di-loweralkylcarbamoyl wherein alkyl moiety contains from 1 to 6 carbons, suchas methylcarbamoyl, ethylcarbamoyl, n-propylcarbamoyl,isopropylcarbamoyl, n-butylcarbamoyl, dimethylcarbamoyl,diethylcarbamoyl, dipropylcarbamoyl, etc.

Preferable “lower alkylcarbamoyl” for R^(1a) is C1-C4 alkoxycarbamoylsuch as methylcarbamoyl, dimethylcarbamoyl, and the like.

The term “thiocarbamoyl” includes a group of the formula—C(═S)—NR^(X)R^(Y) wherein R^(X) and R^(Y) are each independentlyhydrogen, “alkyl” or “alkenyl” as defined above, or “aryl”,“heteroaryl”, “non-aromatic carbocyclic group”, non-aromaticheterocyclic group”, “arylalkyl” or “heteroaryl alkyl” as defined below,and these are optionally and independently substituted with hydroxy,carboxy, “alkyl”, “alkenyl”, “alkynyl”, “halogen”, “alkyloxy”,“alkenyloxy”, “alkynyloxy”, “alkylthio”, “carbamoyl”,“alkyloxycarbonyl”, “aryloxycarbonyl” as defined above or below, and thelike.

The term “sulfinyl” includes a group of the formula —S(═O)—R wherein Ris “alkyl” or “alkenyl” as defined above, or “aryl”, “heteroaryl”,“non-aromatic carbocyclic group”, non-aromatic heterocyclic group”,“arylalkyl” or “heteroaryl alkyl” as defined below, and these areoptionally and independently substituted with hydroxy, carboxy, “alkyl”,“alkenyl”, “alkynyl”, “halogen”, “alkyloxy”, “alkenyloxy”, “alkynyloxy”,“alkylthio”, “carbamoyl”, “alkyloxycarbonyl”, “aryloxycarbonyl” asdefined above or below, and the like.

Preferable “sulfinyl” for R^(1a) and Y is C1-C4 alkylsulfinyl such asmethylsulfinyl, and the like.

The term “sulfonyl” includes a group of the formula —S(═O)₂—R wherein Ris “alkyl” or “alkenyl” as defined above, or “aryl”, “heteroaryl”,“non-aromatic carbocyclic group”, non-aromatic heterocyclic group”,“arylalkyl” or “heteroaryl alkyl” as defined below, and these areoptionally and independently substituted with hydroxy, carboxy, “alkyl”,“alkenyl”, “alkynyl”, “halogen”, “alkyloxy”, “alkenyloxy”, “alkynyloxy”,“alkylthio”, “carbamoyl”, “alkyloxycarbonyl”, “aryloxycarbonyl” asdefined above or below, and the like.

Preferable “sulfonyl” for R^(1a) and Y is C1-C4 alkylsulfonyl such asmethylsulfonyl, and the like.

The term “sulfamoyl” includes a group of the formula —S(═O)₂—NR^(X)R^(Y)wherein R^(X) and R^(Y) are each independently hydrogen, “alkyl” or“alkenyl” as defined above, or “aryl”, “heteroaryl”, “non-aromaticcarbocyclic group”, non-aromatic heterocyclic group”, “arylalkyl” or“heteroaryl alkyl” as defined below, and these are optionally andindependently substituted with hydroxy, carboxy, “alkyl”, “alkenyl”,“alkynyl”, “halogen”, “alkyloxy”, “alkenyloxy”, “alkynyloxy”,“alkylthio”, “carbamoyl”, “alkyloxycarbonyl”, “aryloxycarbonyl” asdefined above or below, and the like.

Substituents for “substituted lower alkyl”, “substituted tert-butyl”,“substituted i-propyl”, “substituted lower alkenyl”, “substituted loweralkynyl”, “substituted lower alkoxy”, “substituted lower alkylthio”,“substituted lower alkoxycarbonyl”, and “substituted loweralkylcarbamoyl” include but are not limited to one or more same ordifferent substituents selected from the group consisting of:

hydroxy, carboxy, halogen (F, Cl, Br, I), lower haloalkoxy (e.g., CF₃O),cycloalkyl (e.g., cyclopropyl), cycloalkenyl (e.g., cyclopropenyl),lower alkoxy (e.g., methoxy, ethoxy, propoxy, butoxy, etc.), loweralkenyloxy (e.g., vinyloxy, allyloxy, etc.), lower alkoxycarbonyl (e.g.,methoxycarbonyl, ethoxycarbonyl, tert-butoxycarbonyl, etc.), nitro,nitroso, amino, lower alkylamino (e.g., methylamino, ethylamino,dimethylamino, etc.), acylamino (e.g., acetylamino, benzoylamino, etc.),aralkylamino (e.g., benzylamino, tritylamino), hydroxyamino, imino,hydroxyimino, lower alkylimino (e.g., methylimino, ethylimino,dimethylimino, etc.), lower alkoxyimino (e.g., methoxyimino,ethoxyimino, etc.), acylimino (e.g., acetylimino, benzoylimino, etc.),azido, aryl (e.g., phenyl, etc.), aralkyl (e.g., benzyl, etc.),aralkyloxy (e.g., benzyloxy), cyano, isocyano, isocyanato, thiocyanato,isothiocyanato, mercapto, lower alkylthio (e.g., methylthio, etc.),lower alkylsulfonyl (e.g., methanesulfonyl, ethanesulfonyl), carbamoyl,lower alkylcarbamoyl (e.g., methylcarbamoyl, ethylcarbamoyl,dimethylcarbamoyl, etc.), sulfamoyl, lower alkylsulfamoyl, acyl (e.g.,formyl, acetyl, etc.), formyloxy, thioformyl, thiocarboxy,dithiocarboxy, thiocarbamoyl, sulfino, sulfo, hydrazino, azido, ureido,amidino, guanidino, phthalimido, tri-lower alkylsilyl (e.g.,trimethylsilyl, etc.), and oxo.

Preferable substituents for “substituted lower alkyl” of R^(1a) andR^(1b) are hydroxy, halogen, nitro, cyano, lower haloalkoxy, loweralkenyloxy and the like. More preferable substituents are hydroxy, loweralkoxy and the like.

Preferable substituents for “substituted lower alkoxy” and “substitutedlower alkylthio” of R^(1a) and R^(1b) are halogen, hydroxy and the like.

Preferable substituents for “substituted lower alkyl” Y are hydroxy,halogen, cyano, carboxy, carbamoyl, lower alkoxy, lower haloalkoxy,lower alkylcarbamoyl, amino, lower alkylamino, amino substituted withlower alkylsulfonyl, lower alkyloxycarbonylmethyloxy and the like.

More preferable substituents are hydroxy, halogen, cyano carboxy,carbamoyl, lower alkoxy, lower alkylcarbamoyl, amino, lower alkylamino,amino substituted with lower alkylsulfonyl, loweralkyloxycarbonylmethyloxy and the like.

Preferable substituents for “substituted lower alkoxy” and “substitutedlower alkylthio” of Y are halogen, carboxy, cyano, hydroxy, lower alkyl,lower alkyl substituted with hydroxy, lower alkoxy, lower haloalkoxy,lower alkenyloxy, lower alkoxycarbonyl, amino, lower alkylamino, aminosubstituted with lower alkylsulfonyl, lower alkylsulfinyl, loweralkylsulfonyl, carbamoyl, lower alkylcarbamoyl, carbamoyl substitutedwith amino, carbamoyl substituted with hydroxy, lower alkylsulfinyl,lower alkylsulfonyl, cycloalkyl, a heterocyclic group and the like.

More preferable substituents are halogen, carboxy, cyano, carbamoyl,lower alkylcarbamoyl, imino substituted with hydroxy, lower alkoxy,amino, lower alkylamino, lower alkoxycarbonyl, lower alkylsulfinyl,tetrazolyl and the like.

Substituents for “substituted acyl” are as defined above for“substituted lower alkyl”. If R in acyl (R—C(═O)—) is “aryl”, “aheterocyclic group”, “cycloalkyl” or “cycloalkenyl”, then each ring maybe substituted with lower alkyl (e.g., methyl, ethyl, isopropyl,tert-butyl, etc.), lower haloalkyl (e.g., CF₃, CH₂CF₃, CH₂CCl₃, etc.),lower alkenyl, lower alkynyl (e.g., ethynyl), etc.

Substituents for “substituted carbamoyl”, “substituted thiocarbamoyl”and “substituted sulfamoyl” are one or more same or different groupsselected from, but are not limited to, the group consisting of:

hydroxy, carboxy, halogen (F, Cl, Br, I), lower alkyl (e.g., methyl),lower alkenyl (e.g., vinyl), lower alkynyl (e.g., ethynyl), cycloalkyl(e.g., cyclopropyl), cycloalkenyl (e.g., cyclopropenyl), loweralkoxycarbonyl (e.g., methoxycarbonyl, ethoxycarbonyl,tert-butoxycarbonyl, etc.), amino, lower alkylamino (e.g., methylamino,ethylamino, dimethylamino, etc.), acylamino (e.g., acetylamino,benzoylamino, etc.), aralkylamino (e.g., benzylamino, tritylamino),hydroxyamino, aryl (e.g., phenyl, etc.), cyano, isocyano, isocyanato,thiocyanato, isothiocyanato and acyl (e.g., formyl, acetyl, etc.).

Preferable substituents for “substituted carbamoyl”, “substitutedthiocarbamoyl” and “substituted sulfamoyl” of R^(1a) and R^(1b) arelower alkyl, lower alkenyl, lower alkynyl, amino, lower alkylamino, acylamino, hydroxy amino and the like.

More preferable substituents are lower alkyl, lower alkylamino and thelike.

Preferable substituents for “substituted carbamoyl” of Y are loweralkyl, lower alkyl substituted with hydroxy, lower alkyl substitutedwith lower alkoxy, lower alkyl substituted with cyano, lower alkenyl,lower alkynyl, lower alkylamino, acyl amino and the like.

More preferable substituents are lower alkyl, lower alkyl substitutedwith hydroxy, lower alkyl substituted with lower alkoxy, lower alkylsubstituted with cyano, lower alkylamino and the like.

Substituents for “substituted amino” are one or more same or differentgroups selected from, but are not limited to, the group consisting of:

hydroxy, halogen (F, Cl, Br, I), lower haloalkyl (e.g., CF₃, CH₂CF₃,CH₂CCl₃, etc.), hydroxy(lower)alkyl (e.g., hydroxyethyl, —C(CH₃)₂CH₂OH,etc.), lower haloalkoxy (e.g., CF₃O), lower alkyl (e.g., methyl, ethyl,isopropyl, tert-butyl, etc.), lower alkenyl (e.g., vinyl), lower alkynyl(e.g., ethynyl), cycloalkyl (e.g., cyclopropyl), cycloalkenyl (e.g.,cyclopropenyl), lower alkoxy (e.g., methoxy, ethoxy, propoxy, butoxy,etc.), lower alkyloxycarbonyl (tert-butyloxycarbonyl, etc.), loweralkenyloxy (e.g., vinyloxy, allyloxy, etc.), amino, lower alkylamino(e.g., methylamino, ethylamino, dimethylamino, etc.), acylamino (e.g.,acetylamino, benzoylamino, etc.), aralkylamino (e.g., benzylamino,tritylamino), hydroxyamino, imino, hydroxyimino, lower alkylimino (e.g.,methylimino, ethylimino, dimethylimino, etc.), lower alkoxyimino (e.g.,methoxyimino, ethoxyimino, etc.), acylimino (e.g., acetylimino,benzoylimino, etc.), aryl (e.g., phenyl, etc.), aralkyl (e.g., benzyl,etc.), cyano and acyl (e.g., formyl, acetyl, etc.).

Preferable substituents for “substituted amino” of R^(1a) and R^(1b) arelower alkyl, lower alkenyl, lower alkynyl, lower haloalkyl, lowerhydroxyalkyl, lower alkoxy, lower haloalkoxy, lower alkenyloxy, acyl andthe like.

More preferable substituents are lower alkyl, acyl and the like.

Preferable substituents for “substituted amino” of Y are lower alkyl,acetyl, lower alkyloxycarbonyl, carbamoyl, lower alkylsulfonyl and thelike.

Substituents for “substituted cycloalkyl”, “substituted cycloalkenyl”,“substituted aryl”, “a substituted heterocyclic group”, “substitutedheteroaryl”, “substituted phenyl”, and “substituted pyridyl” are one ormore same or different groups selected from, but are not limited to, thegroup consisting of:

hydroxy, carboxy, halogen (F, Cl, Br, I), lower haloalkyl (e.g., CF₃,CH₂CF₃, CH₂CCl₃, etc.), lower haloalkoxy (e.g., CF₃O), lower alkyl(e.g., methyl, ethyl, isopropyl, tert-butyl, etc.), lower alkenyl (e.g.,vinyl), lower alkynyl (e.g., ethynyl), cycloalkyl (e.g., cyclopropyl),cycloalkenyl (e.g., cyclopropenyl), lower alkoxy (e.g., methoxy, ethoxy,propoxy, butoxy, etc.), lower alkenyloxy (e.g., vinyloxy, allyloxy,etc.), lower alkoxycarbonyl (e.g., methoxycarbonyl, ethoxycarbonyl,tert-butoxycarbonyl, etc.), nitro, nitroso, amino, lower alkylamino(e.g., methylamino, ethylamino, dimethylamino, etc.), acylamino (e.g.,acetylamino, benzoylamino, etc.), aralkylamino (e.g., benzylamino,tritylamino), hydroxyamino, imino, hydroxyimino, lower alkylimino (e.g.,methylimino, ethylimino, dimethylimino, etc.), lower alkoxyimino (e.g.,methoxyimino, ethoxyimino, etc.), acylimino (e.g., acetylimino,benzoylimino, etc.), azido, aryl (e.g., phenyl, etc.), aralkyl (e.g.,benzyl, etc.), aralkyloxy (e.g., benzyloxy, etc.), cyano, isocyano,isocyanato, thiocyanato, isothiocyanato, mercapto, lower alkylthio(e.g., methylthio, etc.), lower alkylsulfonyl (e.g., methanesulfonyl,ethanesulfonyl), substituted or unsubstituted carbamoyl (e.g.,carbamoyl, N-methyl-N-methoxycarbamoyl, etc.), substituted orunsubstituted lower alkylcarbamoyl (e.g., methylcarbamoyl,ethylcarbamoyl, dimethylcarbamoyl, hydroxy ethylcarbamoyl,trifluoromethylcarbamoyl, trifluoro ethylcarbamoyl, etc.), sulfamoyl,lower alkylsulfamoyl, acyl (e.g., formyl, acetyl, etc.), formyloxy,thioformyl, thiocarboxy, dithiocarboxy, thiocarbamoyl, sulfino, sulfo,hydrazino, azido, ureido, amidino, guanidino, phthalimido and oxo.

Preferable substituents for “substituted cycloalkyl”, “substitutedcycloalkenyl”, “substituted aryl”, “a substituted heterocyclic group”,“substituted heteroaryl”, “substituted phenyl”, and “substitutedpyridyl” are halogen, lower alkyl, lower haloalkyl, lower alkoxy, lowerhaloalkoxy and the like.

The halogen moiety in said “lower haloalkyl” and “lower haloalkoxy” isas defined above for “halogen”.

The alkyl or lower alkyl moiety in said “lower haloalkyl”, “loweralkylamino”, “lower alkylimino”, “lower alkylsulfonyl”, “loweralkylsulfamoyl”, “lower alkylcarbamoyl”, “aralkyl” and “aralkylamino” isas defined above for “lower alkyl”.

The lower alkoxy moiety of said “lower haloalkoxy” and “loweralkoxyimino” is as defined above for “lower alkoxy”.

The term “lower alkenyl” includes a straight or branched chain alkenylcontaining from 2 to 6 carbons, preferably containing from 2 to 3carbons, having one or more double bonds at any position. For example,vinyl, propenyl, isopropenyl, butenyl, isobutenyl, prenyl, butadienyl,pentenyl, isopentenyl, pentadienyl, hexenyl, isohexenyl, hexadienyl,etc. are exemplified.

The lower alkenyl moiety of “lower alkenyloxy” is as defined above for“lower alkenyl”.

The term “lower alkynyl” includes a straight or branched chain alkynylcontaining from 2 to 6 carbons, preferably containing from 2 to 3carbons. For example, ethynyl, propynyl, butynyl, pentynyl, hexynyl,etc. are exemplified. They have one or more triple bonds at anyposition, and optionally, have a double bond.

The term “aralkyl” includes a group “lower alkyl” as defined abovesubstituted with above “aryl” as defined above. For example, benzyl,phenethyl and the like are exemplified.

The aryl moiety of “aralkylamino” and “aralkyl” is as defined above for“aryl”.

The acyl moiety of “acyl”, “acylamino” and “acylimino” is as definedabove for “acyl”.

The protecting groups for “hydroxy optionally protected” and “mercaptooptionally protected” are well known in the art and include for example,a group that forms ether and substituted ether, such as methyl,methoxymethyl, t-butoxymethyl, 1-ethoxyethyl and benzyl, etc.; a groupthat forms silyl ether, such as trimethylsilyl, triethylsilyl,tert-butyldimethylsilyl and methyldiisopropylsilyl; a group that formsester, such as formate, acetate and trichloroacetate, etc.; a group thatforms carbonate, such as methyl carbonate, 2,2,2-trichloroethylcarbonate, and p-nitrophenyl carbonate, etc.; a group that formssulfonyl, such as methanesulfonyl, p-toluenesulfonyl, etc.

Preferable protective groups for “optionally protected hydroxy” and“optionally protected mercapto” are ether, a group that formssubstituted ether and the like. More preferable are a group formed bysubstituted ether and the like.

In addition, one or more hydrogen, carbon or other atoms of a compoundof Formula (I) can be replaced by an isotope of the hydrogen, carbon orother atoms. Compounds of Formula (I) include all radiolabeled forms ofcompounds of Formula (I) “radiolabeled,” “radiolabeled form”, and thelike of a compound of Formula I, each of which is encompassed by theinvention, is useful as a research and/or diagnostic tool in metabolismpharmacokinetic studies and in binding assays. Examples of isotopes thatcan be incorporated into a compound of Formula (I) of the inventioninclude isotopes of hydrogen, carbon, nitrogen, oxygen, phosphorous,sulfur, fluorine and chlorine, such as ²H, ³H, ¹³C, ¹⁴C, ¹⁵N, ¹⁸O, ¹⁷O,³¹P, ³²P, ³⁵S, ¹⁸P, and ³⁶Cl, respectively. Radiolabeled compounds ofthe invention can be prepared by methods known in the art. For example,tritiated compounds of Formula (I) can be prepared by introducingtritium into the particular compound of Formula (I), for example, bycatalytic dehalogenation with tritium. This method may include reactinga suitably halogen-substituted precursor of a compound of Formula (I)with tritium gas in the presence of a suitable catalyst, for example,Pd/C, in the presence or absence of a base. Other suitable methods forpreparing tritiated compounds can be found in Filer, “The Preparationand Characterization of Tritiated Neurochemicals,” Chapter 6, pp.155-192 in Isotopes in the Physical and Biomedical Sciences, Vol. 1,Labeled Compounds (Part A) (1987). ¹⁴C-labeled compounds can be preparedby employing starting materials having a ¹⁴C carbon.

Preferred embodiments of the compound (I′) of the invention are asfollows. Each variant is as defined above.

Z¹′ is hydroxy.

Z²′ is O.

Ring A′ is an aromatic carbocyclic ring or a heterocyclic ring.

For example, an aromatic carbocyclic ring and an aromatic heterocyclicring are exemplified as A′.

For example, benzene ring and pyridine ring are exemplified as Ring A′.

R²′ is substituted or unsubstituted aryl, or a substituted orunsubstituted aromatic heterocyclic group (e.g., thienyl, pyridyl,imidazolyl, pyrimidinyl, isoxazolyl, thiazolyl, isothiazolyl,thiadiazolyl, oxazolyl, pyrazolyl, oxadiazolyl, etc.).

For example, substituted or unsubstituted phenyl is exemplified as R²′.

For example, substituted or unsubstituted pyridyl is exemplified as R²′.

For example, substituted or unsubstituted tert-butyl is exemplified asR²′.

R³′ is substituted or unsubstituted alkyl, substituted or unsubstitutedcycloalkyl, or substituted or unsubstituted phenyl.

For example, substituted or unsubstituted alkyl, substituted orunsubstituted cycloalkyl, substituted or unsubstituted aryl andsubstituted or an unsubstituted heterocyclic group are exemplified asR³′.

For example, a group represented by the following formula:

are exemplified as R³′.

Ring D′ is benzene ring or pyridine ring.

V′ is “—O—C(═O)—”, “—C(═O)—O—”, “—NR¹³′—C(═O)—” or “—C(═O)—NR¹³′—”.

R^(4a)′ and R^(4b)′ are each independently hydrogen or lower alkyl.

For example, hydrogen is exemplified as R^(4a)′ and R^(4b)′.

t′ is 0.

m′ is an integer of 0 to 2.

For example, m′ is 1 or 2.

For example, m′ is 0.

R^(1a)′ is halogen, substituted or unsubstituted lower alkyl, carboxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group.

For example, substituted or unsubstituted lower alkoxycarbonyl,substituted or unsubstituted phenyl, and a substituted or unsubstitutedaromatic heterocyclic group (e.g., thienyl, pyridyl, imidazolyl,pyrimidinyl, isoxazolyl, thiazolyl, isothiazolyl, thiadiazolyl,oxazolyl, pyrazolyl, oxadiazolyl, etc.) are exemplified as R^(1a)′.

For example, substituted or unsubstituted lower alkoxycarbonyl,substituted or unsubstituted aryl and a substituted or unsubstitutedheterocyclic group are exemplified as R^(1a)′.

For example, substituted or unsubstituted lower alkoxycarbonyl,substituted or unsubstituted aryl and a substituted or unsubstitutedheterocyclic group are exemplified as R^(1a)′.

For example, substituted or unsubstituted lower alkoxycarbonyl,substituted or unsubstituted phenyl, a substituted or unsubstitutedaromatic heterocyclic group (e.g., thienyl, pyridyl, imidazolyl,pyrimidinyl, isoxazolyl, thiazolyl, isothiazolyl, thiadiazolyl,oxazolyl, pyrazolyl, oxadiazolyl, etc.) are exemplified as R^(1a)′.

R^(1b)′ is halogen, substituted or unsubstituted lower alkyl, carboxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group.

For example, halogen, substituted or unsubstituted lower alkyl, carboxy,and substituted or unsubstituted lower alkoxycarbonyl are exemplified asR^(1b)′.

Further, a compound represented by all combination of alternatives ineach substituent as defined above is preferable.

Preferable embodiments of the compound (I′) of the present invention areas follows.

A compound wherein

Z² is O;

t is 0;

R²′ is substituted or unsubstituted tert-butyl, or substituted orunsubstituted i-propyl; and

R³ is a group represented by the formula:

A compound wherein

Z²′ is O;

t′ is 0; and

R² is a group represented by the formula:

R³′ is substituted or unsubstituted aryl or a substituted orunsubstituted heterocyclic group.

A compound wherein

t′ is 0;

R²′ is substituted or unsubstituted tert-butyl, or substituted orunsubstituted i-propyl; and

R³′ is a group represented by the formula:

Further, a compound represented by all combination of alternatives ineach substituent as defined above is preferable.

Preferable embodiments of the compound (I) of the present invention areas follows. Each variant is as defined above.

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 4.

For example, a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1 as R².

R³ is a group represented by the formula:

For example, a group represented by the formula:

are exemplified as R³.

For example, a group represented by the formula:

are exemplified as R³.

For example, a group represented by the formula:

are exemplified as R³.

Y is hydroxy, halogen, cyano, carboxy, substituted or unsubstitutedlower alkyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkoxycarbonyl, substituted or unsubstituted acyl,substituted or unsubstituted carbamoyl, substituted or unsubstitutedthiocarbamoyl, substituted or unsubstituted lower alkylthio, substitutedor unsubstituted lower alkylsulfamoyl, substituted or unsubstitutedamino, substituted sulfinyl, substituted sulfonyl, or a substituted orunsubstituted heterocyclic group.

For example, substituted or unsubstituted lower alkyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkoxycarbonyl, substituted or unsubstituted acyl, substituted orunsubstituted carbamoyl, substituted or unsubstituted thiocarbamoyl,substituted or unsubstituted lower alkylthio, substituted orunsubstituted lower alkylsulfamoyl, substituted or unsubstituted amino,substituted sulfinyl and substituted sulfonyl are exemplified as Y.

For example, substituted or unsubstituted lower alkyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkoxycarbonyl, substituted or unsubstituted acyl, substituted orunsubstituted carbamoyl, substituted or unsubstituted thiocarbamoyl,substituted or unsubstituted lower alkylthio, substituted orunsubstituted lower alkylsulfamoyl, substituted or unsubstituted amino,substituted sulfinyl and substituted sulfonyl are exemplified as Y.

R¹⁴ is halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano or nitro.

For example, halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano and nitro are exemplifiedas R¹⁴.

r is an integer of 0 to 2.

Further, a compound represented by all combination of alternatives ineach substituent as defined above is preferable.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(a) A compound wherein

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1; and

R³ is a group represented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group; or Y andR¹⁴ may form a substituted or unsubstituted heterocyclic group withadjacent carbon atom;

R¹⁴ is halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano or nitro; and

r is an integer of 0 to 2;

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(b) A compound wherein

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1; and

R³ is a group represented by the formula:

wherein Y is substituted or unsubstituted alkoxy, substituted orunsubstituted alkylthio, substituted or unsubstituted loweralkoxycarbonyl, substituted or unsubstituted carbamoyl, substituted orunsubstituted lower alkylsulfamoyl, substituted or unsubstituted amino,cyano, carboxy, substituted sulfinyl, substituted sulfonyl, asubstituted or unsubstituted heterocyclic group;

R¹⁴ is halogen, hydroxy, substituted or unsubstituted lower alkyl,substituted or unsubstituted lower alkenyl, substituted or unsubstitutedlower alkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted amino,substituted or unsubstituted sulfamoyl, cyano or nitro; and

r is an integer of 0 to 2;

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(c) A compound wherein

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1; and

R³ is a group represented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group; and

r is 0

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(d) A compound wherein

Z¹ is hydroxy;

Z² is —C(═O)—;

Z^(3a) and Z^(3b) are taken together ═O;

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1;

R³ is a group represented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group; and

r is 0;

t is 0;

k is an integer of 0 or 1;

m is an integer of 0 or 1;

n is an integer of 0 or 1;

R^(1a) and R^(1b) are each independently halogen, hydroxy, substitutedor unsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkylthio, substituted orunsubstituted acyl, carboxy, substituted or unsubstituted loweralkoxycarbonyl, substituted or unsubstituted carbamoyl, substituted orunsubstituted thiocarbamoyl, substituted or unsubstituted amino,substituted sulfinyl, substituted sulfonyl, substituted or unsubstitutedsulfamoyl, cyano, nitro or —C(R^(7a))═N—O—R^(7b); and

R^(7a) and R^(7b) are each independently hydrogen or substituted orunsubstituted lower alkyl;

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(e) A compound wherein

Z¹ is hydroxy;

Z² is —C(═O)—;

Z^(3a) and Z^(3b) are taken together ═O;

Ring A is benzene or pyridine;

B is aromatic carbocyclic ring-diyl or aromatic heterocyclic ring-diyl;

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1;

R³ is a group represented by the formula:

wherein Y is substituted or unsubstituted lower alkyl, substituted orunsubstituted lower alkoxy, substituted or unsubstituted loweralkylthio, or substituted or unsubstituted amino; and

r is 0;

t is 0;

k is 1;

m is an integer of 0 or L

n is an integer of 0 or 1; and

R^(1a) and R^(1b) are each independently halogen, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy, orsubstituted or unsubstituted lower alkylthio

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

Further, more preferable embodiments of the compound (I) of the presentinvention are as follows.

(f) A compound wherein

Z¹ is hydroxy;

Z² is —C(═O)—;

Z^(3a) and Z^(3b) are taken together ═O;

Ring A is benzene or pyridine;

B is aromatic carbocyclic ring-diyl or aromatic heterocyclic ring-diyl;

R² is a group represented by the formula:

wherein Me is methyl and q is an integer of 0 to 1;

R³ is a group represented by the formula:

wherein Y is substituted lower alkoxy, substituted lower alkylthio, orsubstituted amino; and

r is 0;

t is 0;

k is 1;

m is 0 or 1;

n is 0 or 1; and

R^(1a) and R^(1b) are each independently halogen, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy, orsubstituted or unsubstituted lower alkylthio;

provided that the compounds represented by the following formula:

are excluded,or its pharmaceutically acceptable salt, or a solvate thereof.

(g) A compound as defined in the above (a) to (f), wherein Y is loweralkoxy substituted with one or more substituents selected fromSubstituent group A (Substituent group A: hydroxy, carbamoyl, loweralkylcarbamoyl, imino substituted with hydroxy, lower alkoxy, amino,lower alkylamino, lower alkoxycarbonyl, lower alkylsulfinyl and loweralkylsulfonyl), or its pharmaceutically acceptable salt, or a solvatethereof.

(h) A compound as defined in the above (a) to (g), wherein the formularepresented by the formula:

is a formula represented by the formula:

wherein each substituent is as defined in the above (a) to (e), or itspharmaceutically acceptable salt, or a solvate thereof.

General procedures for the synthesis of the compound of the inventionare described bellow. Starting materials and reaction reagents used insuch synthesis are commercially available or can be prepared accordingto methods well known in the art using compounds commercially available.

The compound (I) of the invention, i.e., the compound of the generalformula (I) (compounds represented by other formulae also can bereferred to as such manner), may be prepared via the routes as describedbellow.

[Route 1]

wherein, R¹³ is substituted or unsubstituted lower alkyl; all othervariables are as defined above.

As shown, the compound of the invention of the general formula (Ia) maybe prepared by the reaction of compound (II), compound (III) andcompound (IV) without solvent or in an appropriate solvent, in thepresence or absence of acid.

In this reaction, compound (III) and compound (IV) may be used in anamount of one equivalent or more, preferably 1 to 3 equivalents, inrespect of compound (II).

Acid that may be used includes acetic acid, para-toluenesulfonic acid,hydrochloric acid, etc.

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), ethers (e.g., tetrahydrofuran, diethyl ether, dioxane,etc.) and mixture thereof.

The temperature for such reaction may be −10° C. to 160° C., preferably20° C. to 120° C. Reaction time depends on the compound, such reactionmay be conducted for 10 minutes to 80 hours.

Optionally, desired compound (Ia) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 2]

wherein all variables are as defined above.

As shown, the compound of the invention represented by the generalformula (Ia) may be prepared by the reaction of compound (II) andcompound (V) without solvent or in an appropriate solvent, in thepresence or absence of acid.

In this reaction, compound (V) can be used in an amount of oneequivalent or more, preferably 1 to 3 equivalents, in respect ofcompound (II).

Acid that may be used includes acetic acid, para-toluenesulfonic acid,hydrochloric acid, etc.

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), ethers (e.g., tetrahydrofuran, diethyl ether, dioxane,etc.) and mixture thereof.

The temperature for such reaction may be −10° C. to 160° C., preferably20° C. to 120° C. Although reaction time depends on the compound, suchreaction may be conducted for 10 minutes to 80 hours.

Optionally, desired compound (Ia) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 3]

wherein, one of L and Q is dihydroxyborane, di(lower)alkylborane ordi(lower)alkoxyborane and the other is halogen or —OSO₂(C_(i)F_(2i+1))wherein i is an integer 1 to 4, and all other variants are as definedabove.

As shown, the compound of the invention represented by the generalformula (Ib) may be prepared by Suzuki coupling of compound (VI) withcompound (VII) in an appropriate solvent, in the presence of a palladiumcatalyst and a base.

In this reaction, compound (VII) can be used in an amount of oneequivalent or more, preferably 1 to 3 equivalents, in respect ofcompound (VI).

Base that may be used includes metal hydroxide (e.g., sodium hydroxide,potassium hydroxide, potassium phosphate, etc.), metal hydride (e.g.,sodium hydride, lithium hydride, etc.), metal carbonate (e.g., sodiumcarbonate, potassium carbonate, cesium carbonate, etc.), etc. Such basecan be used in an amount of one equivalent or more, preferably 1 to 5equivalents, in respect of compound (VI).

Palladium catalyst that can be used includestris(dibenzylideneacetone)dipalladium(0), palladium acetate (II),dichlorobis(triphenylphosphine)palladium (II) ortetrakis(triphenylphosphine)palladium(II), etc., and may be used in anamount of 0.001 equivalent or more, preferably 0.01 to 1 equivalent, inrespect of compound (VI).

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), ethers (e.g., tetrahydrofuran, diethyl ether, dioxane,dimethoxyethane, etc.), N,N-dimethylformamide, water and mixturethereof, etc.

The temperature for such reaction may be −10° C. to 180° C., preferably20° C. to 120° C., optionally under microwave radiation. Althoughreaction time depends on the compound, such reaction may be conductedfor 10 minute to 80 hours.

Optionally, desired compound (Ib) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 4]

wherein, one of L and M is trialkyltin (e.g., —SnBu₃, etc.) and theother is halogen or —OSO₂(C_(i)F_(2i+1)) wherein i is an integer 1 to 4and all other variants are as defined above.

As shown, the compound of the invention represented by the generalformula (Ib) may be prepared by Stille coupling of compound (VI) withcompound (VIII) in an appropriate solvent in the presence of a catalyst.

In this reaction, compound (VIII) can be used in an amount of oneequivalent or more, preferably 1 to 3 equivalents, in respect ofcompound (VI).

Catalyst can be used include tris(dibenzylideneacetone)dipalladium(0),palladium acetate (II), dichlorobis(triphenylphosphine)palladium(II) ortetrakis(triphenylphosphine)palladium(II), etc., and may be used in anamount of 0.001 equivalent or more, preferably 0.01 to 1 equivalent, inrespect of compound (VI). Optionally, phosphine ligand such astri-tert-butylphosphine, 2-(di-tert-butylphosphino)biphenyl,2-(dicyclohexylphosphino)biphenyl, triphenylphosphine,tris(2-furyl)phosphine, etc. may be added in twice molar amounts inrespect of the catalyst.

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), ethers (e.g., tetrahydrofuran, diethyl ether, dioxane,dimethoxyethane, etc.), N,N-dimethylformamide and mixture thereof, etc.

The temperature for such reaction may be −10° C. to 180° C., preferably20° C. to 120° C., optionally under microwave radiation. Althoughreaction time depends on the compound, such reaction may be conductedfor 10 minutes to 80 hours.

Optionally, desired compound (Ib) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 5]

wherein all other variants are as defined above.

As shown, the compound of the invention represented by the generalformula (X) may be prepared by the reaction of the compound (IX) in anappropriate solvent, in the presence of an oxidizing agent.

Oxidizing agent that may be used includes manganese dioxide,2-iodoxybenzoic acid, etc., and may be used in an amount of oneequivalent or more, preferably 1 to 1.5 equivalents, in respect ofcompound (IX).

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), halogenated hydrocarbons (e.g., dichloromethane,1,2-dichloroethane, etc.), ethers (e.g., tetrahydrofuran, dioxane,etc.), ketones (e.g., acetone, methylethyl ketone, etc.), nitriles(e.g., acetonitrile, etc.) and mixture thereof, etc.

The temperature for such reaction may be −10° C. to 150° C., preferably20° C. to 100° C. Although reaction time depends on the compound, suchreaction may be conducted for 10 minutes to 80 hours.

The compound (IX) obtained may be used in the next step as a crudeproduct or after purification according to conventional methods (e.g.,column chromatography, recrystallization, etc.).

[Route 5 (continued)]

wherein, i is an integer 0 to 3; X¹ and X² are independently NR¹⁴, O orS; R¹⁴ is hydrogen or lower alkyl; all other variables are as definedabove.

As shown, the compound of the invention represented by the generalformula (Ic) may be prepared by the reaction of compound (X) andcompound (XI) without solvent or in an appropriate solvent, in thepresence or absence of an acid.

In this reaction, compound (XI) can be used in an amount of oneequivalent or more, preferably 1 to 3 equivalents, in respect ofcompound (X).

Acid that may be used includes p-toluenesulfonic acid, sulfuric acid,p-toluenesulfonic acid pyridinium salt, etc.

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), and mixture thereof.

The temperature for such reaction may be −10° C. to 170° C., preferably20° C. to 150° C. Reaction time depends on the compound, such reactionmay be conducted for 10 minutes to 80 hours.

Optionally, desired compound (Ic) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 6]

wherein all variables are as defined above.

As shown, the compound of the invention represented by the generalformula (Id) may be prepared by the reaction of compound (X) andcompound (XII) or a salt thereof in an appropriate solvent. The compound(XII) or a salt thereof can be used in an amount of 1 to 4 equivalents,preferably 1 to 2.5 equivalents, in respect of compound (X).

Salts of compound (XII) include mineral acid salts such ashydrochloride, sulfate, etc. Such salt is neutralized with a base whenit is used in the reaction.

Base that may be used includes sodium acetate, amines (pyridinium,etc.), etc., and can be used in an amount of 1 to 3 equivalents,preferably 1 to 2 equivalents, in respect of the salt of compound (XI).

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), halogenated hydrocarbons (e.g., chloroform,1,2-dichloroethane, etc.), ethers (e.g., tetrahydrofuran, dioxane,etc.), alcohols (e.g., methanol, enthanol, n-propanol, iso-propanol,etc.), water and mixture thereof, etc.

Reaction temperature is 0° C. to 150° C., preferably 20° C. to 120° C.

Reaction time is generally from about 10 minutes to 24 hours.

Optionally, desired compound (Id) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 7]

wherein, Hal is halogen; R⁹ is a hydroxy protecting group; all othervariables are as defined above.

As shown, the compound of the invention represented by the generalformula (Ie) may be prepared by the reaction of the compound (Ia) andthe compound (XIII) in an appropriate solvent in the presence of a base.The compound (XII) can be used in an amount of 1 to 4 equivalents,preferably 1 to 2.5 equivalents, in respect of compound (Ia).

Base that may be used includes sodium hydride, sodium methoxide, amines,etc. (triethylamine, pyridinium, etc.) and can be used in an amount of 1to 3 equivalents, preferably 1 to 2 equivalents, in respect of the saltof compound (Ia).

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), halogenated hydrocarbons (e.g., chloroform,1,2-dichloroethane, etc.), ethers (e.g., tetrahydrofuran, dioxane,etc.), N,N-dimethylformamide, dimethylsulfoxide and mixture thereof,etc.

Reaction temperature is −20° C. to 150° C., preferably 0° C. to 120° C.

Reaction time is generally from about 10 minutes to 24 hours.

Optionally, desired compound (Ie) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 8]

wherein the variables are as defined above.

As shown, the compound of the invention represented by the generalformula (Ih) may be prepared by the reaction of compound (Ia) andcompound (XIV) in an appropriate solvent. The compound (XIV) can be usedin an amount of 1 to 4 equivalents, preferably 1 to 2.5 equivalents, inrespect of compound (Ia).

Solvent that may be used includes acetic acid, hydrocarbons (e.g.,benzene, toluene, xylene, etc.), ethers (e.g., tetrahydrofuran, dioxane,etc.), alcohols (e.g., methanol, enthanol, n-propanol, isopropanol,etc.) and mixture thereof, etc.

Reaction temperature is 0° C. to 150° C., preferably 50° C. to 130° C.

Reaction time is generally from about 10 minutes to 24 hours.

Optionally, desired compound (Ih) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

[Route 9]

wherein the variables are as defined above.

In this reaction, compound (II) and a reagent for optical resolution(XV) (e.g., (R) or (S)-methyl-2-hydroxy-2-phenylacetate) are reactedwith a condensing agent (e.g., Diisopropyl Azodicarboxylate) in anappropriate solvent to give a mixture. The mixture is purified accordingto conventional methods (e.g., column chromatography, recrystallization,etc.) to isolate a diastereomer having a desired configuration. Theobtained diastereomer is subjected to a deprotection reaction (e.g.,hydrogenation, lithium chloride, etc.) to obtain a desired enantiomer.The reagent for optical resolution can be used in an amount of 1 to 4equivalents, preferably 1 to 2.5 equivalents, in respect of compound(Ii).

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexane, 1,3-dimethyl-2-imidazolidinone, etc.), ethers (e.g.,tetrahydrofuran, diethyl ether, dioxane, etc.), amides (e.g.,dimethylformamide, dimethylacetoamide, N-methylpyrolidone, etc.), andmixture thereof, etc.

The temperature for such reaction may be −10° C. to 150° C., preferably0° C. to 80° C. Although reaction time depends on the compound, suchreaction may be conducted for 10 minutes to 48 hours.

[Route 10]

wherein R¹⁴ and R¹⁵ are each independently substituted or unsubstitutedlower alkyl and the other variants are as defined above.

As shown, the compound of the invention represented by the generalformula (Ij) may be prepared by reacting the compound (III), compound(IV), and compound (XIX) without solvent or in an appropriate solvent,in the presence or absence of an acid.

The compound (XIX) may be prepared by reacting the compound (XVII) andthe compound (XVIII) without solvent or in an appropriate solvent, inthe presence or absence of a base.

In this reaction, the compound (XVII) can be used in an amount of 1 ormore equivalents, preferably 1 to 3 equivalents, in respect of compound(XVIII).

Base that may be used includes sodium hydride, sodium methoxide,potassium t-butoxide and the like.

Solvent that may be used includes alcohols (e.g., methanol, enthanol,etc.), aromatic hydrocarbons (e.g., toluene, benzene, xylene, etc.),saturated hydrocarbons (e.g., cyclohexane, hexanes, etc.), ethers (e.g.,tetrahydrofuran, diethyl ether, dioxane, etc.) and mixture thereof, etc.

The temperature for such reaction may be −10° C. to 150° C., preferably20° C. to 100° C. Reaction time depends on the compound, such reactionmay be conducted for 10 minutes to 80 hours.

Optionally, desired compound (Ia) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

In this reaction, compound (III) and compound (IV) may be used in anamount of one equivalent or more, preferably 1 to 3 equivalents, inrespect of compound (XIX).

Acid that may be used includes acetic acid, p-toluenesulfonic acid,hydrochloric acid and the like.

Solvent that may be used includes aromatic hydrocarbons (e.g., toluene,benzene, xylene, etc.), saturated hydrocarbons (e.g., cyclohexane,hexanes, etc.), ethers (e.g., tetrahydrofuran, diethyl ether, dioxane,etc.) and mixture thereof.

The temperature for such reaction may be −10° C. to 150° C., preferably20° C. to 100° C. Reaction time depends on the compound, such reactionmay be conducted for 10 minutes to 80 hours.

Optionally, desired compound (Ia) thus obtained may be purifiedaccording to conventional methods (e.g., column chromatography,recrystallization, etc.).

The compounds of the invention can form salts with pharmaceuticallyacceptable acids or bases, such as salts with an inorganic acid such ashydrochloric acid, sulfuric acid, nitric acid, phosphoric acid,hydrofluoric acid, hydrobromic acid, etc.; salts with an organic acidsuch as formic acid, acetic acid, oxalic acid, succinic acid, maleicacid, tartaric acid, lactic acid, citric acid, fumaric acid, etc.; saltswith an organic base such as ammonium, trimethyl ammonium, triethylammonium, etc.; salts with an alkali metal such as sodium, potassium,etc.; salts with an alkali earth metal such as calcium, magnesium, etc.

Also, the compounds of the invention and pharmaceutically acceptablesalts thereof as described above can be prepared in a form of solvate(preferably hydrate) thereof. Such solvate includes solvates with anorganic solvent and/or water. Any number of solvent molecules can becoordinated to form such solvate.

The compound (I) of the invention is not limited to certain isomer, andthus, all possible isomers and racemates are encompassed by theinvention. Also, the invention is intended to encompass tautomers asshown bellow.

The compound of the invention may be isolated enantiomer having certainconfiguration or a mixture thereof. For example, the compound of theinvention can be isolated enantiomer having a certain configuration atposition 5 of the pyrrolidinone ring or a mixture of such enantiomers.One skilled in the art can readily isolate an enantiomer having suchcertain configuration using conventional techniques such asrecrystallization, enzyme reaction, chromatography, etc.

The compound of the invention represented above by the general formula(I) has an antagonizing action on P2X₃ and/or P2X₂/₃ receptor, andtherefore, is useful as a therapeutic agent for diseases associated witha P2X₃ and/or P2X₂/₃ receptor. Since P2X₃ and/or P2X₂/₃ receptor isbelieved to associate with pain and diseases in urinary system (Nature407, 26, 1011-1015 (2000), Nature, Vol. 407, No. 26, 1015-1017 (2000),Non-Patent Document 1, Non-Patent Document 2, etc.), the compound of theinvention is useful in the treatment of, alleviation of symptoms orprevention of diseases, such as for example, pain associated withrheumatoid arthritis, pain associated with osteoarthritis, headache,migraine, orofacial pain, toothache, glossagra, pain associated withtemporomandibular arthrosis, trigeminal neuralgia, shoulder pain, painassociated with hernia of intervertebral disk, pain associated withcervical spondylosis deformans, pain associated with spinal canalstenosis, pain associated with thoracic outlet syndrome, pain associatedwith traumatic brachial plexus injury syndrome, pain associated withshoulder-hand syndrome, pain associated with whiplash injury, chestpain, abdominal pain, colic pain, pain associated with cholelithiasis,pain associated with pancreatitis, pain associated with urinarycalculosis, pain associated with irritable bowel syndrome, lumbarbackache, sciatica, pain associated with bone fracture, pain associatedwith osteoporosis, joint pain, pain associated with gout, painassociated with cauda equina syndrome, pain associated with ankylosingspondylitis, sore muscle, pain associated with painful spasm, painassociated with myofascial pain syndrome, pain associated withfibromyalgia syndrome, pain associated with arteriosclerosis obliterans,pain associated with Buerger's disease, pain associated with Raynaud'sphenomenon, pain associated with zoster, causalgic pain, pain associatedwith entrapment neuropathy, pain associated with carpal canal syndrome,pain associated with diabetes, pain associated with Guillain-Barresyndrome, pain associated with Hansen's disease, pain associated withdrug therapy, pain associated with radiation therapy, pain associatedwith cord injury, pain associated with syringomyelia, pain associatedwith stroke, thalamic pain, pain associated with deafferentation,sympathetically-maintained pain, pain associated with ABC syndrome, painassociated with multiple sclerosis, pain associated with skin disease,cancer pain, postoperative pain, pain associated with injury, painassociated with gangrene, pain associated with somatoform disorder, painassociated with somatization disorder, pain associated with depression,pain associated with Parkinson's disease, knee joint pain, painassociated with arthritis, neuropathic pain such as menstrual pain,intermenstrual pain, labor pain, etc., inflammatory pain, nociceptivepain, psychogenic pain, and overactive bladder, incontinence,pollakiuria, urinary urgency, cystatrophia, prostatic hypertrophy,prostatitis, prostate pain, detrusor hyperreflesxia, dysuria, nervouspollakiuria, chronic prostatitis, chronic cystitis, etc.

The compound of the invention can be a drug with reduced side-effectsuch as effect on motor function because it has a high affinity for ATPreceptor, especially P2X₃ receptor, and also has high subtypeselectivity and high selectivity for other receptors. Also, the compoundof the invention is advantageous because of its high stability and highoral absorptivity, good bioavailability, low clearance, long half-life,prolonged duration of action, and/or low activity of hepatic enzymeinhibition, etc.

In another embodiment, the invention provides a pharmaceuticalcomposition comprising an effective amount of the compound of theinvention, in combination with a pharmaceutically acceptable carrier.

For use of the compound of the invention as a medicament, apharmaceutical composition can be prepared according to conventionalmethods, using pharmaceutically acceptable carriers well known in theart, such as excipients, binders, disintegrants, lubricants, colourants,flavors, surfactants, etc.

For the pharmaceutical composition of the invention to be administeredin the treatment of mammals including human, an appropriate unit dosageform may be selected depending on the purpose of the treatment and theroute of administration. Specifically, such unit dosage form includesoral formulations such as tablet, coated tablet, powder, granule,capsule, liquid, pill, suspension, emulsion, etc., and parenteralformulations such as injectable solution, suppository, ointment, patch,aerosol, etc. Such unit dosage form can be formulated according tomethods well known in the art.

The amount of the compound in a formulation can be varied depending onits dosage form, route for administration, dosing regimen, etc.

Means for administration of the pharmaceutical composition may beselected depending on dosage form, age, sex, body weight, severity ofthe disease, and other factors, etc., and route for administration canbe selected from various routes such as oral, subcutaneous, transdermal,rectal, intranasal, buccal, etc.

Dose of the compound of the invention in a pharmaceutical composition ofthe invention can be determined depending on the choice of route foradministration, age, sex, body weight, severity of the disease, thecompound to be administered, and other factors, etc., and can begenerally from 0.05 to 1000 mg/kg/day, preferably from 0.1 to 10mg/kg/day, for oral administration to adults. For parenteraladministration, dose can be varied widely depending on its route butgenerally from 0.005 to 100 mg/kg/day, preferably from 0.01 to 1mg/kg/day. Such pharmaceutical composition of the invention may beadministered once a day or in several times at a divided dosage in aday.

Preferred embodiments of the compound of the invention are representedby the formula (a) to (f):

TABLE 1 R¹ R1A COOEt R1B CF₃ R1C SCF₃ R1D isoxazol-3-yl R1E3-Me-isoxazol-5-yl R1F 5-Me-isoxazol-3-yl R1G 1,2,4-oxadiazol-3-yl R1H1,3,4-oxadiazol-2-yl R1I 5-Me-1,2,4-oxadiazol-3-yl R1J3-Me-1,2,4-oxadiazol-5-yl R1K C(Me)═NOMe R1L CH═NOMe R1M 2-oxazolinylR1N 2-thiazolinyl R1O 2-thiazolyl R1P 2- or 3-thienyl R1Q 2- or 3-furyl

TABLE 2 R² R2A iPr R2B cPr R2C tBu R2D Ph R2E 4-Cl or F—Ph R2F 4-CF₃—PhR2G 4-Me₂N—Ph R2H 2- or 3-thienyl R2I 3-pyridyl R2J 6-MeO-3-pyridyl R2K2- or 3- or 4-MeO—Ph R2L HOCH₂C(Me)₂ R2M HOCOC(Me)₂ R2N MeC(CH₂OH)₂ R2OMe₂NCOC(Me)₂ R2P MeNHCOC(Me)₂ R2Q H₂NCOC(Me)₂

TABLE 3 Z ZA Me ZB Et ZC iPr ZD CHF₂ ZE CF₃ ZF HOCH₂CH₂ ZG MeOCH₂CH₂ ZHNCCH₂ ZI MeSCH₂CH₂ ZJ MeSOCH₂CH₂ ZK Me₂NCH₂CH₂ ZL AcNHCH2CH2 ZMMsNHCH₂CH₂ ZN EtOCOCH₂ ZO HOCOCH₂ ZP HOCOCH₂CH₂ ZQ HOCOCH(Me) ZRHOCOC(Me)₂ ZS Me₂NCOCH₂ ZT MeHNCOCH₂ ZU H₂NCOCH₂

TABLE 4 X XA CH XB N

TABLE 5 Y YA O YB Swherein

Ac is acetyl, Ms is mesyl, Me is methyl, Et is ethyl, Pr is propyl, iPris isopropyl, nBu is n-butyl, tBu is t-butyl, cPr is cyclopropyl, cBu iscyclobutyl, cPent is cyclopentyl, cHex is cyclohexyl, Ph is phenyl; and

the combination of R¹, R², Z, X and Y, i.e., (R1,R2,Z,X,Y), is any oneof the following combinations:

(R1,R2,Z,X,Y)=(R1A,R2A,ZA,XA,YA), (R1B,R2A,ZA,XA,YA),(R1C,R2A,ZA,XA,YA), (R1D,R2A,ZA,XA,YA), (R1E,R2A,ZA,XA,YA),(R1F,R2A,ZA,XA,YA), (R1G,R2A,ZA,XA,YA), (R1H,R2A,ZA,XA,YA),(R1I,R2A,ZA,XA,YA), (R1J,R2A,ZA,XA,YA), (R1K,R2A,ZA,XA,YA),(R1L,R2A,ZA,XA,YA), (R1M,R2A,ZA,XA,YA), (R1N,R2A,ZA,XA,YA),(R1O,R2A,ZA,XA,YA), (R1P,R2A,ZA,XA,YA), (R1Q,R2A,ZA,XA,YA),(R1A,R2B,ZA,XA,YA), (R1B,R2B,ZA,XA,YA), (R1C,R2B,ZA,XA,YA),(R1D,R2B,ZA,XA,YA), (R1E,R2B,ZA,XA,YA), (R1F,R2B,ZA,XA,YA),(R1G,R2B,ZA,XA,YA), (R1H,R2B,ZA,XA,YA), (R1I,R2B,ZA,XA,YA),(R1J,R2B,ZA,XA,YA), (R1K,R2B,ZA,XA,YA), (R1L,R2B,ZA,XA,YA),(R1M,R2B,ZA,XA,YA), (R1N,R2B,ZA,XA,YA), (R1O,R2B,ZA,XA,YA),(R1P,R2B,ZA,XA,YA), (R1Q,R2B,ZA,XA,YA), (R1A,R22C,ZA,XA,YA),(R1B,R22C,ZA,XA,YA), (R1C,R22C,ZA,XA,YA), (R1D,R22C,ZA,XA,YA),(R1E,R22C,ZA,XA,YA), (R1F,R22C,ZA,XA,YA), (R1G,R22C,ZA,XA,YA),(R1H,R22C,ZA,XA,YA), (R1I,R22C,ZA,XA,YA), (R1J,R22C,ZA,XA,YA),(R1K,R22C,ZA,XA,YA), (R1L,R22C,ZA,XA,YA), (R1M,R2C,ZA,XA,YA),(R1N,R22C,ZA,XA,YA), (R1O,R22C,ZA,XA,YA), (R1P,R22C,ZA,XA,YA),(R1Q,R22C,ZA,XA,YA), (R1A,R2D,ZA,XA,YA), (R1B,R2D,ZA,XA,YA),(R1C,R2D,ZA,XA,YA), (R1D,R2D,ZA,XA,YA), (R1E,R2D,ZA,XA,YA),(R1F,R2D,ZA,XA,YA), (R1G,R2D,ZA,XA,YA), (R1H,R2D,ZA,XA,YA),(R1I,R2D,ZA,XA,YA), (R1J,R2D,ZA,XA,YA), (R1K,R2D,ZA,XA,YA),(R1L,R2D,ZA,XA,YA), (R1M,R2D,ZA,XA,YA), (R1N,R2D,ZA,XA,YA),(R1O,R2D,ZA,XA,YA), (R1P,R2D,ZA,XA,YA), (R1Q,R2D,ZA,XA,YA),(R1A,R2E,ZA,XA,YA), (R1B,R2E,ZA,XA,YA), (R1C,R2E,ZA,XA,YA),(R1D,R2E,ZA,XA,YA), (R1E,R2E,ZA,XA,YA), (R1F,R2E,ZA,XA,YA),(R1G,R2E,ZA,XA,YA), (R1H,R2E,ZA,XA,YA), (R1I,R2E,ZA,XA,YA),(R1J,R2E,ZA,XA,YA), (R1K,R2E,ZA,XA,YA), (R1L,R2E,ZA,XA,YA),(R1M,R2E,ZA,XA,YA), (R1N,R2E,ZA,XA,YA), (R1O,R2E,ZA,XA,YA),(R1P,R2E,ZA,XA,YA), (R1Q,R2E,ZA,XA,YA), (R1A,R2F,ZA,XA,YA),(R1B,R2F,ZA,XA,YA), (R1C,R2F,ZA,XA,YA), (R1D,R2F,ZA,XA,YA),(R1E,R2F,ZA,XA,YA), (R1,R2F,ZA,XA,YA), (R1G,R2F,ZA,XA,YA),(R1H,R2F,ZA,XA,YA), (R1I,R2F,ZA,XA,YA), (R1J,R2F,ZA,XA,YA),(R1K,R2F,ZA,XA,YA), (R1L,R2F,ZA,XA,YA), (R1M,R2F,ZA,XA,YA),(R1N,R2F,ZA,XA,YA), (R1O,R2F,ZA,XA,YA), (R1P,R2F,ZA,XA,YA),(R1Q,R2F,ZA,XA,YA), (R1A,R2G,ZA,XA,YA), (R1B,R2G,ZA,XA,YA),(R1C,R2G,ZA,XA,YA), (R1D,R2G,ZA,XA,YA), (R1E,R2G,ZA,XA,YA),(R1F,R2G,ZA,XA,YA), (R1G,R2G,ZA,XA,YA), (R1H,R2G,ZA,XA,YA),(R1I,R2G,ZA,XA,YA), (R1J,R2G,ZA,XA,YA), (R1K,R2G,ZA,XA,YA),(R1L,R2G,ZA,XA,YA), (R1M,R2G,ZA,XA,YA), (R1N,R2G,ZA,XA,YA),(R1O,R2G,ZA,XA,YA), (R1P,R2G,ZA,XA,YA), (R1Q,R2G,ZA,XA,YA),(R1A,R2H,ZA,XA,YA), (R1B,R2H,ZA,XA,YA), (R1C,R2H,ZA,XA,YA),(R1D,R2H,ZA,XA,YA), (R1E,R2H,ZA,XA,YA), (R1F,R2H,ZA,XA,YA),(R1G,R2H,ZA,XA,YA), (R1H,R2H,ZA,XA,YA), (R1I,R2H,ZA,XA,YA),(R1J,R2H,ZA,XA,YA), (R1K,R2H,ZA,XA,YA), (R1L,R2H,ZA,XA,YA),(R1M,R2H,ZA,XA,YA), (R1N,R2H,ZA,XA,YA), (R1O,R2H,ZA,XA,YA),(R1P,R2H,ZA,XA,YA), (R1Q,R2H,ZA,XA,YA), (R1A,R2I,ZA,XA,YA),(R1B,R2I,ZA,XA,YA), (R1C,R2I,ZA,XA,YA), (R1D,R2I,ZA,XA,YA),(R1E,R2I,ZA,XA,YA), (R1F,R2I,ZA,XA,YA), (R1G,R2I,ZA,XA,YA),(R1H,R2I,ZA,XA,YA), (R1I,R2I,ZA,XA,YA), (R1J,R2I,ZA,XA,YA),(R1K,R2I,ZA,XA,YA), (R1L,R2I,ZA,XA,YA), (R1M,R2I,ZA,XA,YA),(R1N,R2I,ZA,XA,YA), (R1O,R2I,ZA,XA,YA), (R1P,R2I,ZA,XA,YA),(R1Q,R2I,ZA,XA,YA), (R1A,R2J,ZA,XA,YA), (R1B,R2J,ZA,XA,YA),(R1C,R2J,ZA,XA,YA), (R1D,R2J,ZA,XA,YA), (R1E,R2J,ZA,XA,YA),(R1F,R2J,ZA,XA,YA), (R1G,R2J,ZA,XA,YA), (R1H,R2J,ZA,XA,YA),(R1I,R2J,ZA,XA,YA), (R1J,R2J,ZA,XA,YA), (R1K,R2J,ZA,XA,YA),(R1L,R2J,ZA,XA,YA), (R1M,R2J,ZA,XA,YA), (R1N,R2J,ZA,XA,YA),(R1O,R2J,ZA,XA,YA), (R1P,R2J,ZA,XA,YA), (R1Q,R2J,ZA,XA,YA),(R1A,R2K,ZA,XA,YA), (R1B,R2K,ZA,XA,YA), (R1C,R2K,ZA,XA,YA),(R1D,R2K,ZA,XA,YA), (R1E,R2K,ZA,XA,YA), (R1F,R2K,ZA,XA,YA),(R1G,R2K,ZA,XA,YA), (R1H,R2K,ZA,XA,YA), (R1I,R2K,ZA,XA,YA),(R1J,R2K,ZA,XA,YA), (R1K,R2K,ZA,XA,YA), (R1L,R2K,ZA,XA,YA),(R1M,R2K,ZA,XA,YA), (R1N,R2K,ZA,XA,YA), (R1O,R2K,ZA,XA,YA),(R1P,R2K,ZA,XA,YA), (R1Q,R2K,ZA,XA,YA), (R1A,R2L, ZA,XA,YA),(R1B,R2L,ZA,XA,YA), (R1C,R2L,ZA,XA,YA), (R1D,R2L,ZA,XA,YA),(R1E,R2L,ZA,XA,YA), (R1F,R2L,ZA,XA,YA), (R1G,R2L,ZA,XA,YA),(R1H,R2L,ZA,XA,YA), (R1I,R2L,ZA,XA,YA), (R1J,R2L,ZA,XA,YA),(R1K,R2L,ZA,XA,YA), (R1L,R2L,ZA,XA,YA), (R1M,R2L,ZA,XA,YA),(R1N,R2L,ZA,XA,YA), (R1O,R2L,ZA,XA,YA), (R1P,R2L,ZA,XA,YA),(R1Q,R2L,ZA,XA,YA), (R1A,R2M,ZA,XA,YA), (R1B,R2M,ZA,XA,YA),(R1C,R2M,ZA,XA,YA), (R1D,R2M,ZA,XA,YA), (R1E,R2M,ZA,XA,YA),(R1F,R2M,ZA,XA,YA), (R1G,R2M,ZA,XA,YA), (R1H,R2M,ZA,XA,YA),(R1I,R2M,ZA,XA,YA), (R1J,R2M,ZA,XA,YA), (R1K,R2M,ZA,XA,YA),(R1L,R2M,ZA,XA,YA), (R1M,R2M,ZA,XA,YA), (R1N,R2M,ZA,XA,YA),(R1O,R2M,ZA,XA,YA), (R1P,R2M,ZA,XA,YA), (R1Q,R2M,ZA,XA,YA),(R1A,R2N,ZA,XA,YA), (R1B,R2N,ZA,XA,YA), (R1C,R2N,ZA,XA,YA),(R1D,R2N,ZA,XA,YA), (R1E,R2N,ZA,XA,YA), (R1F,R2N,ZA,XA,YA),(R1G,R2N,ZA,XA,YA), (R1H,R2N,ZA,XA,YA), (R1I,R2N,ZA,XA,YA),(R1J,R2N,ZA,XA,YA), (R1K,R2N,ZA,XA,YA), (R1L,R2N,ZA,XA,YA),(R1M,R2N,ZA,XA,YA), (R1N,R2N,ZA,XA,YA), (R1O,R2N,ZA,XA,YA),(R1P,R2N,ZA,XA,YA), (R1Q,R2N,ZA,XA,YA), (R1A,R2O,ZA,XA,YA),(R1B,R2O,ZA,XA,YA), (R1C,R2O,ZA,XA,YA), (R1D,R2O,ZA,XA,YA),(R1E,R2O,ZA,XA,YA), (R1F,R2O,ZA,XA,YA), (R1G,R2O,ZA,XA,YA),(R1H,R2O,ZA,XA,YA), (R1I,R2O,ZA,XA,YA), (R1J,R2O,ZA,XA,YA),(R1K,R2O,ZA,XA,YA), (R1L,R2O,ZA,XA,YA), (R1M,R2O,ZA,XA,YA),(R1N,R2O,ZA,XA,YA), (R1O,R2O,ZA,XA,YA), (R1P,R2O,ZA,XA,YA),(R1Q,R2O,ZA,XA,YA), (R1A,R2P,ZA,XA,YA), (R1B,R2P,ZA,XA,YA),(R1C,R2P,ZA,XA,YA), (R1D,R2P,ZA,XA,YA), (R1E,R2P,ZA,XA,YA),(R1F,R2P,ZA,XA,YA), (R1G,R2P,ZA,XA,YA), (R1H,R2P,ZA,XA,YA),(R1I,R2P,ZA,XA,YA), (R1J,R2P,ZA,XA,YA), (R1K,R2P,ZA,XA,YA),(R1L,R2P,ZA,XA,YA), (R1M,R2P,ZA,XA,YA), (R1N,R2P,ZA,XA,YA),(R1O,R2P,ZA,XA,YA), (R1P,R2P,ZA,XA,YA), (R1Q,R2P,ZA,XA,YA),(R1A,R2Q,ZA,XA,YA), (R1B,R2Q,ZA,XA,YA), (R1C,R2Q,ZA,XA,YA),(R1D,R2Q,ZA,XA,YA), (R1E,R2Q,ZA,XA,YA), (R1F,R2Q,ZA,XA,YA),(R1G,R2Q,ZA,XA,YA), (R1H,R2Q,ZA,XA,YA), (R1I,R2Q,ZA,XA,YA),(R1J,R2Q,ZA,XA,YA), (R1K,R2Q,ZA,XA,YA), (R1L,R2Q,ZA,XA,YA),(R1M,R2Q,ZA,XA,YA), (R1N,R2Q,ZA,XA,YA), (R1O,R2Q,ZA,XA,YA),(R1P,R2Q,ZA,XA,YA), (R1Q,R2Q,ZA,XA,YA), (R1A,R2A,ZB,XA,YA),(R1B,R2A,ZB,XA,YA), (R1C,R2A,ZB,XA,YA), (R1D,R2A,ZB,XA,YA),(R1E,R2A,ZB,XA,YA), (R1F,R2A,ZB,XA,YA), (R1G,R2A,ZB,XA,YA),(R1H,R2A,ZB,XA,YA), (R1I,R2A,ZB,XA,YA), (R1J,R2A,ZB,XA,YA),(R1K,R2A,ZB,XA,YA), (R1L,R2A,ZB,XA,YA), (R1M,R2A,ZB,XA,YA),(R1N,R2A,ZB,XA,YA), (R1O,R2A,ZB,XA,YA), (R1P,R2A,ZB,XA,YA),(R1Q,R2A,ZB,XA,YA), (R1A,R2B,ZB,XA,YA), (R1B,R2B,ZB,XA,YA),(R1C,R2B,ZB,XA,YA), (R1D,R2B,ZB,XA,YA), (R1E,R2B,ZB,XA,YA),(R1F,R2B,ZB,XA,YA), (R1G,R2B,ZB,XA,YA), (R1H,R2B,ZB,XA,YA),(R1I,R2B,ZB,XA,YA), (R1J,R2B,ZB,XA,YA), (R1K,R2B,ZB,XA,YA),(R1L,R2B,ZB,XA,YA), (R1M,R2B,ZB,XA,YA), (R1N,R2B,ZB,XA,YA),(R1O,R2B,ZB,XA,YA), (R1P,R2B,ZB,XA,YA), (R1Q,R2B,ZB,XA,YA),(R1A,R22C,ZB,XA,YA), (R1B,R22C,ZB,XA,YA), (R1C,R22C,ZB,XA,YA),(R1D,R22C,ZB,XA,YA), (R1E,R22C,ZB,XA,YA), (R1F,R22C,ZB,XA,YA),(R1G,R22C,ZB,XA,YA), (R1H,R22C,ZB,XA,YA), (R1I,R22C,ZB,XA,YA),(R1J,R22C,ZB,XA,YA), (R1K,R22C,ZB,XA,YA), (R1L,R22C,ZB,XA,YA),(R1M,R22C,ZB,XA,YA), (R1N,R22C,ZB,XA,YA), (R1O,R22C,ZB,XA,YA),(R1P,R22C,ZB,XA,YA), (R1Q,R22C,ZB,XA,YA), (R1A,R2D,ZB,XA,YA),(R1B,R2D,ZB,XA,YA), (R1C,R2D,ZB,XA,YA), (R1D,R2D,ZB,XA,YA),(R1E,R2D,ZB,XA,YA), (R1F,R2D,ZB,XA,YA), 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(R1F,R2K,ZT,XB,YB),(R1G,R2K,ZT,XB,YB), (R1H,R2K,ZT,XB,YB), (R1I,R2K,ZT,XB,YB),(R1J,R2K,ZT,XB,YB), (R1K,R2K,ZT,XB,YB), (R1L,R2K,ZT,XB,YB),(R1M,R2K,ZT,XB,YB), (R1N,R2K,ZT,XB,YB), (R1O,R2K,ZT,XB,YB),(R1P,R2K,ZT,XB,YB), (R1Q,R2K,ZT,XB,YB), (R1A,R2L,ZT,XB,YB),(R1B,R2L,ZT,XB,YB), (R1C,R2L,ZT,XB,YB), (R1D,R2L,ZT,XB,YB),(R1E,R2L,ZT,XB,YB), (R1F,R2L,ZT,XB,YB), (R1G,R2L,ZT,XB,YB),(R1H,R2L,ZT,XB,YB), (R1I,R2L,ZT,XB,YB), (R1J,R2L,ZT,XB,YB),(R1K,R2L,ZT,XB,YB), (R1L,R2L,ZT,XB,YB), (R1M,R2L,ZT,XB,YB),(R1N,R2L,ZT,XB,YB), (R1O,R2L,ZT,XB,YB), (R1P,R2L,ZT,XB,YB),(R1Q,R2L,ZT,XB,YB), (R1A,R2M,ZT,XB,YB), (R1B,R2M,ZT,XB,YB),(R1C,R2M,ZT,XB,YB), (R1D,R2M,ZT,XB,YB), (R1E,R2M,ZT,XB,YB),(R1F,R2M,ZT,XB,YB), (R1G,R2M,ZT,XB,YB), (R1H,R2M,ZT,XB,YB),(R1I,R2M,ZT,XB,YB), (R1J,R2M,ZT,XB,YB), (R1K,R2M,ZT,XB,YB),(R1L,R2M,ZT,XB,YB), (R1M,R2M,ZT,XB,YB), (R1N,R2M,ZT,XB,YB),(R1O,R2M,ZT,XB,YB), (R1P,R2M,ZT,XB,YB), (R1Q,R2M,ZT,XB,YB),(R1A,R2N,ZT,XB,YB), (R1B,R2N,ZT,XB,YB), (R1C,R2N,ZT,XB,YB),(R1D,R2N,ZT,XB,YB), (R1E,R2N,ZT,XB,YB), (R1F,R2N,ZT,XB,YB),(R1G,R2N,ZT,XB,YB), (R1H,R2N,ZT,XB,YB), (R1I,R2N,ZT,XB,YB),(R1J,R2N,ZT,XB,YB), (R1K,R2N,ZT,XB,YB), (R1L,R2N,ZT,XB,YB),(R1M,R2N,ZT,XB,YB), (R1N,R2N,ZT,XB,YB), (R1O,R2N,ZT,XB,YB),(R1P,R2N,ZT,XB,YB), (R1Q,R2N,ZT,XB,YB), (R1A,R2O,ZT,XB,YB),(R1B,R2O,ZT,XB,YB), (R1C,R2O,ZT,XB,YB), (R1D,R2O,ZT,XB,YB),(R1E,R2O,ZT,XB,YB), (R1F,R2O,ZT,XB,YB), (R1G,R2O,ZT,XB,YB),(R1H,R2O,ZT,XB,YB), (R1I,R2O,ZT,XB,YB), (R1J,R2O,ZT,XB,YB),(R1K,R2O,ZT,XB,YB), (R1L,R2O,ZT,XB,YB), (R1M,R2O,ZT,XB,YB),(R1N,R2O,ZT,XB,YB), (R1O,R2O,ZT,XB,YB), (R1P,R2O,ZT,XB,YB),(R1Q,R2O,ZT,XB,YB), (R1A,R2P,ZT,XB,YB), (R1B,R2P,ZT,XB,YB),(R1C,R2P,ZT,XB,YB), (R1D,R2P,ZT,XB,YB), (R1E,R2P,ZT,XB,YB),(R1F,R2P,ZT,XB,YB), (R1G,R2P,ZT,XB,YB), (R1H,R2P,ZT,XB,YB),(R1I,R2P,ZT,XB,YB), (R1J,R2P,ZT,XB,YB), (R1K,R2P,ZT,XB,YB),(R1L,R2P,ZT,XB,YB), (R1M,R2P,ZT,XB,YB), (R1N,R2P,ZT,XB,YB),(R1O,R2P,ZT,XB,YB), (R1P,R2P,ZT,XB,YB), (R1Q,R2P,ZT,XB,YB),(R1A,R2Q,ZT,XB,YB), (R1B,R2Q,ZT,XB,YB), (R1C,R2Q,ZT,XB,YB),(R1D,R2Q,ZT,XB,YB), (R1E,R2Q,ZT,XB,YB), (R1F,R2Q,ZT,XB,YB),(R1G,R2Q,ZT,XB,YB), (R1H,R2Q,ZT,XB,YB), (R1I,R2Q,ZT,XB,YB),(R1J,R2Q,ZT,XB,YB), (R1K,R2Q,ZT,XB,YB), (R1L,R2Q,ZT,XB,YB),(R1M,R2Q,ZT,XB,YB), (R1N,R2Q,ZT,XB,YB), (R1O,R2Q,ZT,XB,YB),(R1P,R2Q,ZT,XB,YB), (R1Q,R2Q,ZT,XB,YB), (R1A,R2A,ZU,XB,YB),(R1B,R2A,ZU,XB,YB), (R1C,R2A,ZU,XB,YB), (R1D,R2A,ZU,XB,YB),(R1E,R2A,ZU,XB,YB), (R1F,R2A,ZU,XB,YB), (R1G,R2A,ZU,XB,YB),(R1H,R2A,ZU,XB,YB), (R1I,R2A,ZU,XB,YB), (R1J,R2A,ZU,XB,YB),(R1K,R2A,ZU,XB,YB), (R1L,R2A,ZU,XB,YB), (R1M,R2A,ZU,XB,YB),(R1N,R2A,ZU,XB,YB), (R1O,R2A,ZU,XB,YB), (R1P,R2A,ZU,XB,YB),(R1Q,R2A,ZU,XB,YB), (R1A,R2B,ZU,XB,YB), (R1B,R2B,ZU,XB,YB),(R1C,R2B,ZU,XB,YB), (R1D,R2B,ZU,XB,YB), (R1E,R2B,ZU,XB,YB),(R1F,R2B,ZU,XB,YB), (R1G,R2B,ZU,XB,YB), (R1H,R2B,ZU,XB,YB),(R1I,R2B,ZU,XB,YB), (R1J,R2B,ZU,XB,YB), (R1K,R2B,ZU,XB,YB),(R1L,R2B,ZU,XB,YB), (R1M,R2B,ZU,XB,YB), (R1N,R2B,ZU,XB,YB),(R1O,R2B,ZU,XB,YB), (R1P,R2B,ZU,XB,YB), (R1Q,R2B,ZU,XB,YB),(R1A,R22C,ZU,XB,YB), (R1B,R22C,ZU,XB,YB), (R1C,R22C,ZU,XB,YB),(R1D,R22C,ZU,XB,YB), (R1E,R22C,ZU,XB,YB), (R1F,R22C,ZU,XB,YB),(R1G,R22C,ZU,XB,YB), (R1H,R22C,ZU,XB,YB), (R1I,R22C,ZU,XB,YB),(R1J,R22C,ZU,XB,YB), (R1K,R22C,ZU,XB,YB), (R1L,R22C,ZU,XB,YB),(R1M,R22C,ZU,XB,YB), (R1N,R22C,ZU,XB,YB), (R1O,R2C,ZU,XB,YB),(R1P,R22C,ZU,XB,YB), (R1Q,R22C,ZU,XB,YB), (R1A,R2D,ZU,XB,YB),(R1B,R2D,ZU,XB,YB), (R1C,R2D,ZU,XB,YB), (R1D,R2D,ZU,XB,YB),(R1E,R2D,ZU,XB,YB), (R1F,R2D,ZU,XB,YB), (R1G,R2D,ZU,XB,YB),(R1H,R2D,ZU,XB,YB), (R1I,R2D,ZU,XB,YB), (R1J,R2D,ZU,XB,YB),(R1K,R2D,ZU,XB,YB), (R1L,R2D,ZU,XB,YB), (R1M,R2D,ZU,XB,YB),(R1N,R2D,ZU,XB,YB), (R1O,R2D,ZU,XB,YB), (R1P,R2D,ZU,XB,YB),(R1Q,R2D,ZU,XB,YB), (R1A,R2E,ZU,XB,YB), (R1B,R2E,ZU,XB,YB),(R1C,R2E,ZU,XB,YB), (R1D,R2E,ZU,XB,YB), (R1E,R2E,ZU,XB,YB),(R1F,R2E,ZU,XB,YB), (R1G,R2E,ZU,XB,YB), (R1H,R2E,ZU,XB,YB),(R1I,R2E,ZU,XB,YB), (R1J,R2E,ZU,XB,YB), (R1K,R2E,ZU,XB,YB),(R1L,R2E,ZU,XB,YB), (R1M,R2E,ZU,XB,YB), (R1N,R2E,ZU,XB,YB),(R1O,R2E,ZU,XB,YB), (R1P,R2E,ZU,XB,YB), (R1Q,R2E,ZU,XB,YB),(R1A,R2F,ZU,XB,YB), (R1B,R2F,ZU,XB,YB), (R1C,R2F,ZU,XB,YB),(R1D,R2F,ZU,XB,YB), (R1E,R2F,ZU,XB,YB), (R1F,R2F,ZU,XB,YB),(R1G,R2F,ZU,XB,YB), (R1H,R2F,ZU,XB,YB), (R1I,R2F,ZU,XB,YB),(R1J,R2F,ZU,XB,YB), (R1K,R2F,ZU,XB,YB), (R1L,R2F,ZU,XB,YB),(R1M,R2F,ZU,XB,YB), (R1N,R2F,ZU,XB,YB), (R1O,R2F,ZU,XB,YB),(R1P,R2F,ZU,XB,YB), (R1Q,R2F,ZU,XB,YB), (R1A,R2G,ZU,XB,YB),(R1B,R2G,ZU,XB,YB), (R1C,R2G,ZU,XB,YB), (R1D,R2G,ZU,XB,YB),(R1E,R2G,ZU,XB,YB), (R1F,R2G,ZU,XB,YB), (R1G,R2G,ZU,XB,YB),(R1H,R2G,ZU,XB,YB), (R1I,R2G,ZU,XB,YB), (R1J,R2G,ZU,XB,YB),(R1K,R2G,ZU,XB,YB), (R1L,R2G,ZU,XB,YB), (R1M,R2G,ZU,XB,YB),(R1N,R2G,ZU,XB,YB), (R1O,R2G,ZU,XB,YB), (R1P,R2G,ZU,XB,YB),(R1Q,R2G,ZU,XB,YB), (R1A,R2H,ZU,XB,YB), (R1B,R2H,ZU,XB,YB),(R1C,R2H,ZU,XB,YB), (R1D,R2H,ZU,XB,YB), (R1E,R2H,ZU,XB,YB),(R1F,R2H,ZU,XB,YB), (R1G,R2H,ZU,XB,YB), (R1H,R2H,ZU,XB,YB),(R1I,R2H,ZU,XB,YB), (R1J,R2H,ZU,XB,YB), (R1K,R2H,ZU,XB,YB),(R1L,R2H,ZU,XB,YB), (R1M,R2H,ZU,XB,YB), (R1N,R2H,ZU,XB,YB),(R1O,R2H,ZU,XB,YB), (R1P,R2H,ZU,XB,YB), (R1Q,R2H,ZU,XB,YB),(R1A,R2I,ZU,XB,YB), (R1B,R2I,ZU,XB,YB), (R1C,R2I,ZU,XB,YB),(R1D,R2I,ZU,XB,YB), (R1E,R2I,ZU,XB,YB), (R1F,R2I,ZU,XB,YB),(R1G,R2I,ZU,XB,YB), (R1H,R2I,ZU,XB,YB), (R1I,R2I,ZU,XB,YB),(R1J,R2I,ZU,XB,YB), (R1K,R2I,ZU,XB,YB), (R1L,R2I,ZU,XB,YB),(R1M,R2I,ZU,XB,YB), (R1N,R2I,ZU,XB,YB), (R1O,R2I,ZU,XB,YB),(R1P,R2I,ZU,XB,YB), (R1Q,R2I,ZU,XB,YB), (R1A,R2J,ZU,XB,YB),(R1B,R2J,ZU,XB,YB), (R1C,R2J,ZU,XB,YB), (R1D,R2J,ZU,XB,YB),(R1E,R2J,ZU,XB,YB), (R1F,R2J,ZU,XB,YB), (R1G,R2J,ZU,XB,YB),(R1H,R2J,ZU,XB,YB), (R1I,R2J,ZU,XB,YB), (R1J,R2J,ZU,XB,YB),(R1K,R2J,ZU,XB,YB), (R1L,R2J,ZU,XB,YB), (R1M,R2J,ZU,XB,YB),(R1N,R2J,ZU,XB,YB), (R1O,R2J,ZU,XB,YB), (R1P,R2J,ZU,XB,YB),(R1Q,R2J,ZU,XB,YB), (R1A,R2K,ZU,XB,YB), (R1B,R2K,ZU,XB,YB),(R1C,R2K,ZU,XB,YB), (R1D,R2K,ZU,XB,YB), (R1E,R2K,ZU,XB,YB),(R1F,R2K,ZU,XB,YB), (R1G,R2K,ZU,XB,YB), (R1H,R2K,ZU,XB,YB),(R1I,R2K,ZU,XB,YB), (R1J,R2K,ZU,XB,YB), (R1K,R2K,ZU,XB,YB),(R1L,R2K,ZU,XB,YB), (R1M,R2K,ZU,XB,YB), (R1N,R2K,ZU,XB,YB),(R1O,R2K,ZU,XB,YB), (R1P,R2K,ZU,XB,YB), (R1Q,R2K,ZU,XB,YB),(R1A,R2L,ZU,XB,YB), (R1B,R2L,ZU,XB,YB), (R1C,R2L,ZU,XB,YB),(R1D,R2L,ZU,XB,YB), (R1E,R2L,ZU,XB,YB), (R1F,R2L,ZU,XB,YB),(R1G,R2L,ZU,XB,YB), (R1H,R2L,ZU,XB,YB), (R1I,R2L,ZU,XB,YB),(R1J,R2L,ZU,XB,YB), (R1K,R2L,ZU,XB,YB), (R1L,R2L,ZU,XB,YB),(R1M,R2L,ZU,XB,YB), (R1N,R2L,ZU,XB,YB), (R1O,R2L,ZU,XB,YB),(R1P,R2L,ZU,XB,YB), (R1Q,R2L,ZU,XB,YB), (R1A,R2M,ZU,XB,YB),(R1B,R2M,ZU,XB,YB), (R1C,R2M,ZU,XB,YB), (R1D,R2M,ZU,XB,YB),(R1E,R2M,ZU,XB,YB), (R1F,R2M,ZU,XB,YB), (R1G,R2M,ZU,XB,YB),(R1H,R2M,ZU,XB,YB), (R1I,R2M,ZU,XB,YB), (R1J,R2M,ZU,XB,YB),(R1K,R2M,ZU,XB,YB), (R1L,R2M,ZU,XB,YB), (R1M,R2M,ZU,XB,YB),(R1N,R2M,ZU,XB,YB), (R1O,R2M,ZU,XB,YB), (R1P,R2M,ZU,XB,YB),(R1Q,R2M,ZU,XB,YB), (R1A,R2N,ZU,XB,YB), (R1B,R2N,ZU,XB,YB),(R1C,R2N,ZU,XB,YB), (R1D,R2N,ZU,XB,YB), (R1E,R2N,ZU,XB,YB),(R1F,R2N,ZU,XB,YB), (R1G,R2N,ZU,XB,YB), (R1H,R2N,ZU,XB,YB),(R1I,R2N,ZU,XB,YB), (R1J,R2N,ZU,XB,YB), (R1K,R2N,ZU,XB,YB),(R1L,R2N,ZU,XB,YB), (R1M,R2N,ZU,XB,YB), (R1N,R2N,ZU,XB,YB),(R1O,R2N,ZU,XB,YB), (R1P,R2N,ZU,XB,YB), (R1Q,R2N,ZU,XB,YB),(R1A,R2O,ZU,XB,YB), (R1B,R2O,ZU,XB,YB), (R1C,R2O,ZU,XB,YB),(R1D,R2O,ZU,XB,YB), (R1E,R2O,ZU,XB,YB), (R1F,R2O,ZU,XB,YB),(R1G,R2O,ZU,XB,YB), (R1H,R2O,ZU,XB,YB), (R1I,R2O,ZU,XB,YB),(R1J,R2O,ZU,XB,YB), (R1K,R2O,ZU,XB,YB), (R1L,R2O,ZU,XB,YB),(R1M,R2O,ZU,XB,YB), (R1N,R2O,ZU,XB,YB), (R1O,R2O,ZU,XB,YB),(R1P,R2O,ZU,XB,YB), (R1Q,R2O,ZU,XB,YB), (R1A,R2P,ZU,XB,YB),(R1B,R2P,ZU,XB,YB), (R1C,R2P,ZU,XB,YB), (R1D,R2P,ZU,XB,YB),(R1E,R2P,ZU,XB,YB), (R1F,R2P,ZU,XB,YB), (R1G,R2P,ZU,XB,YB),(R1H,R2P,ZU,XB,YB), (R1I,R2P,ZU,XB,YB), (R1J,R2P,ZU,XB,YB),(R1K,R2P,ZU,XB,YB), (R1L,R2P,ZU,XB,YB), (R1M,R2P,ZU,XB,YB),(R1N,R2P,ZU,XB,YB), (R1O,R2P,ZU,XB,YB), (R1P,R2P,ZU,XB,YB),(R1Q,R2P,ZU,XB,YB), (R1A,R2Q,ZU,XB,YB), (R1B,R2Q,ZU,XB,YB),(R1C,R2Q,ZU,XB,YB), (R1D,R2Q,ZU,XB,YB), (R1E,R2Q,ZU,XB,YB),(R1F,R2Q,ZU,XB,YB), (R1G,R2Q,ZU,XB,YB), (R1H,R2Q,ZU,XB,YB),(R1I,R2Q,ZU,XB,YB), (R1J,R2Q,ZU,XB,YB), (R1K,R2Q,ZU,XB,YB),(R1L,R2Q,ZU,XB,YB), (R1M,R2Q,ZU,XB,YB), (R1N,R2Q,ZU,XB,YB),(R1O,R2Q,ZU,XB,YB), (R1P,R2Q,ZU,XB,YB) and (R1Q,R2Q,ZU,XB,YB).

Other preferred embodiments of the compound of the invention are thecompound having the following groups in the formula (a′) to (f′):

TABLE 6 R^(a)1 R^(a) R^(a)2 COOEt R^(a)3 isoxazol-3-yl R^(a)43-Me-isoxazol-5-yl R^(a)5 5-Me-1,2,4-oxadiazol-3-yl R^(a)63-Me-1,2,4-oxadiazol-5-yl R^(a)7 2-thiazolynyl R^(a)8 2-thiazolyl R^(a)92- or 3-thienyl R^(a)10 2- or 3-furyl R^(a)11 5-Me-2- or 3-thienylR^(a)12 5-Me-2- or 3-furyl R^(a)13 SMe R^(a)14 1-pyrrolidinyl R^(a)151-cyclopentyl R^(a)16 1-cyclopentenyl

TABLE 7 R^(b) R^(b)1 iPr R^(b)2 iBu R^(b)3 tBu R^(b)4 HOCH₂C(Me)₂ R^(b)5Me(CH₂OH)₂Me R^(b)6 Me₂NCOC(Me)₂ R^(b)7 MeNHCOC(Me)₂ R^(b)8 H₂NCOC(Me)₂

TABLE 8 Z Z1 (HOCH₂)₂CHCH₂O Z2 c-PentylO Z3 Et(Me)NCO Z4 EtHNCO Z5 EtOZ6 EtOCH₂O Z7 H₂NCO(CH₂)₂ Z8 H₂NCOCH₂O Z9 HO(CH₂)₂O Z10 HO(CH₂)₃O Z11i-BuO Z12 i-PrHNCO(CH₂)₂ Z13 i-PrO Z14 i-PrOCH₂ Z15 Me₂N(CH₂)₂O Z16Me₂NCO Z17 Me₂NCO(CH₂)₂ Z18 Me₂NCOCH₂ Z19 Me₂NCOCH₂O Z20 MeHNCO(CH₂)₂Z21 MeNHCOCH₂O Z22 MeO Z23 MeO(CH₂)₂ Z24 MeO(CH₂)₂(Me)NCO Z25 MeO(CH₂)₂OZ26 MeO(CH₂)₂OCH₂ Z27 MeO(CH₂)₃O Z28 MeOCH₂ Z29 MeOCH₂O Z30 MeS Z31MeSO(CH₂)₂O Z32 MeSO₂ Z33 Morpholino Z34 NC Z35 NC(CH₂)₂O Z36 NCCH₂O Z37

Z38

Z39

TABLE 9 X X1 CH X2 N

The combination of Ra, Rb, X and Z (Ra,Rb,X,Z) is any one of thefollowing combinations:

(Ra,Rb,X,Z)=(Ra1,Rb1,X1,Z1), (Ra1,Rb1,X1,Z2), (Ra1,Rb1,X1,Z3),(Ra1,Rb1,X1,Z4), (Ra1,Rb1,X1,Z5), (Ra1,Rb1,X1,Z6), (Ra1,Rb1,X1,Z7),(Ra1,Rb1,X1,Z8), (Ra1,Rb1,X1,Z9), (Ra1,Rb1,X1,Z10), (Ra1,Rb1,X1,Z11),(Ra1,Rb1,X1,Z12), (Ra1,Rb1,X1,Z13), (Ra1,Rb1,X1,Z14), (Ra1,Rb1,X1,Z15),(Ra1,Rb1,X1,Z16), (Ra1,Rb1,X1,Z17), (Ra1,Rb1,X1,Z18), (Ra1,Rb1,X1,Z19),(Ra1,Rb1,X1,Z20), (Ra1,Rb1,X1,Z21), (Ra1,Rb1,X1,Z22), (Ra1,Rb1,X1,Z23),(Ra1,Rb1,X1,Z24), (Ra1,Rb1,X1,Z25), (Ra1,Rb1,X1,Z26), (Ra1,Rb1,X1,Z27),(Ra1,Rb1,X1,Z28), (Ra1,Rb1,X1,Z29), (Ra1,Rb1,X1,Z30), (Ra1,Rb1,X1,Z31),(Ra1,Rb1,X1,Z32), (Ra1,Rb1,X1,Z33), (Ra1,Rb1,X1,Z34), (Ra1,Rb1,X1,Z35),(Ra1,Rb1,X1,Z36), (Ra1,Rb1,X1,Z37), (Ra1,Rb1,X1,Z38), (Ra1,Rb1,X1,Z39),(Ra1,Rb1,X2,Z1), (Ra1,Rb1,X2,Z2), (Ra1,Rb1,X2,Z3), (Ra1,Rb1,X2,Z4),(Ra1,Rb1,X2,Z5), (Ra1,Rb1,X2,Z6), (Ra1,Rb1,X2,Z7), (Ra1,Rb1,X2,Z8),(Ra1,Rb1,X2,Z9), (Ra1,Rb1,X2,Z10), (Ra1,Rb1,X2,Z11), (Ra1,Rb1,X2,Z12),(Ra1,Rb1,X2,Z13), (Ra1,Rb1,X2,Z14), (Ra1,Rb1,X2,Z15), (Ra1,Rb1,X2,Z16),(Ra1,Rb1,X2,Z17), (Ra1,Rb1,X2,Z18), (Ra1,Rb1,X2,Z19), (Ra1,Rb1,X2,Z20),(Ra1,Rb1,X2,Z21), (Ra1,Rb1,X2,Z22), (Ra1,Rb1,X2,Z23), (Ra1,Rb1,X2,Z24),(Ra1,Rb1,X2,Z25), (Ra1,Rb1,X2,Z26), (Ra1,Rb1,X2,Z27), (Ra1,Rb1,X2,Z28),(Ra1,Rb1,X2,Z29), (Ra1,Rb1,X2,Z30), (Ra1,Rb1,X2,Z31), (Ra1,Rb1,X2,Z32),(Ra1,Rb1,X2,Z33), (Ra1,Rb1,X2,Z34), (Ra1,Rb1,X2,Z35), (Ra1,Rb1,X2,Z36),(Ra1,Rb1,X2,Z37), (Ra1,Rb1,X2,Z38), (Ra1,Rb1,X2,Z39), (Ra1,Rb2,X1,Z1),(Ra1,Rb2,X1,Z2), (Ra1,Rb2,X1,Z3), (Ra1,Rb2,X1,Z4), (Ra1,Rb2,X1,Z5),(Ra1,Rb2,X1,Z6), (Ra1,Rb2,X1,Z7), (Ra1,Rb2,X1,Z8), (Ra1,Rb2,X1,Z9),(Ra1,Rb2,X1,Z10), (Ra1,Rb2,X1,Z11), (Ra1,Rb2,X1,Z12), (Ra1,Rb2,X1,Z13),(Ra1,Rb2,X1,Z14), (Ra1,Rb2,X1,Z15), (Ra1,Rb2,X1,Z16), (Ra1,Rb2,X1,Z17),(Ra1,Rb2,X1,Z18), (Ra1,Rb2,X1,Z19), (Ra1,Rb2,X1,Z20), (Ra1,Rb2,X1,Z21),(Ra1,Rb2,X1,Z22), (Ra1,Rb2,X1,Z23), (Ra1,Rb2,X1,Z24), (Ra1,Rb2,X1,Z25),(Ra1,Rb2,X1,Z26), (Ra1,Rb2,X1,Z27), (Ra1,Rb2,X1,Z28), (Ra1,Rb2,X1,Z29),(Ra1,Rb2,X1,Z30), (Ra1,Rb2,X1,Z31), (Ra1,Rb2,X1,Z32), (Ra1,Rb2,X1,Z33),(Ra1,Rb2,X1,Z34), (Ra1,Rb2,X1,Z35), (Ra1,Rb2,X1,Z36), (Ra1,Rb2,X1,Z37),(Ra1,Rb2,X1,Z38), (Ra1,Rb2,X1,Z39), (Ra1,Rb2,X2,Z1), (Ra1,Rb2,X2,Z2),(Ra1,Rb2,X2,Z3), (Ra1,Rb2,X2,Z4), (Ra1,Rb2,X2,Z5), (Ra1,Rb2,X2,Z6),(Ra1,Rb2,X2,Z7), (Ra1,Rb2,X2,Z8), (Ra1,Rb2,X2,Z9), (Ra1,Rb2,X2,Z10),(Ra1,Rb2,X2,Z11), (Ra1,Rb2,X2,Z12), (Ra1,Rb2,X2,Z13), (Ra1,Rb2,X2,Z14),(Ra1,Rb2,X2,Z15), (Ra1,Rb2,X2,Z16), (Ra1,Rb2,X2,Z17), (Ra1,Rb2,X2,Z18),(Ra1,Rb2,X2,Z19), (Ra1,Rb2,X2,Z20), (Ra1,Rb2,X2,Z21), (Ra1,Rb2,X2,Z22),(Ra1,Rb2,X2,Z23), (Ra1,Rb2,X2,Z24), (Ra1,Rb2,X2,Z25), (Ra1,Rb2,X2,Z26),(Ra1,Rb2,X2,Z27), (Ra1,Rb2,X2,Z28), (Ra1,Rb2,X2,Z29), (Ra1,Rb2,X2,Z30),(Ra1,Rb2,X2,Z31), (Ra1,Rb2,X2,Z32), (Ra1,Rb2,X2,Z33), (Ra1,Rb2,X2,Z34),(Ra1,Rb2,X2,Z35), (Ra1,Rb2,X2,Z36), (Ra1,Rb2,X2,Z37), (Ra1,Rb2,X2,Z38),(Ra1,Rb2,X2,Z39), (Ra1,Rb3,X1,Z1), (Ra1,Rb3,X1,Z2), (Ra1,Rb3,X1,Z3),(Ra1,Rb3,X1,Z4), (Ra1,Rb3,X1,Z5), (Ra1,Rb3,X1,Z6), (Ra1,Rb3,X1,Z7),(Ra1,Rb3,X1,Z8), (Ra1,Rb3,X1,Z9), (Ra1,Rb3,X1,Z10), (Ra1,Rb3,X1,Z11),(Ra1,Rb3,X1,Z12), (Ra1,Rb3,X1,Z13), (Ra1,Rb3,X1,Z14), (Ra1,Rb3,X1,Z15),(Ra1,Rb3,X1,Z16), (Ra1,Rb3,X1,Z17), (Ra1,Rb3,X1,Z18), (Ra1,Rb3,X1,Z19),(Ra1,Rb3,X1,Z20), (Ra1,Rb3,X1,Z21), (Ra1,Rb3,X1,Z22), (Ra1,Rb3,X1,Z23),(Ra1,Rb3,X1,Z24), (Ra1,Rb3,X1,Z25), (Ra1,Rb3,X1,Z26), (Ra1,Rb3,X1,Z27),(Ra1,Rb3,X1,Z28), (Ra1,Rb3,X1,Z29), (Ra1,Rb3,X1,Z30), (Ra1,Rb3,X1,Z31),(Ra1,Rb3,X1,Z32), (Ra1,Rb3,X1,Z33), (Ra1,Rb3,X1,Z34), (Ra1,Rb3,X1,Z35),(Ra1,Rb3,X1,Z36), (Ra1,Rb3,X1,Z37), (Ra1,Rb3,X1,Z38), (Ra1,Rb3,X1,Z39),(Ra1,Rb3,X2,Z1), (Ra1,Rb3,X2,Z2), (Ra1,Rb3,X2,Z3), (Ra1,Rb3,X2,Z4),(Ra1,Rb3,X2,Z5), (Ra1,Rb3,X2,Z6), (Ra1,Rb3,X2,Z7), (Ra1,Rb3,X2,Z8),(Ra1,Rb3,X2,Z9), (Ra1,Rb3,X2,Z10), (Ra1,Rb3,X2,Z11), (Ra1,Rb3,X2,Z12),(Ra1,Rb3,X2,Z13), (Ra1,Rb3,X2,Z14), (Ra1,Rb3,X2,Z15), (Ra1,Rb3,X2,Z16),(Ra1,Rb3,X2,Z17), (Ra1,Rb3,X2,Z18), (Ra1,Rb3,X2,Z19), (Ra1,Rb3,X2,Z20),(Ra1,Rb3,X2,Z21), (Ra1,Rb3,X2,Z22), (Ra1,Rb3,X2,Z23), (Ra1,Rb3,X2,Z24),(Ra1,Rb3,X2,Z25), (Ra1,Rb3,X2,Z26), (Ra1,Rb3,X2,Z27), (Ra1,Rb3,X2,Z28),(Ra1,Rb3,X2,Z29), (Ra1,Rb3,X2,Z30), (Ra1,Rb3,X2,Z31), (Ra1,Rb3,X2,Z32),(Ra1,Rb3,X2,Z33), (Ra1,Rb3,X2,Z34), (Ra1,Rb3,X2,Z35), (Ra1,Rb3,X2,Z36),(Ra1,Rb3,X2,Z37), (Ra1,Rb3,X2,Z38), (Ra1,Rb3,X2,Z39), (Ra1,Rb4,X1,Z1),(Ra1,Rb4,X1,Z2), (Ra1,Rb4,X1,Z3), (Ra1,Rb4,X1,Z4), (Ra1,Rb4,X1,Z5),(Ra1,Rb4,X1,Z6), (Ra1,Rb4,X1,Z7), (Ra1,Rb4,X1,Z8), (Ra1,Rb4,X1,Z9),(Ra1,Rb4,X1,Z10), (Ra1,Rb4,X1,Z11), (Ra1,Rb4,X1,Z12), (Ra1,Rb4,X1,Z13),(Ra1,Rb4,X1,Z14), (Ra1,Rb4,X1,Z15), (Ra1,Rb4,X1,Z16), (Ra1,Rb4,X1,Z17),(Ra1,Rb4,X1,Z18), (Ra1,Rb4,X1,Z19), (Ra1,Rb4,X1,Z20), (Ra1,Rb4,X1,Z21),(Ra1,Rb4,X1,Z22), (Ra1,Rb4,X1,Z23), (Ra1,Rb4,X1,Z24), (Ra1,Rb4,X1,Z25),(Ra1,Rb4,X1,Z26), (Ra1,Rb4,X1,Z27), (Ra1,Rb4,X1,Z28), (Ra1,Rb4,X1,Z29),(Ra1,Rb4,X1,Z30), (Ra1,Rb4,X1,Z31), (Ra1,Rb4,X1,Z32), (Ra1,Rb4,X1,Z33),(Ra1,Rb4,X1,Z34), (Ra1,Rb4,X1,Z35), (Ra1,Rb4,X1,Z36), (Ra1,Rb4,X1,Z37),(Ra1,Rb4,X1,Z38), (Ra1,Rb4,X1,Z39), (Ra1,Rb4,X2,Z1), (Ra1,Rb4,X2,Z2),(Ra1,Rb4,X2,Z3), (Ra1,Rb4,X2,Z4), (Ra1,Rb4,X2,Z5), (Ra1,Rb4,X2,Z6),(Ra1,Rb4,X2,Z7), (Ra1,Rb4,X2,Z8), (Ra1,Rb4,X2,Z9), (Ra1,Rb4,X2,Z10),(Ra1,Rb4,X2,Z11), (Ra1,Rb4,X2,Z12), (Ra1,Rb4,X2,Z13), (Ra1,Rb4,X2,Z14),(Ra1,Rb4,X2,Z15), (Ra1,Rb4,X2,Z16), (Ra1,Rb4,X2,Z17), (Ra1,Rb4,X2,Z18),(Ra1,Rb4,X2,Z19), (Ra1,Rb4,X2,Z20), (Ra1,Rb4,X2,Z21), (Ra1,Rb4,X2,Z22),(Ra1,Rb4,X2,Z23), (Ra1,Rb4,X2,Z24), (Ra1,Rb4,X2,Z25), (Ra1,Rb4,X2,Z26),(Ra1,Rb4,X2,Z27), (Ra1,Rb4,X2,Z28), (Ra1,Rb4,X2,Z29), (Ra1,Rb4,X2,Z30),(Ra1,Rb4,X2,Z31), (Ra1,Rb4,X2,Z32), (Ra1,Rb4,X2,Z33), (Ra1,Rb4,X2,Z34),(Ra1,Rb4,X2,Z35), (Ra1,Rb4,X2,Z36), (Ra1,Rb4,X2,Z37), (Ra1,Rb4,X2,Z38),(Ra1,Rb4,X2,Z39), (Ra1,Rb5,X1,Z1), (Ra1,Rb5,X1,Z2), (Ra1,Rb5,X1,Z3),(Ra1,Rb5,X1,Z4), (Ra1,Rb5,X1,Z5), (Ra1,Rb5,X1,Z6), (Ra1,Rb5,X1,Z7),(Ra1,Rb5,X1,Z8), (Ra1,Rb5,X1,Z9), (Ra1,Rb5,X1,Z10), (Ra1,Rb5,X1,Z11),(Ra1,Rb5,X1,Z12), (Ra1,Rb5,X1,Z13), (Ra1,Rb5,X1,Z14), (Ra1,Rb5,X1,Z15),(Ra1,Rb5,X1,Z16), (Ra1,Rb5,X1,Z17), (Ra1,Rb5,X1,Z18), (Ra1,Rb5,X1,Z19),(Ra1,Rb5,X1,Z20), (Ra1,Rb5,X1,Z21), (Ra1,Rb5,X1,Z22), (Ra1,Rb5,X1,Z23),(Ra1,Rb5,X1,Z24), (Ra1,Rb5,X1,Z25), (Ra1,Rb5,X1,Z26), (Ra1,Rb5,X1,Z27),(Ra1,Rb5,X1,Z28), (Ra1,Rb5,X1,Z29), (Ra1,Rb5,X1,Z30), (Ra1,Rb5,X1,Z31),(Ra1,Rb5,X1,Z32), (Ra1,Rb5,X1,Z33), (Ra1,Rb5,X1,Z34), (Ra1,Rb5,X1,Z35),(Ra1,Rb5,X1,Z36), (Ra1,Rb5,X1,Z37), (Ra1,Rb5,X1,Z38), (Ra1,Rb5,X1,Z39),(Ra1,Rb5,X2,Z1), (Ra1,Rb5,X2,Z2), (Ra1,Rb5,X2,Z3), (Ra1,Rb5,X2,Z4),(Ra1,Rb5,X2,Z5), (Ra1,Rb5,X2,Z6), (Ra1,Rb5,X2,Z7), (Ra1,Rb5,X2,Z8),(Ra1,Rb5,X2,Z9), (Ra1,Rb5,X2,Z10), (Ra1,Rb5,X2,Z11), (Ra1,Rb5,X2,Z12),(Ra1,Rb5,X2,Z13), (Ra1,Rb5,X2,Z14), (Ra1,Rb5,X2,Z15), (Ra1,Rb5,X2,Z16),(Ra1,Rb5,X2,Z17), (Ra1,Rb5,X2,Z18), (Ra1,Rb5,X2,Z19), (Ra1,Rb5,X2,Z20),(Ra1,Rb5,X2,Z21), (Ra1,Rb5,X2,Z22), (Ra1,Rb5,X2,Z23), (Ra1,Rb5,X2,Z24),(Ra1,Rb5,X2,Z25), (Ra1,Rb5,X2,Z26), (Ra1,Rb5,X2,Z27), (Ra1,Rb5,X2,Z28),(Ra1,Rb5,X2,Z29), (Ra1,Rb5,X2,Z30), (Ra1,Rb5,X2,Z31), (Ra1,Rb5,X2,Z32),(Ra1,Rb5,X2,Z33), (Ra1,Rb5,X2,Z34), (Ra1,Rb5,X2,Z35), (Ra1,Rb5,X2,Z36),(Ra1,Rb5,X2,Z37), (Ra1,Rb5,X2,Z38), (Ra1,Rb5,X2,Z39), (Ra1,Rb6,X1,Z1),(Ra1,Rb6,X1,Z2), (Ra1,Rb6,X1,Z3), (Ra1,Rb6,X1,Z4), (Ra1,Rb6,X1,Z5),(Ra1,Rb6,X1,Z6), (Ra1,Rb6,X1,Z7), (Ra1,Rb6,X1,Z8), (Ra1,Rb6,X1,Z9),(Ra1,Rb6,X1,Z10), (Ra1,Rb6,X1,Z11), (Ra1,Rb6,X1,Z12), (Ra1,Rb6,X1,Z13),(Ra1,Rb6,X1,Z14), (Ra1,Rb6,X1,Z15), (Ra1,Rb6,X1,Z16), (Ra1,Rb6,X1,Z17),(Ra1,Rb6,X1,Z18), (Ra1,Rb6,X1,Z19), (Ra1,Rb6,X1,Z20), (Ra1,Rb6,X1,Z21),(Ra1,Rb6,X1,Z22), (Ra1,Rb6,X1,Z23), (Ra1,Rb6,X1,Z24), (Ra1,Rb6,X1,Z25),(Ra1,Rb6,X1,Z26), (Ra1,Rb6,X1,Z27), (Ra1,Rb6,X1,Z28), (Ra1,Rb6,X1,Z29),(Ra1,Rb6,X1,Z30), (Ra1,Rb6,X1,Z31), (Ra1,Rb6,X1,Z32), (Ra1,Rb6,X1,Z33),(Ra1,Rb6,X1,Z34), (Ra1,Rb6,X1,Z35), (Ra1,Rb6,X1,Z36), (Ra1,Rb6,X1,Z37),(Ra1,Rb6,X1,Z38), (Ra1,Rb6,X1,Z39), (Ra1,Rb6,X2,Z1), (Ra1,Rb6,X2,Z2),(Ra1,Rb6,X2,Z3), (Ra1,Rb6,X2,Z4), (Ra1,Rb6,X2,Z5), (Ra1,Rb6,X2,Z6),(Ra1,Rb6,X2,Z7), (Ra1,Rb6,X2,Z8), (Ra1,Rb6,X2,Z9), (Ra1,Rb6,X2,Z10),(Ra1,Rb6,X2,Z11), (Ra1,Rb6,X2,Z12), (Ra1,Rb6,X2,Z13), (Ra1,Rb6,X2,Z14),(Ra1,Rb6,X2,Z15), (Ra1,Rb6,X2,Z16), (Ra1,Rb6,X2,Z17), (Ra1,Rb6,X2,Z18),(Ra1,Rb6,X2,Z19), (Ra1,Rb6,X2,Z20), (Ra1,Rb6,X2,Z21), (Ra1,Rb6,X2,Z22),(Ra1,Rb6,X2,Z23), (Ra1,Rb6,X2,Z24), (Ra1,Rb6,X2,Z25), (Ra1,Rb6,X2,Z26),(Ra1,Rb6,X2,Z27), (Ra1,Rb6,X2,Z28), (Ra1,Rb6,X2,Z29), (Ra1,Rb6,X2,Z30),(Ra1,Rb6,X2,Z31), (Ra1,Rb6,X2,Z32), (Ra1,Rb6,X2,Z33), (Ra1,Rb6,X2,Z34),(Ra1,Rb6,X2,Z35), (Ra1,Rb6,X2,Z36), (Ra1,Rb6,X2,Z37), (Ra1,Rb6,X2,Z38),(Ra1,Rb6,X2,Z39), (Ra1,Rb7,X1,Z1), (Ra1,Rb7,X1,Z2), (Ra1,Rb7,X1,Z3),(Ra1,Rb7,X1,Z4), (Ra1,Rb7,X1,Z5), (Ra1,Rb7,X1,Z6), (Ra1,Rb7,X1,Z7),(Ra1,Rb7,X1,Z8), (Ra1,Rb7,X1,Z9), (Ra1,Rb7,X1,Z10), (Ra1,Rb7,X1,Z11),(Ra1,Rb7,X1,Z12), (Ra1,Rb7,X1,Z13), (Ra1,Rb7,X1,Z14), (Ra1,Rb7,X1,Z15),(Ra1,Rb7,X1,Z16), (Ra1,Rb7,X1,Z17), (Ra1,Rb7,X1,Z18), (Ra1,Rb7,X1,Z19),(Ra1,Rb7,X1,Z20), (Ra1,Rb7,X1,Z21), (Ra1,Rb7,X1,Z22), (Ra1,Rb7,X1,Z23),(Ra1,Rb7,X1,Z24), (Ra1,Rb7,X1,Z25), (Ra1,Rb7,X1,Z26), (Ra1,Rb7,X1,Z27),(Ra1,Rb7,X1,Z28), (Ra1,Rb7,X1,Z29), (Ra1,Rb7,X1,Z30), (Ra1,Rb7,X1,Z31),(Ra1,Rb7,X1,Z32), (Ra1,Rb7,X1,Z33), (Ra1,Rb7,X1,Z34), (Ra1,Rb7,X1,Z35),(Ra1,Rb7,X1,Z36), (Ra1,Rb7,X1,Z37), (Ra1,Rb7,X1,Z38), (Ra1,Rb7,X1,Z39),(Ra1,Rb7,X2,Z1), (Ra1,Rb7,X2,Z2), (Ra1,Rb7,X2,Z3), (Ra1,Rb7,X2,Z4),(Ra1,Rb7,X2,Z5), (Ra1,Rb7,X2,Z6), (Ra1,Rb7,X2,Z7), (Ra1,Rb7,X2,Z8),(Ra1,Rb7,X2,Z9), (Ra1,Rb7,X2,Z10), (Ra1,Rb7,X2,Z11), (Ra1,Rb7,X2,Z12),(Ra1,Rb7,X2,Z13), (Ra1,Rb7,X2,Z14), (Ra1,Rb7,X2,Z15), (Ra1,Rb7,X2,Z16),(Ra1,Rb7,X2,Z17), (Ra1,Rb7,X2,Z18), (Ra1,Rb7,X2,Z19), (Ra1,Rb7,X2,Z20),(Ra1,Rb7,X2,Z21), (Ra1,Rb7,X2,Z22), (Ra1,Rb7,X2,Z23), (Ra1,Rb7,X2,Z24),(Ra1,Rb7,X2,Z25), (Ra1,Rb7,X2,Z26), (Ra1,Rb7,X2,Z27), (Ra1,Rb7,X2,Z28),(Ra1,Rb7,X2,Z29), (Ra1,Rb7,X2,Z30), (Ra1,Rb7,X2,Z31), (Ra1,Rb7,X2,Z32),(Ra1,Rb7,X2,Z33), (Ra1,Rb7,X2,Z34), (Ra1,Rb7,X2,Z35), (Ra1,Rb7,X2,Z36),(Ra1,Rb7,X2,Z37), (Ra1,Rb7,X2,Z38), (Ra1,Rb7,X2,Z39), (Ra1,Rb8,X1,Z1),(Ra1,Rb8,X1,Z2), (Ra1,Rb8,X1,Z3), (Ra1,Rb8,X1,Z4), (Ra1,Rb8,X1,Z5),(Ra1,Rb8,X1,Z6), (Ra1,Rb8,X1,Z7), (Ra1,Rb8,X1,Z8), (Ra1,Rb8,X1,Z9),(Ra1,Rb8,X1,Z10), (Ra1,Rb8,X1,Z11), (Ra1,Rb8,X1,Z12), (Ra1,Rb8,X1,Z13),(Ra1,Rb8,X1,Z14), (Ra1,Rb8,X1,Z15), (Ra1,Rb8,X1,Z16), (Ra1,Rb8,X1,Z17),(Ra1,Rb8,X1,Z18), (Ra1,Rb8,X1,Z19), (Ra1,Rb8,X1,Z20), (Ra1,Rb8,X1,Z21),(Ra1,Rb8,X1,Z22), (Ra1,Rb8,X1,Z23), (Ra1,Rb8,X1,Z24), (Ra1,Rb8,X1,Z25),(Ra1,Rb8,X1,Z26), (Ra1,Rb8,X1,Z27), (Ra1,Rb8,X1,Z28), (Ra1,Rb8,X1,Z29),(Ra1,Rb8,X1,Z30), (Ra1,Rb8,X1,Z31), (Ra1,Rb8,X1,Z32), (Ra1,Rb8,X1,Z33),(Ra1,Rb8,X1,Z34), (Ra1,Rb8,X1,Z35), (Ra1,Rb8,X1,Z36), (Ra1,Rb8,X1,Z37),(Ra1,Rb8,X1,Z38), (Ra1,Rb8,X1,Z39), (Ra1,Rb8,X2,Z1), (Ra1,Rb8,X2,Z2),(Ra1,Rb8,X2,Z3), (Ra1,Rb8,X2,Z4), (Ra1,Rb8,X2,Z5), (Ra1,Rb8,X2,Z6),(Ra1,Rb8,X2,Z7), (Ra1,Rb8,X2,Z8), (Ra1,Rb8,X2,Z9), (Ra1,Rb8,X2,Z10),(Ra1,Rb8,X2,Z11), (Ra1,Rb8,X2,Z12), (Ra1,Rb8,X2,Z13), (Ra1,Rb8,X2,Z14),(Ra1,Rb8,X2,Z15), (Ra1,Rb8,X2,Z16), (Ra1,Rb8,X2,Z17), (Ra1,Rb8,X2,Z18),(Ra1,Rb8,X2,Z19), (Ra1,Rb8,X2,Z20), (Ra1,Rb8,X2,Z21), (Ra1,Rb8,X2,Z22),(Ra1,Rb8,X2,Z23), (Ra1,Rb8,X2,Z24), (Ra1,Rb8,X2,Z25), (Ra1,Rb8,X2,Z26),(Ra1,Rb8,X2,Z27), (Ra1,Rb8,X2,Z28), (Ra1,Rb8,X2,Z29), (Ra1,Rb8,X2,Z30),(Ra1,Rb8,X2,Z31), (Ra1,Rb8,X2,Z32), (Ra1,Rb8,X2,Z33), (Ra1,Rb8,X2,Z34),(Ra1,Rb8,X2,Z35), (Ra1,Rb8,X2,Z36), (Ra1,Rb8,X2,Z37), (Ra1,Rb8,X2,Z38),(Ra1,Rb8,X2,Z39), (Ra2,Rb1,X1,Z1), (Ra2,Rb1,X1,Z2), (Ra2,Rb1,X1,Z3),(Ra2,Rb1,X1,Z4), (Ra2,Rb1,X1,Z5), (Ra2,Rb1,X1,Z6), (Ra2,Rb1,X1,Z7),(Ra2,Rb1,X1,Z8), (Ra2,Rb1,X1,Z9), (Ra2,Rb1,X1,Z10), (Ra2,Rb1,X1,Z11),(Ra2,Rb1,X1,Z12), (Ra2,Rb1,X1,Z13), (Ra2,Rb1,X1,Z14), (Ra2,Rb1,X1,Z15),(Ra2,Rb1,X1,Z16), (Ra2,Rb1,X1,Z17), (Ra2,Rb1,X1,Z18), (Ra2,Rb1,X1,Z19),(Ra2,Rb1,X1,Z20), (Ra2,Rb1,X1,Z21), (Ra2,Rb1,X1,Z22), (Ra2,Rb1,X1,Z23),(Ra2,Rb1,X1,Z24), (Ra2,Rb1,X1,Z25), (Ra2,Rb1,X1,Z26), (Ra2,Rb1,X1,Z27),(Ra2,Rb1,X1,Z28), (Ra2,Rb1,X1,Z29), (Ra2,Rb1,X1,Z30), (Ra2,Rb1,X1,Z31),(Ra2,Rb1,X1,Z32), (Ra2,Rb1,X1,Z33), (Ra2,Rb1,X1,Z34), (Ra2,Rb1,X1,Z35),(Ra2,Rb1,X1,Z36), (Ra2,Rb1,X1,Z37), (Ra2,Rb1,X1,Z38), (Ra2,Rb1,X1,Z39),(Ra2,Rb1,X2,Z1), (Ra2,Rb1,X2,Z2), (Ra2,Rb1,X2,Z3), (Ra2,Rb1,X2,Z4),(Ra2,Rb1,X2,Z5), (Ra2,Rb1,X2,Z6), (Ra2,Rb1,X2,Z7), (Ra2,Rb1,X2,Z8),(Ra2,Rb1,X2,Z9), (Ra2,Rb1,X2,Z10), (Ra2,Rb1,X2,Z11), (Ra2,Rb1,X2,Z12),(Ra2,Rb1,X2,Z13), (Ra2,Rb1,X2,Z14), (Ra2,Rb1,X2,Z15), (Ra2,Rb1,X2,Z16),(Ra2,Rb1,X2,Z17), (Ra2,Rb1,X2,Z18), (Ra2,Rb1,X2,Z19), (Ra2,Rb1,X2,Z20),(Ra2,Rb1,X2,Z21), (Ra2,Rb1,X2,Z22), (Ra2,Rb1,X2,Z23), (Ra2,Rb1,X2,Z24),(Ra2,Rb1,X2,Z25), (Ra2,Rb1,X2,Z26), (Ra2,Rb1,X2,Z27), (Ra2,Rb1,X2,Z28),(Ra2,Rb1,X2,Z29), (Ra2,Rb1,X2,Z30), (Ra2,Rb1,X2,Z31), (Ra2,Rb1,X2,Z32),(Ra2,Rb1,X2,Z33), (Ra2,Rb1,X2,Z34), (Ra2,Rb1,X2,Z35), (Ra2,Rb1,X2,Z36),(Ra2,Rb1,X2,Z37), (Ra2,Rb1,X2,Z38), (Ra2,Rb1,X2,Z39), (Ra2,Rb2,X1,Z1),(Ra2,Rb2,X1,Z2), (Ra2,Rb2,X1,Z3), (Ra2,Rb2,X1,Z4), (Ra2,Rb2,X1,Z5),(Ra2,Rb2,X1,Z6), (Ra2,Rb2,X1,Z7), (Ra2,Rb2,X1,Z8), (Ra2,Rb2,X1,Z9),(Ra2,Rb2,X1,Z10), (Ra2,Rb2,X1,Z11), (Ra2,Rb2,X1,Z12), (Ra2,Rb2,X1,Z13),(Ra2,Rb2,X1,Z14), (Ra2,Rb2,X1,Z15), (Ra2,Rb2,X1,Z16), (Ra2,Rb2,X1,Z17),(Ra2,Rb2,X1,Z18), (Ra2,Rb2,X1,Z19), (Ra2,Rb2,X1,Z20), (Ra2,Rb2,X1,Z21),(Ra2,Rb2,X1,Z22), (Ra2,Rb2,X1,Z23), (Ra2,Rb2,X1,Z24), (Ra2,Rb2,X1,Z25),(Ra2,Rb2,X1,Z26), (Ra2,Rb2,X1,Z27), (Ra2,Rb2,X1,Z28), (Ra2,Rb2,X1,Z29),(Ra2,Rb2,X1,Z30), (Ra2,Rb2,X1,Z31), (Ra2,Rb2,X1,Z32), (Ra2,Rb2,X1,Z33),(Ra2,Rb2,X1,Z34), (Ra2,Rb2,X1,Z35), (Ra2,Rb2,X1,Z36), (Ra2,Rb2,X1,Z37),(Ra2,Rb2,X1,Z38), (Ra2,Rb2,X1,Z39), (Ra2,Rb2,X2,Z1), (Ra2,Rb2,X2,Z2),(Ra2,Rb2,X2,Z3), (Ra2,Rb2,X2,Z4), (Ra2,Rb2,X2,Z5), (Ra2,Rb2,X2,Z6),(Ra2,Rb2,X2,Z7), (Ra2,Rb2,X2,Z8), (Ra2,Rb2,X2,Z9), (Ra2,Rb2,X2,Z10),(Ra2,Rb2,X2,Z11), (Ra2,Rb2,X2,Z12), (Ra2,Rb2,X2,Z13), (Ra2,Rb2,X2,Z14),(Ra2,Rb2,X2,Z15), (Ra2,Rb2,X2,Z16), (Ra2,Rb2,X2,Z17), (Ra2,Rb2,X2,Z18),(Ra2,Rb2,X2,Z19), (Ra2,Rb2,X2,Z20), (Ra2,Rb2,X2,Z21), (Ra2,Rb2,X2,Z22),(Ra2,Rb2,X2,Z23), (Ra2,Rb2,X2,Z24), (Ra2,Rb2,X2,Z25), (Ra2,Rb2,X2,Z26),(Ra2,Rb2,X2,Z27), (Ra2,Rb2,X2,Z28), (Ra2,Rb2,X2,Z29), (Ra2,Rb2,X2,Z30),(Ra2,Rb2,X2,Z31), (Ra2,Rb2,X2,Z32), (Ra2,Rb2,X2,Z33), (Ra2,Rb2,X2,Z34),(Ra2,Rb2,X2,Z35), (Ra2,Rb2,X2,Z36), (Ra2,Rb2,X2,Z37), (Ra2,Rb2,X2,Z38),(Ra2,Rb2,X2,Z39), (Ra2,Rb3,X1,Z1), (Ra2,Rb3,X1,Z2), (Ra2,Rb3,X1,Z3),(Ra2,Rb3,X1,Z4), (Ra2,Rb3,X1,Z5), (Ra2,Rb3,X1,Z6), (Ra2,Rb3,X1,Z7),(Ra2,Rb3,X1,Z8), (Ra2,Rb3,X1,Z9), (Ra2,Rb3,X1,Z10), (Ra2,Rb3,X1,Z11),(Ra2,Rb3,X1,Z12), (Ra2,Rb3,X1,Z13), (Ra2,Rb3,X1,Z14), (Ra2,Rb3,X1,Z15),(Ra2,Rb3,X1,Z16), (Ra2,Rb3,X1,Z17), (Ra2,Rb3,X1,Z18), (Ra2,Rb3,X1,Z19),(Ra2,Rb3,X1,Z20), (Ra2,Rb3,X1,Z21), (Ra2,Rb3,X1,Z22), (Ra2,Rb3,X1,Z23),(Ra2,Rb3,X1,Z24), (Ra2,Rb3,X1,Z25), (Ra2,Rb3,X1,Z26), (Ra2,Rb3,X1,Z27),(Ra2,Rb3,X1,Z28), (Ra2,Rb3,X1,Z29), (Ra2,Rb3,X1,Z30), (Ra2,Rb3,X1,Z31),(Ra2,Rb3,X1,Z32), (Ra2,Rb3,X1,Z33), (Ra2,Rb3,X1,Z34), (Ra2,Rb3,X1,Z35),(Ra2,Rb3,X1,Z36), (Ra2,Rb3,X1,Z37), (Ra2,Rb3,X1,Z38), (Ra2,Rb3,X1,Z39),(Ra2,Rb3,X2,Z1), (Ra2,Rb3,X2,Z2), (Ra2,Rb3,X2,Z3), (Ra2,Rb3,X2,Z4),(Ra2,Rb3,X2,Z5), (Ra2,Rb3,X2,Z6), (Ra2,Rb3,X2,Z7), (Ra2,Rb3,X2,Z8),(Ra2,Rb3,X2,Z9), (Ra2,Rb3,X2,Z10), (Ra2,Rb3,X2,Z11), (Ra2,Rb3,X2,Z12),(Ra2,Rb3,X2,Z13), (Ra2,Rb3,X2,Z14), (Ra2,Rb3,X2,Z15), (Ra2,Rb3,X2,Z16),(Ra2,Rb3,X2,Z17), (Ra2,Rb3,X2,Z18), (Ra2,Rb3,X2,Z19), (Ra2,Rb3,X2,Z20),(Ra2,Rb3,X2,Z21), (Ra2,Rb3,X2,Z22), (Ra2,Rb3,X2,Z23), (Ra2,Rb3,X2,Z24),(Ra2,Rb3,X2,Z25), (Ra2,Rb3,X2,Z26), (Ra2,Rb3,X2,Z27), (Ra2,Rb3,X2,Z28),(Ra2,Rb3,X2,Z29), (Ra2,Rb3,X2,Z30), (Ra2,Rb3,X2,Z31), (Ra2,Rb3,X2,Z32),(Ra2,Rb3,X2,Z33), (Ra2,Rb3,X2,Z34), (Ra2,Rb3,X2,Z35), (Ra2,Rb3,X2,Z36),(Ra2,Rb3,X2,Z37), (Ra2,Rb3,X2,Z38), (Ra2,Rb3,X2,Z39), (Ra2,Rb4,X1,Z1),(Ra2,Rb4,X1,Z2), (Ra2,Rb4,X1,Z3), (Ra2,Rb4,X1,Z4), (Ra2,Rb4,X1,Z5),(Ra2,Rb4,X1,Z6), (Ra2,Rb4,X1,Z7), (Ra2,Rb4,X1,Z8), (Ra2,Rb4,X1,Z9),(Ra2,Rb4,X1,Z10), (Ra2,Rb4,X1,Z11), (Ra2,Rb4,X1,Z12), (Ra2,Rb4,X1,Z13),(Ra2,Rb4,X1,Z14), (Ra2,Rb4,X1,Z15), (Ra2,Rb4,X1,Z16), (Ra2,Rb4,X1,Z17),(Ra2,Rb4,X1,Z18), (Ra2,Rb4,X1,Z19), (Ra2,Rb4,X1,Z20), (Ra2,Rb4,X1,Z21),(Ra2,Rb4,X1,Z22), (Ra2,Rb4,X1,Z23), (Ra2,Rb4,X1,Z24), (Ra2,Rb4,X1,Z25),(Ra2,Rb4,X1,Z26), (Ra2,Rb4,X1,Z27), (Ra2,Rb4,X1,Z28), (Ra2,Rb4,X1,Z29),(Ra2,Rb4,X1,Z30), (Ra2,Rb4,X1,Z31), (Ra2,Rb4,X1,Z32), (Ra2,Rb4,X1,Z33),(Ra2,Rb4,X1,Z34), (Ra2,Rb4,X1,Z35), (Ra2,Rb4,X1,Z36), (Ra2,Rb4,X1,Z37),(Ra2,Rb4,X1,Z38), (Ra2,Rb4,X1,Z39), (Ra2,Rb4,X2,Z1), (Ra2,Rb4,X2,Z2),(Ra2,Rb4,X2,Z3), (Ra2,Rb4,X2,Z4), (Ra2,Rb4,X2,Z5), (Ra2,Rb4,X2,Z6),(Ra2,Rb4,X2,Z7), (Ra2,Rb4,X2,Z8), (Ra2,Rb4,X2,Z9), (Ra2,Rb4,X2,Z10),(Ra2,Rb4,X2,Z11), (Ra2,Rb4,X2,Z12), (Ra2,Rb4,X2,Z13), (Ra2,Rb4,X2,Z14),(Ra2,Rb4,X2,Z15), (Ra2,Rb4,X2,Z16), (Ra2,Rb4,X2,Z17), (Ra2,Rb4,X2,Z18),(Ra2,Rb4,X2,Z19), (Ra2,Rb4,X2,Z20), (Ra2,Rb4,X2,Z21), (Ra2,Rb4,X2,Z22),(Ra2,Rb4,X2,Z23), (Ra2,Rb4,X2,Z24), (Ra2,Rb4,X2,Z25), (Ra2,Rb4,X2,Z26),(Ra2,Rb4,X2,Z27), (Ra2,Rb4,X2,Z28), (Ra2,Rb4,X2,Z29), (Ra2,Rb4,X2,Z30),(Ra2,Rb4,X2,Z31), (Ra2,Rb4,X2,Z32), (Ra2,Rb4,X2,Z33), (Ra2,Rb4,X2,Z34),(Ra2,Rb4,X2,Z35), (Ra2,Rb4,X2,Z36), (Ra2,Rb4,X2,Z37), (Ra2,Rb4,X2,Z38),(Ra2,Rb4,X2,Z39), (Ra2,Rb5,X1,Z1), (Ra2,Rb5,X1,Z2), (Ra2,Rb5,X1,Z3),(Ra2,Rb5,X1,Z4), (Ra2,Rb5,X1,Z5), (Ra2,Rb5,X1,Z6), (Ra2,Rb5,X1,Z7),(Ra2,Rb5,X1,Z8), (Ra2,Rb5,X1,Z9), (Ra2,Rb5,X1,Z10), (Ra2,Rb5,X1,Z11),(Ra2,Rb5,X1,Z12), (Ra2,Rb5,X1,Z13), (Ra2,Rb5,X1,Z14), (Ra2,Rb5,X1,Z15),(Ra2,Rb5,X1,Z16), (Ra2,Rb5,X1,Z17), (Ra2,Rb5,X1,Z18), (Ra2,Rb5,X1,Z19),(Ra2,Rb5,X1,Z20), (Ra2,Rb5,X1,Z21), (Ra2,Rb5,X1,Z22), (Ra2,Rb5,X1,Z23),(Ra2,Rb5,X1,Z24), (Ra2,Rb5,X1,Z25), (Ra2,Rb5,X1,Z26), (Ra2,Rb5,X1,Z27),(Ra2,Rb5,X1,Z28), (Ra2,Rb5,X1,Z29), (Ra2,Rb5,X1,Z30), (Ra2,Rb5,X1,Z31),(Ra2,Rb5,X1,Z32), (Ra2,Rb5,X1,Z33), (Ra2,Rb5,X1,Z34), (Ra2,Rb5,X1,Z35),(Ra2,Rb5,X1,Z36), (Ra2,Rb5,X1,Z37), (Ra2,Rb5,X1,Z38), (Ra2,Rb5,X1,Z39),(Ra2,Rb5,X2,Z1), (Ra2,Rb5,X2,Z2), (Ra2,Rb5,X2,Z3), (Ra2,Rb5,X2,Z4),(Ra2,Rb5,X2,Z5), (Ra2,Rb5,X2,Z6), (Ra2,Rb5,X2,Z7), (Ra2,Rb5,X2,Z8),(Ra2,Rb5,X2,Z9), (Ra2,Rb5,X2,Z10), (Ra2,Rb5,X2,Z11), (Ra2,Rb5,X2,Z12),(Ra2,Rb5,X2,Z13), (Ra2,Rb5,X2,Z14), (Ra2,Rb5,X2,Z15), (Ra2,Rb5,X2,Z16),(Ra2,Rb5,X2,Z17), (Ra2,Rb5,X2,Z18), (Ra2,Rb5,X2,Z19), (Ra2,Rb5,X2,Z20),(Ra2,Rb5,X2,Z21), (Ra2,Rb5,X2,Z22), (Ra2,Rb5,X2,Z23), (Ra2,Rb5,X2,Z24),(Ra2,Rb5,X2,Z25), (Ra2,Rb5,X2,Z26), (Ra2,Rb5,X2,Z27), (Ra2,Rb5,X2,Z28),(Ra2,Rb5,X2,Z29), (Ra2,Rb5,X2,Z30), (Ra2,Rb5,X2,Z31), (Ra2,Rb5,X2,Z32),(Ra2,Rb5,X2,Z33), (Ra2,Rb5,X2,Z34), (Ra2,Rb5,X2,Z35), (Ra2,Rb5,X2,Z36),(Ra2,Rb5,X2,Z37), (Ra2,Rb5,X2,Z38), (Ra2,Rb5,X2,Z39), (Ra2,Rb6,X1,Z1),(Ra2,Rb6,X1,Z2), (Ra2,Rb6,X1,Z3), (Ra2,Rb6,X1,Z4), (Ra2,Rb6,X1,Z5),(Ra2,Rb6,X1,Z6), (Ra2,Rb6,X1,Z7), (Ra2,Rb6,X1,Z8), (Ra2,Rb6,X1,Z9),(Ra2,Rb6,X1,Z10), (Ra2,Rb6,X1,Z11), (Ra2,Rb6,X1,Z12), (Ra2,Rb6,X1,Z13),(Ra2,Rb6,X1,Z14), (Ra2,Rb6,X1,Z15), (Ra2,Rb6,X1,Z16), (Ra2,Rb6,X1,Z17),(Ra2,Rb6,X1,Z18), (Ra2,Rb6,X1,Z19), (Ra2,Rb6,X1,Z20), (Ra2,Rb6,X1,Z21),(Ra2,Rb6,X1,Z22), (Ra2,Rb6,X1,Z23), (Ra2,Rb6,X1,Z24), (Ra2,Rb6,X1,Z25),(Ra2,Rb6,X1,Z26), (Ra2,Rb6,X1,Z27), (Ra2,Rb6,X1,Z28), (Ra2,Rb6,X1,Z29),(Ra2,Rb6,X1,Z30), (Ra2,Rb6,X1,Z31), (Ra2,Rb6,X1,Z32), (Ra2,Rb6,X1,Z33),(Ra2,Rb6,X1,Z34), (Ra2,Rb6,X1,Z35), (Ra2,Rb6,X1,Z36), (Ra2,Rb6,X1,Z37),(Ra2,Rb6,X1,Z38), (Ra2,Rb6,X1,Z39), (Ra2,Rb6,X2,Z1), (Ra2,Rb6,X2,Z2),(Ra2,Rb6,X2,Z3), (Ra2,Rb6,X2,Z4), (Ra2,Rb6,X2,Z5), (Ra2,Rb6,X2,Z6),(Ra2,Rb6,X2,Z7), (Ra2,Rb6,X2,Z8), (Ra2,Rb6,X2,Z9), (Ra2,Rb6,X2,Z10),(Ra2,Rb6,X2,Z11), (Ra2,Rb6,X2,Z12), (Ra2,Rb6,X2,Z13), (Ra2,Rb6,X2,Z14),(Ra2,Rb6,X2,Z15), (Ra2,Rb6,X2,Z16), (Ra2,Rb6,X2,Z17), (Ra2,Rb6,X2,Z18),(Ra2,Rb6,X2,Z19), (Ra2,Rb6,X2,Z20), (Ra2,Rb6,X2,Z21), (Ra2,Rb6,X2,Z22),(Ra2,Rb6,X2,Z23), (Ra2,Rb6,X2,Z24), (Ra2,Rb6,X2,Z25), (Ra2,Rb6,X2,Z26),(Ra2,Rb6,X2,Z27), (Ra2,Rb6,X2,Z28), (Ra2,Rb6,X2,Z29), (Ra2,Rb6,X2,Z30),(Ra2,Rb6,X2,Z31), (Ra2,Rb6,X2,Z32), (Ra2,Rb6,X2,Z33), (Ra2,Rb6,X2,Z34),(Ra2,Rb6,X2,Z35), (Ra2,Rb6,X2,Z36), (Ra2,Rb6,X2,Z37), (Ra2,Rb6,X2,Z38),(Ra2,Rb6,X2,Z39), (Ra2,Rb7,X1,Z1), (Ra2,Rb7,X1,Z2), (Ra2,Rb7,X1,Z3),(Ra2,Rb7,X1,Z4), (Ra2,Rb7,X1,Z5), (Ra2,Rb7,X1,Z6), (Ra2,Rb7,X1,Z7),(Ra2,Rb7,X1,Z8), (Ra2,Rb7,X1,Z9), (Ra2,Rb7,X1,Z10), (Ra2,Rb7,X1,Z11),(Ra2,Rb7,X1,Z12), (Ra2,Rb7,X1,Z13), (Ra2,Rb7,X1,Z14), (Ra2,Rb7,X1,Z15),(Ra2,Rb7,X1,Z16), (Ra2,Rb7,X1,Z17), (Ra2,Rb7,X1,Z18), (Ra2,Rb7,X1,Z19),(Ra2,Rb7,X1,Z20), (Ra2,Rb7,X1,Z21), (Ra2,Rb7,X1,Z22), (Ra2,Rb7,X1,Z23),(Ra2,Rb7,X1,Z24), (Ra2,Rb7,X1,Z25), (Ra2,Rb7,X1,Z26), (Ra2,Rb7,X1,Z27),(Ra2,Rb7,X1,Z28), (Ra2,Rb7,X1,Z29), (Ra2,Rb7,X1,Z30), (Ra2,Rb7,X1,Z31),(Ra2,Rb7,X1,Z32), (Ra2,Rb7,X1,Z33), (Ra2,Rb7,X1,Z34), (Ra2,Rb7,X1,Z35),(Ra2,Rb7,X1,Z36), (Ra2,Rb7,X1,Z37), (Ra2,Rb7,X1,Z38), (Ra2,Rb7,X1,Z39),(Ra2,Rb7,X2,Z1), (Ra2,Rb7,X2,Z2), (Ra2,Rb7,X2,Z3), (Ra2,Rb7,X2,Z4),(Ra2,Rb7,X2,Z5), (Ra2,Rb7,X2,Z6), (Ra2,Rb7,X2,Z7), (Ra2,Rb7,X2,Z8),(Ra2,Rb7,X2,Z9), (Ra2,Rb7,X2,Z10), (Ra2,Rb7,X2,Z11), (Ra2,Rb7,X2,Z12),(Ra2,Rb7,X2,Z13), (Ra2,Rb7,X2,Z14), (Ra2,Rb7,X2,Z15), (Ra2,Rb7,X2,Z16),(Ra2,Rb7,X2,Z17), (Ra2,Rb7,X2,Z18), (Ra2,Rb7,X2,Z19), (Ra2,Rb7,X2,Z20),(Ra2,Rb7,X2,Z21), (Ra2,Rb7,X2,Z22), (Ra2,Rb7,X2,Z23), (Ra2,Rb7,X2,Z24),(Ra2,Rb7,X2,Z25), (Ra2,Rb7,X2,Z26), (Ra2,Rb7,X2,Z27), (Ra2,Rb7,X2,Z28),(Ra2,Rb7,X2,Z29), (Ra2,Rb7,X2,Z30), (Ra2,Rb7,X2,Z31), (Ra2,Rb7,X2,Z32),(Ra2,Rb7,X2,Z33), (Ra2,Rb7,X2,Z34), (Ra2,Rb7,X2,Z35), (Ra2,Rb7,X2,Z36),(Ra2,Rb7,X2,Z37), (Ra2,Rb7,X2,Z38), (Ra2,Rb7,X2,Z39), (Ra2,Rb8,X1,Z1),(Ra2,Rb8,X1,Z2), (Ra2,Rb8,X1,Z3), (Ra2,Rb8,X1,Z4), (Ra2,Rb8,X1,Z5),(Ra2,Rb8,X1,Z6), (Ra2,Rb8,X1,Z7), (Ra2,Rb8,X1,Z8), (Ra2,Rb8,X1,Z9),(Ra2,Rb8,X1,Z10), (Ra2,Rb8,X1,Z11), (Ra2,Rb8,X1,Z12), (Ra2,Rb8,X1,Z13),(Ra2,Rb8,X1,Z14), (Ra2,Rb8,X1,Z15), (Ra2,Rb8,X1,Z16), (Ra2,Rb8,X1,Z17),(Ra2,Rb8,X1,Z18), (Ra2,Rb8,X1,Z19), (Ra2,Rb8,X1,Z20), (Ra2,Rb8,X1,Z21),(Ra2,Rb8,X1,Z22), (Ra2,Rb8,X1,Z23), (Ra2,Rb8,X1,Z24), (Ra2,Rb8,X1,Z25),(Ra2,Rb8,X1,Z26), (Ra2,Rb8,X1,Z27), (Ra2,Rb8,X1,Z28), (Ra2,Rb8,X1,Z29),(Ra2,Rb8,X1,Z30), (Ra2,Rb8,X1,Z31), (Ra2,Rb8,X1,Z32), (Ra2,Rb8,X1,Z33),(Ra2,Rb8,X1,Z34), (Ra2,Rb8,X1,Z35), (Ra2,Rb8,X1,Z36), (Ra2,Rb8,X1,Z37),(Ra2,Rb8,X1,Z38), (Ra2,Rb8,X1,Z39), (Ra2,Rb8,X2,Z1), (Ra2,Rb8,X2,Z2),(Ra2,Rb8,X2,Z3), (Ra2,Rb8,X2,Z4), (Ra2,Rb8,X2,Z5), (Ra2,Rb8,X2,Z6),(Ra2,Rb8,X2,Z7), (Ra2,Rb8,X2,Z8), (Ra2,Rb8,X2,Z9), (Ra2,Rb8,X2,Z10),(Ra2,Rb8,X2,Z11), (Ra2,Rb8,X2,Z12), (Ra2,Rb8,X2,Z13), (Ra2,Rb8,X2,Z14),(Ra2,Rb8,X2,Z15), (Ra2,Rb8,X2,Z16), (Ra2,Rb8,X2,Z17), (Ra2,Rb8,X2,Z18),(Ra2,Rb8,X2,Z19), (Ra2,Rb8,X2,Z20), (Ra2,Rb8,X2,Z21), (Ra2,Rb8,X2,Z22),(Ra2,Rb8,X2,Z23), (Ra2,Rb8,X2,Z24), (Ra2,Rb8,X2,Z25), (Ra2,Rb8,X2,Z26),(Ra2,Rb8,X2,Z27), (Ra2,Rb8,X2,Z28), (Ra2,Rb8,X2,Z29), (Ra2,Rb8,X2,Z30),(Ra2,Rb8,X2,Z31), (Ra2,Rb8,X2,Z32), (Ra2,Rb8,X2,Z33), (Ra2,Rb8,X2,Z34),(Ra2,Rb8,X2,Z35), (Ra2,Rb8,X2,Z36), (Ra2,Rb8,X2,Z37), (Ra2,Rb8,X2,Z38),(Ra2,Rb8,X2,Z39), (Ra3,Rb1,X1,Z1), (Ra3,Rb1,X1,Z2), (Ra3,Rb1,X1,Z3),(Ra3,Rb1,X1,Z4), (Ra3,Rb1,X1,Z5), (Ra3,Rb1,X1,Z6), (Ra3,Rb1,X1,Z7),(Ra3,Rb1,X1,Z8), (Ra3,Rb1,X1,Z9), (Ra3,Rb1,X1,Z10), (Ra3,Rb1,X1,Z11),(Ra3,Rb1,X1,Z12), (Ra3,Rb1,X1,Z13), (Ra3,Rb1,X1,Z14), (Ra3,Rb1,X1,Z15),(Ra3,Rb1,X1,Z16), (Ra3,Rb1,X1,Z17), (Ra3,Rb1,X1,Z18), (Ra3,Rb1,X1,Z19),(Ra3,Rb1,X1,Z20), (Ra3,Rb1,X1,Z21), (Ra3,Rb1,X1,Z22), (Ra3,Rb1,X1,Z23),(Ra3,Rb1,X1,Z24), (Ra3,Rb1,X1,Z25), (Ra3,Rb1,X1,Z26), (Ra3,Rb1,X1,Z27),(Ra3,Rb1,X1,Z28), (Ra3,Rb1,X1,Z29), (Ra3,Rb1,X1,Z30), (Ra3,Rb1,X1,Z31),(Ra3,Rb1,X1,Z32), (Ra3,Rb1,X1,Z33), (Ra3,Rb1,X1,Z34), (Ra3,Rb1,X1,Z35),(Ra3,Rb1,X1,Z36), (Ra3,Rb1,X1,Z37), (Ra3,Rb1,X1,Z38), (Ra3,Rb1,X1,Z39),(Ra3,Rb1,X2,Z1), (Ra3,Rb1,X2,Z2), (Ra3,Rb1,X2,Z3), (Ra3,Rb1,X2,Z4),(Ra3,Rb1,X2,Z5), (Ra3,Rb1,X2,Z6), (Ra3,Rb1,X2,Z7), (Ra3,Rb1,X2,Z8),(Ra3,Rb1,X2,Z9), (Ra3,Rb1,X2,Z10), (Ra3,Rb1,X2,Z11), (Ra3,Rb1,X2,Z12),(Ra3,Rb1,X2,Z13), (Ra3,Rb1,X2,Z14), (Ra3,Rb1,X2,Z15), (Ra3,Rb1,X2,Z16),(Ra3,Rb1,X2,Z17), (Ra3,Rb1,X2,Z18), (Ra3,Rb1,X2,Z19), (Ra3,Rb1,X2,Z20),(Ra3,Rb1,X2,Z21), (Ra3,Rb1,X2,Z22), (Ra3,Rb1,X2,Z23), (Ra3,Rb1,X2,Z24),(Ra3,Rb1,X2,Z25), (Ra3,Rb1,X2,Z26), (Ra3,Rb1,X2,Z27), (Ra3,Rb1,X2,Z28),(Ra3,Rb1,X2,Z29), (Ra3,Rb1,X2,Z30), (Ra3,Rb1,X2,Z31), (Ra3,Rb1,X2,Z32),(Ra3,Rb1,X2,Z33), (Ra3,Rb1,X2,Z34), (Ra3,Rb1,X2,Z35), (Ra3,Rb1,X2,Z36),(Ra3,Rb1,X2,Z37), (Ra3,Rb1,X2,Z38), (Ra3,Rb1,X2,Z39), (Ra3,Rb2,X1,Z1),(Ra3,Rb2,X1,Z2), (Ra3,Rb2,X1,Z3), (Ra3,Rb2,X1,Z4), (Ra3,Rb2,X1,Z5),(Ra3,Rb2,X1,Z6), (Ra3,Rb2,X1,Z7), (Ra3,Rb2,X1,Z8), (Ra3,Rb2,X1,Z9),(Ra3,Rb2,X1,Z10), (Ra3,Rb2,X1,Z11), (Ra3,Rb2,X1,Z12), (Ra3,Rb2,X1,Z13),(Ra3,Rb2,X1,Z14), (Ra3,Rb2,X1,Z15), (Ra3,Rb2,X1,Z16), (Ra3,Rb2,X1,Z17),(Ra3,Rb2,X1,Z18), (Ra3,Rb2,X1,Z19), (Ra3,Rb2,X1,Z20), (Ra3,Rb2,X1,Z21),(Ra3,Rb2,X1,Z22), (Ra3,Rb2,X1,Z23), (Ra3,Rb2,X1,Z24), (Ra3,Rb2,X1,Z25),(Ra3,Rb2,X1,Z26), (Ra3,Rb2,X1,Z27), (Ra3,Rb2,X1,Z28), (Ra3,Rb2,X1,Z29),(Ra3,Rb2,X1,Z30), (Ra3,Rb2,X1,Z31), (Ra3,Rb2,X1,Z32), (Ra3,Rb2,X1,Z33),(Ra3,Rb2,X1,Z34), (Ra3,Rb2,X1,Z35), (Ra3,Rb2,X1,Z36), (Ra3,Rb2,X1,Z37),(Ra3,Rb2,X1,Z38), (Ra3,Rb2,X1,Z39), (Ra3,Rb2,X2,Z1), (Ra3,Rb2,X2,Z2),(Ra3,Rb2,X2,Z3), (Ra3,Rb2,X2,Z4), (Ra3,Rb2,X2,Z5), (Ra3,Rb2,X2,Z6),(Ra3,Rb2,X2,Z7), (Ra3,Rb2,X2,Z8), (Ra3,Rb2,X2,Z9), (Ra3,Rb2,X2,Z10),(Ra3,Rb2,X2,Z11), (Ra3,Rb2,X2,Z12), (Ra3,Rb2,X2,Z13), (Ra3,Rb2,X2,Z14),(Ra3,Rb2,X2,Z15), (Ra3,Rb2,X2,Z16), (Ra3,Rb2,X2,Z17), (Ra3,Rb2,X2,Z18),(Ra3,Rb2,X2,Z19), (Ra3,Rb2,X2,Z20), (Ra3,Rb2,X2,Z21), (Ra3,Rb2,X2,Z22),(Ra3,Rb2,X2,Z23), (Ra3,Rb2,X2,Z24), (Ra3,Rb2,X2,Z25), (Ra3,Rb2,X2,Z26),(Ra3,Rb2,X2,Z27), (Ra3,Rb2,X2,Z28), (Ra3,Rb2,X2,Z29), (Ra3,Rb2,X2,Z30),(Ra3,Rb2,X2,Z31), (Ra3,Rb2,X2,Z32), (Ra3,Rb2,X2,Z33), (Ra3,Rb2,X2,Z34),(Ra3,Rb2,X2,Z35), (Ra3,Rb2,X2,Z36), (Ra3,Rb2,X2,Z37), (Ra3,Rb2,X2,Z38),(Ra3,Rb2,X2,Z39), (Ra3,Rb3,X1,Z1), (Ra3,Rb3,X1,Z2), (Ra3,Rb3,X1,Z3),(Ra3,Rb3,X1,Z4), (Ra3,Rb3,X1,Z5), (Ra3,Rb3,X1,Z6), (Ra3,Rb3,X1,Z7),(Ra3,Rb3,X1,Z8), (Ra3,Rb3,X1,Z9), (Ra3,Rb3,X1,Z10), (Ra3,Rb3,X1,Z11),(Ra3,Rb3,X1,Z12), (Ra3,Rb3,X1,Z13), (Ra3,Rb3,X1,Z14), (Ra3,Rb3,X1,Z15),(Ra3,Rb3,X1,Z16), (Ra3,Rb3,X1,Z17), (Ra3,Rb3,X1,Z18), (Ra3,Rb3,X1,Z19),(Ra3,Rb3,X1,Z20), (Ra3,Rb3,X1,Z21), (Ra3,Rb3,X1,Z22), (Ra3,Rb3,X1,Z23),(Ra3,Rb3,X1,Z24), (Ra3,Rb3,X1,Z25), (Ra3,Rb3,X1,Z26), (Ra3,Rb3,X1,Z27),(Ra3,Rb3,X1,Z28), (Ra3,Rb3,X1,Z29), (Ra3,Rb3,X1,Z30), (Ra3,Rb3,X1,Z31),(Ra3,Rb3,X1,Z32), (Ra3,Rb3,X1,Z33), (Ra3,Rb3,X1,Z34), (Ra3,Rb3,X1,Z35),(Ra3,Rb3,X1,Z36), (Ra3,Rb3,X1,Z37), (Ra3,Rb3,X1,Z38), (Ra3,Rb3,X1,Z39),(Ra3,Rb3,X2,Z1), (Ra3,Rb3,X2,Z2), (Ra3,Rb3,X2,Z3), (Ra3,Rb3,X2,Z4),(Ra3,Rb3,X2,Z5), (Ra3,Rb3,X2,Z6), (Ra3,Rb3,X2,Z7), (Ra3,Rb3,X2,Z8),(Ra3,Rb3,X2,Z9), (Ra3,Rb3,X2,Z10), (Ra3,Rb3,X2,Z11), (Ra3,Rb3,X2,Z12),(Ra3,Rb3,X2,Z13), (Ra3,Rb3,X2,Z14), (Ra3,Rb3,X2,Z15), (Ra3,Rb3,X2,Z16),(Ra3,Rb3,X2,Z17), (Ra3,Rb3,X2,Z18), (Ra3,Rb3,X2,Z19), (Ra3,Rb3,X2,Z20),(Ra3,Rb3,X2,Z21), (Ra3,Rb3,X2,Z22), (Ra3,Rb3,X2,Z23), (Ra3,Rb3,X2,Z24),(Ra3,Rb3,X2,Z25), (Ra3,Rb3,X2,Z26), (Ra3,Rb3,X2,Z27), (Ra3,Rb3,X2,Z28),(Ra3,Rb3,X2,Z29), (Ra3,Rb3,X2,Z30), (Ra3,Rb3,X2,Z31), (Ra3,Rb3,X2,Z32),(Ra3,Rb3,X2,Z33), (Ra3,Rb3,X2,Z34), (Ra3,Rb3,X2,Z35), (Ra3,Rb3,X2,Z36),(Ra3,Rb3,X2,Z37), (Ra3,Rb3,X2,Z38), (Ra3,Rb3,X2,Z39), (Ra3,Rb4,X1,Z1),(Ra3,Rb4,X1,Z2), (Ra3,Rb4,X1,Z3), (Ra3,Rb4,X1,Z4), (Ra3,Rb4,X1,Z5),(Ra3,Rb4,X1,Z6), (Ra3,Rb4,X1,Z7), (Ra3,Rb4,X1,Z8), (Ra3,Rb4,X1,Z9),(Ra3,Rb4,X1,Z10), (Ra3,Rb4,X1,Z11), (Ra3,Rb4,X1,Z12), (Ra3,Rb4,X1,Z13),(Ra3,Rb4,X1,Z14), (Ra3,Rb4,X1,Z15), (Ra3,Rb4,X1,Z16), (Ra3,Rb4,X1,Z17),(Ra3,Rb4,X1,Z18), (Ra3,Rb4,X1,Z19), (Ra3,Rb4,X1,Z20), (Ra3,Rb4,X1,Z21),(Ra3,Rb4,X1,Z22), (Ra3,Rb4,X1,Z23), (Ra3,Rb4,X1,Z24), (Ra3,Rb4,X1,Z25),(Ra3,Rb4,X1,Z26), (Ra3,Rb4,X1,Z27), (Ra3,Rb4,X1,Z28), (Ra3,Rb4,X1,Z29),(Ra3,Rb4,X1,Z30), (Ra3,Rb4,X1,Z31), (Ra3,Rb4,X1,Z32), (Ra3,Rb4,X1,Z33),(Ra3,Rb4,X1,Z34), (Ra3,Rb4,X1,Z35), (Ra3,Rb4,X1,Z36), (Ra3,Rb4,X1,Z37),(Ra3,Rb4,X1,Z38), (Ra3,Rb4,X1,Z39), (Ra3,Rb4,X2,Z1), (Ra3,Rb4,X2,Z2),(Ra3,Rb4,X2,Z3), (Ra3,Rb4,X2,Z4), (Ra3,Rb4,X2,Z5), (Ra3,Rb4,X2,Z6),(Ra3,Rb4,X2,Z7), (Ra3,Rb4,X2,Z8), (Ra3,Rb4,X2,Z9), (Ra3,Rb4,X2,Z10),(Ra3,Rb4,X2,Z11), (Ra3,Rb4,X2,Z12), (Ra3,Rb4,X2,Z13), (Ra3,Rb4,X2,Z14),(Ra3,Rb4,X2,Z15), (Ra3,Rb4,X2,Z16), (Ra3,Rb4,X2,Z17), (Ra3,Rb4,X2,Z18),(Ra3,Rb4,X2,Z19), (Ra3,Rb4,X2,Z20), (Ra3,Rb4,X2,Z21), (Ra3,Rb4,X2,Z22),(Ra3,Rb4,X2,Z23), (Ra3,Rb4,X2,Z24), (Ra3,Rb4,X2,Z25), (Ra3,Rb4,X2,Z26),(Ra3,Rb4,X2,Z27), (Ra3,Rb4,X2,Z28), (Ra3,Rb4,X2,Z29), (Ra3,Rb4,X2,Z30),(Ra3,Rb4,X2,Z31), (Ra3,Rb4,X2,Z32), (Ra3,Rb4,X2,Z33), (Ra3,Rb4,X2,Z34),(Ra3,Rb4,X2,Z35), (Ra3,Rb4,X2,Z36), (Ra3,Rb4,X2,Z37), (Ra3,Rb4,X2,Z38),(Ra3,Rb4,X2,Z39), (Ra3,Rb5,X1,Z1), (Ra3,Rb5,X1,Z2), (Ra3,Rb5,X1,Z3),(Ra3,Rb5,X1,Z4), (Ra3,Rb5,X1,Z5), (Ra3,Rb5,X1,Z6), (Ra3,Rb5,X1,Z7),(Ra3,Rb5,X1,Z8), (Ra3,Rb5,X1,Z9), (Ra3,Rb5,X1,Z10), (Ra3,Rb5,X1,Z11),(Ra3,Rb5,X1,Z12), (Ra3,Rb5,X1,Z13), (Ra3,Rb5,X1,Z14), (Ra3,Rb5,X1,Z15),(Ra3,Rb5,X1,Z16), (Ra3,Rb5,X1,Z17), (Ra3,Rb5,X1,Z18), (Ra3,Rb5,X1,Z19),(Ra3,Rb5,X1,Z20), (Ra3,Rb5,X1,Z21), (Ra3,Rb5,X1,Z22), (Ra3,Rb5,X1,Z23),(Ra3,Rb5,X1,Z24), (Ra3,Rb5,X1,Z25), (Ra3,Rb5,X1,Z26), (Ra3,Rb5,X1,Z27),(Ra3,Rb5,X1,Z28), (Ra3,Rb5,X1,Z29), (Ra3,Rb5,X1,Z30), (Ra3,Rb5,X1,Z31),(Ra3,Rb5,X1,Z32), (Ra3,Rb5,X1,Z33), (Ra3,Rb5,X1,Z34), (Ra3,Rb5,X1,Z35),(Ra3,Rb5,X1,Z36), (Ra3,Rb5,X1,Z37), (Ra3,Rb5,X1,Z38), (Ra3,Rb5,X1,Z39),(Ra3,Rb5,X2,Z1), (Ra3,Rb5,X2,Z2), (Ra3,Rb5,X2,Z3), (Ra3,Rb5,X2,Z4),(Ra3,Rb5,X2,Z5), (Ra3,Rb5,X2,Z6), (Ra3,Rb5,X2,Z7), (Ra3,Rb5,X2,Z8),(Ra3,Rb5,X2,Z9), (Ra3,Rb5,X2,Z10), (Ra3,Rb5,X2,Z11), (Ra3,Rb5,X2,Z12),(Ra3,Rb5,X2,Z13), (Ra3,Rb5,X2,Z14), (Ra3,Rb5,X2,Z15), (Ra3,Rb5,X2,Z16),(Ra3,Rb5,X2,Z17), (Ra3,Rb5,X2,Z18), (Ra3,Rb5,X2,Z19), (Ra3,Rb5,X2,Z20),(Ra3,Rb5,X2,Z21), (Ra3,Rb5,X2,Z22), (Ra3,Rb5,X2,Z23), (Ra3,Rb5,X2,Z24),(Ra3,Rb5,X2,Z25), (Ra3,Rb5,X2,Z26), (Ra3,Rb5,X2,Z27), (Ra3,Rb5,X2,Z28),(Ra3,Rb5,X2,Z29), (Ra3,Rb5,X2,Z30), (Ra3,Rb5,X2,Z31), (Ra3,Rb5,X2,Z32),(Ra3,Rb5,X2,Z33), (Ra3,Rb5,X2,Z34), (Ra3,Rb5,X2,Z35), (Ra3,Rb5,X2,Z36),(Ra3,Rb5,X2,Z37), (Ra3,Rb5,X2,Z38), (Ra3,Rb5,X2,Z39), (Ra3,Rb6,X1,Z1),(Ra3,Rb6,X1,Z2), (Ra3,Rb6,X1,Z3), (Ra3,Rb6,X1,Z4), (Ra3,Rb6,X1,Z5),(Ra3,Rb6,X1,Z6), (Ra3,Rb6,X1,Z7), (Ra3,Rb6,X1,Z8), (Ra3,Rb6,X1,Z9),(Ra3,Rb6,X1,Z10), (Ra3,Rb6,X1,Z11), (Ra3,Rb6,X1,Z12), (Ra3,Rb6,X1,Z13),(Ra3,Rb6,X1,Z14), (Ra3,Rb6,X1,Z15), (Ra3,Rb6,X1,Z16), (Ra3,Rb6,X1,Z17),(Ra3,Rb6,X1,Z18), (Ra3,Rb6,X1,Z19), (Ra3,Rb6,X1,Z20), (Ra3,Rb6,X1,Z21),(Ra3,Rb6,X1,Z22), (Ra3,Rb6,X1,Z23), (Ra3,Rb6,X1,Z24), (Ra3,Rb6,X1,Z25),(Ra3,Rb6,X1,Z26), (Ra3,Rb6,X1,Z27), (Ra3,Rb6,X1,Z28), (Ra3,Rb6,X1,Z29),(Ra3,Rb6,X1,Z30), (Ra3,Rb6,X1,Z31), (Ra3,Rb6,X1,Z32), (Ra3,Rb6,X1,Z33),(Ra3,Rb6,X1,Z34), (Ra3,Rb6,X1,Z35), (Ra3,Rb6,X1,Z36), (Ra3,Rb6,X1,Z37),(Ra3,Rb6,X1,Z38), (Ra3,Rb6,X1,Z39), (Ra3,Rb6,X2,Z1), (Ra3,Rb6,X2,Z2),(Ra3,Rb6,X2,Z3), (Ra3,Rb6,X2,Z4), (Ra3,Rb6,X2,Z5), (Ra3,Rb6,X2,Z6),(Ra3,Rb6,X2,Z7), (Ra3,Rb6,X2,Z8), (Ra3,Rb6,X2,Z9), (Ra3,Rb6,X2,Z10),(Ra3,Rb6,X2,Z11), (Ra3,Rb6,X2,Z12), (Ra3,Rb6,X2,Z13), (Ra3,Rb6,X2,Z14),(Ra3,Rb6,X2,Z15), (Ra3,Rb6,X2,Z16), (Ra3,Rb6,X2,Z17), (Ra3,Rb6,X2,Z18),(Ra3,Rb6,X2,Z19), (Ra3,Rb6,X2,Z20), (Ra3,Rb6,X2,Z21), (Ra3,Rb6,X2,Z22),(Ra3,Rb6,X2,Z23), (Ra3,Rb6,X2,Z24), (Ra3,Rb6,X2,Z25), (Ra3,Rb6,X2,Z26),(Ra3,Rb6,X2,Z27), (Ra3,Rb6,X2,Z28), (Ra3,Rb6,X2,Z29), (Ra3,Rb6,X2,Z30),(Ra3,Rb6,X2,Z31), (Ra3,Rb6,X2,Z32), (Ra3,Rb6,X2,Z33), (Ra3,Rb6,X2,Z34),(Ra3,Rb6,X2,Z35), (Ra3,Rb6,X2,Z36), (Ra3,Rb6,X2,Z37), (Ra3,Rb6,X2,Z38),(Ra3,Rb6,X2,Z39), (Ra3,Rb7,X1,Z1), (Ra3,Rb7,X1,Z2), (Ra3,Rb7,X1,Z3),(Ra3,Rb7,X1,Z4), (Ra3,Rb7,X1,Z5), (Ra3,Rb7,X1,Z6), (Ra3,Rb7,X1,Z7),(Ra3,Rb7,X1,Z8), (Ra3,Rb7,X1,Z9), (Ra3,Rb7,X1,Z10), (Ra3,Rb7,X1,Z11),(Ra3,Rb7,X1,Z12), (Ra3,Rb7,X1,Z13), (Ra3,Rb7,X1,Z14), (Ra3,Rb7,X1,Z15),(Ra3,Rb7,X1,Z16), (Ra3,Rb7,X1,Z17), (Ra3,Rb7,X1,Z18), (Ra3,Rb7,X1,Z19),(Ra3,Rb7,X1,Z20), (Ra3,Rb7,X1,Z21), (Ra3,Rb7,X1,Z22), (Ra3,Rb7,X1,Z23),(Ra3,Rb7,X1,Z24), (Ra3,Rb7,X1,Z25), (Ra3,Rb7,X1,Z26), (Ra3,Rb7,X1,Z27),(Ra3,Rb7,X1,Z28), (Ra3,Rb7,X1,Z29), (Ra3,Rb7,X1,Z30), (Ra3,Rb7,X1,Z31),(Ra3,Rb7,X1,Z32), (Ra3,Rb7,X1,Z33), (Ra3,Rb7,X1,Z34), (Ra3,Rb7,X1,Z35),(Ra3,Rb7,X1,Z36), (Ra3,Rb7,X1,Z37), (Ra3,Rb7,X1,Z38), (Ra3,Rb7,X1,Z39),(Ra3,Rb7,X2,Z1), (Ra3,Rb7,X2,Z2), (Ra3,Rb7,X2,Z3), (Ra3,Rb7,X2,Z4),(Ra3,Rb7,X2,Z5), (Ra3,Rb7,X2,Z6), (Ra3,Rb7,X2,Z7), (Ra3,Rb7,X2,Z8),(Ra3,Rb7,X2,Z9), (Ra3,Rb7,X2,Z10), (Ra3,Rb7,X2,Z11), (Ra3,Rb7,X2,Z12),(Ra3,Rb7,X2,Z13), (Ra3,Rb7,X2,Z14), (Ra3,Rb7,X2,Z15), (Ra3,Rb7,X2,Z16),(Ra3,Rb7,X2,Z17), (Ra3,Rb7,X2,Z18), (Ra3,Rb7,X2,Z19), (Ra3,Rb7,X2,Z20),(Ra3,Rb7,X2,Z21), (Ra3,Rb7,X2,Z22), (Ra3,Rb7,X2,Z23), (Ra3,Rb7,X2,Z24),(Ra3,Rb7,X2,Z25), (Ra3,Rb7,X2,Z26), (Ra3,Rb7,X2,Z27), (Ra3,Rb7,X2,Z28),(Ra3,Rb7,X2,Z29), (Ra3,Rb7,X2,Z30), (Ra3,Rb7,X2,Z31), (Ra3,Rb7,X2,Z32),(Ra3,Rb7,X2,Z33), (Ra3,Rb7,X2,Z34), (Ra3,Rb7,X2,Z35), (Ra3,Rb7,X2,Z36),(Ra3,Rb7,X2,Z37), (Ra3,Rb7,X2,Z38), (Ra3,Rb7,X2,Z39), (Ra3,Rb8,X1,Z1),(Ra3,Rb8,X1,Z2), (Ra3,Rb8,X1,Z3), (Ra3,Rb8,X1,Z4), (Ra3,Rb8,X1,Z5),(Ra3,Rb8,X1,Z6), (Ra3,Rb8,X1,Z7), (Ra3,Rb8,X1,Z8), (Ra3,Rb8,X1,Z9),(Ra3,Rb8,X1,Z10), (Ra3,Rb8,X1,Z11), (Ra3,Rb8,X1,Z12), (Ra3,Rb8,X1,Z13),(Ra3,Rb8,X1,Z14), (Ra3,Rb8,X1,Z15), (Ra3,Rb8,X1,Z16), (Ra3,Rb8,X1,Z17),(Ra3,Rb8,X1,Z18), (Ra3,Rb8,X1,Z19), (Ra3,Rb8,X1,Z20), (Ra3,Rb8,X1,Z21),(Ra3,Rb8,X1,Z22), (Ra3,Rb8,X1,Z23), (Ra3,Rb8,X1,Z24), (Ra3,Rb8,X1,Z25),(Ra3,Rb8,X1,Z26), (Ra3,Rb8,X1,Z27), (Ra3,Rb8,X1,Z28), (Ra3,Rb8,X1,Z29),(Ra3,Rb8,X1,Z30), (Ra3,Rb8,X1,Z31), (Ra3,Rb8,X1,Z32), (Ra3,Rb8,X1,Z33),(Ra3,Rb8,X1,Z34), (Ra3,Rb8,X1,Z35), (Ra3,Rb8,X1,Z36), (Ra3,Rb8,X1,Z37),(Ra3,Rb8,X1,Z38), (Ra3,Rb8,X1,Z39), (Ra3,Rb8,X2,Z1), (Ra3,Rb8,X2,Z2),(Ra3,Rb8,X2,Z3), (Ra3,Rb8,X2,Z4), (Ra3,Rb8,X2,Z5), (Ra3,Rb8,X2,Z6),(Ra3,Rb8,X2,Z7), (Ra3,Rb8,X2,Z8), (Ra3,Rb8,X2,Z9), (Ra3,Rb8,X2,Z10),(Ra3,Rb8,X2,Z11), (Ra3,Rb8,X2,Z12), (Ra3,Rb8,X2,Z13), (Ra3,Rb8,X2,Z14),(Ra3,Rb8,X2,Z15), (Ra3,Rb8,X2,Z16), (Ra3,Rb8,X2,Z17), (Ra3,Rb8,X2,Z18),(Ra3,Rb8,X2,Z19), (Ra3,Rb8,X2,Z20), (Ra3,Rb8,X2,Z21), (Ra3,Rb8,X2,Z22),(Ra3,Rb8,X2,Z23), (Ra3,Rb8,X2,Z24), (Ra3,Rb8,X2,Z25), (Ra3,Rb8,X2,Z26),(Ra3,Rb8,X2,Z27), (Ra3,Rb8,X2,Z28), (Ra3,Rb8,X2,Z29), (Ra3,Rb8,X2,Z30),(Ra3,Rb8,X2,Z31), (Ra3,Rb8,X2,Z32), (Ra3,Rb8,X2,Z33), (Ra3,Rb8,X2,Z34),(Ra3,Rb8,X2,Z35), (Ra3,Rb8,X2,Z36), (Ra3,Rb8,X2,Z37), (Ra3,Rb8,X2,Z38),(Ra3,Rb8,X2,Z39), (Ra4,Rb1,X1,Z1), (Ra4,Rb1,X1,Z2), (Ra4,Rb1,X1,Z3),(Ra4,Rb1,X1,Z4), (Ra4,Rb1,X1,Z5), (Ra4,Rb1,X1,Z6), (Ra4,Rb1,X1,Z7),(Ra4,Rb1,X1,Z8), (Ra4,Rb1,X1,Z9), (Ra4,Rb1,X1,Z10), (Ra4,Rb1,X1,Z11),(Ra4,Rb1,X1,Z12), (Ra4,Rb1,X1,Z13), (Ra4,Rb1,X1,Z14), (Ra4,Rb1,X1,Z15),(Ra4,Rb1,X1,Z16), (Ra4,Rb1,X1,Z17), (Ra4,Rb1,X1,Z18), (Ra4,Rb1,X1,Z19),(Ra4,Rb1,X1,Z20), (Ra4,Rb1,X1,Z21), (Ra4,Rb1,X1,Z22), (Ra4,Rb1,X1,Z23),(Ra4,Rb1,X1,Z24), (Ra4,Rb1,X1,Z25), (Ra4,Rb1,X1,Z26), (Ra4,Rb1,X1,Z27),(Ra4,Rb1,X1,Z28), (Ra4,Rb1,X1,Z29), (Ra4,Rb1,X1,Z30), (Ra4,Rb1,X1,Z31),(Ra4,Rb1,X1,Z32), (Ra4,Rb1,X1,Z33), (Ra4,Rb1,X1,Z34), (Ra4,Rb1,X1,Z35),(Ra4,Rb1,X1,Z36), (Ra4,Rb1,X1,Z37), (Ra4,Rb1,X1,Z38), (Ra4,Rb1,X1,Z39),(Ra4,Rb1,X2,Z1), (Ra4,Rb1,X2,Z2), (Ra4,Rb1,X2,Z3), (Ra4,Rb1,X2,Z4),(Ra4,Rb1,X2,Z5), (Ra4,Rb1,X2,Z6), (Ra4,Rb1,X2,Z7), (Ra4,Rb1,X2,Z8),(Ra4,Rb1,X2,Z9), (Ra4,Rb1,X2,Z10), (Ra4,Rb1,X2,Z11), (Ra4,Rb1,X2,Z12),(Ra4,Rb1,X2,Z13), (Ra4,Rb1,X2,Z14), (Ra4,Rb1,X2,Z15), (Ra4,Rb1,X2,Z16),(Ra4,Rb1,X2,Z17), (Ra4,Rb1,X2,Z18), (Ra4,Rb1,X2,Z19), (Ra4,Rb1,X2,Z20),(Ra4,Rb1,X2,Z21), (Ra4,Rb1,X2,Z22), (Ra4,Rb1,X2,Z23), (Ra4,Rb1,X2,Z24),(Ra4,Rb1,X2,Z25), (Ra4,Rb1,X2,Z26), (Ra4,Rb1,X2,Z27), (Ra4,Rb1,X2,Z28),(Ra4,Rb1,X2,Z29), (Ra4,Rb1,X2,Z30), (Ra4,Rb1,X2,Z31), (Ra4,Rb1,X2,Z32),(Ra4,Rb1,X2,Z33), (Ra4,Rb1,X2,Z34), (Ra4,Rb1,X2,Z35), (Ra4,Rb1,X2,Z36),(Ra4,Rb1,X2,Z37), (Ra4,Rb1,X2,Z38), (Ra4,Rb1,X2,Z39), (Ra4,Rb2,X1,Z1),(Ra4,Rb2,X1,Z2), (Ra4,Rb2,X1,Z3), (Ra4,Rb2,X1,Z4), (Ra4,Rb2,X1,Z5),(Ra4,Rb2,X1,Z6), (Ra4,Rb2,X1,Z7), (Ra4,Rb2,X1,Z8), (Ra4,Rb2,X1,Z9),(Ra4,Rb2,X1,Z10), (Ra4,Rb2,X1,Z11), (Ra4,Rb2,X1,Z12), (Ra4,Rb2,X1,Z13),(Ra4,Rb2,X1,Z14), (Ra4,Rb2,X1,Z15), (Ra4,Rb2,X1,Z16), (Ra4,Rb2,X1,Z17),(Ra4,Rb2,X1,Z18), (Ra4,Rb2,X1,Z19), (Ra4,Rb2,X1,Z20), (Ra4,Rb2,X1,Z21),(Ra4,Rb2,X1,Z22), (Ra4,Rb2,X1,Z23), (Ra4,Rb2,X1,Z24), (Ra4,Rb2,X1,Z25),(Ra4,Rb2,X1,Z26), (Ra4,Rb2,X1,Z27), (Ra4,Rb2,X1,Z28), (Ra4,Rb2,X1,Z29),(Ra4,Rb2,X1,Z30), (Ra4,Rb2,X1,Z31), (Ra4,Rb2,X1,Z32), (Ra4,Rb2,X1,Z33),(Ra4,Rb2,X1,Z34), (Ra4,Rb2,X1,Z35), (Ra4,Rb2,X1,Z36), (Ra4,Rb2,X1,Z37),(Ra4,Rb2,X1,Z38), (Ra4,Rb2,X1,Z39), (Ra4,Rb2,X2,Z1), (Ra4,Rb2,X2,Z2),(Ra4,Rb2,X2,Z3), (Ra4,Rb2,X2,Z4), (Ra4,Rb2,X2,Z5), (Ra4,Rb2,X2,Z6),(Ra4,Rb2,X2,Z7), (Ra4,Rb2,X2,Z8), (Ra4,Rb2,X2,Z9), (Ra4,Rb2,X2,Z10),(Ra4,Rb2,X2,Z11), (Ra4,Rb2,X2,Z12), (Ra4,Rb2,X2,Z13), (Ra4,Rb2,X2,Z14),(Ra4,Rb2,X2,Z15), (Ra4,Rb2,X2,Z16), (Ra4,Rb2,X2,Z17), (Ra4,Rb2,X2,Z18),(Ra4,Rb2,X2,Z19), (Ra4,Rb2,X2,Z20), (Ra4,Rb2,X2,Z21), (Ra4,Rb2,X2,Z22),(Ra4,Rb2,X2,Z23), (Ra4,Rb2,X2,Z24), (Ra4,Rb2,X2,Z25), (Ra4,Rb2,X2,Z26),(Ra4,Rb2,X2,Z27), (Ra4,Rb2,X2,Z28), (Ra4,Rb2,X2,Z29), (Ra4,Rb2,X2,Z30),(Ra4,Rb2,X2,Z31), (Ra4,Rb2,X2,Z32), (Ra4,Rb2,X2,Z33), (Ra4,Rb2,X2,Z34),(Ra4,Rb2,X2,Z35), (Ra4,Rb2,X2,Z36), (Ra4,Rb2,X2,Z37), (Ra4,Rb2,X2,Z38),(Ra4,Rb2,X2,Z39), (Ra4,Rb3,X1,Z1), (Ra4,Rb3,X1,Z2), (Ra4,Rb3,X1,Z3),(Ra4,Rb3,X1,Z4), (Ra4,Rb3,X1,Z5), (Ra4,Rb3,X1,Z6), (Ra4,Rb3,X1,Z7),(Ra4,Rb3,X1,Z8), (Ra4,Rb3,X1,Z9), (Ra4,Rb3,X1,Z10), (Ra4,Rb3,X1,Z11),(Ra4,Rb3,X1,Z12), (Ra4,Rb3,X1,Z13), (Ra4,Rb3,X1,Z14), (Ra4,Rb3,X1,Z15),(Ra4,Rb3,X1,Z16), (Ra4,Rb3,X1,Z17), (Ra4,Rb3,X1,Z18), (Ra4,Rb3,X1,Z19),(Ra4,Rb3,X1,Z20), (Ra4,Rb3,X1,Z21), (Ra4,Rb3,X1,Z22), (Ra4,Rb3,X1,Z23),(Ra4,Rb3,X1,Z24), (Ra4,Rb3,X1,Z25), (Ra4,Rb3,X1,Z26), (Ra4,Rb3,X1,Z27),(Ra4,Rb3,X1,Z28), (Ra4,Rb3,X1,Z29), (Ra4,Rb3,X1,Z30), (Ra4,Rb3,X1,Z31),(Ra4,Rb3,X1,Z32), (Ra4,Rb3,X1,Z33), (Ra4,Rb3,X1,Z34), (Ra4,Rb3,X1,Z35),(Ra4,Rb3,X1,Z36), (Ra4,Rb3,X1,Z37), (Ra4,Rb3,X1,Z38), (Ra4,Rb3,X1,Z39),(Ra4,Rb3,X2,Z1), (Ra4,Rb3,X2,Z2), (Ra4,Rb3,X2,Z3), (Ra4,Rb3,X2,Z4),(Ra4,Rb3,X2,Z5), (Ra4,Rb3,X2,Z6), (Ra4,Rb3,X2,Z7), (Ra4,Rb3,X2,Z8),(Ra4,Rb3,X2,Z9), (Ra4,Rb3,X2,Z10), (Ra4,Rb3,X2,Z11), (Ra4,Rb3,X2,Z12),(Ra4,Rb3,X2,Z13), (Ra4,Rb3,X2,Z14), (Ra4,Rb3,X2,Z15), (Ra4,Rb3,X2,Z16),(Ra4,Rb3,X2,Z17), (Ra4,Rb3,X2,Z18), (Ra4,Rb3,X2,Z19), (Ra4,Rb3,X2,Z20),(Ra4,Rb3,X2,Z21), (Ra4,Rb3,X2,Z22), (Ra4,Rb3,X2,Z23), (Ra4,Rb3,X2,Z24),(Ra4,Rb3,X2,Z25), (Ra4,Rb3,X2,Z26), (Ra4,Rb3,X2,Z27), (Ra4,Rb3,X2,Z28),(Ra4,Rb3,X2,Z29), (Ra4,Rb3,X2,Z30), (Ra4,Rb3,X2,Z31), (Ra4,Rb3,X2,Z32),(Ra4,Rb3,X2,Z33), (Ra4,Rb3,X2,Z34), (Ra4,Rb3,X2,Z35), (Ra4,Rb3,X2,Z36),(Ra4,Rb3,X2,Z37), (Ra4,Rb3,X2,Z38), (Ra4,Rb3,X2,Z39), (Ra4,Rb4,X1,Z1),(Ra4,Rb4,X1,Z2), (Ra4,Rb4,X1,Z3), (Ra4,Rb4,X1,Z4), (Ra4,Rb4,X1,Z5),(Ra4,Rb4,X1,Z6), (Ra4,Rb4,X1,Z7), (Ra4,Rb4,X1,Z8), (Ra4,Rb4,X1,Z9),(Ra4,Rb4,X1,Z10), (Ra4,Rb4,X1,Z11), (Ra4,Rb4,X1,Z12), (Ra4,Rb4,X1,Z13),(Ra4,Rb4,X1,Z14), (Ra4,Rb4,X1,Z15), (Ra4,Rb4,X1,Z16), (Ra4,Rb4,X1,Z17),(Ra4,Rb4,X1,Z18), (Ra4,Rb4,X1,Z19), (Ra4,Rb4,X1,Z20), (Ra4,Rb4,X1,Z21),(Ra4,Rb4,X1,Z22), (Ra4,Rb4,X1,Z23), (Ra4,Rb4,X1,Z24), (Ra4,Rb4,X1,Z25),(Ra4,Rb4,X1,Z26), (Ra4,Rb4,X1,Z27), (Ra4,Rb4,X1,Z28), (Ra4,Rb4,X1,Z29),(Ra4,Rb4,X1,Z30), (Ra4,Rb4,X1,Z31), (Ra4,Rb4,X1,Z32), (Ra4,Rb4,X1,Z33),(Ra4,Rb4,X1,Z34), (Ra4,Rb4,X1,Z35), (Ra4,Rb4,X1,Z36), (Ra4,Rb4,X1,Z37),(Ra4,Rb4,X1,Z38), (Ra4,Rb4,X1,Z39), (Ra4,Rb4,X2,Z1), (Ra4,Rb4,X2,Z2),(Ra4,Rb4,X2,Z3), (Ra4,Rb4,X2,Z4), (Ra4,Rb4,X2,Z5), (Ra4,Rb4,X2,Z6),(Ra4,Rb4,X2,Z7), (Ra4,Rb4,X2,Z8), (Ra4,Rb4,X2,Z9), (Ra4,Rb4,X2,Z10),(Ra4,Rb4,X2,Z11), (Ra4,Rb4,X2,Z12), (Ra4,Rb4,X2,Z13), (Ra4,Rb4,X2,Z14),(Ra4,Rb4,X2,Z15), (Ra4,Rb4,X2,Z16), (Ra4,Rb4,X2,Z17), (Ra4,Rb4,X2,Z18),(Ra4,Rb4,X2,Z19), (Ra4,Rb4,X2,Z20), (Ra4,Rb4,X2,Z21), (Ra4,Rb4,X2,Z22),(Ra4,Rb4,X2,Z23), (Ra4,Rb4,X2,Z24), (Ra4,Rb4,X2,Z25), (Ra4,Rb4,X2,Z26),(Ra4,Rb4,X2,Z27), (Ra4,Rb4,X2,Z28), (Ra4,Rb4,X2,Z29), (Ra4,Rb4,X2,Z30),(Ra4,Rb4,X2,Z31), (Ra4,Rb4,X2,Z32), (Ra4,Rb4,X2,Z33), (Ra4,Rb4,X2,Z34),(Ra4,Rb4,X2,Z35), (Ra4,Rb4,X2,Z36), (Ra4,Rb4,X2,Z37), (Ra4,Rb4,X2,Z38),(Ra4,Rb4,X2,Z39), (Ra4,Rb5,X1,Z1), (Ra4,Rb5,X1,Z2), (Ra4,Rb5,X1,Z3),(Ra4,Rb5,X1,Z4), (Ra4,Rb5,X1,Z5), (Ra4,Rb5,X1,Z6), (Ra4,Rb5,X1,Z7),(Ra4,Rb5,X1,Z8), (Ra4,Rb5,X1,Z9), (Ra4,Rb5,X1, Z10), (Ra4,Rb5,X1,Z11),(Ra4,Rb5,X1,Z12), (Ra4,Rb5,X1,Z13), (Ra4,Rb5,X1,Z14), (Ra4,Rb5,X1,Z15),(Ra4,Rb5,X1,Z16), (Ra4,Rb5,X1,Z17), (Ra4,Rb5,X1,Z18), (Ra4,Rb5,X1,Z19),(Ra4,Rb5,X1,Z20), (Ra4,Rb5,X1,Z21), (Ra4,Rb5,X1,Z22), (Ra4,Rb5,X1,Z23),(Ra4,Rb5,X1,Z24), (Ra4,Rb5,X1,Z25), (Ra4,Rb5,X1,Z26), (Ra4,Rb5,X1,Z27),(Ra4,Rb5,X1,Z28), (Ra4,Rb5,X1,Z29), (Ra4,Rb5,X1,Z30), (Ra4,Rb5,X1,Z31),(Ra4,Rb5,X1,Z32), (Ra4,Rb5,X1,Z33), (Ra4,Rb5,X1,Z34), (Ra4,Rb5,X1,Z35),(Ra4,Rb5,X1,Z36), (Ra4,Rb5,X1,Z37), (Ra4,Rb5,X1,Z38), (Ra4,Rb5,X1,Z39),(Ra4,Rb5,X2,Z1), (Ra4,Rb5,X2,Z2), (Ra4,Rb5,X2,Z3), (Ra4,Rb5,X2,Z4),(Ra4,Rb5,X2,Z5), (Ra4,Rb5,X2,Z6), (Ra4,Rb5,X2,Z7), (Ra4,Rb5,X2,Z8),(Ra4,Rb5,X2,Z9), (Ra4,Rb5,X2,Z10), (Ra4,Rb5,X2,Z11), (Ra4,Rb5,X2,Z12),(Ra4,Rb5,X2,Z13), (Ra4,Rb5,X2,Z14), (Ra4,Rb5,X2,Z15), (Ra4,Rb5,X2,Z16),(Ra4,Rb5,X2,Z17), (Ra4,Rb5,X2,Z18), (Ra4,Rb5,X2,Z19), (Ra4,Rb5,X2,Z20),(Ra4,Rb5,X2,Z21), (Ra4,Rb5,X2,Z22), (Ra4,Rb5,X2,Z23), (Ra4,Rb5,X2,Z24),(Ra4,Rb5,X2,Z25), (Ra4,Rb5,X2,Z26), (Ra4,Rb5,X2,Z27), (Ra4,Rb5,X2,Z28),(Ra4,Rb5,X2,Z29), (Ra4,Rb5,X2,Z30), (Ra4,Rb5,X2,Z31), (Ra4,Rb5,X2,Z32),(Ra4,Rb5,X2,Z33), (Ra4,Rb5,X2,Z34), (Ra4,Rb5,X2,Z35), (Ra4,Rb5,X2,Z36),(Ra4,Rb5,X2,Z37), (Ra4,Rb5,X2,Z38), (Ra4,Rb5,X2,Z39), (Ra4,Rb6,X1,Z1),(Ra4,Rb6,X1,Z2), (Ra4,Rb6,X1,Z3), (Ra4,Rb6,X1,Z4), (Ra4,Rb6,X1,Z5),(Ra4,Rb6,X1,Z6), (Ra4,Rb6,X1,Z7), (Ra4,Rb6,X1,Z8), (Ra4,Rb6,X1,Z9),(Ra4,Rb6,X1,Z10), (Ra4,Rb6,X1,Z11), (Ra4,Rb6,X1,Z12), (Ra4,Rb6,X1,Z13),(Ra4,Rb6,X1,Z14), (Ra4,Rb6,X1,Z15), (Ra4,Rb6,X1,Z16), (Ra4,Rb6,X1,Z17),(Ra4,Rb6,X1,Z18), (Ra4,Rb6,X1,Z19), (Ra4,Rb6,X1,Z20), (Ra4,Rb6,X1,Z21),(Ra4,Rb6,X1,Z22), (Ra4,Rb6,X1,Z23), (Ra4,Rb6,X1,Z24), (Ra4,Rb6,X1,Z25),(Ra4,Rb6,X1,Z26), (Ra4,Rb6,X1,Z27), (Ra4,Rb6,X1,Z28), (Ra4,Rb6,X1,Z29),(Ra4,Rb6,X1,Z30), (Ra4,Rb6,X1,Z31), (Ra4,Rb6,X1,Z32), (Ra4,Rb6,X1,Z33),(Ra4,Rb6,X1,Z34), (Ra4,Rb6,X1,Z35), (Ra4,Rb6,X1,Z36), (Ra4,Rb6,X1,Z37),(Ra4,Rb6,X1,Z38), (Ra4,Rb6,X1,Z39), (Ra4,Rb6,X2,Z1), (Ra4,Rb6,X2,Z2),(Ra4,Rb6,X2,Z3), (Ra4,Rb6,X2,Z4), (Ra4,Rb6,X2,Z5), (Ra4,Rb6,X2,Z6),(Ra4,Rb6,X2,Z7), (Ra4,Rb6,X2,Z8), (Ra4,Rb6,X2,Z9), (Ra4,Rb6,X2,Z10),(Ra4,Rb6,X2,Z11), (Ra4,Rb6,X2,Z12), (Ra4,Rb6,X2,Z13), (Ra4,Rb6,X2,Z14),(Ra4,Rb6,X2,Z15), (Ra4,Rb6,X2,Z16), (Ra4,Rb6,X2,Z17), (Ra4,Rb6,X2,Z 18),(Ra4,Rb6,X2,Z19), (Ra4,Rb6,X2,Z20), (Ra4,Rb6,X2,Z21), (Ra4,Rb6,X2,Z22),(Ra4,Rb6,X2,Z23), (Ra4,Rb6,X2,Z24), (Ra4,Rb6,X2,Z25), (Ra4,Rb6,X2,Z26),(Ra4,Rb6,X2,Z27), (Ra4,Rb6,X2,Z28), (Ra4,Rb6,X2,Z29), (Ra4,Rb6,X2,Z30),(Ra4,Rb6,X2,Z31), (Ra4,Rb6,X2,Z32), (Ra4,Rb6,X2,Z33), (Ra4,Rb6,X2,Z34),(Ra4,Rb6,X2,Z35), (Ra4,Rb6,X2,Z36), (Ra4,Rb6,X2,Z37), (Ra4,Rb6,X2,Z38),(Ra4,Rb6,X2,Z39), (Ra4,Rb7,X1,Z1), (Ra4,Rb7,X1,Z2), (Ra4,Rb7,X1,Z3),(Ra4,Rb7,X1,Z4), (Ra4,Rb7,X1,Z5), (Ra4,Rb7,X1,Z6), (Ra4,Rb7,X1,Z7),(Ra4,Rb7,X1,Z8), (Ra4,Rb7,X1,Z9), (Ra4,Rb7,X1,Z10), (Ra4,Rb7,X1,Z11),(Ra4,Rb7,X1,Z12), (Ra4,Rb7,X1,Z13), (Ra4,Rb7,X1,Z14), (Ra4,Rb7,X1,Z15),(Ra4,Rb7,X1,Z16), (Ra4,Rb7,X1,Z17), (Ra4,Rb7,X1,Z18), (Ra4,Rb7,X1,Z19),(Ra4,Rb7,X1,Z20), (Ra4,Rb7,X1,Z21), (Ra4,Rb7,X1,Z22), (Ra4,Rb7,X1,Z23),(Ra4,Rb7,X1,Z24), (Ra4,Rb7,X1,Z25), (Ra4,Rb7,X1,Z26), (Ra4,Rb7,X1,Z27),(Ra4,Rb7,X1,Z28), (Ra4,Rb7,X1,Z29), (Ra4,Rb7,X1,Z30), (Ra4,Rb7,X1,Z31),(Ra4,Rb7,X1,Z32), (Ra4,Rb7,X1,Z33), (Ra4,Rb7,X1,Z34), (Ra4,Rb7,X1,Z35),(Ra4,Rb7,X1,Z (Ra4,Rb7,X1,Z37), (Ra4,Rb7,X1,Z38), (Ra4,Rb7,X1,Z39),(Ra4,Rb7,X2,Z1), (Ra4,Rb7,X2,Z2), (Ra4,Rb7,X2,Z3), (Ra4,Rb7,X2,Z4),(Ra4,Rb7,X2,Z5), (Ra4,Rb7,X2,Z6), (Ra4,Rb7,X2,Z7), (Ra4,Rb7,X2,Z8),(Ra4,Rb7,X2,Z9), (Ra4,Rb7,X2,Z10), (Ra4,Rb7,X2,Z11), (Ra4,Rb7,X2,Z12),(Ra4,Rb7,X2,Z13), (Ra4,Rb7,X2,Z14), (Ra4,Rb7,X2,Z15), (Ra4,Rb7,X2,Z16),(Ra4,Rb7,X2,Z17), (Ra4,Rb7,X2,Z18), (Ra4,Rb7,X2,Z19), (Ra4,Rb7,X2,Z20),(Ra4,Rb7,X2,Z21), (Ra4,Rb7,X2,Z22), (Ra4,Rb7,X2,Z23), (Ra4,Rb7,X2,Z24),(Ra4,Rb7,X2,Z25), (Ra4,Rb7,X2,Z26), (Ra4,Rb7,X2,Z27), (Ra4,Rb7,X2,Z28),(Ra4,Rb7,X2,Z29), (Ra4,Rb7,X2,Z30), (Ra4,Rb7,X2,Z31), (Ra4,Rb7,X2,Z32),(Ra4,Rb7,X2,Z33), (Ra4,Rb7,X2,Z34), (Ra4,Rb7,X2,Z35), (Ra4,Rb7,X2,Z36),(Ra4,Rb7,X2,Z37), (Ra4,Rb7,X2,Z38), (Ra4,Rb7,X2,Z39), (Ra4,Rb8,X1,Z1),(Ra4,Rb8,X1,Z2), (Ra4,Rb8,X1,Z3), (Ra4,Rb8,X1,Z4), (Ra4,Rb8,X1,Z5),(Ra4,Rb8,X1,Z6), (Ra4,Rb8,X1,Z7), (Ra4,Rb8,X1,Z8), (Ra4,Rb8,X1,Z9),(Ra4,Rb8,X1,Z10), (Ra4,Rb8,X1,Z11), (Ra4,Rb8,X1,Z12), (Ra4,Rb8,X1,Z13),(Ra4,Rb8,X1,Z14), (Ra4,Rb8,X1,Z15), (Ra4,Rb8,X1,Z16), (Ra4,Rb8,X1,Z17),(Ra4,Rb8,X1,Z18), (Ra4,Rb8,X1,Z19), (Ra4,Rb8,X1,Z20), (Ra4,Rb8,X1,Z21),(Ra4,Rb8,X1,Z22), (Ra4,Rb8,X1,Z23), (Ra4,Rb8,X1,Z24), (Ra4,Rb8,X1,Z25),(Ra4,Rb8,X1,Z26), (Ra4,Rb8,X1,Z27), (Ra4,Rb8,X1,Z28), (Ra4,Rb8,X1,Z29),(Ra4,Rb8,X1,Z30), (Ra4,Rb8,X1,Z31), (Ra4,Rb8,X1,Z32), (Ra4,Rb8,X1,Z33),(Ra4,Rb8,X1,Z34), (Ra4,Rb8,X1,Z35), (Ra4,Rb8,X1,Z36), (Ra4,Rb8,X1,Z37),(Ra4,Rb8,X1,Z38), (Ra4,Rb8,X1,Z39), (Ra4,Rb8,X2,Z1), (Ra4,Rb8,X2,Z2),(Ra4,Rb8,X2,Z3), (Ra4,Rb8,X2,Z4), (Ra4,Rb8,X2,Z5), (Ra4,Rb8,X2,Z6),(Ra4,Rb8,X2,Z7), (Ra4,Rb8,X2,Z8), (Ra4,Rb8,X2,Z9), (Ra4,Rb8,X2,Z10),(Ra4,Rb8,X2,Z11), (Ra4,Rb8,X2,Z12), (Ra4,Rb8,X2,Z13), (Ra4,Rb8,X2,Z14),(Ra4,Rb8,X2,Z15), (Ra4,Rb8,X2,Z16), (Ra4,Rb8,X2,Z17), (Ra4,Rb8,X2,Z18),(Ra4,Rb8,X2,Z19), (Ra4,Rb8,X2,Z20), (Ra4,Rb8,X2,Z21), (Ra4,Rb8,X2,Z22),(Ra4,Rb8,X2,Z23), (Ra4,Rb8,X2,Z24), (Ra4,Rb8,X2,Z25), (Ra4,Rb8,X2,Z26),(Ra4,Rb8,X2,Z27), (Ra4,Rb8,X2,Z28), (Ra4,Rb8,X2,Z29), (Ra4,Rb8,X2,Z30),(Ra4,Rb8,X2,Z31), (Ra4,Rb8,X2,Z32), (Ra4,Rb8,X2,Z33), (Ra4,Rb8,X2,Z34),(Ra4,Rb8,X2,Z35), (Ra4,Rb8,X2,Z36), (Ra4,Rb8,X2,Z37), (Ra4,Rb8,X2,Z38),(Ra4,Rb8,X2,Z39), (Ra5,Rb1,X1,Z1), (Ra5,Rb1,X1,Z2), (Ra5,Rb1,X1,Z3),(Ra5,Rb1,X1,Z4), (Ra5,Rb1,X1,Z5), (Ra5,Rb1,X1,Z6), (Ra5,Rb1,X1,Z7),(Ra5,Rb1,X1,Z8), (Ra5,Rb1,X1,Z9), (Ra5,Rb1,X1,Z10), (Ra5,Rb1,X1,Z11),(Ra5,Rb1,X1,Z12), (Ra5,Rb1,X1,Z13), (Ra5,Rb1,X1,Z14), (Ra5,Rb1,X1,Z15),(Ra5,Rb1,X1,Z16), (Ra5,Rb1,X1,Z17), (Ra5,Rb1,X1,Z18), (Ra5,Rb1,X1,Z19),(Ra5,Rb1,X1,Z20), (Ra5,Rb1,X1,Z21), (Ra5,Rb1,X1,Z22), (Ra5,Rb1,X1,Z23),(Ra5,Rb1,X1,Z24), (Ra5,Rb1,X1,Z25), (Ra5,Rb1,X1,Z26), (Ra5,Rb1,X1,Z27),(Ra5,Rb1,X1,Z28), (Ra5,Rb1,X1,Z29), (Ra5,Rb1,X1,Z30), (Ra5,Rb1,X1,Z31),(Ra5,Rb1,X1,Z32), (Ra5,Rb1,X1,Z33), (Ra5,Rb1,X1,Z34), (Ra5,Rb1,X1,Z35),(Ra5,Rb1,X1,Z36), (Ra5,Rb1,X1,Z37), (Ra5,Rb1,X1,Z38), (Ra5,Rb1,X1,Z39),(Ra5,Rb1,X2,Z1), (Ra5,Rb1,X2,Z2), (Ra5,Rb1,X2,Z3), (Ra5,Rb1,X2,Z4),(Ra5,Rb1,X2,Z5), (Ra5,Rb1,X2,Z6), (Ra5,Rb1,X2,Z7), (Ra5,Rb1,X2,Z8),(Ra5,Rb1,X2,Z9), (Ra5,Rb1,X2,Z10), (Ra5,Rb1,X2,Z11), (Ra5,Rb1,X2,Z12),(Ra5,Rb1,X2,Z13), (Ra5,Rb1,X2,Z14), (Ra5,Rb1,X2,Z15), (Ra5,Rb1,X2,Z16),(Ra5,Rb1,X2,Z17), (Ra5,Rb1,X2,Z18), (Ra5,Rb1,X2,Z19), (Ra5,Rb1,X2,Z20),(Ra5,Rb1,X2,Z21), (Ra5,Rb1,X2,Z22), (Ra5,Rb1,X2,Z23), (Ra5,Rb1,X2,Z24),(Ra5,Rb1,X2,Z25), (Ra5,Rb1,X2,Z26), (Ra5,Rb1,X2,Z27), (Ra5,Rb1,X2,Z28),(Ra5,Rb1,X2,Z29), (Ra5,Rb1,X2,Z30), (Ra5,Rb1,X2,Z31), (Ra5,Rb1,X2,Z32),(Ra5,Rb1,X2,Z33), (Ra5,Rb1,X2,Z34), (Ra5,Rb1,X2,Z35), (Ra5,Rb1,X2,Z36),(Ra5,Rb1,X2,Z37), (Ra5,Rb1,X2,Z38), (Ra5,Rb1,X2,Z39), (Ra5,Rb2,X1,Z1),(Ra5,Rb2,X1,Z2), (Ra5,Rb2,X1,Z3), (Ra5,Rb2,X1,Z4), (Ra5,Rb2,X1,Z5),(Ra5,Rb2,X1,Z6), (Ra5,Rb2,X1,Z7), (Ra5,Rb2,X1,Z8), (Ra5,Rb2,X1,Z9),(Ra5,Rb2,X1,Z10), (Ra5,Rb2,X1,Z11), (Ra5,Rb2,X1,Z12), (Ra5,Rb2,X1,Z13),(Ra5,Rb2,X1,Z14), (Ra5,Rb2,X1,Z15), (Ra5,Rb2,X1,Z16), (Ra5,Rb2,X1,Z17),(Ra5,Rb2,X1,Z18), (Ra5,Rb2,X1,Z19), (Ra5,Rb2,X1,Z20), (Ra5,Rb2,X1,Z21),(Ra5,Rb2,X1,Z22), (Ra5,Rb2,X1,Z23), (Ra5,Rb2,X1,Z24), (Ra5,Rb2,X1,Z25),(Ra5,Rb2,X1,Z26), (Ra5,Rb2,X1,Z27), (Ra5,Rb2,X1,Z28), (Ra5,Rb2,X1,Z29),(Ra5,Rb2,X1,Z30), (Ra5,Rb2,X1,Z31), (Ra5,Rb2,X1,Z32), (Ra5,Rb2,X1,Z33),(Ra5,Rb2,X1,Z34), (Ra5,Rb2,X1,Z35), (Ra5,Rb2,X1,Z36), (Ra5,Rb2,X1,Z37),(Ra5,Rb2,X1,Z38), (Ra5,Rb2,X1,Z39), (Ra5,Rb2,X2,Z1), (Ra5,Rb2,X2,Z2),(Ra5,Rb2,X2,Z3), (Ra5,Rb2,X2,Z4), (Ra5,Rb2,X2,Z5), (Ra5,Rb2,X2,Z6),(Ra5,Rb2,X2,Z7), (Ra5,Rb2,X2,Z8), (Ra5,Rb2,X2,Z9), (Ra5,Rb2,X2,Z10),(Ra5,Rb2,X2,Z11), (Ra5,Rb2,X2,Z12), (Ra5,Rb2,X2,Z13), (Ra5,Rb2,X2,Z14),(Ra5,Rb2,X2,Z15), (Ra5,Rb2,X2,Z16), (Ra5,Rb2,X2,Z17), (Ra5,Rb2,X2,Z18),(Ra5,Rb2,X2,Z19), (Ra5,Rb2,X2,Z20), (Ra5,Rb2,X2,Z21), (Ra5,Rb2,X2,Z22),(Ra5,Rb2,X2,Z23), (Ra5,Rb2,X2,Z24), (Ra5,Rb2,X2,Z25), (Ra5,Rb2,X2,Z26),(Ra5,Rb2,X2,Z27), (Ra5,Rb2,X2,Z28), (Ra5,Rb2,X2,Z29), (Ra5,Rb2,X2,Z30),(Ra5,Rb2,X2,Z31), (Ra5,Rb2,X2,Z32), (Ra5,Rb2,X2,Z33), (Ra5,Rb2,X2,Z34),(Ra5,Rb2,X2,Z35), (Ra5,Rb2,X2,Z36), (Ra5,Rb2,X2,Z37), (Ra5,Rb2,X2,Z38),(Ra5,Rb2,X2,Z39), (Ra5,Rb3,X1,Z1), (Ra5,Rb3,X1,Z2), (Ra5,Rb3,X1,Z3),(Ra5,Rb3,X1,Z4), (Ra5,Rb3,X1,Z5), (Ra5,Rb3,X1,Z6), (Ra5,Rb3,X1,Z7),(Ra5,Rb3,X1,Z8), (Ra5,Rb3,X1,Z9), (Ra5,Rb3,X1,Z10), (Ra5,Rb3,X1,Z11),(Ra5,Rb3,X1,Z12), (Ra5,Rb3,X1,Z13), (Ra5,Rb3,X1,Z14), (Ra5,Rb3,X1,Z15),(Ra5,Rb3,X1,Z16), (Ra5,Rb3,X1,Z17), (Ra5,Rb3,X1,Z18), (Ra5,Rb3,X1,Z19),(Ra5,Rb3,X1,Z20), (Ra5,Rb3,X1,Z21), (Ra5,Rb3,X1,Z22), (Ra5,Rb3,X1,Z23),(Ra5,Rb3,X1,Z24), (Ra5,Rb3,X1,Z25), (Ra5,Rb3,X1,Z26), (Ra5,Rb3,X1,Z27),(Ra5,Rb3,X1,Z28), (Ra5,Rb3,X1,Z29), (Ra5,Rb3,X1,Z30), (Ra5,Rb3,X1,Z31),(Ra5,Rb3,X1,Z32), (Ra5,Rb3,X1,Z33), (Ra5,Rb3,X1,Z34), (Ra5,Rb3,X1,Z35),(Ra5,Rb3,X1,Z36), (Ra5,Rb3,X1,Z37), (Ra5,Rb3,X1,Z38), (Ra5,Rb3,X1,Z39),(Ra5,Rb3,X2,Z1), (Ra5,Rb3,X2,Z2), (Ra5,Rb3,X2,Z3), (Ra5,Rb3,X2,Z4),(Ra5,Rb3,X2,Z5), (Ra5,Rb3,X2,Z6), (Ra5,Rb3,X2,Z7), (Ra5,Rb3,X2,Z8),(Ra5,Rb3,X2,Z9), (Ra5,Rb3,X2,Z10), (Ra5,Rb3,X2,Z11), (Ra5,Rb3,X2,Z12),(Ra5,Rb3,X2,Z13), (Ra5,Rb3,X2,Z14), (Ra5,Rb3,X2,Z15), (Ra5,Rb3,X2,Z16),(Ra5,Rb3,X2,Z17), (Ra5,Rb3,X2,Z18), (Ra5,Rb3,X2,Z19), (Ra5,Rb3,X2,Z20),(Ra5,Rb3,X2,Z21), (Ra5,Rb3,X2,Z22), (Ra5,Rb3,X2,Z23), (Ra5,Rb3,X2,Z24),(Ra5,Rb3,X2,Z25), (Ra5,Rb3,X2,Z26), (Ra5,Rb3,X2,Z27), (Ra5,Rb3,X2,Z28),(Ra5,Rb3,X2,Z29), (Ra5,Rb3,X2,Z30), (Ra5,Rb3,X2,Z31), (Ra5,Rb3,X2,Z32),(Ra5,Rb3,X2,Z33), (Ra5,Rb3,X2,Z34), (Ra5,Rb3,X2,Z35), (Ra5,Rb3,X2,Z36),(Ra5,Rb3,X2,Z37), (Ra5,Rb3,X2,Z38), (Ra5,Rb3,X2,Z39), (Ra5,Rb4,X1,Z1),(Ra5,Rb4,X1,Z2), (Ra5,Rb4,X1,Z3), (Ra5,Rb4,X1,Z4), (Ra5,Rb4,X1,Z5),(Ra5,Rb4,X1,Z6), (Ra5,Rb4,X1,Z7), (Ra5,Rb4,X1,Z8), (Ra5,Rb4,X1,Z9),(Ra5,Rb4,X1,Z10), (Ra5,Rb4,X1,Z11), (Ra5,Rb4,X1,Z12), (Ra5,Rb4,X1,Z13),(Ra5,Rb4,X1,Z14), (Ra5,Rb4,X1,Z15), (Ra5,Rb4,X1,Z16), (Ra5,Rb4,X1,Z17),(Ra5,Rb4,X1,Z18), (Ra5,Rb4,X1,Z19), (Ra5,Rb4,X1,Z20), (Ra5,Rb4,X1,Z21),(Ra5,Rb4,X1,Z22), (Ra5,Rb4,X1,Z23), (Ra5,Rb4,X1,Z24), (Ra5,Rb4,X1,Z25),(Ra5,Rb4,X1,Z26), (Ra5,Rb4,X1,Z27), (Ra5,Rb4,X1,Z28), (Ra5,Rb4,X1,Z29),(Ra5,Rb4,X1,Z30), (Ra5,Rb4,X1,Z31), (Ra5,Rb4,X1,Z32), (Ra5,Rb4,X1,Z33),(Ra5,Rb4,X1,Z34), (Ra5,Rb4,X1,Z35), (Ra5,Rb4,X1,Z36), (Ra5,Rb4,X1,Z37),(Ra5,Rb4,X1,Z38), (Ra5,Rb4,X1,Z39), (Ra5,Rb4,X2,Z1), (Ra5,Rb4,X2,Z2),(Ra5,Rb4,X2,Z3), (Ra5,Rb4,X2,Z4), (Ra5,Rb4,X2,Z5), (Ra5,Rb4,X2,Z6),(Ra5,Rb4,X2,Z7), (Ra5,Rb4,X2,Z8), (Ra5,Rb4,X2,Z9), (Ra5,Rb4,X2,Z10),(Ra5,Rb4,X2,Z11), (Ra5,Rb4,X2,Z12), (Ra5,Rb4,X2,Z13), (Ra5,Rb4,X2,Z14),(Ra5,Rb4,X2,Z15), (Ra5,Rb4,X2,Z16), (Ra5,Rb4,X2,Z17), (Ra5,Rb4,X2,Z18),(Ra5,Rb4,X2,Z19), (Ra5,Rb4,X2,Z20), (Ra5,Rb4,X2,Z21), (Ra5,Rb4,X2,Z22),(Ra5,Rb4,X2,Z23), (Ra5,Rb4,X2,Z24), (Ra5,Rb4,X2,Z25), (Ra5,Rb4,X2,Z26),(Ra5,Rb4,X2,Z27), (Ra5,Rb4,X2,Z28), (Ra5,Rb4,X2,Z29), (Ra5,Rb4,X2,Z30),(Ra5,Rb4,X2,Z31), (Ra5,Rb4,X2,Z32), (Ra5,Rb4,X2,Z33), (Ra5,Rb4,X2,Z34),(Ra5,Rb4,X2,Z35), (Ra5,Rb4,X2,Z36), (Ra5,Rb4,X2,Z37), (Ra5,Rb4,X2,Z38),(Ra5,Rb4,X2,Z39), (Ra5,Rb5,X1,Z1), (Ra5,Rb5,X1,Z2), (Ra5,Rb5,X1,Z3),(Ra5,Rb5,X1,Z4), (Ra5,Rb5,X1,Z5), (Ra5,Rb5,X1,Z6), (Ra5,Rb5,X1,Z7),(Ra5,Rb5,X1,Z8), (Ra5,Rb5,X1,Z9), (Ra5,Rb5,X1,Z10), (Ra5,Rb5,X1,Z11),(Ra5,Rb5,X1,Z12), (Ra5,Rb5,X1,Z13), (Ra5,Rb5,X1,Z14), (Ra5,Rb5,X1,Z15),(Ra5,Rb5,X1,Z16), (Ra5,Rb5,X1,Z17), (Ra5,Rb5,X1,Z18), (Ra5,Rb5,X1,Z19),(Ra5,Rb5,X1,Z20), (Ra5,Rb5,X1,Z21), (Ra5,Rb5,X1,Z22), (Ra5,Rb5,X1,Z23),(Ra5,Rb5,X1,Z24), (Ra5,Rb5,X1,Z25), (Ra5,Rb5,X1,Z26), (Ra5,Rb5,X1,Z27),(Ra5,Rb5,X1,Z28), (Ra5,Rb5,X1,Z29), (Ra5,Rb5,X1,Z30), (Ra5,Rb5,X1,Z31),(Ra5,Rb5,X1,Z32), (Ra5,Rb5,X1,Z33), (Ra5,Rb5,X1,Z34), (Ra5,Rb5,X1,Z35),(Ra5,Rb5,X1,Z36), (Ra5,Rb5,X1,Z37), (Ra5,Rb5,X1,Z38), (Ra5,Rb5,X1,Z39),(Ra5,Rb5,X2,Z1), (Ra5,Rb5,X2,Z2), (Ra5,Rb5,X2,Z3), (Ra5,Rb5,X2,Z4),(Ra5,Rb5,X2,Z5), (Ra5,Rb5,X2,Z6), (Ra5,Rb5,X2,Z7), (Ra5,Rb5,X2,Z8),(Ra5,Rb5,X2,Z9), (Ra5,Rb5,X2,Z10), (Ra5,Rb5,X2,Z11), (Ra5,Rb5,X2,Z12),(Ra5,Rb5,X2,Z13), (Ra5,Rb5,X2,Z14), (Ra5,Rb5,X2,Z15), (Ra5,Rb5,X2,Z16),(Ra5,Rb5,X2,Z17), (Ra5,Rb5,X2,Z18), (Ra5,Rb5,X2,Z19), (Ra5,Rb5,X2,Z20),(Ra5,Rb5,X2,Z21), (Ra5,Rb5,X2,Z22), (Ra5,Rb5,X2,Z23), (Ra5,Rb5,X2,Z24),(Ra5,Rb5,X2,Z25), (Ra5,Rb5,X2,Z26), (Ra5,Rb5,X2,Z27), (Ra5,Rb5,X2,Z28),(Ra5,Rb5,X2,Z29), (Ra5,Rb5,X2,Z30), (Ra5,Rb5,X2,Z31), (Ra5,Rb5,X2,Z32),(Ra5,Rb5,X2,Z33), (Ra5,Rb5,X2,Z34), (Ra5,Rb5,X2,Z35), (Ra5,Rb5,X2,Z36),(Ra5,Rb5,X2,Z37), (Ra5,Rb5,X2,Z38), (Ra5,Rb5,X2,Z39), (Ra5,Rb6,X1,Z1),(Ra5,Rb6,X1,Z2), (Ra5,Rb6,X1,Z3), (Ra5,Rb6,X1,Z4), (Ra5,Rb6,X1,Z5),(Ra5,Rb6,X1,Z6), (Ra5,Rb6,X1,Z7), (Ra5,Rb6,X1,Z8), (Ra5,Rb6,X1,Z9),(Ra5,Rb6,X1,Z10), (Ra5,Rb6,X1,Z11), (Ra5,Rb6,X1,Z12), (Ra5,Rb6,X1,Z13),(Ra5,Rb6,X1,Z14), (Ra5,Rb6,X1,Z15), (Ra5,Rb6,X1,Z16), (Ra5,Rb6,X1,Z17),(Ra5,Rb6,X1,Z18), (Ra5,Rb6,X1,Z19), (Ra5,Rb6,X1,Z20), (Ra5,Rb6,X1,Z21),(Ra5,Rb6,X1,Z22), (Ra5,Rb6,X1,Z23), (Ra5,Rb6,X1,Z24), (Ra5,Rb6,X1,Z25),(Ra5,Rb6,X1,Z26), (Ra5,Rb6,X1,Z27), (Ra5,Rb6,X1,Z28), (Ra5,Rb6,X1,Z29),(Ra5,Rb6,X1,Z30), (Ra5,Rb6,X1,Z31), (Ra5,Rb6,X1,Z32), (Ra5,Rb6,X1,Z33),(Ra5,Rb6,X1,Z34), (Ra5,Rb6,X1,Z35), (Ra5,Rb6,X1,Z36), (Ra5,Rb6,X1,Z37),(Ra5,Rb6,X1,Z38), (Ra5,Rb6,X1,Z39), (Ra5,Rb6,X2,Z1), (Ra5,Rb6,X2,Z2),(Ra5,Rb6,X2,Z3), (Ra5,Rb6,X2,Z4), (Ra5,Rb6,X2,Z5), (Ra5,Rb6,X2,Z6),(Ra5,Rb6,X2,Z7), (Ra5,Rb6,X2,Z8), (Ra5,Rb6,X2,Z9), (Ra5,Rb6,X2,Z10),(Ra5,Rb6,X2,Z11), (Ra5,Rb6,X2,Z12), (Ra5,Rb6,X2,Z13), (Ra5,Rb6,X2,Z14),(Ra5,Rb6,X2,Z15), (Ra5,Rb6,X2,Z16), (Ra5,Rb6,X2,Z17), (Ra5,Rb6,X2,Z18),(Ra5,Rb6,X2,Z19), (Ra5,Rb6,X2,Z20), (Ra5,Rb6,X2,Z21), (Ra5,Rb6,X2,Z22),(Ra5,Rb6,X2,Z23), (Ra5,Rb6,X2,Z24), (Ra5,Rb6,X2,Z25), (Ra5,Rb6,X2,Z26),(Ra5,Rb6,X2,Z27), (Ra5,Rb6,X2,Z28), (Ra5,Rb6,X2,Z29), (Ra5,Rb6,X2,Z30),(Ra5,Rb6,X2,Z31), (Ra5,Rb6,X2,Z32), (Ra5,Rb6,X2,Z33), (Ra5,Rb6,X2,Z34),(Ra5,Rb6,X2,Z35), (Ra5,Rb6,X2,Z36), (Ra5,Rb6,X2,Z37), (Ra5,Rb6,X2,Z38),(Ra5,Rb6,X2,Z39), (Ra5,Rb7,X1,Z1), (Ra5,Rb7,X1,Z2), (Ra5,Rb7,X1,Z3),(Ra5,Rb7,X1,Z4), (Ra5,Rb7,X1,Z5), (Ra5,Rb7,X1,Z6), (Ra5,Rb7,X1,Z7),(Ra5,Rb7,X1,Z8), (Ra5,Rb7,X1,Z9), (Ra5,Rb7,X1,Z10), (Ra5,Rb7,X1,Z11),(Ra5,Rb7,X1,Z12), (Ra5,Rb7,X1,Z13), (Ra5,Rb7,X1,Z14), (Ra5,Rb7,X1,Z15),(Ra5,Rb7,X1,Z16), (Ra5,Rb7,X1,Z17), (Ra5,Rb7,X1,Z18), (Ra5,Rb7,X1,Z19),(Ra5,Rb7,X1,Z20), (Ra5,Rb7,X1,Z21), (Ra5,Rb7,X1,Z22), (Ra5,Rb7,X1,Z23),(Ra5,Rb7,X1,Z24), (Ra5,Rb7,X1,Z25), (Ra5,Rb7,X1,Z26), (Ra5,Rb7,X1,Z27),(Ra5,Rb7,X1,Z28), (Ra5,Rb7,X1,Z29), (Ra5,Rb7,X1,Z30), (Ra5,Rb7,X1,Z31),(Ra5,Rb7,X1,Z32), (Ra5,Rb7,X1,Z33), (Ra5,Rb7,X1,Z34), (Ra5,Rb7,X1,Z35),(Ra5,Rb7,X1,Z36), (Ra5,Rb7,X1,Z37), (Ra5,Rb7,X1,Z38), (Ra5,Rb7,X1,Z39),(Ra5,Rb7,X2,Z1), (Ra5,Rb7,X2,Z2), (Ra5,Rb7,X2,Z3), (Ra5,Rb7,X2,Z4),(Ra5,Rb7,X2,Z5), (Ra5,Rb7,X2,Z6), (Ra5,Rb7,X2,Z7), (Ra5,Rb7,X2,Z8),(Ra5,Rb7,X2,Z9), (Ra5,Rb7,X2,Z10), (Ra5,Rb7,X2,Z11), (Ra5,Rb7,X2,Z12),(Ra5,Rb7,X2,Z13), (Ra5,Rb7,X2,Z14), (Ra5,Rb7,X2,Z15), (Ra5,Rb7,X2,Z16),(Ra5,Rb7,X2,Z17), (Ra5,Rb7,X2,Z18), (Ra5,Rb7,X2,Z19), (Ra5,Rb7,X2,Z20),(Ra5,Rb7,X2,Z21), (Ra5,Rb7,X2,Z22), (Ra5,Rb7,X2,Z23), (Ra5,Rb7,X2,Z24),(Ra5,Rb7,X2,Z25), (Ra5,Rb7,X2,Z26), (Ra5,Rb7,X2,Z27), (Ra5,Rb7,X2,Z28),(Ra5,Rb7,X2,Z29), (Ra5,Rb7,X2,Z30), (Ra5,Rb7,X2,Z31), (Ra5,Rb7,X2,Z32),(Ra5,Rb7,X2,Z33), (Ra5,Rb7,X2,Z34), (Ra5,Rb7,X2,Z35), (Ra5,Rb7,X2,Z36),(Ra5,Rb7,X2,Z37), (Ra5,Rb7,X2,Z38), (Ra5,Rb7,X2,Z39), (Ra5,Rb8,X1,Z1),(Ra5,Rb8,X1,Z2), (Ra5,Rb8,X1,Z3), (Ra5,Rb8,X1,Z4), (Ra5,Rb8,X1,Z5),(Ra5,Rb8,X1,Z6), (Ra5,Rb8,X1,Z7), (Ra5,Rb8,X1,Z8), (Ra5,Rb8,X1,Z9),(Ra5,Rb8,X1,Z10), (Ra5,Rb8,X1,Z11), (Ra5,Rb8,X1,Z12), (Ra5,Rb8,X1,Z13),(Ra5,Rb8,X1,Z14), (Ra5,Rb8,X1,Z15), (Ra5,Rb8,X1,Z16), (Ra5,Rb8,X1,Z17),(Ra5,Rb8,X1,Z18), (Ra5,Rb8,X1,Z19), (Ra5,Rb8,X1,Z20), (Ra5,Rb8,X1,Z21),(Ra5,Rb8,X1,Z22), (Ra5,Rb8,X1,Z23), (Ra5,Rb8,X1,Z24), (Ra5,Rb8,X1,Z25),(Ra5,Rb8,X1,Z26), (Ra5,Rb8,X1,Z27), (Ra5,Rb8,X1,Z28), (Ra5,Rb8,X1,Z29),(Ra5,Rb8,X1,Z30), (Ra5,Rb8,X1,Z31), (Ra5,Rb8,X1,Z32), (Ra5,Rb8,X1,Z33),(Ra5,Rb8,X1,Z34), (Ra5,Rb8,X1,Z35), (Ra5,Rb8,X1,Z36), (Ra5,Rb8,X1,Z37),(Ra5,Rb8,X1,Z38), (Ra5,Rb8,X1,Z39), (Ra5,Rb8,X2,Z1), (Ra5,Rb8,X2,Z2),(Ra5,Rb8,X2,Z3), (Ra5,Rb8,X2,Z4), (Ra5,Rb8,X2,Z5), (Ra5,Rb8,X2,Z6),(Ra5,Rb8,X2,Z7), (Ra5,Rb8,X2,Z8), (Ra5,Rb8,X2,Z9), (Ra5,Rb8,X2,Z10),(Ra5,Rb8,X2,Z11), (Ra5,Rb8,X2,Z12), (Ra5,Rb8,X2,Z13), (Ra5,Rb8,X2,Z14),(Ra5,Rb8,X2,Z15), (Ra5,Rb8,X2,Z16), (Ra5,Rb8,X2,Z17), (Ra5,Rb8,X2,Z18),(Ra5,Rb8,X2,Z19), (Ra5,Rb8,X2,Z20), (Ra5,Rb8,X2,Z21), (Ra5,Rb8,X2,Z22),(Ra5,Rb8,X2,Z23), (Ra5,Rb8,X2,Z24), (Ra5,Rb8,X2,Z25), (Ra5,Rb8,X2,Z26),(Ra5,Rb8,X2,Z27), (Ra5,Rb8,X2,Z28), (Ra5,Rb8,X2,Z29), (Ra5,Rb8,X2,Z30),(Ra5,Rb8,X2,Z31), (Ra5,Rb8,X2,Z32), (Ra5,Rb8,X2,Z33), (Ra5,Rb8,X2,Z34),(Ra5,Rb8,X2,Z35), (Ra5,Rb8,X2,Z36), (Ra5,Rb8,X2,Z37), (Ra5,Rb8,X2,Z38),(Ra5,Rb8,X2,Z39), (Ra6,Rb1,X1,Z1), (Ra6,Rb1,X1,Z2), (Ra6,Rb1,X1,Z3),(Ra6,Rb1,X1,Z4), (Ra6,Rb1,X1,Z5), (Ra6,Rb1,X1,Z6), (Ra6,Rb1,X1,Z7),(Ra6,Rb1,X1,Z8), (Ra6,Rb1,X1,Z9), (Ra6,Rb1,X1,Z10), (Ra6,Rb1,X1,Z11),(Ra6,Rb1,X1,Z12), (Ra6,Rb1,X1,Z13), (Ra6,Rb1,X1,Z14), (Ra6,Rb1,X1,Z15),(Ra6,Rb1,X1,Z16), (Ra6,Rb1,X1,Z17), (Ra6,Rb1,X1,Z18), (Ra6,Rb1,X1,Z19),(Ra6,Rb1,X1,Z20), (Ra6,Rb1,X1,Z21), (Ra6,Rb1,X1,Z22), (Ra6,Rb1,X1,Z23),(Ra6,Rb1,X1,Z24), (Ra6,Rb1,X1,Z25), (Ra6,Rb1,X1,Z26), (Ra6,Rb1,X1,Z27),(Ra6,Rb1,X1,Z28), (Ra6,Rb1,X1,Z29), (Ra6,Rb1,X1,Z30), (Ra6,Rb1,X1,Z31),(Ra6,Rb1,X1,Z32), (Ra6,Rb1,X1,Z33), (Ra6,Rb1,X1,Z34), (Ra6,Rb1,X1,Z35),(Ra6,Rb1,X1,Z36), (Ra6,Rb1,X1,Z37), (Ra6,Rb1,X1,Z38), (Ra6,Rb1,X1,Z39),(Ra6,Rb1,X2,Z1), (Ra6,Rb1,X2,Z2), (Ra6,Rb1,X2,Z3), (Ra6,Rb1,X2,Z4),(Ra6,Rb1,X2,Z5), (Ra6,Rb1,X2,Z6), (Ra6,Rb1,X2,Z7), (Ra6,Rb1,X2,Z8),(Ra6,Rb1,X2,Z9), (Ra6,Rb1,X2,Z10), (Ra6,Rb1,X2,Z11), (Ra6,Rb1,X2,Z12),(Ra6,Rb1,X2,Z13), (Ra6,Rb1,X2,Z14), (Ra6,Rb1,X2,Z15), (Ra6,Rb1,X2,Z16),(Ra6,Rb1,X2,Z17), (Ra6,Rb1,X2,Z18), (Ra6,Rb1,X2,Z19), (Ra6,Rb1,X2,Z20),(Ra6,Rb1,X2,Z21), (Ra6,Rb1,X2,Z22), (Ra6,Rb1,X2,Z23), (Ra6,Rb1,X2,Z24),(Ra6,Rb1,X2,Z25), (Ra6,Rb1,X2,Z26), (Ra6,Rb1,X2,Z27), (Ra6,Rb1,X2,Z28),(Ra6,Rb1,X2,Z29), (Ra6,Rb1,X2,Z30), (Ra6,Rb1,X2,Z31), (Ra6,Rb1,X2,Z32),(Ra6,Rb1,X2,Z33), (Ra6,Rb1,X2,Z34), (Ra6,Rb1,X2,Z35), (Ra6,Rb1,X2,Z36),(Ra6,Rb1,X2,Z37), (Ra6,Rb1,X2,Z38), (Ra6,Rb1,X2,Z39), (Ra6,Rb2,X1,Z1),(Ra6,Rb2,X1,Z2), (Ra6,Rb2,X1,Z3), (Ra6,Rb2,X1,Z4), (Ra6,Rb2,X1,Z5),(Ra6,Rb2,X1,Z6), (Ra6,Rb2,X1,Z7), (Ra6,Rb2,X1,Z8), (Ra6,Rb2,X1,Z9),(Ra6,Rb2,X1,Z10), (Ra6,Rb2,X1,Z11), (Ra6,Rb2,X1,Z12), (Ra6,Rb2,X1,Z13),(Ra6,Rb2,X1,Z14), (Ra6,Rb2,X1,Z15), (Ra6,Rb2,X1,Z16), (Ra6,Rb2,X1,Z17),(Ra6,Rb2,X1,Z18), (Ra6,Rb2,X1,Z19), (Ra6,Rb2,X1,Z20), (Ra6,Rb2,X1,Z21),(Ra6,Rb2,X1,Z22), (Ra6,Rb2,X1,Z23), (Ra6,Rb2,X1,Z24), (Ra6,Rb2,X1,Z25),(Ra6,Rb2,X1,Z26), (Ra6,Rb2,X1,Z27), (Ra6,Rb2,X1,Z28), (Ra6,Rb2,X1,Z29),(Ra6,Rb2,X1,Z30), (Ra6,Rb2,X1,Z31), (Ra6,Rb2,X1,Z32), (Ra6,Rb2,X1,Z33),(Ra6,Rb2,X1,Z34), (Ra6,Rb2,X1,Z35), (Ra6,Rb2,X1,Z36), (Ra6,Rb2,X1,Z37),(Ra6,Rb2,X1,Z38), (Ra6,Rb2,X1,Z39), (Ra6,Rb2,X2,Z1), (Ra6,Rb2,X2,Z2),(Ra6,Rb2,X2,Z3), (Ra6,Rb2,X2,Z4), (Ra6,Rb2,X2,Z5), (Ra6,Rb2,X2,Z6),(Ra6,Rb2,X2,Z7), (Ra6,Rb2,X2,Z8), (Ra6,Rb2,X2,Z9), (Ra6,Rb2,X2,Z10),(Ra6,Rb2,X2,Z11), (Ra6,Rb2,X2,Z12), (Ra6,Rb2,X2,Z13), (Ra6,Rb2,X2,Z14),(Ra6,Rb2,X2,Z15), (Ra6,Rb2,X2,Z16), (Ra6,Rb2,X2,Z17), (Ra6,Rb2,X2,Z18),(Ra6,Rb2,X2,Z19), (Ra6,Rb2,X2,Z20), (Ra6,Rb2,X2,Z21), (Ra6,Rb2,X2,Z22),(Ra6,Rb2,X2,Z23), (Ra6,Rb2,X2,Z24), (Ra6,Rb2,X2,Z25), (Ra6,Rb2,X2,Z26),(Ra6,Rb2,X2,Z27), (Ra6,Rb2,X2,Z28), (Ra6,Rb2,X2,Z29), (Ra6,Rb2,X2,Z30),(Ra6,Rb2,X2,Z31), (Ra6,Rb2,X2,Z32), (Ra6,Rb2,X2,Z33), (Ra6,Rb2,X2,Z34),(Ra6,Rb2,X2,Z35), (Ra6,Rb2,X2,Z36), (Ra6,Rb2,X2,Z37), (Ra6,Rb2,X2,Z38),(Ra6,Rb2,X2,Z39), (Ra6,Rb3,X1,Z1), (Ra6,Rb3,X1,Z2), (Ra6,Rb3,X1,Z3),(Ra6,Rb3,X1,Z4), (Ra6,Rb3,X1,Z5), (Ra6,Rb3,X1,Z6), (Ra6,Rb3,X1,Z7),(Ra6,Rb3,X1,Z8), (Ra6,Rb3,X1,Z9), (Ra6,Rb3,X1,Z10), (Ra6,Rb3,X1,Z11),(Ra6,Rb3,X1,Z12), (Ra6,Rb3,X1,Z13), (Ra6,Rb3,X1,Z14), (Ra6,Rb3,X1,Z15),(Ra6,Rb3,X1,Z16), (Ra6,Rb3,X1,Z17), (Ra6,Rb3,X1,Z18), (Ra6,Rb3,X1,Z19),(Ra6,Rb3,X1,Z20), (Ra6,Rb3,X1,Z21), (Ra6,Rb3,X1,Z22), (Ra6,Rb3,X1,Z23),(Ra6,Rb3,X1,Z24), (Ra6,Rb3,X1,Z25), (Ra6,Rb3,X1,Z26), (Ra6,Rb3,X1,Z27),(Ra6,Rb3,X1,Z28), (Ra6,Rb3,X1,Z29), (Ra6,Rb3,X1,Z30), (Ra6,Rb3,X1,Z31),(Ra6,Rb3,X1,Z32), (Ra6,Rb3,X1,Z33), (Ra6,Rb3,X1,Z34), (Ra6,Rb3,X1,Z35),(Ra6,Rb3,X1,Z36), (Ra6,Rb3,X1,Z37), (Ra6,Rb3,X1,Z38), (Ra6,Rb3,X1,Z39),(Ra6,Rb3,X2,Z1), (Ra6,Rb3,X2,Z2), (Ra6,Rb3,X2,Z3), (Ra6,Rb3,X2,Z4),(Ra6,Rb3,X2,Z5), (Ra6,Rb3,X2,Z6), (Ra6,Rb3,X2,Z7), (Ra6,Rb3,X2,Z8),(Ra6,Rb3,X2,Z9), (Ra6,Rb3,X2,Z10), (Ra6,Rb3,X2,Z11), (Ra6,Rb3,X2,Z12),(Ra6,Rb3,X2,Z13), (Ra6,Rb3,X2,Z14), (Ra6,Rb3,X2,Z15), (Ra6,Rb3,X2,Z16),(Ra6,Rb3,X2,Z17), (Ra6,Rb3,X2,Z18), (Ra6,Rb3,X2,Z19), (Ra6,Rb3,X2,Z20),(Ra6,Rb3,X2,Z21), (Ra6,Rb3,X2,Z22), (Ra6,Rb3,X2,Z23), (Ra6,Rb3,X2,Z24),(Ra6,Rb3,X2,Z25), (Ra6,Rb3,X2,Z26), (Ra6,Rb3,X2,Z27), (Ra6,Rb3,X2,Z28),(Ra6,Rb3,X2,Z29), (Ra6,Rb3,X2,Z30), (Ra6,Rb3,X2,Z31), (Ra6,Rb3,X2,Z32),(Ra6,Rb3,X2,Z33), (Ra6,Rb3,X2,Z34), (Ra6,Rb3,X2,Z35), (Ra6,Rb3,X2,Z36),(Ra6,Rb3,X2,Z37), (Ra6,Rb3,X2,Z38), (Ra6,Rb3,X2,Z39), (Ra6,Rb4,X1,Z1),(Ra6,Rb4,X1,Z2), (Ra6,Rb4,X1,Z3), (Ra6,Rb4,X1,Z4), (Ra6,Rb4,X1,Z5),(Ra6,Rb4,X1,Z6), (Ra6,Rb4,X1,Z7), (Ra6,Rb4,X1,Z8), (Ra6,Rb4,X1,Z9),(Ra6,Rb4,X1,Z10), (Ra6,Rb4,X1,Z11), (Ra6,Rb4,X1,Z12), (Ra6,Rb4,X1,Z13),(Ra6,Rb4,X1,Z14), (Ra6,Rb4,X1,Z15), (Ra6,Rb4,X1,Z16), (Ra6,Rb4,X1,Z17),(Ra6,Rb4,X1,Z18), (Ra6,Rb4,X1,Z19), (Ra6,Rb4,X1,Z20), (Ra6,Rb4,X1,Z21),(Ra6,Rb4,X1,Z22), (Ra6,Rb4,X1,Z23), (Ra6,Rb4,X1,Z24), (Ra6,Rb4,X1,Z25),(Ra6,Rb4,X1,Z26), (Ra6,Rb4,X1,Z27), (Ra6,Rb4,X1,Z28), (Ra6,Rb4,X1,Z29),(Ra6,Rb4,X1,Z30), (Ra6,Rb4,X1,Z31), (Ra6,Rb4,X1,Z32), (Ra6,Rb4,X1,Z33),(Ra6,Rb4,X1,Z34), (Ra6,Rb4,X1,Z35), (Ra6,Rb4,X1,Z36), (Ra6,Rb4,X1,Z37),(Ra6,Rb4,X1,Z38), (Ra6,Rb4,X1,Z39), (Ra6,Rb4,X2,Z1), (Ra6,Rb4,X2,Z2),(Ra6,Rb4,X2,Z3), (Ra6,Rb4,X2,Z4), (Ra6,Rb4,X2,Z5), (Ra6,Rb4,X2,Z6),(Ra6,Rb4,X2,Z7), (Ra6,Rb4,X2,Z8), (Ra6,Rb4,X2,Z9), (Ra6,Rb4,X2,Z10),(Ra6,Rb4,X2,Z11), (Ra6,Rb4,X2,Z12), (Ra6,Rb4,X2,Z13), (Ra6,Rb4,X2,Z14),(Ra6,Rb4,X2,Z15), (Ra6,Rb4,X2,Z16), (Ra6,Rb4,X2,Z17), (Ra6,Rb4,X2,Z18),(Ra6,Rb4,X2,Z19), (Ra6,Rb4,X2,Z20), (Ra6,Rb4,X2,Z21), (Ra6,Rb4,X2,Z22),(Ra6,Rb4,X2,Z23), (Ra6,Rb4,X2,Z24), (Ra6,Rb4,X2,Z25), (Ra6,Rb4,X2,Z26),(Ra6,Rb4,X2,Z27), (Ra6,Rb4,X2,Z28), (Ra6,Rb4,X2,Z29), (Ra6,Rb4,X2,Z30),(Ra6,Rb4,X2,Z31), (Ra6,Rb4,X2,Z32), (Ra6,Rb4,X2,Z33), (Ra6,Rb4,X2,Z34),(Ra6,Rb4,X2,Z35), (Ra6,Rb4,X2,Z36), (Ra6,Rb4,X2,Z37), (Ra6,Rb4,X2,Z38),(Ra6,Rb4,X2,Z39), (Ra6,Rb5,X1,Z1), (Ra6,Rb5,X1,Z2), (Ra6,Rb5,X1,Z3),(Ra6,Rb5,X1,Z4), (Ra6,Rb5,X1,Z5), (Ra6,Rb5,X1,Z6), (Ra6,Rb5,X1,Z7),(Ra6,Rb5,X1,Z8), (Ra6,Rb5,X1,Z9), (Ra6,Rb5,X1,Z10), (Ra6,Rb5,X1,Z11),(Ra6,Rb5,X1,Z12), (Ra6,Rb5,X1,Z13), (Ra6,Rb5,X1,Z14), (Ra6,Rb5,X1,Z15),(Ra6,Rb5,X1,Z16), (Ra6,Rb5,X1,Z17), (Ra6,Rb5,X1,Z18), (Ra6,Rb5,X1,Z19),(Ra6,Rb5,X1,Z20), (Ra6,Rb5,X1,Z21), (Ra6,Rb5,X1,Z22), (Ra6,Rb5,X1,Z23),(Ra6,Rb5,X1,Z24), (Ra6,Rb5,X1,Z25), (Ra6,Rb5,X1,Z26), (Ra6,Rb5,X1,Z27),(Ra6,Rb5,X1,Z28), (Ra6,Rb5,X1,Z29), (Ra6,Rb5,X1,Z30), (Ra6,Rb5,X1,Z31),(Ra6,Rb5,X1,Z32), (Ra6,Rb5,X1,Z33), (Ra6,Rb5,X1,Z34), (Ra6,Rb5,X1,Z35),(Ra6,Rb5,X1,Z36), (Ra6,Rb5,X1,Z37), (Ra6,Rb5,X1,Z38), (Ra6,Rb5,X1,Z39),(Ra6,Rb5,X2,Z1), (Ra6,Rb5,X2,Z2), (Ra6,Rb5,X2,Z3), (Ra6,Rb5,X2,Z4),(Ra6,Rb5,X2,Z5), (Ra6,Rb5,X2,Z6), (Ra6,Rb5,X2,Z7), (Ra6,Rb5,X2,Z8),(Ra6,Rb5,X2,Z9), (Ra6,Rb5,X2,Z10), (Ra6,Rb5,X2,Z11), (Ra6,Rb5,X2,Z12),(Ra6,Rb5,X2,Z13), (Ra6,Rb5,X2,Z14), (Ra6,Rb5,X2,Z15), (Ra6,Rb5,X2,Z16),(Ra6,Rb5,X2,Z17), (Ra6,Rb5,X2,Z18), (Ra6,Rb5,X2,Z19), (Ra6,Rb5,X2,Z20),(Ra6,Rb5,X2,Z21), (Ra6,Rb5,X2,Z22), (Ra6,Rb5,X2,Z23), (Ra6,Rb5,X2,Z24),(Ra6,Rb5,X2,Z25), (Ra6,Rb5,X2,Z26), (Ra6,Rb5, X2,Z27), (Ra6,Rb5,X2,Z28),(Ra6,Rb5,X2,Z29), (Ra6,Rb5,X2,Z30), (Ra6,Rb5,X2,Z31), (Ra6,Rb5,X2,Z32),(Ra6,Rb5,X2,Z33), (Ra6,Rb5,X2,Z34), (Ra6,Rb5,X2,Z35), (Ra6,Rb5,X2,Z36),(Ra6,Rb5,X2,Z37), (Ra6,Rb5,X2,Z38), (Ra6,Rb5,X2,Z39), (Ra6,Rb6,X1,Z1),(Ra6,Rb6,X1,Z2), (Ra6,Rb6,X1,Z3), (Ra6,Rb6,X1,Z4), (Ra6,Rb6,X1,Z5),(Ra6,Rb6,X1,Z6), (Ra6,Rb6,X1,Z7), (Ra6,Rb6,X1,Z8), (Ra6,Rb6,X1,Z9),(Ra6,Rb6,X1,Z10), (Ra6,Rb6,X1,Z11), (Ra6,Rb6,X1,Z12), (Ra6,Rb6,X1,Z13),(Ra6,Rb6,X1,Z14), (Ra6,Rb6,X1,Z15), (Ra6,Rb6,X1,Z16), (Ra6,Rb6,X1,Z17),(Ra6,Rb6,X1,Z18), (Ra6,Rb6,X1,Z19), (Ra6,Rb6,X1,Z20), (Ra6,Rb6,X1,Z21),(Ra6,Rb6,X1,Z22), (Ra6,Rb6,X1,Z23), (Ra6,Rb6,X1,Z24), (Ra6,Rb6,X1,Z25),(Ra6,Rb6,X1,Z26), (Ra6,Rb6,X1,Z27), (Ra6,Rb6,X1,Z28), (Ra6,Rb6,X1,Z29),(Ra6,Rb6,X1,Z30), (Ra6,Rb6,X1,Z31), (Ra6,Rb6,X1,Z32), (Ra6,Rb6,X1,Z33),(Ra6,Rb6,X1,Z34), (Ra6,Rb6,X1,Z35), (Ra6,Rb6,X1,Z36), (Ra6,Rb6,X1,Z37),(Ra6,Rb6,X1,Z38), (Ra6,Rb6,X1,Z39), (Ra6,Rb6,X2,Z1), (Ra6,Rb6,X2,Z2),(Ra6,Rb6,X2,Z3), (Ra6,Rb6,X2,Z4), (Ra6,Rb6,X2,Z5), (Ra6,Rb6,X2,Z6),(Ra6,Rb6,X2,Z7), (Ra6,Rb6,X2,Z8), (Ra6,Rb6,X2,Z9), (Ra6,Rb6,X2,Z10),(Ra6,Rb6,X2,Z11), (Ra6,Rb6,X2,Z12), (Ra6,Rb6,X2,Z13), (Ra6,Rb6,X2,Z14),(Ra6,Rb6,X2,Z15), (Ra6,Rb6,X2,Z16), (Ra6,Rb6,X2,Z17), (Ra6,Rb6,X2,Z18),(Ra6,Rb6,X2,Z19), (Ra6,Rb6,X2,Z20), (Ra6,Rb6,X2,Z21), (Ra6,Rb6,X2,Z22),(Ra6,Rb6,X2,Z23), (Ra6,Rb6,X2,Z24), (Ra6,Rb6,X2,Z25), (Ra6,Rb6,X2,Z26),(Ra6,Rb6,X2,Z27), (Ra6,Rb6,X2,Z28), (Ra6,Rb6,X2,Z29), (Ra6,Rb6,X2,Z30),(Ra6,Rb6,X2,Z31), (Ra6,Rb6,X2,Z32), (Ra6,Rb6,X2,Z33), (Ra6,Rb6,X2,Z34),(Ra6,Rb6,X2,Z35), (Ra6,Rb6,X2,Z36), (Ra6,Rb6,X2,Z37), (Ra6,Rb6,X2,Z38),(Ra6,Rb6,X2,Z39), (Ra6,Rb7,X1,Z1), (Ra6,Rb7,X1,Z2), (Ra6,Rb7,X1,Z3),(Ra6,Rb7,X1,Z4), (Ra6,Rb7,X1,Z5), (Ra6,Rb7,X1,Z6), (Ra6,Rb7,X1,Z7),(Ra6,Rb7,X1,Z8), (Ra6,Rb7,X1,Z9), (Ra6,Rb7,X1,Z10), (Ra6,Rb7,X1,Z11),(Ra6,Rb7,X1,Z12), (Ra6,Rb7,X1,Z13), (Ra6,Rb7,X1,Z14), (Ra6,Rb7,X1,Z15),(Ra6,Rb7,X1,Z16), (Ra6,Rb7,X1,Z17), (Ra6,Rb7,X1,Z18), (Ra6,Rb7,X1,Z19),(Ra6,Rb7,X1,Z20), (Ra6,Rb7,X1,Z21), (Ra6,Rb7,X1,Z22), (Ra6,Rb7,X1,Z23),(Ra6,Rb7,X1,Z24), (Ra6,Rb7,X1,Z25), (Ra6,Rb7,X1,Z26), (Ra6,Rb7,X1,Z27),(Ra6,Rb7,X1,Z28), (Ra6,Rb7,X1,Z29), (Ra6,Rb7,X1,Z30), (Ra6,Rb7,X1,Z31),(Ra6,Rb7,X1,Z32), (Ra6,Rb7,X1,Z33), (Ra6,Rb7,X1,Z34), (Ra6,Rb7,X1,Z35),(Ra6,Rb7,X1,Z36), (Ra6,Rb7,X1,Z37), (Ra6,Rb7,X1,Z38), (Ra6,Rb7,X1,Z39),(Ra6,Rb7,X2,Z1), (Ra6,Rb7,X2,Z2), (Ra6,Rb7,X2,Z3), (Ra6,Rb7,X2,Z4),(Ra6,Rb7,X2,Z5), (Ra6,Rb7,X2,Z6), (Ra6,Rb7,X2,Z7), (Ra6,Rb7,X2,Z8),(Ra6,Rb7,X2,Z9), (Ra6,Rb7,X2,Z10), (Ra6,Rb7,X2,Z11), (Ra6,Rb7,X2,Z12),(Ra6,Rb7,X2,Z13), (Ra6,Rb7,X2,Z14), (Ra6,Rb7,X2,Z15), (Ra6,Rb7,X2,Z16),(Ra6,Rb7,X2,Z17), (Ra6,Rb7,X2,Z18), (Ra6,Rb7,X2,Z19), (Ra6,Rb7,X2,Z20),(Ra6,Rb7,X2,Z21), (Ra6,Rb7,X2,Z22), (Ra6,Rb7,X2,Z23), (Ra6,Rb7,X2,Z24),(Ra6,Rb7,X2,Z25), (Ra6,Rb7,X2,Z26), (Ra6,Rb7,X2,Z27), (Ra6,Rb7,X2,Z28),(Ra6,Rb7,X2,Z29), (Ra6,Rb7,X2,Z30), (Ra6,Rb7,X2,Z31), (Ra6,Rb7,X2,Z32),(Ra6,Rb7,X2,Z33), (Ra6,Rb7,X2,Z34), (Ra6,Rb7,X2,Z35), (Ra6,Rb7,X2,Z36),(Ra6,Rb7,X2,Z37), (Ra6,Rb7,X2,Z38), (Ra6,Rb7,X2,Z39), (Ra6,Rb8,X1,Z1),(Ra6,Rb8,X1,Z2), (Ra6,Rb8,X1,Z3), (Ra6,Rb8,X1,Z4), (Ra6,Rb8,X1,Z5),(Ra6,Rb8,X1,Z6), (Ra6,Rb8,X1,Z7), (Ra6,Rb8,X1,Z8), (Ra6,Rb8,X1,Z9),(Ra6,Rb8,X1,Z10), (Ra6,Rb8,X1,Z11), (Ra6,Rb8,X1,Z12), (Ra6,Rb8,X1,Z13),(Ra6,Rb8,X1,Z14), (Ra6,Rb8,X1,Z15), (Ra6,Rb8,X1,Z16), (Ra6,Rb8,X1,Z17),(Ra6,Rb8,X1,Z18), (Ra6,Rb8,X1,Z19), (Ra6,Rb8,X1,Z20), (Ra6,Rb8,X1,Z21),(Ra6,Rb8,X1,Z22), (Ra6,Rb8,X1,Z23), (Ra6,Rb8,X1,Z24), (Ra6,Rb8,X1,Z25),(Ra6,Rb8,X1,Z26), (Ra6,Rb8,X1,Z27), (Ra6,Rb8,X1,Z28), (Ra6,Rb8,X1,Z29),(Ra6,Rb8,X1,Z30), (Ra6,Rb8,X1,Z31), (Ra6,Rb8,X1,Z32), (Ra6,Rb8,X1,Z33),(Ra6,Rb8,X1,Z34), (Ra6,Rb8,X1,Z35), (Ra6,Rb8,X1,Z36), (Ra6,Rb8,X1,Z37),(Ra6,Rb8,X1,Z38), (Ra6,Rb8,X1,Z39), (Ra6,Rb8,X2,Z1), (Ra6,Rb8,X2,Z2),(Ra6,Rb8,X2,Z3), (Ra6,Rb8,X2,Z4), (Ra6,Rb8,X2,Z5), (Ra6,Rb8,X2,Z6),(Ra6,Rb8,X2,Z7), (Ra6,Rb8,X2,Z8), (Ra6,Rb8,X2,Z9), (Ra6,Rb8,X2,Z10),(Ra6,Rb8,X2,Z11), (Ra6,Rb8,X2,Z12), (Ra6,Rb8,X2,Z13), (Ra6,Rb8,X2,Z14),(Ra6,Rb8,X2,Z15), (Ra6,Rb8,X2,Z16), (Ra6,Rb8,X2,Z17), (Ra6,Rb8,X2,Z18),(Ra6,Rb8,X2,Z19), (Ra6,Rb8,X2,Z20), (Ra6,Rb8,X2,Z21), (Ra6,Rb8,X2,Z22),(Ra6,Rb8,X2,Z23), (Ra6,Rb8,X2,Z24), (Ra6,Rb8,X2,Z25), (Ra6,Rb8,X2,Z26),(Ra6,Rb8,X2,Z27), (Ra6,Rb8,X2,Z28), (Ra6,Rb8,X2,Z29), (Ra6,Rb8,X2,Z30),(Ra6,Rb8,X2,Z31), (Ra6,Rb8,X2,Z32), (Ra6,Rb8,X2,Z33), (Ra6,Rb8,X2,Z34),(Ra6,Rb8,X2,Z35), (Ra6,Rb8,X2,Z36), (Ra6,Rb8,X2,Z37), (Ra6,Rb8,X2,Z38),(Ra6,Rb8,X2,Z39), (Ra7,Rb1,X1,Z1), (Ra7,Rb1,X1,Z2), (Ra7,Rb1,X1,Z3),(Ra7,Rb1,X1,Z4), (Ra7,Rb1,X1,Z5), (Ra7,Rb1,X1,Z6), (Ra7,Rb1,X1,Z7),(Ra7,Rb1,X1,Z8), (Ra7,Rb1,X1,Z9), (Ra7,Rb1,X1,Z10), (Ra7,Rb1,X1,Z11),(Ra7,Rb1,X1,Z12), (Ra7,Rb1,X1,Z13), (Ra7,Rb1,X1,Z14), (Ra7,Rb1,X1,Z15),(Ra7,Rb1,X1,Z16), (Ra7,Rb1,X1,Z17), (Ra7,Rb1,X1,Z18), (Ra7,Rb1,X1,Z19),(Ra7,Rb1,X1,Z20), (Ra7,Rb1,X1,Z21), (Ra7,Rb1,X1,Z22), (Ra7,Rb1,X1,Z23),(Ra7,Rb1,X1,Z24), (Ra7,Rb1,X1,Z25), (Ra7,Rb1,X1,Z26), (Ra7,Rb1,X1,Z27),(Ra7,Rb1,X1,Z28), (Ra7,Rb1,X1,Z29), (Ra7,Rb1,X1,Z30), (Ra7,Rb1,X1,Z31),(Ra7,Rb1,X1,Z32), (Ra7,Rb1,X1,Z33), (Ra7,Rb1,X1,Z34), (Ra7,Rb1,X1,Z35),(Ra7,Rb1,X1,Z36), (Ra7,Rb1,X1,Z37), (Ra7,Rb1,X1,Z38), (Ra7,Rb1,X1,Z39),(Ra7,Rb1,X2,Z1), (Ra7,Rb1,X2,Z2), (Ra7,Rb1,X2,Z3), (Ra7,Rb1,X2,Z4),(Ra7,Rb1,X2,Z5), (Ra7,Rb1,X2,Z6), (Ra7,Rb1,X2,Z7), (Ra7,Rb1,X2,Z8),(Ra7,Rb1,X2,Z9), (Ra7,Rb1,X2,Z10), (Ra7,Rb1,X2,Z11), (Ra7,Rb1,X2,Z12),(Ra7,Rb1,X2,Z13), (Ra7,Rb1,X2,Z14), (Ra7,Rb1,X2,Z15), (Ra7,Rb1,X2,Z16),(Ra7,Rb1,X2,Z17), (Ra7,Rb1,X2,Z18), (Ra7,Rb1,X2,Z19), (Ra7,Rb1,X2,Z20),(Ra7,Rb1,X2,Z21), (Ra7,Rb1,X2,Z22), (Ra7,Rb1,X2,Z23), (Ra7,Rb1,X2,Z24),(Ra7,Rb1,X2,Z25), (Ra7,Rb1,X2,Z26), (Ra7,Rb1,X2,Z27), (Ra7,Rb1,X2,Z28),(Ra7,Rb1,X2,Z29), (Ra7,Rb1,X2,Z30), (Ra7,Rb1,X2,Z31), (Ra7,Rb1,X2,Z32),(Ra7,Rb1,X2,Z33), (Ra7,Rb1,X2,Z34), (Ra7,Rb1,X2,Z35), (Ra7,Rb1,X2,Z36),(Ra7,Rb1,X2,Z37), (Ra7,Rb1,X2,Z38), (Ra7,Rb1,X2,Z39), (Ra7,Rb2,X1,Z1),(Ra7,Rb2,X1,Z2), (Ra7,Rb2,X1,Z3), (Ra7,Rb2,X1,Z4), (Ra7,Rb2,X1,Z5),(Ra7,Rb2,X1,Z6), (Ra7,Rb2,X1,Z7), (Ra7,Rb2,X1,Z8), (Ra7,Rb2,X1,Z9),(Ra7,Rb2,X1,Z10), (Ra7,Rb2,X1,Z11), (Ra7,Rb2,X1,Z12), (Ra7,Rb2,X1,Z13),(Ra7,Rb2,X1,Z14), (Ra7,Rb2,X1,Z15), (Ra7,Rb2,X1,Z16), (Ra7,Rb2,X1,Z17),(Ra7,Rb2,X1,Z18), (Ra7,Rb2,X1,Z19), (Ra7,Rb2,X1,Z20), (Ra7,Rb2,X1,Z21),(Ra7,Rb2,X1,Z22), (Ra7,Rb2,X1,Z23), (Ra7,Rb2,X1,Z24), (Ra7,Rb2,X1,Z25),(Ra7,Rb2,X1,Z26), (Ra7,Rb2,X1,Z27), (Ra7,Rb2,X1,Z28), (Ra7,Rb2,X1,Z29),(Ra7,Rb2,X1,Z30), (Ra7,Rb2,X1,Z31), (Ra7,Rb2,X1,Z32), (Ra7,Rb2,X1,Z33),(Ra7,Rb2,X1,Z34), (Ra7,Rb2,X1,Z35), (Ra7,Rb2,X1,Z36), (Ra7,Rb2,X1,Z37),(Ra7,Rb2,X1,Z38), (Ra7,Rb2,X1,Z39), (Ra7,Rb2,X2,Z1), (Ra7,Rb2,X2,Z2),(Ra7,Rb2,X2,Z3), (Ra7,Rb2,X2,Z4), (Ra7,Rb2,X2,Z5), (Ra7,Rb2,X2,Z6),(Ra7,Rb2,X2,Z7), (Ra7,Rb2,X2,Z8), (Ra7,Rb2,X2,Z9), (Ra7,Rb2,X2,Z10),(Ra7,Rb2,X2,Z11), (Ra7,Rb2,X2,Z12), (Ra7,Rb2,X2,Z13), (Ra7,Rb2,X2,Z14),(Ra7,Rb2,X2,Z15), (Ra7,Rb2,X2,Z16), (Ra7,Rb2,X2,Z17), (Ra7,Rb2,X2,Z18),(Ra7,Rb2,X2,Z19), (Ra7,Rb2,X2,Z20), (Ra7,Rb2,X2,Z21), (Ra7,Rb2,X2,Z22),(Ra7,Rb2,X2,Z23), (Ra7,Rb2,X2,Z24), (Ra7,Rb2,X2,Z25), (Ra7,Rb2,X2,Z26),(Ra7,Rb2,X2,Z27), (Ra7,Rb2,X2,Z28), (Ra7,Rb2,X2,Z29), (Ra7,Rb2,X2,Z30),(Ra7,Rb2,X2,Z31), (Ra7,Rb2,X2,Z32), (Ra7,Rb2,X2,Z33), (Ra7,Rb2,X2,Z34),(Ra7,Rb2,X2,Z35), (Ra7,Rb2,X2,Z36), (Ra7,Rb2,X2,Z37), (Ra7,Rb2,X2,Z38),(Ra7,Rb2,X2,Z39), (Ra7,Rb3,X1,Z1), (Ra7,Rb3,X1,Z2), (Ra7,Rb3,X1,Z3),(Ra7,Rb3,X1,Z4), (Ra7,Rb3,X1,Z5), (Ra7,Rb3,X1,Z6), (Ra7,Rb3,X1,Z7),(Ra7,Rb3,X1,Z8), (Ra7,Rb3,X1,Z9), (Ra7,Rb3,X1,Z10), (Ra7,Rb3,X1,Z11),(Ra7,Rb3,X1,Z12), (Ra7,Rb3,X1,Z13), (Ra7,Rb3,X1,Z14), (Ra7,Rb3,X1,Z15),(Ra7,Rb3,X1,Z16), (Ra7,Rb3,X1,Z17), (Ra7,Rb3,X1,Z18), (Ra7,Rb3,X1,Z19),(Ra7,Rb3,X1,Z20), (Ra7,Rb3,X1,Z21), (Ra7,Rb3,X1,Z22), (Ra7,Rb3,X1,Z23),(Ra7,Rb3,X1,Z24), (Ra7,Rb3,X1,Z25), (Ra7,Rb3,X1,Z26), (Ra7,Rb3,X1,Z27),(Ra7,Rb3,X1,Z28), (Ra7,Rb3,X1,Z29), (Ra7,Rb3,X1,Z30), (Ra7,Rb3,X1,Z31),(Ra7,Rb3,X1,Z32), (Ra7,Rb3,X1,Z33), (Ra7,Rb3,X1,Z34), (Ra7,Rb3,X1,Z35),(Ra7,Rb3,X1,Z36), (Ra7,Rb3,X1,Z37), (Ra7,Rb3,X1,Z38), (Ra7,Rb3,X1,Z39),(Ra7,Rb3,X2,Z1), (Ra7,Rb3,X2,Z2), (Ra7,Rb3,X2,Z3), (Ra7,Rb3,X2,Z4),(Ra7,Rb3,X2,Z5), (Ra7,Rb3,X2,Z6), (Ra7,Rb3,X2,Z7), (Ra7,Rb3,X2,Z8),(Ra7,Rb3,X2,Z9), (Ra7,Rb3,X2,Z10), (Ra7,Rb3,X2,Z11), (Ra7,Rb3,X2,Z12),(Ra7,Rb3,X2,Z13), (Ra7,Rb3,X2,Z14), (Ra7,Rb3,X2,Z15), (Ra7,Rb3,X2,Z16),(Ra7,Rb3,X2,Z17), (Ra7,Rb3,X2,Z18), (Ra7,Rb3,X2,Z19), (Ra7,Rb3,X2,Z20),(Ra7,Rb3,X2,Z21), (Ra7,Rb3,X2,Z22), (Ra7,Rb3,X2,Z23), (Ra7,Rb3,X2,Z24),(Ra7,Rb3,X2,Z25), (Ra7,Rb3,X2,Z26), (Ra7,Rb3,X2,Z27), (Ra7,Rb3,X2,Z28),(Ra7,Rb3,X2,Z29), (Ra7,Rb3,X2,Z30), (Ra7,Rb3,X2,Z31), (Ra7,Rb3,X2,Z32),(Ra7,Rb3,X2,Z33), (Ra7,Rb3,X2,Z34), (Ra7,Rb3,X2,Z35), (Ra7,Rb3,X2,Z36),(Ra7,Rb3,X2,Z37), (Ra7,Rb3,X2,Z38), (Ra7,Rb3,X2,Z39), (Ra7,Rb4,X1,Z1),(Ra7,Rb4,X1,Z2), (Ra7,Rb4,X1,Z3), (Ra7,Rb4,X1,Z4), (Ra7,Rb4,X1,Z5),(Ra7,Rb4,X1,Z6), (Ra7,Rb4,X1,Z7), (Ra7,Rb4,X1,Z8), (Ra7,Rb4,X1,Z9),(Ra7,Rb4,X1,Z10), (Ra7,Rb4,X1,Z11), (Ra7,Rb4,X1,Z12), (Ra7,Rb4,X1,Z13),(Ra7,Rb4,X1,Z14), (Ra7,Rb4,X1,Z15), (Ra7,Rb4,X1,Z16), (Ra7,Rb4,X1,Z17),(Ra7,Rb4,X1,Z18), (Ra7,Rb4,X1,Z19), (Ra7,Rb4,X1,Z20), (Ra7,Rb4,X1,Z21),(Ra7,Rb4,X1,Z22), (Ra7,Rb4,X1,Z23), (Ra7,Rb4,X1,Z24), (Ra7,Rb4,X1,Z25),(Ra7,Rb4,X1,Z26), (Ra7,Rb4,X1,Z27), (Ra7,Rb4,X1,Z28), (Ra7,Rb4,X1,Z29),(Ra7,Rb4,X1,Z30), (Ra7,Rb4,X1,Z31), (Ra7,Rb4,X1,Z32), (Ra7,Rb4,X1,Z33),(Ra7,Rb4,X1,Z34), (Ra7,Rb4,X1,Z35), (Ra7,Rb4,X1,Z36), (Ra7,Rb4,X1,Z37),(Ra7,Rb4,X1,Z38), (Ra7,Rb4,X1,Z39), (Ra7,Rb4,X2,Z1), (Ra7,Rb4,X2,Z2),(Ra7,Rb4,X2,Z3), (Ra7,Rb4,X2,Z4), (Ra7,Rb4,X2,Z5), (Ra7,Rb4,X2,Z6),(Ra7,Rb4,X2,Z7), (Ra7,Rb4,X2,Z8), (Ra7,Rb4,X2,Z9), (Ra7,Rb4,X2,Z10),(Ra7,Rb4,X2,Z11), (Ra7,Rb4,X2,Z12), (Ra7,Rb4,X2,Z13), (Ra7,Rb4,X2,Z14),(Ra7,Rb4,X2,Z15), (Ra7,Rb4,X2,Z16), (Ra7,Rb4,X2,Z17), (Ra7,Rb4,X2,Z18),(Ra7,Rb4,X2,Z19), (Ra7,Rb4,X2,Z20), (Ra7,Rb4,X2,Z21), (Ra7,Rb4,X2,Z22),(Ra7,Rb4,X2,Z23), (Ra7,Rb4,X2,Z24), (Ra7,Rb4,X2,Z25), (Ra7,Rb4,X2,Z26),(Ra7,Rb4,X2,Z27), (Ra7,Rb4,X2,Z28), (Ra7,Rb4,X2,Z29), (Ra7,Rb4,X2,Z30),(Ra7,Rb4,X2,Z31), (Ra7,Rb4,X2,Z32), (Ra7,Rb4,X2,Z33), (Ra7,Rb4,X2,Z34),(Ra7,Rb4,X2,Z35), (Ra7,Rb4,X2,Z36), (Ra7,Rb4,X2,Z37), (Ra7,Rb4,X2,Z38),(Ra7,Rb4,X2,Z39), (Ra7,Rb5,X1,Z1), (Ra7,Rb5,X1,Z2), (Ra7,Rb5,X1,Z3),(Ra7,Rb5,X1,Z4), (Ra7,Rb5,X1,Z5), (Ra7,Rb5,X1,Z6), (Ra7,Rb5,X1,Z7),(Ra7,Rb5,X1,Z8), (Ra7,Rb5,X1,Z9), (Ra7,Rb5,X1,Z10), (Ra7,Rb5,X1,Z11),(Ra7,Rb5,X1,Z12), (Ra7,Rb5,X1,Z13), (Ra7,Rb5,X1,Z14), (Ra7,Rb5,X1,Z15),(Ra7,Rb5,X1,Z16), (Ra7,Rb5,X1,Z17), (Ra7,Rb5,X1,Z18), (Ra7,Rb5,X1,Z19),(Ra7,Rb5,X1,Z20), (Ra7,Rb5,X1,Z21), (Ra7,Rb5,X1,Z22), (Ra7,Rb5,X1,Z23),(Ra7,Rb5,X1,Z24), (Ra7,Rb5,X1,Z25), (Ra7,Rb5,X1,Z26), (Ra7,Rb5,X1,Z27),(Ra7,Rb5,X1,Z28), (Ra7,Rb5,X1,Z29), (Ra7,Rb5,X1,Z30), (Ra7,Rb5,X1,Z31),(Ra7,Rb5,X1,Z32), (Ra7,Rb5,X1,Z33), (Ra7,Rb5,X1,Z34), (Ra7,Rb5,X1,Z35),(Ra7,Rb5,X1,Z36), (Ra7,Rb5,X1,Z37), (Ra7,Rb5,X1,Z38), (Ra7,Rb5,X1,Z39),(Ra7,Rb5,X2,Z1), (Ra7,Rb5,X2,Z2), (Ra7,Rb5,X2,Z3), (Ra7,Rb5,X2,Z4),(Ra7,Rb5,X2,Z5), (Ra7,Rb5,X2,Z6), (Ra7,Rb5,X2,Z7), (Ra7,Rb5,X2,Z8),(Ra7,Rb5,X2,Z9), (Ra7,Rb5,X2,Z10), (Ra7,Rb5,X2,Z11), (Ra7,Rb5,X2,Z12),(Ra7,Rb5,X2,Z13), (Ra7,Rb5,X2,Z14), (Ra7,Rb5,X2,Z15), (Ra7,Rb5,X2,Z16),(Ra7,Rb5,X2,Z17), (Ra7,Rb5,X2,Z18), (Ra7,Rb5,X2,Z19), (Ra7,Rb5,X2,Z20),(Ra7,Rb5,X2,Z21), (Ra7,Rb5,X2,Z22), (Ra7,Rb5,X2,Z23), (Ra7,Rb5,X2,Z24),(Ra7,Rb5,X2,Z25), (Ra7,Rb5,X2,Z26), (Ra7,Rb5,X2,Z27), (Ra7,Rb5,X2,Z28),(Ra7,Rb5,X2,Z29), (Ra7,Rb5,X2,Z30), (Ra7,Rb5,X2,Z31), (Ra7,Rb5,X2,Z32),(Ra7,Rb5,X2,Z33), (Ra7,Rb5,X2,Z34), (Ra7,Rb5,X2,Z35), (Ra7,Rb5,X2,Z36),(Ra7,Rb5,X2,Z37), (Ra7,Rb5,X2,Z38), (Ra7,Rb5,X2,Z39), (Ra7,Rb6,X1,Z1),(Ra7,Rb6,X1,Z2), (Ra7,Rb6,X1,Z3), (Ra7,Rb6,X1,Z4), (Ra7,Rb6,X1,Z5),(Ra7,Rb6,X1,Z6), (Ra7,Rb6,X1,Z7), (Ra7,Rb6,X1,Z8), (Ra7,Rb6,X1,Z9),(Ra7,Rb6,X1,Z10), (Ra7,Rb6,X1,Z11), (Ra7,Rb6,X1,Z12), (Ra7,Rb6,X1,Z13),(Ra7,Rb6,X1,Z14), (Ra7,Rb6,X1,Z15), (Ra7,Rb6,X1,Z16), (Ra7,Rb6,X1,Z17),(Ra7,Rb6,X1,Z18), (Ra7,Rb6,X1,Z19), (Ra7,Rb6,X1,Z20), (Ra7,Rb6,X1,Z21),(Ra7,Rb6,X1,Z22), (Ra7,Rb6,X1,Z23), (Ra7,Rb6,X1,Z24), (Ra7,Rb6,X1,Z25),(Ra7,Rb6,X1,Z26), (Ra7,Rb6,X1,Z27), (Ra7,Rb6,X1,Z28), (Ra7,Rb6,X1,Z29),(Ra7,Rb6,X1,Z30), (Ra7,Rb6,X1,Z31), (Ra7,Rb6,X1,Z32), (Ra7,Rb6,X1,Z33),(Ra7,Rb6,X1,Z34), (Ra7,Rb6,X1,Z35), (Ra7,Rb6,X1,Z36), (Ra7,Rb6,X1,Z37),(Ra7,Rb6,X1,Z38), (Ra7,Rb6,X1,Z39), (Ra7,Rb6,X2,Z1), (Ra7,Rb6,X2,Z2),(Ra7,Rb6,X2,Z3), (Ra7,Rb6,X2,Z4), (Ra7,Rb6,X2,Z5), (Ra7,Rb6,X2,Z6),(Ra7,Rb6,X2,Z7), (Ra7,Rb6,X2,Z8), (Ra7,Rb6,X2,Z9), (Ra7,Rb6,X2,Z10),(Ra7,Rb6,X2,Z11), (Ra7,Rb6,X2,Z12), (Ra7,Rb6,X2,Z13), (Ra7,Rb6,X2,Z14),(Ra7,Rb6,X2,Z15), (Ra7,Rb6,X2,Z16), (Ra7,Rb6,X2,Z17), (Ra7,Rb6,X2,Z18),(Ra7,Rb6,X2,Z19), (Ra7,Rb6,X2,Z20), (Ra7,Rb6,X2,Z21), (Ra7,Rb6,X2,Z22),(Ra7,Rb6,X2,Z23), (Ra7,Rb6,X2,Z24), (Ra7,Rb6,X2,Z25), (Ra7,Rb6,X2,Z26),(Ra7,Rb6,X2,Z27), (Ra7,Rb6,X2,Z28), (Ra7,Rb6,X2,Z29), (Ra7,Rb6,X2,Z30),(Ra7,Rb6,X2,Z31), (Ra7,Rb6,X2,Z32), (Ra7,Rb6,X2,Z33), (Ra7,Rb6,X2,Z34),(Ra7,Rb6,X2,Z35), (Ra7,Rb6,X2,Z36), (Ra7,Rb6,X2,Z37), (Ra7,Rb6,X2,Z38),(Ra7,Rb6,X2,Z39), (Ra7,Rb7,X1,Z1), (Ra7,Rb7,X1,Z2), (Ra7,Rb7,X1,Z3),(Ra7,Rb7,X1,Z4), (Ra7,Rb7,X1,Z5), (Ra7,Rb7,X1,Z6), (Ra7,Rb7,X1,Z7),(Ra7,Rb7,X1,Z8), (Ra7,Rb7,X1,Z9), (Ra7,Rb7,X1,Z10), (Ra7,Rb7,X1,Z11),(Ra7,Rb7,X1,Z12), (Ra7,Rb7,X1,Z13), (Ra7,Rb7,X1,Z14), (Ra7,Rb7,X1,Z15),(Ra7,Rb7,X1,Z16), (Ra7,Rb7,X1,Z17), (Ra7,Rb7,X1,Z18), (Ra7,Rb7,X1,Z19),(Ra7,Rb7,X1,Z20), (Ra7,Rb7,X1,Z21), (Ra7,Rb7,X1,Z22), (Ra7,Rb7,X1,Z23),(Ra7,Rb7,X1,Z24), (Ra7,Rb7,X1,Z25), (Ra7,Rb7,X1,Z26), (Ra7,Rb7,X1,Z27),(Ra7,Rb7,X1,Z28), (Ra7,Rb7,X1,Z29), (Ra7,Rb7,X1,Z30), (Ra7,Rb7,X1,Z31),(Ra7,Rb7,X1,Z32), (Ra7,Rb7,X1,Z33), (Ra7,Rb7,X1,Z34), (Ra7,Rb7,X1,Z35),(Ra7,Rb7,X1,Z36), (Ra7,Rb7,X1,Z37), (Ra7,Rb7,X1,Z38), (Ra7,Rb7,X1,Z39),(Ra7,Rb7,X2,Z1), (Ra7,Rb7,X2,Z2), (Ra7,Rb7,X2,Z3), (Ra7,Rb7,X2,Z4),(Ra7,Rb7,X2,Z5), (Ra7,Rb7,X2,Z6), (Ra7,Rb7,X2,Z7), (Ra7,Rb7,X2,Z8),(Ra7,Rb7,X2,Z9), (Ra7,Rb7,X2,Z10), (Ra7,Rb7,X2,Z11), (Ra7,Rb7,X2,Z12),(Ra7,Rb7,X2,Z13), (Ra7,Rb7,X2,Z14), (Ra7,Rb7,X2,Z15), (Ra7,Rb7,X2,Z16),(Ra7,Rb7,X2,Z17), (Ra7,Rb7,X2,Z18), (Ra7,Rb7,X2,Z19), (Ra7,Rb7,X2,Z20),(Ra7,Rb7,X2,Z21), (Ra7,Rb7,X2,Z22), (Ra7,Rb7,X2,Z23), (Ra7,Rb7,X2,Z24),(Ra7,Rb7,X2,Z25), (Ra7,Rb7,X2,Z26), (Ra7,Rb7,X2,Z27), (Ra7,Rb7,X2,Z28),(Ra7,Rb7,X2,Z29), (Ra7,Rb7,X2,Z30), (Ra7,Rb7,X2,Z31), (Ra7,Rb7,X2,Z32),(Ra7,Rb7,X2,Z33), (Ra7,Rb7,X2,Z34), (Ra7,Rb7,X2,Z35), (Ra7,Rb7,X2,Z36),(Ra7,Rb7,X2,Z37), (Ra7,Rb7,X2,Z38), (Ra7,Rb7,X2,Z39), (Ra7,Rb8,X1,Z1),(Ra7,Rb8,X1,Z2), (Ra7,Rb8,X1,Z3), (Ra7,Rb8,X1,Z4), (Ra7,Rb8,X1,Z5),(Ra7,Rb8,X1,Z6), (Ra7,Rb8,X1,Z7), (Ra7,Rb8,X1,Z8), (Ra7,Rb8,X1,Z9),(Ra7,Rb8,X1,Z10), (Ra7,Rb8,X1,Z11), (Ra7,Rb8,X1,Z12), (Ra7,Rb8,X1,Z13),(Ra7,Rb8,X1,Z14), (Ra7,Rb8,X1,Z15), (Ra7,Rb8,X1,Z16), (Ra7,Rb8,X1,Z17),(Ra7,Rb8,X1,Z18), (Ra7,Rb8,X1,Z19), (Ra7,Rb8,X1,Z20), (Ra7,Rb8,X1,Z21),(Ra7,Rb8,X1,Z22), (Ra7,Rb8,X1,Z23), (Ra7,Rb8,X1,Z24), (Ra7,Rb8,Z25),(Ra7,Rb8,X1,Z26), (Ra7,Rb8,X1,Z27), (Ra7,Rb8,X1,Z28), (Ra7,Rb8,X1,Z29),(Ra7,Rb8,X1,Z30), (Ra7,Rb8,X1,Z31), (Ra7,Rb8,X1,Z32), (Ra7,Rb8,X1,Z33),(Ra7,Rb8,X1,Z34), (Ra7,Rb8,X1,Z35), (Ra7,Rb8,X1,Z36), (Ra7,Rb8,X1,Z37),(Ra7,Rb8,X1,Z38), (Ra7,Rb8,X1,Z39), (Ra7,Rb8,X2,Z1), (Ra7,Rb8,X2,Z2),(Ra7,Rb8,X2,Z3), (Ra7,Rb8,X2,Z4), (Ra7,Rb8,X2,Z5), (Ra7,Rb8,X2,Z6),(Ra7,Rb8,X2,Z7), (Ra7,Rb8,X2,Z8), (Ra7,Rb8,X2,Z9), (Ra7,Rb8,X2,Z10),(Ra7,Rb8,X2,Z11), (Ra7,Rb8,X2,Z12), (Ra7,Rb8,X2,Z13), (Ra7,Rb8,X2,Z14),(Ra7,Rb8,X2,Z15), (Ra7,Rb8,X2,Z16), (Ra7,Rb8,X2,Z17), (Ra7,Rb8,X2,Z18),(Ra7,Rb8,X2,Z19), (Ra7,Rb8,X2,Z20), (Ra7,Rb8,X2,Z21), (Ra7,Rb8,X2,Z22),(Ra7,Rb8,X2,Z23), (Ra7,Rb8,X2,Z24), (Ra7,Rb8,X2,Z25), (Ra7,Rb8,X2,Z26),(Ra7,Rb8,X2,Z27), (Ra7,Rb8,X2,Z28), (Ra7,Rb8,X2,Z29), (Ra7,Rb8,X2,Z30),(Ra7,Rb8,X2,Z31), (Ra7,Rb8,X2,Z32), (Ra7,Rb8,X2,Z33), (Ra7,Rb8,X2,Z34),(Ra7,Rb8,X2,Z35), (Ra7,Rb8,X2,Z36), (Ra7,Rb8,X2,Z37), (Ra7,Rb8,X2,Z38),(Ra7,Rb8,X2,Z39), (Ra8,Rb1,X1,Z1), (Ra8,Rb1,X1,Z2), (Ra8,Rb1,X1,Z3),(Ra8,Rb1,X1,Z4), (Ra8,Rb1,X1,Z5), (Ra8,Rb1,X1,Z6), (Ra8,Rb1,X1,Z7),(Ra8,Rb1,X1,Z8), (Ra8,Rb1,X1,Z9), (Ra8,Rb1,X1,Z10), (Ra8,Rb1,X1,Z11),(Ra8,Rb1,X1,Z12), (Ra8,Rb1,X1,Z13), (Ra8,Rb1,X1,Z14), (Ra8,Rb1,X1,Z15),(Ra8,Rb1,X1,Z16), (Ra8,Rb1,X1,Z17), (Ra8,Rb1,X1,Z18), (Ra8,Rb1,X1,Z19),(Ra8,Rb1,X1,Z20), (Ra8,Rb1,X1,Z21), (Ra8,Rb1,X1,Z22), (Ra8,Rb1,X1,Z23),(Ra8,Rb1,X1,Z24), (Ra8,Rb1,X1,Z25), (Ra8,Rb1,X1,Z26), (Ra8,Rb1,X1,Z27),(Ra8,Rb1,X1,Z28), (Ra8,Rb1,X1,Z29), (Ra8,Rb1,X1,Z30), (Ra8,Rb1,X1,Z31),(Ra8,Rb1,X1,Z32), (Ra8,Rb1,X1,Z33), (Ra8,Rb1,X1,Z34), (Ra8,Rb1,X1,Z35),(Ra8,Rb1,X1,Z36), (Ra8,Rb1,X1,Z37), (Ra8,Rb1,X1,Z38), (Ra8,Rb1,X1,Z39),(Ra8,Rb1,X2,Z1), (Ra8,Rb1,X2,Z2), (Ra8,Rb1,X2,Z3), (Ra8,Rb1,X2,Z4),(Ra8,Rb1,X2,Z5), (Ra8,Rb1,X2,Z6), (Ra8,Rb1,X2,Z7), (Ra8,Rb1,X2,Z8),(Ra8,Rb1,X2,Z9), (Ra8,Rb1,X2,Z10), (Ra8,Rb1,X2,Z11), (Ra8,Rb1,X2,Z12),(Ra8,Rb1,X2,Z13), (Ra8,Rb1,X2,Z14), (Ra8,Rb1,X2,Z15), (Ra8,Rb1,X2,Z16),(Ra8,Rb1,X2,Z17), (Ra8,Rb1,X2,Z18), (Ra8,Rb1,X2,Z19), (Ra8,Rb1,X2,Z20),(Ra8,Rb1,X2,Z21), (Ra8,Rb1,X2,Z22), (Ra8,Rb1,X2,Z23), (Ra8,Rb1,X2,Z24),(Ra8,Rb1,X2,Z25), (Ra8,Rb1,X2,Z26), (Ra8,Rb1,X2,Z27), (Ra8,Rb1,X2,Z28),(Ra8,Rb1,X2,Z29), (Ra8,Rb1,X2,Z30), (Ra8,Rb1,X2,Z31), (Ra8,Rb1,X2,Z32),(Ra8,Rb1,X2,Z33), (Ra8,Rb1,X2,Z34), (Ra8,Rb1,X2,Z35), (Ra8,Rb1,X2,Z36),(Ra8,Rb1,X2,Z37), (Ra8,Rb1,X2,Z38), (Ra8,Rb1,X2,Z39), (Ra8,Rb2,X1,Z1),(Ra8,Rb2,X1,Z2), (Ra8,Rb2,X1,Z3), (Ra8,Rb2,X1,Z4), (Ra8,Rb2,X1,Z5),(Ra8,Rb2,X1,Z6), (Ra8,Rb2,X1,Z7), (Ra8,Rb2,X1,Z8), (Ra8,Rb2,X1,Z9),(Ra8,Rb2,X1,Z10), (Ra8,Rb2,X1,Z11), (Ra8,Rb2,X1,Z12), (Ra8,Rb2,X1,Z13),(Ra8,Rb2,X1,Z14), (Ra8,Rb2,X1,Z15), (Ra8,Rb2,X1,Z16), (Ra8,Rb2,X1,Z17),(Ra8,Rb2,X1,Z18), (Ra8,Rb2,X1,Z19), (Ra8,Rb2,X1,Z20), (Ra8,Rb2,X1,Z21),(Ra8,Rb2,X1,Z22), (Ra8,Rb2,X1,Z23), (Ra8,Rb2,X1,Z24), (Ra8,Rb2,X1,Z25),(Ra8,Rb2,X1,Z26), (Ra8,Rb2,X1,Z27), (Ra8,Rb2,X1,Z28), (Ra8,Rb2,X1,Z29),(Ra8,Rb2,X1,Z30), (Ra8,Rb2,X1,Z31), (Ra8,Rb2,X1,Z32), (Ra8,Rb2,X1,Z33),(Ra8,Rb2,X1,Z34), (Ra8,Rb2,X1,Z35), (Ra8,Rb2,X1,Z36), (Ra8,Rb2,X1,Z37),(Ra8,Rb2,X1,Z38), (Ra8,Rb2,X1,Z39), (Ra8,Rb2,X2,Z1), (Ra8,Rb2,X2,Z2),(Ra8,Rb2,X2,Z3), (Ra8,Rb2,X2,Z4), (Ra8,Rb2,X2,Z5), (Ra8,Rb2,X2,Z6),(Ra8,Rb2,X2,Z7), (Ra8,Rb2,X2,Z8), (Ra8,Rb2,X2,Z9), (Ra8,Rb2,X2,Z10),(Ra8,Rb2,X2,Z11), (Ra8,Rb2,X2,Z12), (Ra8,Rb2,X2,Z13), (Ra8,Rb2,X2,Z14),(Ra8,Rb2,X2,Z15), (Ra8,Rb2,X2,Z16), (Ra8,Rb2,X2,Z17), (Ra8,Rb2,X2,Z18),(Ra8,Rb2,X2,Z19), (Ra8,Rb2,X2,Z20), (Ra8,Rb2,X2,Z21), (Ra8,Rb2,X2,Z22),(Ra8,Rb2,X2,Z23), (Ra8,Rb2,X2,Z24), (Ra8,Rb2,X2,Z25), (Ra8,Rb2,X2,Z26),(Ra8,Rb2,X2,Z27), (Ra8,Rb2,X2,Z28), (Ra8,Rb2,X2,Z29), (Ra8,Rb2,X2,Z30),(Ra8,Rb2,X2,Z31), (Ra8,Rb2,X2,Z32), (Ra8,Rb2,X2,Z33), (Ra8,Rb2,X2,Z34),(Ra8,Rb2,X2,Z35), (Ra8,Rb2,X2,Z36), (Ra8,Rb2,X2,Z37), (Ra8,Rb2,X2,Z38),(Ra8,Rb2,X2,Z39), (Ra8,Rb3,X1,Z1), (Ra8,Rb3,X1,Z2), (Ra8,Rb3,X1,Z3),(Ra8,Rb3,X1,Z4), (Ra8,Rb3,X1,Z5), (Ra8,Rb3,X1,Z6), (Ra8,Rb3,X1,Z7),(Ra8,Rb3,X1,Z8), (Ra8,Rb3,X1,Z9), (Ra8,Rb3,X1,Z10), (Ra8,Rb3,X1,Z11),(Ra8,Rb3,X1,Z12), (Ra8,Rb3,X1,Z13), (Ra8,Rb3,X1,Z14), (Ra8,Rb3,X1,Z15),(Ra8,Rb3,X1,Z16), (Ra8,Rb3,X1,Z17), (Ra8,Rb3,X1,Z18), (Ra8,Rb3,X1,Z19),(Ra8,Rb3,X1,Z20), (Ra8,Rb3,X1,Z21), (Ra8,Rb3,X1,Z22), (Ra8,Rb3,X1,Z23),(Ra8,Rb3,X1,Z24), (Ra8,Rb3,X1,Z25), (Ra8,Rb3,X1,Z26), (Ra8,Rb3,X1,Z27),(Ra8,Rb3,X1,Z28), (Ra8,Rb3,X1,Z29), (Ra8,Rb3,X1,Z30), (Ra8,Rb3,X1,Z31),(Ra8,Rb3,X1,Z32), (Ra8,Rb3,X1,Z33), (Ra8,Rb3,X1,Z34), (Ra8,Rb3,X1,Z35),(Ra8,Rb3,X1,Z36), (Ra8,Rb3,X1,Z37), (Ra8,Rb3,X1,Z38), (Ra8,Rb3,X1,Z39),(Ra8,Rb3,X2,Z1), (Ra8,Rb3,X2,Z2), (Ra8,Rb3,X2,Z3), (Ra8,Rb3,X2,Z4),(Ra8,Rb3,X2,Z5), (Ra8,Rb3,X2,Z6), (Ra8,Rb3,X2,Z7), (Ra8,Rb3,X2,Z8),(Ra8,Rb3,X2,Z9), (Ra8,Rb3,X2,Z10), (Ra8,Rb3,X2,Z11), (Ra8,Rb3,X2,Z12),(Ra8,Rb3,X2,Z13), (Ra8,Rb3,X2,Z14), (Ra8,Rb3,X2,Z15), (Ra8,Rb3,X2,Z16),(Ra8,Rb3,X2,Z17), (Ra8,Rb3,X2,Z18), (Ra8,Rb3,X2,Z19), (Ra8,Rb3,X2,Z20),(Ra8,Rb3,X2,Z21), (Ra8,Rb3,X2,Z22), (Ra8,Rb3,X2,Z23), (Ra8,Rb3,X2,Z24),(Ra8,Rb3,X2,Z25), (Ra8,Rb3,X2,Z26), (Ra8,Rb3,X2,Z27), (Ra8,Rb3,X2,Z28),(Ra8,Rb3,X2,Z29), (Ra8,Rb3,X2,Z30), (Ra8,Rb3,X2,Z31), (Ra8,Rb3,X2,Z32),(Ra8,Rb3,X2,Z33), (Ra8,Rb3,X2,Z34), (Ra8,Rb3,X2,Z35), (Ra8,Rb3,X2,Z36),(Ra8,Rb3,X2,Z37), (Ra8,Rb3,X2,Z38), (Ra8,Rb3,X2,Z39), (Ra8,Rb4,X1,Z1),(Ra8,Rb4,X1,Z2), (Ra8,Rb4,X1,Z3), (Ra8,Rb4,X1,Z4), (Ra8,Rb4,X1,Z5),(Ra8,Rb4,X1,Z6), (Ra8,Rb4,X1,Z7), (Ra8,Rb4,X1,Z8), (Ra8,Rb4,X1,Z9),(Ra8,Rb4,X1,Z10), (Ra8,Rb4,X1,Z11), (Ra8,Rb4,X1,Z12), (Ra8,Rb4,X1,Z13),(Ra8,Rb4,X1,Z14), (Ra8,Rb4,X1,Z15), (Ra8,Rb4,X1,Z16), (Ra8,Rb4,X1,Z17),(Ra8,Rb4,X1,Z18), (Ra8,Rb4,X1,Z19), (Ra8,Rb4,X1,Z20), (Ra8,Rb4,X1,Z21),(Ra8,Rb4,X1,Z22), (Ra8,Rb4,X1,Z23), (Ra8,Rb4,X1,Z24), (Ra8,Rb4,X1,Z25),(Ra8,Rb4,X1,Z26), (Ra8,Rb4,X1,Z27), (Ra8,Rb4,X1,Z28), (Ra8,Rb4,X1,Z29),(Ra8,Rb4,X1,Z30), (Ra8,Rb4,X1,Z31), (Ra8,Rb4,X1,Z32), (Ra8,Rb4,X1,Z33),(Ra8,Rb4,X1,Z34), (Ra8,Rb4,X1,Z35), (Ra8,Rb4,X1,Z36), (Ra8,Rb4,X1,Z37),(Ra8,Rb4,X1,Z38), (Ra8,Rb4,X1,Z39), (Ra8,Rb4,X2,Z1), (Ra8,Rb4,X2,Z2),(Ra8,Rb4,X2,Z3), (Ra8,Rb4,X2,Z4), (Ra8,Rb4,X2,Z5), (Ra8,Rb4,X2,Z6),(Ra8,Rb4,X2,Z7), (Ra8,Rb4,X2,Z8), (Ra8,Rb4,X2,Z9), (Ra8,Rb4,X2,Z10),(Ra8,Rb4,X2,Z11), (Ra8,Rb4,X2,Z12), (Ra8,Rb4,X2,Z13), (Ra8,Rb4,X2,Z14),(Ra8,Rb4,X2,Z15), (Ra8,Rb4,X2,Z16), (Ra8,Rb4,X2,Z17), (Ra8,Rb4,X2,Z18),(Ra8,Rb4,X2,Z19), (Ra8,Rb4,X2,Z20), (Ra8,Rb4,X2,Z21), (Ra8,Rb4,X2,Z22),(Ra8,Rb4,X2,Z23), (Ra8,Rb4,X2,Z24), (Ra8,Rb4,X2,Z25), (Ra8,Rb4,X2,Z26),(Ra8,Rb4,X2,Z27), (Ra8,Rb4,X2,Z28), (Ra8,Rb4,X2,Z29), (Ra8,Rb4,X2,Z30),(Ra8,Rb4,X2,Z31), (Ra8,Rb4,X2,Z32), (Ra8,Rb4,X2,Z33), (Ra8,Rb4,X2,Z34),(Ra8,Rb4,X2,Z35), (Ra8,Rb4,X2,Z36), (Ra8,Rb4,X2,Z37), (Ra8,Rb4,X2,Z38),(Ra8,Rb4,X2,Z39), (Ra8,Rb5,X1,Z1), (Ra8,Rb5,X1,Z2), (Ra8,Rb5,X1,Z3),(Ra8,Rb5,X1,Z4), (Ra8,Rb5,X1,Z5), (Ra8,Rb5,X1,Z6), (Ra8,Rb5,X1,Z7),(Ra8,Rb5,X1,Z8), (Ra8,Rb5,X1,Z9), (Ra8,Rb5,X1,Z10), (Ra8,Rb5,X1,Z11),(Ra8,Rb5,X1,Z12), (Ra8,Rb5,X1,Z13), (Ra8,Rb5,X1,Z14), (Ra8,Rb5,X1,Z15),(Ra8,Rb5,X1,Z16), (Ra8,Rb5,X1,Z17), (Ra8,Rb5,X1,Z18), (Ra8,Rb5,X1,Z19),(Ra8,Rb5,X1,Z20), (Ra8,Rb5,X1,Z21), (Ra8,Rb5,X1,Z22), (Ra8,Rb5,X1,Z23),(Ra8,Rb5,X1,Z24), (Ra8,Rb5,X1,Z25), (Ra8,Rb5,X1,Z26), (Ra8,Rb5,X1,Z27),(Ra8,Rb5,X1,Z28), (Ra8,Rb5,X1,Z29), (Ra8,Rb5,X1,Z30), (Ra8,Rb5,X1,Z31),(Ra8,Rb5,X1,Z32), (Ra8,Rb5,X1,Z33), (Ra8,Rb5,X1,Z34), (Ra8,Rb5,X1,Z35),(Ra8,Rb5,X1,Z36), (Ra8,Rb5,X1,Z37), (Ra8,Rb5,X1,Z38), (Ra8,Rb5,X1,Z39),(Ra8,Rb5,X2,Z1), (Ra8,Rb5,X2,Z2), (Ra8,Rb5,X2,Z3), (Ra8,Rb5,X2,Z4),(Ra8,Rb5,X2,Z5), (Ra8,Rb5,X2,Z6), (Ra8,Rb5,X2,Z7), (Ra8,Rb5,X2,Z8),(Ra8,Rb5,X2,Z9), (Ra8,Rb5,X2,Z10), (Ra8,Rb5,X2,Z11), (Ra8,Rb5,X2,Z12),(Ra8,Rb5,X2,Z13), (Ra8,Rb5,X2,Z14), (Ra8,Rb5,X2,Z15), (Ra8,Rb5,X2,Z16),(Ra8,Rb5,X2,Z17), (Ra8,Rb5,X2,Z18), (Ra8,Rb5,X2,Z19), (Ra8,Rb5,X2,Z20),(Ra8,Rb5,X2,Z21), (Ra8,Rb5,X2,Z22), (Ra8,Rb5,X2,Z23), (Ra8,Rb5,X2,Z24),(Ra8,Rb5,X2,Z25), (Ra8,Rb5,X2,Z26), (Ra8,Rb5,X2,Z27), (Ra8,Rb5,X2,Z28),(Ra8,Rb5,X2,Z29), (Ra8,Rb5,X2,Z30), (Ra8,Rb5,X2,Z31), (Ra8,Rb5,X2,Z32),(Ra8,Rb5,X2,Z33), (Ra8,Rb5,X2,Z34), (Ra8,Rb5,X2,Z35), (Ra8,Rb5,X2,Z36),(Ra8,Rb5,X2,Z37), (Ra8,Rb5,X2,Z38), (Ra8,Rb5,X2,Z39), (Ra8,Rb6,X1,Z1),(Ra8,Rb6,X1,Z2), (Ra8,Rb6,X1,Z3), (Ra8,Rb6,X1,Z4), (Ra8,Rb6,X1,Z5),(Ra8,Rb6,X1,Z6), (Ra8,Rb6,X1,Z7), (Ra8,Rb6,X1,Z8), (Ra8,Rb6,X1,Z9),(Ra8,Rb6,X1,Z10), (Ra8,Rb6,X1,Z11), (Ra8,Rb6,X1,Z12), (Ra8,Rb6,X1,Z13),(Ra8,Rb6,X1,Z14), (Ra8,Rb6,X1,Z15), (Ra8,Rb6,X1,Z16), (Ra8,Rb6,X1,Z17),(Ra8,Rb6,X1,Z18), (Ra8,Rb6,X1,Z19), (Ra8,Rb6,X1,Z20), (Ra8,Rb6,X1,Z21),(Ra8,Rb6,X1,Z22), (Ra8,Rb6,X1,Z23), (Ra8,Rb6,X1,Z24), (Ra8,Rb6,X1,Z25),(Ra8,Rb6,X1,Z26), (Ra8,Rb6,X1,Z27), (Ra8,Rb6,X1,Z28), (Ra8,Rb6,X1,Z29),(Ra8,Rb6,X1,Z30), (Ra8,Rb6,X1,Z31), (Ra8,Rb6,X1,Z32), (Ra8,Rb6,X1,Z33),(Ra8,Rb6,X1,Z34), (Ra8,Rb6,X1,Z35), (Ra8,Rb6,X1,Z36), (Ra8,Rb6,X1,Z37),(Ra8,Rb6,X1,Z38), (Ra8,Rb6,X1,Z39), (Ra8,Rb6,X2,Z1), (Ra8,Rb6,X2,Z2),(Ra8,Rb6,X2,Z3), (Ra8,Rb6,X2,Z4), (Ra8,Rb6,X2,Z5), (Ra8,Rb6,X2,Z6),(Ra8,Rb6,X2,Z7), (Ra8,Rb6,X2,Z8), (Ra8,Rb6,X2,Z9), (Ra8,Rb6,X2,Z10),(Ra8,Rb6,X2,Z11), (Ra8,Rb6,X2,Z12), (Ra8,Rb6,X2,Z13), (Ra8,Rb6,X2,Z14),(Ra8,Rb6,X2,Z15), (Ra8,Rb6,X2,Z16), (Ra8,Rb6,X2,Z17), (Ra8,Rb6,X2,Z18),(Ra8,Rb6,X2,Z19), (Ra8,Rb6,X2,Z20), (Ra8,Rb6,X2,Z21), (Ra8,Rb6,X2,Z22),(Ra8,Rb6,X2,Z23), (Ra8,Rb6,X2,Z24), (Ra8,Rb6,X2,Z25), (Ra8,Rb6,X2,Z26),(Ra8,Rb6,X2,Z27), (Ra8,Rb6,X2,Z28), (Ra8,Rb6,X2,Z29), (Ra8,Rb6,X2,Z30),(Ra8,Rb6,X2,Z31), (Ra8,Rb6,X2,Z32), (Ra8,Rb6,X2,Z33), (Ra8,Rb6,X2,Z34),(Ra8,Rb6,X2,Z35), (Ra8,Rb6,X2,Z36), (Ra8,Rb6,X2,Z37), (Ra8,Rb6,X2,Z38),(Ra8,Rb6,X2,Z39), (Ra8,Rb7,X1,Z1), (Ra8,Rb7,X1,Z2), (Ra8,Rb7,X1,Z3),(Ra8,Rb7,X1,Z4), (Ra8,Rb7,X1,Z5), (Ra8,Rb7,X1,Z6), (Ra8,Rb7,X1,Z7),(Ra8,Rb7,X1,Z8), (Ra8,Rb7,X1,Z9), (Ra8,Rb7,X1,Z10), (Ra8,Rb7,X1,Z11),(Ra8,Rb7,X1,Z12), (Ra8,Rb7,X1,Z13), (Ra8,Rb7,X1,Z14), (Ra8,Rb7,X1,Z15),(Ra8,Rb7,X1,Z16), (Ra8,Rb7,X1,Z17), (Ra8,Rb7,X1,Z18), (Ra8,Rb7,X1,Z19),(Ra8,Rb7,X1,Z20), (Ra8,Rb7,X1,Z21), (Ra8,Rb7,X1,Z22), (Ra8,Rb7,X1,Z23),(Ra8,Rb7,X1,Z24), (Ra8,Rb7,X1,Z25), (Ra8,Rb7,X1,Z26), (Ra8,Rb7,X1,Z27),(Ra8,Rb7,X1,Z28), (Ra8,Rb7,X1,Z29), (Ra8,Rb7,X1,Z30), (Ra8,Rb7,X1,Z31),(Ra8,Rb7,X1,Z32), (Ra8,Rb7,X1,Z33), (Ra8,Rb7,X1,Z34), (Ra8,Rb7,X1,Z35),(Ra8,Rb7,X1,Z36), (Ra8,Rb7,X1,Z37), (Ra8,Rb7,X1,Z38), (Ra8,Rb7,X1,Z39),(Ra8,Rb7,X2,Z1), (Ra8,Rb7,X2,Z2), (Ra8,Rb7,X2,Z3), (Ra8,Rb7,X2,Z4),(Ra8,Rb7,X2,Z5), (Ra8,Rb7,X2,Z6), (Ra8,Rb7,X2,Z7), (Ra8,Rb7,X2,Z8),(Ra8,Rb7,X2,Z9), (Ra8,Rb7,X2,Z10), (Ra8,Rb7,X2,Z11), (Ra8,Rb7,X2,Z12),(Ra8,Rb7,X2,Z13), (Ra8,Rb7,X2,Z14), (Ra8,Rb7,X2,Z15), (Ra8,Rb7,X2,Z16),(Ra8,Rb7,X2,Z17), (Ra8,Rb7,X2,Z18), (Ra8,Rb7,X2,Z19), (Ra8,Rb7,X2,Z20),(Ra8,Rb7,X2,Z21), (Ra8,Rb7,X2,Z22), (Ra8,Rb7,X2,Z23), (Ra8,Rb7,X2,Z24),(Ra8,Rb7,X2,Z25), (Ra8,Rb7,X2,Z26), (Ra8,Rb7,X2,Z27), (Ra8,Rb7,X2,Z28),(Ra8,Rb7,X2,Z29), (Ra8,Rb7,X2,Z30), (Ra8,Rb7,X2,Z31), (Ra8,Rb7,X2,Z32),(Ra8,Rb7,X2,Z33), (Ra8,Rb7,X2,Z34), (Ra8,Rb7,X2,Z35), (Ra8,Rb7,X2,Z36),(Ra8,Rb7,X2,Z37), (Ra8,Rb7,X2,Z38), (Ra8,Rb7,X2,Z39), (Ra8,Rb8,X1,Z1),(Ra8,Rb8,X1,Z2), (Ra8,Rb8,X1,Z3), (Ra8,Rb8,X1,Z4), (Ra8,Rb8,X1,Z5),(Ra8,Rb8,X1,Z6), (Ra8,Rb8,X1,Z7), (Ra8,Rb8,X1,Z8), (Ra8,Rb8,X1,Z9),(Ra8,Rb8,X1,Z10), (Ra8,Rb8,X1,Z11), (Ra8,Rb8,X1,Z12), (Ra8,Rb8,X1,Z13),(Ra8,Rb8,X1,Z14), (Ra8,Rb8,X1,Z15), (Ra8,Rb8,X1,Z16), (Ra8,Rb8,X1,Z17),(Ra8,Rb8,X1,Z18), (Ra8,Rb8,X1,Z19), (Ra8,Rb8,X1,Z20), (Ra8,Rb8,X1,Z21),(Ra8,Rb8,X1,Z22), (Ra8,Rb8,X1,Z23), (Ra8,Rb8,X1,Z24), (Ra8,Rb8,X1,Z25),(Ra8,Rb8,X1,Z26), (Ra8,Rb8,X1,Z27), (Ra8,Rb8,X1,Z28), (Ra8,Rb8,X1,Z29),(Ra8,Rb8,X1,Z30), (Ra8,Rb8,X1,Z31), (Ra8,Rb8,X1,Z32), (Ra8,Rb8,X1,Z33),(Ra8,Rb8,X1,Z34), (Ra8,Rb8,X1,Z35), (Ra8,Rb8,X1,Z36), (Ra8,Rb8,X1,Z37),(Ra8,Rb8,X1,Z38), (Ra8,Rb8,X1,Z39), (Ra8,Rb8,X2,Z1), (Ra8,Rb8,X2,Z2),(Ra8,Rb8,X2,Z3), (Ra8,Rb8,X2,Z4), (Ra8,Rb8,X2,Z5), (Ra8,Rb8,X2,Z6),(Ra8,Rb8,X2,Z7), (Ra8,Rb8,X2,Z8), (Ra8,Rb8,X2,Z9), (Ra8,Rb8,X2,Z10),(Ra8,Rb8,X2,Z11), (Ra8,Rb8,X2,Z12), (Ra8,Rb8,X2,Z13), (Ra8,Rb8,X2,Z14),(Ra8,Rb8,X2,Z15), (Ra8,Rb8,X2,Z16), (Ra8,Rb8,X2,Z17), (Ra8,Rb8,X2,Z18),(Ra8,Rb8,X2,Z19), (Ra8,Rb8,X2,Z20), (Ra8,Rb8,X2,Z21), (Ra8,Rb8,X2,Z22),(Ra8,Rb8,X2,Z23), (Ra8,Rb8,X2,Z24), (Ra8,Rb8,X2,Z25), (Ra8,Rb8,X2,Z26),(Ra8,Rb8,X2,Z27), (Ra8,Rb8,X2,Z28), (Ra8,Rb8,X2,Z29), (Ra8,Rb8,X2,Z30),(Ra8,Rb8,X2,Z31), (Ra8,Rb8,X2,Z32), (Ra8,Rb8,X2,Z33), (Ra8,Rb8,X2,Z34),(Ra8,Rb8,X2,Z35), (Ra8,Rb8,X2,Z36), (Ra8,Rb8,X2,Z37), (Ra8,Rb8,X2,Z38),(Ra8,Rb8,X2,Z39), (Ra9,Rb1,X1,Z1), (Ra9,Rb1,X1,Z2), (Ra9,Rb1,X1,Z3),(Ra9,Rb1,X1,Z4), (Ra9,Rb1,X1,Z5), (Ra9,Rb1,X1,Z6), (Ra9,Rb1,X1,Z7),(Ra9,Rb1,X1,Z8), (Ra9,Rb1,X1,Z9), (Ra9,Rb1,X1,Z10), (Ra9,Rb1,X1,Z11),(Ra9,Rb1,X1,Z12), (Ra9,Rb1,X1,Z13), (Ra9,Rb1,X1,Z14), (Ra9,Rb1,X1,Z15),(Ra9,Rb1,X1,Z16), (Ra9,Rb1,X1,Z17), (Ra9,Rb1,X1,Z18), (Ra9,Rb1,X1,Z19),(Ra9,Rb1,X1,Z20), (Ra9,Rb1,X1,Z21), (Ra9,Rb1,X1,Z22), (Ra9,Rb1,X1,Z23),(Ra9,Rb1,X1,Z24), (Ra9,Rb1,X1,Z25), (Ra9,Rb1,X1,Z26), (Ra9,Rb1,X1,Z27),(Ra9,Rb1,X1,Z28), (Ra9,Rb1,X1,Z29), (Ra9,Rb1,X1,Z30), (Ra9,Rb1,X1,Z31),(Ra9,Rb1,X1,Z32), (Ra9,Rb1,X1,Z33), (Ra9,Rb1,X1,Z34), (Ra9,Rb1,X1,Z35),(Ra9,Rb1,X1,Z36), (Ra9,Rb1,X1,Z37), (Ra9,Rb1,X1,Z38), (Ra9,Rb1,X1,Z39),(Ra9,Rb1,X2,Z1), (Ra9,Rb1,X2,Z2), (Ra9,Rb1,X2,Z3), (Ra9,Rb1,X2,Z4),(Ra9,Rb1,X2,Z5), (Ra9,Rb1,X2,Z6), (Ra9,Rb1,X2,Z7), (Ra9,Rb1,X2,Z8),(Ra9,Rb1,X2,Z9), (Ra9,Rb1,X2,Z10), (Ra9,Rb1,X2,Z11), (Ra9,Rb1,X2,Z12),(Ra9,Rb1,X2,Z13), (Ra9,Rb1,X2,Z14), (Ra9,Rb1,X2,Z15), (Ra9,Rb1,X2,Z16),(Ra9,Rb1,X2,Z17), (Ra9,Rb1,X2,Z18), (Ra9,Rb1,X2,Z19), (Ra9,Rb1,X2,Z20),(Ra9,Rb1,X2,Z21), (Ra9,Rb1,X2,Z22), (Ra9,Rb1,X2,Z23), (Ra9,Rb1,X2,Z24),(Ra9,Rb1,X2,Z25), (Ra9,Rb1,X2,Z26), (Ra9,Rb1,X2,Z27), (Ra9,Rb1,X2,Z28),(Ra9,Rb1,X2,Z29), (Ra9,Rb1,X2,Z30), (Ra9,Rb1,X2,Z31), (Ra9,Rb1,X2,Z32),(Ra9,Rb1,X2,Z33), (Ra9,Rb1,X2,Z34), (Ra9,Rb1,X2,Z35), (Ra9,Rb1,X2,Z36),(Ra9,Rb1,X2,Z37), (Ra9,Rb1,X2,Z38), (Ra9,Rb1,X2,Z39), (Ra9,Rb2,X1,Z1),(Ra9,Rb2,X1,Z2), (Ra9,Rb2,X1,Z3), (Ra9,Rb2,X1,Z4), (Ra9,Rb2,X1,Z5),(Ra9,Rb2,X1,Z6), (Ra9,Rb2,X1,Z7), (Ra9,Rb2,X1,Z8), (Ra9,Rb2,X1,Z9),(Ra9,Rb2,X1,Z10), (Ra9,Rb2,X1,Z11), (Ra9,Rb2,X1,Z12), (Ra9,Rb2,X1,Z13),(Ra9,Rb2,X1,Z14), (Ra9,Rb2,X1,Z15), (Ra9,Rb2,X1,Z16), (Ra9,Rb2,X1,Z17),(Ra9,Rb2,X1,Z18), (Ra9,Rb2,X1,Z19), (Ra9,Rb2,X1,Z20), (Ra9,Rb2,X1,Z21),(Ra9,Rb2,X1,Z22), (Ra9,Rb2,X1,Z23), (Ra9,Rb2,X1,Z24), (Ra9,Rb2,X1,Z25),(Ra9,Rb2,X1,Z26), (Ra9,Rb2,X1,Z27), (Ra9,Rb2,X1,Z28), (Ra9,Rb2,X1,Z29),(Ra9,Rb2,X1,Z30), (Ra9,Rb2,X1,Z31), (Ra9,Rb2,X1,Z32), (Ra9,Rb2,X1,Z33),(Ra9,Rb2,X1,Z34), (Ra9,Rb2,X1,Z35), (Ra9,Rb2,X1,Z36), (Ra9,Rb2,X1,Z37),(Ra9,Rb2,X1,Z38), (Ra9,Rb2,X1,Z39), (Ra9,Rb2,X2,Z1), (Ra9,Rb2,X2,Z2),(Ra9,Rb2,X2,Z3), (Ra9,Rb2,X2,Z4), (Ra9,Rb2,X2,Z5), (Ra9,Rb2,X2,Z6),(Ra9,Rb2,X2,Z7), (Ra9,Rb2,X2,Z8), (Ra9,Rb2,X2,Z9), (Ra9,Rb2,X2,Z10),(Ra9,Rb2,X2,Z11), (Ra9,Rb2,X2,Z12), (Ra9,Rb2,X2,Z13), (Ra9,Rb2,X2,Z14),(Ra9,Rb2,X2,Z15), (Ra9,Rb2,X2,Z16), (Ra9,Rb2,X2,Z17), (Ra9,Rb2,X2,Z18),(Ra9,Rb2,X2,Z19), (Ra9,Rb2,X2,Z20), (Ra9,Rb2,X2,Z21), (Ra9,Rb2,X2,Z22),(Ra9,Rb2,X2,Z23), (Ra9,Rb2,X2,Z24), (Ra9,Rb2,X2,Z25), (Ra9,Rb2,X2,Z26),(Ra9,Rb2,X2,Z27), (Ra9,Rb2,X2,Z28), (Ra9,Rb2,X2,Z29), (Ra9,Rb2,X2,Z30),(Ra9,Rb2,X2,Z31), (Ra9,Rb2,X2,Z32), (Ra9,Rb2,X2,Z33), (Ra9,Rb2,X2,Z34),(Ra9,Rb2,X2,Z35), (Ra9,Rb2,X2,Z36), (Ra9,Rb2,X2,Z37), (Ra9,Rb2,X2,Z38),(Ra9,Rb2,X2,Z39), (Ra9,Rb3,X1,Z1), (Ra9,Rb3,X1,Z2), (Ra9,Rb3,X1,Z3),(Ra9,Rb3,X1,Z4), (Ra9,Rb3,X1,Z5), (Ra9,Rb3,X1,Z6), (Ra9,Rb3,X1,Z7),(Ra9,Rb3,X1,Z8), (Ra9,Rb3,X1,Z9), (Ra9,Rb3,X1,Z10), (Ra9,Rb3,X1,Z11),(Ra9,Rb3,X1,Z12), (Ra9,Rb3,X1,Z13), (Ra9,Rb3,X1,Z14), (Ra9,Rb3,X1,Z15),(Ra9,Rb3,X1,Z16), (Ra9,Rb3,X1,Z17), (Ra9,Rb3,X1,Z18), (Ra9,Rb3,X1,Z19),(Ra9,Rb3,X1,Z20), (Ra9,Rb3,X1,Z21), (Ra9,Rb3,X1,Z22), (Ra9,Rb3,X1,Z23),(Ra9,Rb3,X1,Z24), (Ra9,Rb3,X1,Z25), (Ra9,Rb3,X1,Z26), (Ra9,Rb3,X1,Z27),(Ra9,Rb3,X1,Z28), (Ra9,Rb3,X1,Z29), (Ra9,Rb3,X1,Z30), (Ra9,Rb3,X1,Z31),(Ra9,Rb3,X1,Z32), (Ra9,Rb3,X1,Z33), (Ra9,Rb3,X1,Z34), (Ra9,Rb3,X1,Z35),(Ra9,Rb3,X1,Z36), (Ra9,Rb3,X1,Z37), (Ra9,Rb3,X1,Z38), (Ra9,Rb3,X1,Z39),(Ra9,Rb3,X2,Z1), (Ra9,Rb3,X2,Z2), (Ra9,Rb3,X2,Z3), (Ra9,Rb3,X2,Z4),(Ra9,Rb3,X2,Z5), (Ra9,Rb3,X2,Z6), (Ra9,Rb3,X2,Z7), (Ra9,Rb3,X2,Z8),(Ra9,Rb3,X2,Z9), (Ra9,Rb3,X2,Z (Ra9,Rb3,X2,Z11), (Ra9,Rb3,X2,Z12),(Ra9,Rb3,X2,Z13), (Ra9,Rb3,X2,Z14), (Ra9,Rb3,X2,Z15), (Ra9,Rb3,X2,Z16),(Ra9,Rb3,X2,Z17), (Ra9,Rb3,X2,Z18), (Ra9,Rb3,X2,Z19), (Ra9,Rb3,X2,Z20),(Ra9,Rb3,X2,Z21), (Ra9,Rb3,X2,Z22), (Ra9,Rb3,X2,Z23), (Ra9,Rb3,X2,Z24),(Ra9,Rb3,X2,Z25), (Ra9,Rb3,X2,Z26), (Ra9,Rb3,X2,Z27), (Ra9,Rb3,X2,Z28),(Ra9,Rb3,X2,Z29), (Ra9,Rb3,X2,Z30), (Ra9,Rb3,X2,Z31), (Ra9,Rb3,X2,Z32),(Ra9,Rb3,X2,Z33), (Ra9,Rb3,X2,Z34), (Ra9,Rb3,X2,Z35), (Ra9,Rb3,X2,Z36),(Ra9,Rb3,X2,Z37), (Ra9,Rb3,X2,Z38), (Ra9,Rb3,X2,Z39), (Ra9,Rb4,X1,Z1),(Ra9,Rb4,X1,Z2), (Ra9,Rb4,X1,Z3), (Ra9,Rb4,X1,Z4), (Ra9,Rb4,X1,Z5),(Ra9,Rb4,X1,Z6), (Ra9,Rb4,X1,Z7), (Ra9,Rb4,X1,Z8), (Ra9,Rb4,X1,Z9),(Ra9,Rb4,X1,Z10), (Ra9,Rb4,X1,Z11), (Ra9,Rb4,X1,Z12), (Ra9,Rb4,X1,Z13),(Ra9,Rb4,X1,Z14), (Ra9,Rb4,X1,Z15), (Ra9,Rb4,X1,Z16), (Ra9,Rb4,X1,Z17),(Ra9,Rb4,X1,Z18), (Ra9,Rb4,X1,Z19), (Ra9,Rb4,X1,Z20), (Ra9,Rb4,X1,Z21),(Ra9,Rb4,X1,Z22), (Ra9,Rb4,X1,Z23), (Ra9,Rb4,X1,Z24), (Ra9,Rb4,X1,Z25),(Ra9,Rb4,X1,Z26), (Ra9,Rb4,X1,Z27), (Ra9,Rb4,X1,Z28), (Ra9,Rb4,X1,Z29),(Ra9,Rb4,X1,Z30), (Ra9,Rb4,X1,Z31), (Ra9,Rb4,X1,Z32), (Ra9,Rb4,X1,Z33),(Ra9,Rb4,X1,Z34), (Ra9,Rb4,X1,Z35), (Ra9,Rb4,X1,Z36), (Ra9,Rb4,X1,Z37),(Ra9,Rb4,X1,Z38), (Ra9,Rb4,X1,Z39), (Ra9,Rb4,X2,Z1), (Ra9,Rb4,X2,Z2),(Ra9,Rb4,X2,Z3), (Ra9,Rb4,X2,Z4), (Ra9,Rb4,X2,Z5), (Ra9,Rb4,X2,Z6),(Ra9,Rb4,X2,Z7), (Ra9,Rb4,X2,Z8), (Ra9,Rb4,X2,Z9), (Ra9,Rb4,X2,Z10),(Ra9,Rb4,X2,Z11), (Ra9,Rb4,X2,Z12), (Ra9,Rb4,X2,Z13), (Ra9,Rb4,X2,Z14),(Ra9,Rb4,X2,Z15), (Ra9,Rb4,X2,Z16), (Ra9,Rb4,X2,Z17), (Ra9,Rb4,X2,Z18),(Ra9,Rb4,X2,Z19), (Ra9,Rb4,X2,Z20), (Ra9,Rb4,X2,Z21), (Ra9,Rb4,X2,Z22),(Ra9,Rb4,X2,Z23), (Ra9,Rb4,X2,Z24), (Ra9,Rb4,X2,Z25), (Ra9,Rb4,X2,Z26),(Ra9,Rb4,X2,Z27), (Ra9,Rb4,X2,Z28), (Ra9,Rb4,X2,Z29), (Ra9,Rb4,X2,Z30),(Ra9,Rb4,X2,Z31), (Ra9,Rb4,X2,Z32), (Ra9,Rb4,X2,Z33), (Ra9,Rb4,X2,Z34),(Ra9,Rb4,X2,Z35), (Ra9,Rb4,X2,Z36), (Ra9,Rb4,X2,Z37), (Ra9,Rb4,X2,Z38),(Ra9,Rb4,X2,Z39), (Ra9,Rb5,X1,Z1), (Ra9,Rb5,X1,Z2), (Ra9,Rb5,X1,Z3),(Ra9,Rb5,X1,Z4), (Ra9,Rb5,X1,Z5), (Ra9,Rb5,X1,Z6), (Ra9,Rb5,X1,Z7),(Ra9,Rb5,X1,Z8), (Ra9,Rb5,X1,Z9), (Ra9,Rb5,X1,Z10), (Ra9,Rb5,X1,Z11),(Ra9,Rb5,X1,Z12), (Ra9,Rb5,X1,Z13), (Ra9,Rb5,X1,Z14), (Ra9,Rb5,X1,Z15),(Ra9,Rb5,X1,Z16), (Ra9,Rb5,X1,Z17), (Ra9,Rb5,X1,Z18), (Ra9,Rb5,X1,Z19),(Ra9,Rb5,X1,Z20), (Ra9,Rb5,X1,Z21), (Ra9,Rb5,X1,Z22), (Ra9,Rb5,X1,Z23),(Ra9,Rb5,X1,Z24), (Ra9,Rb5,X1,Z25), (Ra9,Rb5,X1,Z26), (Ra9,Rb5,X1,Z27),(Ra9,Rb5,X1,Z28), (Ra9,Rb5,X1,Z29), (Ra9,Rb5,X1,Z30), (Ra9,Rb5,X1,Z31),(Ra9,Rb5,X1,Z32), (Ra9,Rb5,X1,Z33), (Ra9,Rb5,X1,Z34), (Ra9,Rb5,X1,Z35),(Ra9,Rb5,X1,Z36), (Ra9,Rb5,X1,Z37), (Ra9,Rb5,X1,Z38), (Ra9,Rb5,X1,Z39),(Ra9,Rb5,X2,Z1), (Ra9,Rb5,X2,Z2), (Ra9,Rb5,X2,Z3), (Ra9,Rb5,X2,Z4),(Ra9,Rb5,X2,Z5), (Ra9,Rb5,X2,Z6), (Ra9,Rb5,X2,Z7), (Ra9,Rb5,X2,Z8),(Ra9,Rb5,X2,Z9), (Ra9,Rb5,X2,Z10), (Ra9,Rb5,X2,Z11), (Ra9,Rb5,X2,Z12),(Ra9,Rb5,X2,Z13), (Ra9,Rb5,X2,Z14), (Ra9,Rb5,X2,Z15), (Ra9,Rb5,X2,Z16),(Ra9,Rb5,X2,Z17), (Ra9,Rb5,X2,Z18), (Ra9,Rb5,X2,Z19), (Ra9,Rb5,X2,Z20),(Ra9,Rb5,X2,Z21), (Ra9,Rb5,X2,Z22), (Ra9,Rb5,X2,Z23), (Ra9,Rb5,X2,Z24),(Ra9,Rb5,X2,Z25), (Ra9,Rb5,X2,Z26), (Ra9,Rb5,X2,Z27), (Ra9,Rb5,X2,Z28),(Ra9,Rb5,X2,Z29), (Ra9,Rb5,X2,Z30), (Ra9,Rb5,X2,Z31), (Ra9,Rb5,X2,Z32),(Ra9,Rb5,X2,Z33), (Ra9,Rb5,X2,Z34), (Ra9,Rb5,X2,Z35), (Ra9,Rb5,X2,Z36),(Ra9,Rb5,X2,Z37), (Ra9,Rb5,X2,Z38), (Ra9,Rb5,X2,Z39), (Ra9,Rb6,X1,Z1),(Ra9,Rb6,X1,Z2), (Ra9,Rb6,X1,Z3), (Ra9,Rb6,X1,Z4), (Ra9,Rb6,X1,Z5),(Ra9,Rb6,X1,Z6), (Ra9,Rb6,X1,Z7), (Ra9,Rb6,X1,Z8), (Ra9,Rb6,X1,Z9),(Ra9,Rb8,X1,Z10), (Ra9,Rb6,X1,Z11), (Ra9,Rb6,X1,Z12), (Ra9,Rb6,X1,Z13),(Ra9,Rb6,X1,Z14), (Ra9,Rb6,X1,Z15), (Ra9,Rb6,X1,Z16), (Ra9,Rb6,X1,Z17),(Ra9,Rb6,X1,Z18), (Ra9,Rb6,X1,Z19), (Ra9,Rb6,X1,Z20), (Ra9,Rb6,X1,Z21),(Ra9,Rb6,X1,Z22), (Ra9,Rb6,X1,Z23), (Ra9,Rb6,X1,Z24), (Ra9,Rb6,X1,Z25),(Ra9,Rb6,X1,Z26), (Ra9,Rb6,X1,Z27), (Ra9,Rb6,X1,Z28), (Ra9,Rb6,X1,Z29),(Ra9,Rb6,X1,Z30), (Ra9,Rb6,X1,Z31), (Ra9,Rb6,X1,Z32), (Ra9,Rb6,X1,Z33),(Ra9,Rb6,X1,Z34), (Ra9,Rb6,X1,Z35), (Ra9,Rb6,X1,Z36), (Ra9,Rb6,X1,Z37),(Ra9,Rb6,X1,Z38), (Ra9,Rb6,X1,Z39), (Ra9,Rb6,X2,Z1), (Ra9,Rb6,X2,Z2),(Ra9,Rb6,X2,Z3), (Ra9,Rb6,X2,Z4), (Ra9,Rb6,X2,Z5), (Ra9,Rb6,X2,Z6),(Ra9,Rb6,X2,Z7), (Ra9,Rb6,X2,Z8), (Ra9,Rb6,X2,Z9), (Ra9,Rb6,X2,Z10),(Ra9,Rb6,X2,Z11), (Ra9,Rb6,X2,Z12), (Ra9,Rb6,X2,Z13), (Ra9,Rb6,X2,Z14),(Ra9,Rb6,X2,Z15), (Ra9,Rb6,X2,Z16), (Ra9,Rb6,X2,Z17), (Ra9,Rb6,X2,Z18),(Ra9,Rb6,X2,Z19), (Ra9,Rb6,X2,Z20), (Ra9,Rb6,X2,Z21), (Ra9,Rb6,X2,Z22),(Ra9,Rb6,X2,Z23), (Ra9,Rb6,X2,Z24), (Ra9,Rb6,X2,Z25), (Ra9,Rb6,X2,Z26),(Ra9,Rb6,X2,Z27), (Ra9,Rb6,X2,Z28), (Ra9,Rb6,X2,Z29), (Ra9,Rb6,X2,Z30),(Ra9,Rb6,X2,Z31), (Ra9,Rb6,X2,Z32), (Ra9,Rb6,X2,Z33), (Ra9,Rb6,X2,Z34),(Ra9,Rb6,X2,Z35), (Ra9,Rb6,X2,Z36), (Ra9,Rb6,X2,Z37), (Ra9,Rb8,X2,Z38),(Ra9,Rb6,X2,Z39), (Ra9,Rb7,X1,Z1), (Ra9,Rb7,X1,Z2), (Ra9,Rb7,X1,Z3),(Ra9,Rb7,X1,Z4), (Ra9,Rb7,X1,Z5), (Ra9,Rb7,X1,Z6), (Ra9,Rb7,X1,Z7),(Ra9,Rb7,X1,Z8), (Ra9,Rb7,X1,Z9), (Ra9,Rb7,X1,Z10), (Ra9,Rb7,X1,Z11),(Ra9,Rb7,X1,Z12), (Ra9,Rb7,X1,Z13), (Ra9,Rb7,X1,Z14), (Ra9,Rb7,X1,Z15),(Ra9,Rb7,X1,Z16), (Ra9,Rb7,X1,Z17), (Ra9,Rb7,X1,Z18), (Ra9,Rb7,X1,Z19),(Ra9,Rb7,X1,Z20), (Ra9,Rb7,X1,Z21), (Ra9,Rb7,X1,Z22), (Ra9,Rb7,X1,Z23),(Ra9,Rb7,X1,Z24), (Ra9,Rb7,X1,Z25), (Ra9,Rb7,X1,Z26), (Ra9,Rb7,X1,Z27),(Ra9,Rb7,X1,Z28), (Ra9,Rb7,X1,Z29), (Ra9,Rb7,X1,Z30), (Ra9,Rb7,X1,Z31),(Ra9,Rb7,X1,Z32), (Ra9,Rb7,X1,Z33), (Ra9,Rb7,X1,Z34), (Ra9,Rb7,X1,Z35),(Ra9,Rb7,X1,Z36), (Ra9,Rb7,X1,Z37), (Ra9,Rb7,X1,Z38), (Ra9,Rb7,X1,Z39),(Ra9,Rb7,X2,Z1), (Ra9,Rb7,X2,Z2), (Ra9,Rb7,X2,Z3), (Ra9,Rb7,X2,Z4),(Ra9,Rb7,X2,Z5), (Ra9,Rb7,X2,Z8), (Ra9,Rb7,X2,Z7), (Ra9,Rb7,X2,Z8),(Ra9,Rb7,X2,Z9), (Ra9,Rb7,X2,Z10), (Ra9,Rb7,X2,Z11), (Ra9,Rb7,X2,Z12),(Ra9,Rb7,X2,Z13), (Ra9,Rb7,X2,Z14), (Ra9,Rb7,X2,Z15), (Ra9,Rb7,X2,Z16),(Ra9,Rb7,X2,Z17), (Ra9,Rb7,X2,Z18), (Ra9,Rb7,X2,Z19), (Ra9,Rb7,X2,Z20),(Ra9,Rb7,X2,Z21), (Ra9,Rb7,X2,Z22), (Ra9,Rb7,X2,Z23), (Ra9,Rb7,X2,Z24),(Ra9,Rb7,X2,Z25), (Ra9,Rb7,X2,Z26), (Ra9,Rb7,X2,Z27), (Ra9,Rb7,X2,Z28),(Ra9,Rb7,X2,Z29), (Ra9,Rb7,X2,Z30), (Ra9,Rb7,X2,Z31), (Ra9,Rb7,X2,Z32),(Ra9,Rb7,X2,Z33), (Ra9,Rb7,X2,Z34), (Ra9,Rb7,X2,Z35), (Ra9,Rb7,X2,Z36),(Ra9,Rb7,X2,Z37), (Ra9,Rb7,X2,Z38), (Ra9,Rb7,X2,Z39), (Ra9,Rb8,X1,Z1),(Ra9,Rb8,X1,Z2), (Ra9,Rb8,X1,Z3), (Ra9,Rb8,X1,Z4), (Ra9,Rb8,X1,Z5),(Ra9,Rb8,X1,Z6), (Ra9,Rb8,X1,Z7), (Ra9,Rb8,X1,Z8), (Ra9,Rb8,X1,Z9),(Ra9,Rb8,X1,Z10), (Ra9,Rb8,X1,Z11), (Ra9,Rb8,X1,Z12), (Ra9,Rb8,X1,Z13),(Ra9,Rb8,X1,Z14), (Ra9,Rb8,X1,Z15), (Ra9,Rb8,X1,Z16), (Ra9,Rb8,X1,Z17),(Ra9,Rb8,X1,Z18), (Ra9,Rb8,X1,Z19), (Ra9,Rb8,X1,Z20), (Ra9,Rb8,X1,Z21),(Ra9,Rb8,X1,Z22), (Ra9,Rb8,X1,Z23), (Ra9,Rb8,X1,Z24), (Ra9,Rb8,X1,Z25),(Ra9,Rb8,X1,Z26), (Ra9,Rb8,X1,Z27), (Ra9,Rb8,X1,Z28), (Ra9,Rb8,X1,Z29),(Ra9,Rb8,X1,Z30), (Ra9,Rb8,X1,Z31), (Ra9,Rb8,X1,Z32), (Ra9,Rb8,X1,Z33),(Ra9,Rb8,X1,Z34), (Ra9,Rb8,X1,Z35), (Ra9,Rb8,X1,Z36), (Ra9,Rb8,X1,Z37),(Ra9,Rb8,X1,Z38), (Ra9,Rb8,X1,Z39), (Ra9,Rb8,X2,Z1), (Ra9,Rb8,X2,Z2),(Ra9,Rb8,X2,Z3), (Ra9,Rb8,X2,Z4), (Ra9,Rb8,X2,Z5), (Ra9,Rb8,X2,Z6),(Ra9,Rb8,X2,Z7), (Ra9,Rb8,X2,Z8), (Ra9,Rb8,X2,Z9), (Ra9,Rb8,X2,Z10),(Ra9,Rb8,X2,Z11), (Ra9,Rb8,X2,Z12), (Ra9,Rb8,X2,Z13), (Ra9,Rb8,X2,Z14),(Ra9,Rb8,X2,Z15), (Ra9,Rb8,X2,Z16), (Ra9,Rb8,X2,Z17), (Ra9,Rb8,X2,Z18),(Ra9,Rb8,X2,Z19), (Ra9,Rb8,X2,Z20), (Ra9,Rb8,X2,Z21), (Ra9,Rb8,X2,Z22),(Ra9,Rb8,X2,Z23), (Ra9,Rb8,X2,Z24), (Ra9,Rb8,X2,Z25), (Ra9,Rb8,X2,Z26),(Ra9,Rb8,X2,Z27), (Ra9,Rb8,X2,Z28), (Ra9,Rb8,X2,Z29), (Ra9,Rb8,X2,Z30),(Ra9,Rb8,X2,Z31), (Ra9,Rb8,X2,Z32), (Ra9,Rb8,X2,Z33), (Ra9,Rb8,X2,Z34),(Ra9,Rb8,X2,Z35), (Ra9,Rb8,X2,Z36), (Ra9,Rb8,X2,Z37), (Ra9,Rb8,X2,Z38),(Ra9,Rb8,X2,Z39), (Ra10,Rb1,X1,Z1), (Ra10,Rb1,X1,Z2), (Ra10,Rb1,X1,Z3),(Ra10,Rb1,X1,Z4), (Ra10,Rb1,X1,Z5), (Ra10,Rb1,X1,Z6), (Ra10,Rb1,X1,Z7),(Ra10,Rb1,X1,Z8), (Ra10,Rb1,X1,Z9), (Ra10,Rb1,X1,Z10),(Ra10,Rb1,X1,Z11), (Ra10,Rb1,X1,Z12), (Ra10,Rb1,X1,Z13),(Ra10,Rb1,X1,Z14), (Ra10,Rb1,X1,Z15), (Ra10,Rb1,X1,Z16),(Ra10,Rb1,X1,Z17), (Ra10,Rb1,X1,Z18), (Ra10,Rb1,X1,Z19),(Ra10,Rb1,X1,Z20), (Ra10,Rb1,X1,Z21), (Ra10,Rb1,X1,Z22),(Ra10,Rb1,X1,Z23), (Ra10,Rb1,X1,Z24), (Ra10,Rb1,X1,Z25),(Ra10,Rb1,X1,Z26), (Ra10,Rb1,X1,Z27), (Ra10,Rb1,X1,Z28),(Ra10,Rb1,X1,Z29), (Ra10,Rb1,X1,Z30), (Ra10,Rb1,X1,Z31),(Ra10,Rb1,X1,Z32), (Ra10,Rb1,X1,Z33), (Ra10,Rb1,X1,Z34),(Ra10,Rb1,X1,Z35), (Ra10,Rb1,X1,Z36), (Ra10,Rb1,X1,Z37),(Ra10,Rb1,X1,Z38), (Ra10,Rb1,X1,Z39), (Ra10,Rb1,X2,Z1),(Ra10,Rb1,X2,Z2), (Ra10,Rb1,X2,Z3), (Ra10,Rb1,X2,Z4), (Ra10,Rb1,X2,Z5),(Ra10,Rb1,X2,Z6), (Ra10,Rb1,X2,Z7), (Ra10,Rb1,X2,Z8), (Ra10,Rb1,X2,Z9),(Ra10,Rb1,X2,Z10), (Ra10,Rb1,X2,Z11), (Ra10,Rb1,X2,Z12),(Ra10,Rb1,X2,Z13), (Ra10,Rb1,X2,Z14), (Ra10,Rb1,X2,Z15),(Ra10,Rb1,X2,Z16), (Ra10,Rb1,X2,Z17), (Ra10,Rb1,X2,Z18),(Ra10,Rb1,X2,Z19), (Ra10,Rb1,X2,Z20), (Ra10,Rb1,X2,Z21),(Ra10,Rb1,X2,Z22), (Ra10,Rb1,X2,Z23), (Ra10,Rb1,X2,Z24),(Ra10,Rb1,X2,Z25), (Ra10,Rb1,X2,Z26), (Ra10,Rb1,X2,Z27),(Ra10,Rb1,X2,Z28), (Ra10,Rb1,X2,Z29), (Ra10,Rb1,X2,Z30),(Ra10,Rb1,X2,Z31), (Ra10,Rb1,X2,Z32), (Ra10,Rb1,X2,Z33),(Ra10,Rb1,X2,Z34), (Ra10,Rb1,X2,Z35), (Ra10,Rb1,X2,Z36),(Ra10,Rb1,X2,Z37), (Ra10,Rb1,X2,Z38), (Ra10,Rb1,X2,Z39),(Ra10,Rb2,X1,Z1), (Ra10,Rb2,X1,Z2), (Ra10,Rb2,X1,Z3), (Ra10,Rb2,X1,Z4),(Ra10,Rb2,X1,Z5), (Ra10,Rb2,X1,Z6), (Ra10,Rb2,X1,Z7), (Ra10,Rb2,X1,Z8),(Ra10,Rb2,X1,Z9), (Ra10,Rb2,X1,Z10), (Ra10,Rb2,X1,Z11),(Ra10,Rb2,X1,Z12), (Ra10,Rb2,X1,Z13), (Ra10,Rb2,X1,Z14),(Ra10,Rb2,X1,Z15), (Ra10,Rb2,X1,Z16), (Ra10,Rb2,X1,Z17),(Ra10,Rb2,X1,Z18), (Ra10,Rb2,X1,Z19), (Ra10,Rb2,X1,Z20),(Ra10,Rb2,X1,Z21), (Ra10,Rb2,X1,Z22), (Ra10,Rb2,X1,Z23),(Ra10,Rb2,X1,Z24), (Ra10,Rb2,X1,Z25), (Ra10,Rb2,X1,Z26),(Ra10,Rb2,X1,Z27), (Ra10,Rb2,X1,Z28), (Ra10,Rb2,X1,Z29),(Ra10,Rb2,X1,Z30), (Ra10,Rb2,X1,Z31), (Ra10,Rb2,X1,Z32),(Ra10,Rb2,X1,Z33), (Ra10,Rb2,X1,Z34), (Ra10,Rb2,X1,Z35),(Ra10,Rb2,X1,Z36), (Ra10,Rb2,X1,Z37), (Ra10,Rb2,X1,Z38),(Ra10,Rb2,X1,Z39), (Ra10,Rb2,X2,Z1), (Ra10,Rb2,X2,Z2), (Ra10,Rb2,X2,Z3),(Ra10,Rb2,X2,Z4), (Ra10,Rb2,X2,Z5), (Ra10,Rb2,X2,Z6), (Ra10,Rb2,X2,Z7),(Ra10,Rb2,X2,Z8), (Ra10,Rb2,X2,Z9), (Ra10,Rb2,X2,Z10),(Ra10,Rb2,X2,Z11), (Ra10,Rb2,X2,Z12), (Ra10,Rb2,X2,Z13),(Ra10,Rb2,X2,Z14), (Ra10,Rb2,X2,Z15), (Ra10,Rb2,X2,Z16),(Ra10,Rb2,X2,Z17), (Ra10,Rb2,X2,Z18), (Ra10,Rb2,X2,Z19),(Ra10,Rb2,X2,Z20), (Ra10,Rb2,X2,Z21), (Ra10,Rb2,X2,Z22),(Ra10,Rb2,X2,Z23), (Ra10,Rb2,X2,Z24), (Ra10,Rb2,X2,Z25),(Ra10,Rb2,X2,Z26), (Ra10,Rb2,X2,Z27), (Ra10,Rb2,X2,Z28),(Ra10,Rb2,X2,Z29), (Ra10,Rb2,X2,Z30), (Ra10,Rb2,X2,Z31),(Ra10,Rb2,X2,Z32), (Ra10,Rb2,X2,Z33), (Ra10,Rb2,X2,Z34),(Ra10,Rb2,X2,Z35), (Ra10,Rb2,X2,Z36), (Ra10,Rb2,X2,Z37),(Ra10,Rb2,X2,Z38), (Ra10,Rb2,X2,Z39), (Ra10,Rb3,X1,Z1),(Ra10,Rb3,X1,Z2), (Ra10,Rb3,X1,Z3), (Ra10,Rb3,X1,Z4), (Ra10,Rb3,X1,Z5),(Ra10,Rb3,X1,Z6), (Ra10,Rb3,X1,Z7), (Ra10,Rb3,X1,Z8), (Ra10,Rb3,X1,Z9),(Ra10,Rb3,X1,Z10), (Ra10,Rb3,X1,Z11), (Ra10,Rb3,X1,Z12),(Ra10,Rb3,X1,Z13), (Ra10,Rb3,X1,Z14), (Ra10,Rb3,X1,Z15),(Ra10,Rb3,X1,Z16), (Ra10,Rb3,X1,Z17), (Ra10,Rb3,X1,Z18),(Ra10,Rb3,X1,Z19), (Ra10,Rb3,X1,Z20), (Ra10,Rb3,X1,Z21),(Ra10,Rb3,X1,Z22), (Ra10,Rb3,X1,Z23), (Ra10,Rb3,X1,Z24),(Ra10,Rb3,X1,Z25), (Ra10,Rb3,X1,Z26), (Ra10,Rb3,X1,Z27),(Ra10,Rb3,X1,Z28), (Ra10,Rb3,X1,Z29), (Ra10,Rb3,X1,Z30),(Ra10,Rb3,X1,Z31), (Ra10,Rb3,X1,Z32), (Ra10,Rb3,X1,Z33),(Ra10,Rb3,X1,Z34), (Ra10,Rb3,X1,Z35), (Ra10,Rb3,X1,Z36),(Ra10,Rb3,X1,Z37), (Ra10,Rb3,X1,Z38), (Ra10,Rb3,X1,Z39),(Ra10,Rb3,X2,Z1), (Ra10,Rb3,X2,Z2), (Ra10,Rb3,X2,Z3), (Ra10,Rb3,X2,Z4),(Ra10,Rb3,X2,Z5), (Ra10,Rb3,X2,Z6), (Ra10,Rb3,X2,Z7), (Ra10,Rb3,X2,Z8),(Ra10,Rb3,X2,Z9), (Ra10,Rb3,X2,Z10), (Ra10,Rb3,X2,Z11),(Ra10,Rb3,X2,Z12), (Ra10,Rb3,X2,Z13), (Ra10,Rb3,X2,Z14),(Ra10,Rb3,X2,Z15), (Ra10,Rb3,X2,Z16), (Ra10,Rb3,X2,Z17),(Ra10,Rb3,X2,Z18), (Ra10,Rb3,X2,Z19), (Ra10,Rb3,X2,Z20),(Ra10,Rb3,X2,Z21), (Ra10,Rb3,X2,Z22), (Ra10,Rb3,X2,Z23),(Ra10,Rb3,X2,Z24), (Ra10,Rb3,X2,Z25), (Ra10,Rb3,X2,Z26),(Ra10,Rb3,X2,Z27), (Ra10,Rb3,X2,Z28), (Ra10,Rb3,X2,Z29),(Ra10,Rb3,X2,Z30), (Ra10,Rb3,X2,Z31), (Ra10,Rb3,X2,Z32),(Ra10,Rb3,X2,Z33), (Ra10,Rb3,X2,Z34), (Ra10,Rb3,X2,Z35),(Ra10,Rb3,X2,Z36), (Ra10,Rb3,X2,Z37), (Ra10,Rb3,X2,Z38),(Ra10,Rb3,X2,Z39), (Ra10,Rb4,X1,Z1), (Ra10,Rb4,X1,Z2), (Ra10,Rb4,X1,Z3),(Ra10,Rb4,X1,Z4), (Ra10,Rb4,X1,Z5), (Ra10,Rb4,X1,Z6), (Ra10,Rb4,X1,Z7),(Ra10,Rb4,X1,Z8), (Ra10,Rb4,X1,Z9), (Ra10,Rb4,X1,Z10),(Ra10,Rb4,X1,Z11), (Ra10,Rb4,X1,Z12), (Ra10,Rb4,X1,Z13),(Ra10,Rb4,X1,Z14), (Ra10,Rb4,X1,Z15), (Ra10,Rb4,X1,Z16),(Ra10,Rb4,X1,Z17), (Ra10,Rb4,X1,Z18), (Ra10,Rb4,X1,Z19),(Ra10,Rb4,X1,Z20), (Ra10,Rb4,X1,Z21), (Ra10,Rb4,X1,Z22),(Ra10,Rb4,X1,Z23), (Ra10,Rb4,X1,Z24), (Ra10,Rb4,X1,Z25),(Ra10,Rb4,X1,Z26), (Ra10,Rb4,X1,Z27), (Ra10,Rb4,X1,Z28),(Ra10,Rb4,X1,Z29), (Ra10,Rb4,X1,Z30), (Ra10,Rb4,X1,Z31),(Ra10,Rb4,X1,Z32), (Ra10,Rb4,X1,Z33), (Ra10,Rb4,X1,Z34),(Ra10,Rb4,X1,Z35), (Ra10,Rb4,X1,Z36), (Ra10,Rb4,X1,Z37),(Ra10,Rb4,X1,Z38), (Ra10,Rb4,X1,Z39), (Ra10,Rb4,X2,Z1),(Ra10,Rb4,X2,Z2), (Ra10,Rb4,X2,Z3), (Ra10,Rb4,X2,Z4), (Ra10,Rb4,X2,Z5),(Ra10,Rb4,X2,Z6), (Ra10,Rb4,X2,Z7), (Ra10,Rb4,X2,Z8), (Ra10,Rb4,X2,Z9),(Ra10,Rb4,X2,Z10), (Ra10,Rb4,X2,Z11), (Ra10,Rb4,X2,Z12),(Ra10,Rb4,X2,Z13), (Ra10,Rb4,X2,Z14), (Ra10,Rb4,X2,Z15),(Ra10,Rb4,X2,Z10, (Ra10,Rb4,X2,Z17), (Ra10,Rb4,X2,Z18),(Ra10,Rb4,X2,Z19), (Ra10,Rb4,X2,Z20), (Ra10,Rb4,X2,Z21),(Ra10,Rb4,X2,Z22), (Ra10,Rb4,X2,Z23), (Ra10,Rb4,X2,Z24),(Ra10,Rb4,X2,Z25), (Ra10,Rb4,X2,Z26), (Ra10,Rb4,X2,Z27),(Ra10,Rb4,X2,Z28), (Ra10,Rb4,X2,Z29), (Ra10,Rb4,X2,Z30),(Ra10,Rb4,X2,Z31), (Ra10,Rb4,X2,Z32), (Ra10,Rb4,X2,Z33),(Ra10,Rb4,X2,Z34), (Ra10,Rb4,X2,Z35), (Ra10,Rb4,X2,Z36),(Ra10,Rb4,X2,Z37), (Ra10,Rb4,X2,Z38), (Ra10,Rb4,X2,Z39),(Ra10,Rb5,X1,Z1), (Ra10,Rb5,X1,Z2), (Ra10,Rb5,X1,Z3), (Ra10,Rb5,X1,Z4),(Ra10,Rb5,X1,Z5), (Ra10,Rb5,X1,Z6), (Ra10,Rb5,X1,Z7), (Ra10,Rb5,X1,Z8),(Ra10,Rb5,X1,Z9), (Ra10,Rb5,X1,Z10), (Ra10,Rb5,X1,Z11),(Ra10,Rb5,X1,Z12), (Ra10,Rb5,X1,Z13), (Ra10,Rb5,X1,Z14),(Ra10,Rb5,X1,Z15), (Ra10,Rb5,X1,Z16), (Ra10,Rb5,X1,Z17),(Ra10,Rb5,X1,Z18), (Ra10,Rb5,X1,Z19), (Ra10,Rb5,X1,Z20),(Ra10,Rb5,X1,Z21), (Ra10,Rb5,X1,Z22), (Ra10,Rb5,X1,Z23),(Ra10,Rb5,X1,Z24), (Ra10,Rb5,X1,Z25), (Ra10,Rb5,X1,Z26),(Ra10,Rb5,X1,Z27), (Ra10,Rb5,X1,Z28), (Ra10,Rb5,X1,Z29),(Ra10,Rb5,X1,Z30), (Ra10,Rb5,X1,Z31), (Ra10,Rb5,X1,Z32),(Ra10,Rb5,X1,Z33), (Ra10,Rb5,X1,Z34), (Ra10,Rb5,X1,Z35),(Ra10,Rb5,X1,Z36), (Ra10,Rb5,X1,Z37), (Ra10,Rb5,X1,Z38),(Ra10,Rb5,X1,Z39), (Ra10,Rb5,X2,Z1), (Ra10,Rb5,X2,Z2), (Ra10,Rb5,X2,Z3),(Ra10,Rb5,X2,Z4), (Ra10,Rb5,X2,Z5), (Ra10,Rb5,X2,Z6), (Ra10,Rb5,X2,Z7),(Ra10,Rb5,X2,Z8), (Ra10,Rb5,X2,Z9), (Ra10,Rb5,X2,Z10),(Ra10,Rb5,X2,Z11), (Ra10,Rb5,X2,Z12), (Ra10,Rb5,X2,Z13),(Ra10,Rb5,X2,Z14), (Ra10,Rb5,X2,Z15), (Ra10,Rb5,X2,Z16),(Ra10,Rb5,X2,Z17), (Ra10,Rb5,X2,Z18), (Ra10,Rb5,X2,Z19),(Ra10,Rb5,X2,Z20), (Ra10,Rb5,X2,Z21), (Ra10,Rb5,X2,Z22),(Ra10,Rb5,X2,Z23), (Ra10,Rb5,X2,Z24), (Ra10,Rb5,X2,Z25),(Ra10,Rb5,X2,Z26), (Ra10,Rb5,X2,Z27), (Ra10,Rb5,X2,Z28),(Ra10,Rb5,X2,Z29), (Ra10,Rb5,X2,Z30), (Ra10,Rb5,X2,Z31),(Ra10,Rb5,X2,Z32), (Ra10,Rb5,X2,Z33), (Ra10,Rb5,X2,Z34),(Ra10,Rb5,X2,Z35), (Ra10,Rb5,X2,Z36), (Ra10,Rb5,X2,Z37),(Ra10,Rb5,X2,Z38), (Ra10,Rb5,X2,Z39), (Ra10,Rb6,X1,Z1),(Ra10,Rb6,X1,Z2), (Ra10,Rb6,X1,Z3), (Ra10,Rb6,X1,Z4), (Ra10,Rb6,X1,Z5),(Ra10,Rb6,X1,Z6), (Ra10,Rb6,X1,Z7), (Ra10,Rb6,X1,Z8), (Ra10,Rb6,X1,Z9),(Ra10,Rb6,X1,Z10), (Ra10,Rb6,X1,Z11), (Ra10,Rb6,X1,Z12),(Ra10,Rb6,X1,Z13), (Ra10,Rb6,X1,Z14), (Ra10,Rb6,X1,Z15),(Ra10,Rb6,X1,Z16), (Ra10,Rb6,X1,Z17), (Ra10,Rb6,X1,Z18),(Ra10,Rb6,X1,Z19), (Ra10,Rb6,X1,Z20), (Ra10,Rb6,X1,Z21),(Ra10,Rb6,X1,Z22), (Ra10,Rb6,X1,Z23), (Ra10,Rb6,X1,Z24),(Ra10,Rb6,X1,Z25), (Ra10,Rb6,X1,Z26), (Ra10,Rb6,X1,Z27),(Ra10,Rb6,X1,Z28), (Ra10,Rb6,X1,Z29), (Ra10,Rb6,X1,Z30),(Ra10,Rb6,X1,Z31), (Ra10,Rb6,X1,Z32), (Ra10,Rb6,X1,Z33),(Ra10,Rb6,X1,Z34), (Ra10,Rb6,X1,Z35), (Ra10,Rb6,X1,Z36),(Ra10,Rb6,X1,Z37), (Ra10,Rb6,X1,Z38), (Ra10,Rb6,X1,Z39),(Ra10,Rb6,X2,Z1), (Ra10,Rb6,X2,Z2), (Ra10,Rb6,X2,Z3), (Ra10,Rb6,X2,Z4),(Ra10,Rb6,X2,Z5), (Ra10,Rb6,X2,Z6), (Ra10,Rb6,X2,Z7), (Ra10,Rb6,X2,Z8),(Ra10,Rb6,X2,Z9), (Ra10,Rb6,X2,Z10), (Ra10,Rb6,X2,Z11),(Ra10,Rb6,X2,Z12), (Ra10,Rb6,X2,Z13), (Ra10,Rb6,X2,Z14),(Ra10,Rb6,X2,Z15), (Ra10,Rb6,X2,Z16), (Ra10,Rb6,X2,Z17),(Ra10,Rb6,X2,Z18), (Ra10,Rb6,X2,Z19), (Ra10,Rb6,X2,Z20),(Ra10,Rb6,X2,Z21), (Ra10,Rb6,X2,Z22), (Ra10,Rb6,X2,Z23),(Ra10,Rb6,X2,Z24), (Ra10,Rb6,X2,Z25), (Ra10,Rb6,X2,Z26),(Ra10,Rb6,X2,Z27), (Ra10,Rb6,X2,Z28), (Ra10,Rb6,X2,Z29),(Ra10,Rb6,X2,Z30), (Ra10,Rb6,X2,Z31), (Ra10,Rb6,X2,Z32),(Ra10,Rb6,X2,Z33), (Ra10,Rb6,X2,Z34), (Ra10,Rb6,X2,Z35),(Ra10,Rb6,X2,Z36), (Ra10,Rb6,X2,Z37), (Ra10,Rb6,X2,Z38),(Ra10,Rb6,X2,Z39), (Ra10,Rb7,X1,Z1), (Ra10,Rb7,X1,Z2), (Ra10,Rb7,X1,Z3),(Ra10,Rb7,X1,Z4), (Ra10,Rb7,X1,Z5), (Ra10,Rb7,X1,Z6), (Ra10,Rb7,X1,Z7),(Ra10,Rb7,X1,Z8), (Ra10,Rb7,X1,Z9), (Ra10,Rb7,X1,Z10),(Ra10,Rb7,X1,Z11), (Ra10,Rb7,X1,Z12), (Ra10,Rb7,X1,Z13),(Ra10,Rb7,X1,Z14), (Ra10,Rb7,X1,Z15), (Ra10,Rb7,X1,Z16),(Ra10,Rb7,X1,Z17), (Ra10,Rb7,X1,Z18), (Ra10,Rb7,X1,Z19),(Ra10,Rb7,X1,Z20), (Ra10,Rb7,X1,Z21), (Ra10,Rb7,X1,Z22),(Ra10,Rb7,X1,Z23), (Ra10,Rb7,X1,Z24), (Ra10,Rb7,X1,Z25),(Ra10,Rb7,X1,Z26), (Ra10,Rb7,X1,Z27), (Ra10,Rb7,X1,Z28),(Ra10,Rb7,X1,Z29), (Ra10,Rb7,X1,Z30), (Ra10,Rb7,X1,Z31),(Ra10,Rb7,X1,Z32), (Ra10,Rb7,X1,Z33), (Ra10,Rb7,X1,Z34),(Ra10,Rb7,X1,Z35), (Ra10,Rb7,X1,Z36), (Ra10,Rb7,X1,Z37),(Ra10,Rb7,X1,Z38), (Ra10,Rb7,X1,Z39), (Ra10,Rb7,X2,Z1),(Ra10,Rb7,X2,Z2), (Ra10,Rb7,X2,Z3), (Ra10,Rb7,X2,Z4), (Ra10,Rb7,X2,Z5),(Ra10,Rb7,X2,Z6), (Ra10,Rb7,X2,Z7), (Ra10,Rb7,X2,Z8), (Ra10,Rb7,X2,Z9),(Ra10,Rb7,X2,Z10), (Ra10,Rb7,X2,Z11), (Ra10,Rb7,X2,Z12),(Ra10,Rb7,X2,Z13), (Ra10,Rb7,X2,Z14), (Ra10,Rb7,X2,Z15),(Ra10,Rb7,X2,Z16), (Ra10,Rb7,X2,Z17), (Ra10,Rb7,X2,Z18),(Ra10,Rb7,X2,Z19), (Ra10,Rb7,X2,Z20), (Ra10,Rb7,X2,Z21),(Ra10,Rb7,X2,Z22), (Ra10,Rb7,X2,Z23), (Ra10,Rb7,X2,Z24),(Ra10,Rb7,X2,Z25), (Ra10,Rb7,X2,Z26), (Ra10,Rb7,X2,Z27),(Ra10,Rb7,X2,Z28), (Ra10,Rb7,X2,Z29), (Ra10,Rb7,X2,Z30),(Ra10,Rb7,X2,Z31), (Ra10,Rb7,X2,Z32), (Ra10,Rb7,X2,Z33),(Ra10,Rb7,X2,Z34), (Ra10,Rb7,X2,Z35), (Ra10,Rb7,X2,Z36),(Ra10,Rb7,X2,Z37), (Ra10,Rb7,X2,Z38), (Ra10,Rb7,X2,Z39),(Ra10,Rb8,X1,Z1), (Ra10,Rb8,X1,Z2), (Ra10,Rb8,X1,Z3), (Ra10,Rb8,X1,Z4),(Ra10,Rb8,X1,Z5), (Ra10,Rb8,X1,Z6), (Ra10,Rb8,X1,Z7), (Ra10,Rb8,X1,Z8),(Ra10,Rb8,X1,Z9), (Ra10,Rb8,X1,Z10), (Ra10,Rb8,X1,Z11),(Ra10,Rb8,X1,Z12), (Ra10,Rb8,X1,Z13), (Ra10,Rb8,X1,Z14),(Ra10,Rb8,X1,Z15), (Ra10,Rb8,X1,Z16), (Ra10,Rb8,X1,Z17),(Ra10,Rb8,X1,Z18), (Ra10,Rb8,X1,Z19), (Ra10,Rb8,X1,Z20),(Ra10,Rb8,X1,Z21), (Ra10,Rb8,X1,Z22), (Ra10,Rb8,X1,Z23),(Ra10,Rb8,X1,Z24), (Ra10,Rb8,X1,Z25), (Ra10,Rb8,X1,Z26),(Ra10,Rb8,X1,Z27), (Ra10,Rb8,X1,Z28), (Ra10,Rb8,X1,Z29),(Ra10,Rb8,X1,Z30), (Ra10,Rb8,X1,Z31), (Ra10,Rb8,X1,Z32),(Ra10,Rb8,X1,Z33), (Ra10,Rb8,X1,Z34), (Ra10,Rb8,X1,Z35),(Ra10,Rb8,X1,Z36), (Ra10,Rb8,X1,Z37), (Ra10,Rb8,X1,Z38),(Ra10,Rb8,X1,Z39), (Ra10,Rb8,X2,Z1), (Ra10,Rb8,X2,Z2), (Ra10,Rb8,X2,Z3),(Ra10,Rb8,X2,Z4), (Ra10,Rb8,X2,Z5), (Ra10,Rb8,X2,Z6), (Ra10,Rb8,X2,Z7),(Ra10,Rb8,X2,Z8), (Ra10,Rb8,X2,Z9), (Ra10,Rb8,X2,Z10),(Ra10,Rb8,X2,Z11), (Ra10,Rb8,X2,Z12), (Ra10,Rb8,X2,Z13),(Ra10,Rb8,X2,Z14), (Ra10,Rb8,X2,Z15), (Ra10,Rb8,X2,Z16),(Ra10,Rb8,X2,Z17), (Ra10,Rb8,X2,Z18), (Ra10,Rb8,X2,Z19),(Ra10,Rb8,X2,Z20), (Ra10,Rb8,X2,Z21), (Ra10,Rb8,X2,Z22),(Ra10,Rb8,X2,Z23), (Ra10,Rb8,X2,Z24), (Ra10,Rb8,X2,Z25),(Ra10,Rb8,X2,Z26), (Ra10,Rb8,X2,Z27), (Ra10,Rb8,X2,Z28),(Ra10,Rb8,X2,Z29), (Ra10,Rb8,X2,Z30), (Ra10,Rb8,X2,Z31),(Ra10,Rb8,X2,Z32), (Ra10,Rb8,X2,Z33), (Ra10,Rb8,X2,Z34),(Ra10,Rb8,X2,Z35), (Ra10,Rb8,X2,Z36), (Ra10,Rb8,X2,Z37),(Ra10,Rb8,X2,Z38), (Ra10,Rb8,X2,Z39), (Ra11,Rb1,X1,Z1),(Ra11,Rb1,X1,Z2), (Ra11,Rb1,X1,Z3), (Ra11,Rb1,X1,Z4), (Ra11,Rb1,X1,Z5),(Ra11,Rb1,X1,Z6), (Ra11,Rb1,X1,Z7), (Ra11,Rb1,X1,Z8), (Ra11,Rb1,X1,Z9),(Ra11,Rb1,X1,Z10), (Ra11,Rb1,X1,Z11), (Ra11,Rb1,X1,Z12),(Ra11,Rb1,X1,Z13), (Ra11,Rb1,X1,Z14), (Ra11,Rb1,X1,Z15),(Ra11,Rb1,X1,Z16), (Ra11,Rb1,X1,Z17), (Ra11,Rb1,X1,Z18),(Ra11,Rb1,X1,Z19), (Ra11,Rb1,X1,Z20), (Ra11,Rb1,X1,Z21),(Ra11,Rb1,X1,Z22), (Ra11,Rb1,X1,Z23), (Ra11,Rb1,X1,Z24),(Ra11,Rb1,X1,Z25), (Ra11,Rb1,X1,Z26), (Ra11,Rb1,X1,Z27),(Ra11,Rb1,X1,Z28), (Ra11,Rb1,X1,Z29), (Ra11,Rb1,X1,Z30),(Ra11,Rb1,X1,Z31), (Ra11,Rb1,X1,Z32), (Ra11,Rb1,X1,Z33),(Ra11,Rb1,X1,Z34), (Ra11,Rb1,X1,Z35), (Ra11,Rb1,X1,Z36),(Ra11,Rb1,X1,Z37), (Ra11,Rb1,X1,Z38), (Ra11,Rb1,X1,Z39),(Ra11,Rb1,X2,Z1), (Ra11,Rb1,X2,Z2), (Ra11,Rb1,X2,Z3), (Ra11,Rb1,X2,Z4),(Ra11,Rb1,X2,Z5), (Ra11,Rb1,X2,Z6), (Ra11,Rb1,X2,Z7), (Ra11,Rb1,X2,Z8),(Ra11,Rb1,X2,Z9), (Ra11,Rb1,X2,Z10), (Ra11,Rb1,X2,Z11),(Ra11,Rb1,X2,Z12), (Ra11,Rb1,X2,Z13), (Ra11,Rb1,X2,Z14),(Ra11Rb1,X2,Z15), (Ra11,Rb1,X2,Z16), (Ra11,Rb1,X2,Z17),(Ra11,Rb1,X2,Z18), (Ra11,Rb1,X2,Z19), (Ra11,Rb1,X2,Z20),(Ra11,Rb1,X2,Z21), (Ra11,Rb1,X2,Z22), (Ra11,Rb1,X2,Z23),(Ra11,Rb1,X2,Z24), (Ra11,Rb1,X2,Z25), (Ra11,Rb1,X2,Z26),(Ra11,Rb1,X2,Z27), (Ra11,Rb1,X2,Z28), (Ra11,Rb1,X2,Z29),(Ra11,Rb1,X2,Z30), (Ra11,Rb1,X2,Z31), (Ra11,Rb1,X2,Z32),(Ra11,Rb1,X2,Z33), (Ra11,Rb1,X2,Z34), (Ra11,Rb1,X2,Z35),(Ra11,Rb1,X2,Z36), (Ra11,Rb1,X2,Z37), (Ra11,Rb1,X2,Z38),(Ra11,Rb1,X2,Z39), (Ra11,Rb2,X1,Z1), (Ra11,Rb2,X1,Z2), (Ra11,Rb2,X1,Z3),(Ra11,Rb2,X1,Z4), (Ra11,Rb2,X1,Z5), (Ra11,Rb2,X1,Z6), (Ra11,Rb2,X1,Z7),(Ra11,Rb2,X1,Z8), (Ra11,Rb2,X1,Z9), (Ra11,Rb2,X1,Z10),(Ra11,Rb2,X1,Z11), (Ra11,Rb2,X1,Z12), (Ra11,Rb2,X1,Z13),(Ra11,Rb2,X1,Z14), (Ra11,Rb2,X1,Z15), (Ra11,Rb2,X1,Z16),(Ra11,Rb2,X1,Z17), (Ra11,Rb2,X1,Z18), (Ra11,Rb2,X1,Z19),(Ra11,Rb2,X1,Z20), (Ra11,Rb2,X1,Z21), (Ra11,Rb2,X1,Z22),(Ra11,Rb2,X1,Z23), (Ra11,Rb2,X1,Z24), (Ra11,Rb2,X1,Z25),(Ra11,Rb2,X1,Z26), (Ra11,Rb2,X1,Z27), (Ra11,Rb2,X1,Z28),(Ra11,Rb2,X1,Z29), (Ra11,Rb2,X1,Z30), (Ra11,Rb2,X1,Z31),(Ra11,Rb2,X1,Z32), (Ra11,Rb2,X1,Z33), (Ra11,Rb2,X1,Z34),(Ra11,Rb2,X1,Z35), (Ra11,Rb2,X1,Z36), (Ra11,Rb2,X1,Z37),(Ra11,Rb2,X1,Z38), (Ra11,Rb2,X1,Z39), (Ra11,Rb2,X2,Z1),(Ra11,Rb2,X2,Z2), (Ra11,Rb2,X2,Z3), (Ra11,Rb2,X2,Z4), (Ra11,Rb2,X2,Z5),(Ra11,Rb2,X2,Z6), (Ra11,Rb2,X2,Z7), (Ra11,Rb2,X2,Z8), (Ra11,Rb2,X2,Z9),(Ra11,Rb2,X2,Z10), (Ra11,Rb2,X2,Z11), (Ra11,Rb2,X2,Z12),(Ra11,Rb2,X2,Z13), (Ra11,Rb2,X2,Z14), (Ra11,Rb2,X2,Z15),(Ra11,Rb2,X2,Z16), (Ra11,Rb2,X2,Z17), (Ra11,Rb2,X2,Z18),(Ra11,Rb2,X2,Z19), (Ra11,Rb2,X2,Z20), (Ra11,Rb2,X2,Z21),(Ra11,Rb2,X2,Z22), (Ra11,Rb2,X2,Z23), (Ra11,Rb2,X2,Z24),(Ra11,Rb2,X2,Z25), (Ra11,Rb2,X2,Z26), (Ra11,Rb2,X2,Z27),(Ra11,Rb2,X2,Z28), (Ra11,Rb2,X2,Z29), (Ra11,Rb2,X2,Z30),(Ra11,Rb2,X2,Z31), (Ra11,Rb2,X2,Z32), (Ra11,Rb2,X2,Z33),(Ra11,Rb2,X2,Z34), (Ra11,Rb2,X2,Z35), (Ra11,Rb2,X2,Z36),(Ra11,Rb2,X2,Z37), (Ra11,Rb2,X2,Z38), (Ra11,Rb2,X2,Z39),(Ra11,Rb3,X1,Z1), (Ra11,Rb3,X1,Z2), (Ra11,Rb3,X1,Z3), (Ra11,Rb3,X1,Z4),(Ra11,Rb3,X1,Z5), (Ra11,Rb3,X1,Z6), (Ra11,Rb3,X1,Z7), (Ra11,Rb3,X1,Z8),(Ra11,Rb3,X1,Z9), (Ra11,Rb3,X1,Z10), (Ra11,Rb3,X1,Z11),(Ra11,Rb3,X1,Z12), (Ra11,Rb3,X1,Z13), (Ra11,Rb3,X1,Z14),(Ra11,Rb3,X1,Z15), (Ra11,Rb3,X1,Z16), (Ra11,Rb3,X1,Z17),(Ra11,Rb3,X1,Z18), (Ra11,Rb3,X1,Z19), (Ra11,Rb3,X1,Z20),(Ra11,Rb3,X1,Z21), (Ra11,Rb3,X1,Z22), (Ra11,Rb3,X1,Z23),(Ra11,Rb3,X1,Z24), (Ra11,Rb3,X1,Z25), (Ra11,Rb3,X1,Z26),(Ra11,Rb3,X1,Z27), (Ra11,Rb3,X1,Z28), (Ra11,Rb3,X1,Z29),(Ra11,Rb3,X1,Z30), (Ra11,Rb3,X1,Z31), (Ra11,Rb3,X1,Z32),(Ra11,Rb3,X1,Z33), (Ra11,Rb3,X1,Z34), (Ra11,Rb3,X1,Z35),(Ra11,Rb3,X1,Z36), (Ra11,Rb3,X1,Z37), (Ra11,Rb3,X1,Z38),(Ra11,Rb3,X1,Z39), (Ra11,Rb3,X2,Z1), (Ra11,Rb3,X2,Z2), (Ra11,Rb3,X2,Z3),(Ra11,Rb3,X2,Z4), (Ra11,Rb3,X2,Z5), (Ra11,Rb3,X2,Z6), (Ra11,Rb3,X2,Z7),(Ra11,Rb3,X2,Z8), (Ra11,Rb3,X2,Z9), (Ra11,Rb3,X2,Z10),(Ra11,Rb3,X2,Z11), (Ra11,Rb3,X2,Z12), (Ra11,Rb3,X2,Z13),(Ra11,Rb3,X2,Z14), (Ra11,Rb3,X2,Z15), (Ra11,Rb3,X2,Z16),(Ra11,Rb3,X2,Z17), (Ra11,Rb3,X2,Z18), (Ra11,Rb3,X2,Z19),(Ra11,Rb3,X2,Z20), (Ra11,Rb3,X2,Z21), (Ra11,Rb3,X2,Z22),(Ra11,Rb3,X2,Z23), (Ra11,Rb3,X2,Z24), (Ra11,Rb3,X2,Z25),(Ra11,Rb3,X2,Z26), (Ra11,Rb3,X2,Z27), (Ra11,Rb3,X2,Z28),(Ra11,Rb3,X2,Z29), (Ra11,Rb3,X2,Z30), (Ra11,Rb3,X2,Z31),(Ra11,Rb3,X2,Z32), (Ra11,Rb3,X2,Z33), (Ra11,Rb3,X2,Z34),(Ra11,Rb3,X2,Z35), (Ra11,Rb3,X2,Z36), (Ra11,Rb3,X2,Z37),(Ra11,Rb3,X2,Z38), (Ra11,Rb3,X2,Z39), (Ra11,Rb4,X1,Z1),(Ra11,Rb4,X1,Z2), (Ra11,Rb4,X1,Z3), (Ra11,Rb4,X1,Z4), (Ra11,Rb4,X1,Z5),(Ra11,Rb4,X1,Z6), (Ra11,Rb4,X1,Z7), (Ra11,Rb4,X1,Z8), (Ra11,Rb4,X1,Z9),(Ra11,Rb4,X1,Z10), (Ra11,Rb4,X1,Z11), (Ra11,Rb4,X1,Z12),(Ra11,Rb4,X1,Z13), (Ra11,Rb4,X1,Z14), (Ra11,Rb4,X1,Z15),(Ra11,Rb4,X1,Z16), (Ra11,Rb4,X1,Z17), (Ra11,Rb4,X1,Z18),(Ra11,Rb4,X1,Z19), (Ra11,Rb4,X1,Z20), (Ra11,Rb4,X1,Z21),(Ra11,Rb4,X1,Z22), (Ra11,Rb4,X1,Z23), (Ra11,Rb4,X1,Z24),(Ra11,Rb4,X1,Z25), (Ra11,Rb4,X1,Z26), (Ra11,Rb4,X1,Z27),(Ra11,Rb4,X1,Z28), (Ra11,Rb4,X1,Z29), (Ra11,Rb4,X1,Z30),(Ra11,Rb4,X1,Z31), (Ra11,Rb4,X1,Z32), (Ra11,Rb4,X1,Z33),(Ra11,Rb4,X1,Z34), (Ra11,Rb4,X1,Z35), (Ra11,Rb4,X1,Z36),(Ra11,Rb4,X1,Z37), (Ra11,Rb4,X1,Z38), (Ra11,Rb4,X1,Z39),(Ra11,Rb4,X2,Z1), (Ra11,Rb4,X2,Z2), (Ra11,Rb4,X2,Z3), (Ra11,Rb4,X2,Z4),(Ra11,Rb4,X2,Z5), (Ra11,Rb4,X2,Z6), (Ra11,Rb4,X2,Z7), (Ra11,Rb4,X2,Z8),(Ra11,Rb4,X2,Z9), (Ra11,Rb4,X2,Z10), (Ra11,Rb4,X2,Z11),(Ra11,Rb4,X2,Z12), (Ra11,Rb4,X2,Z13), (Ra11,Rb4,X2,Z14),(Ra11,Rb4,X2,Z15), (Ra11,Rb4,X2,Z16), (Ra11,Rb4,X2,Z17),(Ra11,Rb4,X2,Z18), (Ra11,Rb4,X2,Z19), (Ra11,Rb4,X2,Z20),(Ra11,Rb4,X2,Z21), (Ra11,Rb4,X2,Z22), (Ra11,Rb4,X2,Z23),(Ra11,Rb4,X2,Z24), (Ra11,Rb4,X2,Z25), (Ra11,Rb4,X2,Z26),(Ra11,Rb4,X2,Z27), (Ra11,Rb4,X2,Z28), (Ra11,Rb4,X2,Z29),(Ra11,Rb4,X2,Z30), (Ra11,Rb4,X2,Z31), (Ra11,Rb4,X2,Z32),(Ra11,Rb4,X2,Z33), (Ra11,Rb4,X2,Z34), (Ra11,Rb4,X2,Z35),(Ra11,Rb4,X2,Z36), (Ra11,Rb4,X2,Z37), (Ra11,Rb4,X2,Z38),(Ra11,Rb4,X2,Z39), (Ra11,Rb5,X1,Z1), (Ra11,Rb5,X1,Z2), (Ra11,Rb5,X1,Z3),(Ra11,Rb5,X1,Z4), (Ra11,Rb5,X1,Z5), (Ra11,Rb5,X1,Z6), (Ra11,Rb5,X1,Z7),(Ra11,Rb5,X1,Z8), (Ra11,Rb5,X1,Z9), (Ra11,Rb5,X1,Z10),(Ra11,Rb5,X1,Z11), (Ra11,Rb5,X1,Z12), (Ra11,Rb5,X1,Z13),(Ra11,Rb5,X1,Z14), (Ra11,Rb5,X1,Z15), (Ra11,Rb5,X1,Z16),(Ra11,Rb5,X1,Z17), (Ra11,Rb5,X1,Z18), (Ra11,Rb5,X1,Z19),(Ra11,Rb5,X1,Z20), (Ra11,Rb5,X1,Z21), (Ra11,Rb5,X1,Z22),(Ra11,Rb5,X1,Z23), (Ra11,Rb5,X1,Z24), (Ra11,Rb5,X1,Z25),(Ra11,Rb5,X1,Z26), (Ra11,Rb5,X1,Z27), (Ra11,Rb5,X1,Z28),(Ra11,Rb5,X1,Z29), (Ra11,Rb5,X1,Z30), (Ra11,Rb5,X1,Z31),(Ra11,Rb5,X1,Z32), (Ra11,Rb5,X1,Z33), (Ra11,Rb5,X1,Z34),(Ra11,Rb5,X1,Z35), (Ra11,Rb5,X1,Z36), (Ra11,Rb5,X1,Z37),(Ra11,Rb5,X1,Z38), (Ra11,Rb5,X1,Z39), (Ra11,Rb5,X2,Z1),(Ra11,Rb5,X2,Z2), (Ra11,Rb5,X2,Z3), (Ra11,Rb5,X2,Z4), (Ra11,Rb5,X2,Z5),(Ra11,Rb5,X2,Z6), (Ra11,Rb5,X2,Z7), (Ra11,Rb5,X2,Z8), (Ra11,Rb5,X2,Z9),(Ra11,Rb5,X2,Z10), (Ra11,Rb5,X2,Z11), (Ra11,Rb5,X2,Z12),(Ra11,Rb5,X2,Z13), (Ra11,Rb5,X2,Z14), (Ra11,Rb5,X2,Z15),(Ra11,Rb5,X2,Z16), (Ra11,Rb5,X2,Z17), (Ra11,Rb5,X2,Z18),(Ra11,Rb5,X2,Z19), (Ra11,Rb5,X2,Z20), (Ra11,Rb5,X2,Z21),(Ra11,Rb5,X2,Z22), (Ra11,Rb5,X2,Z23), (Ra11,Rb5,X2,Z24),(Ra11,Rb5,X2,Z25), (Ra11,Rb5,X2,Z26), (Ra11,Rb5,X2,Z27),(Ra11,Rb5,X2,Z28), (Ra11,Rb5,X2,Z29), (Ra11,Rb5,X2,Z30),(Ra11,Rb5,X2,Z31), (Ra11,Rb5,X2,Z32), (Ra11,Rb5,X2,Z33),(Ra11,Rb5,X2,Z34), (Ra11,Rb5,X2,Z35), (Ra11,Rb5,X2,Z36),(Ra11,Rb5,X2,Z37), (Ra11,Rb5,X2,Z38), (Ra11,Rb5,X2,Z39),(Ra11,Rb6,X1,Z1), (Ra11,Rb6,X1,Z2), (Ra11,Rb6,X1,Z3), (Ra11,Rb6,X1,Z4),(Ra11,Rb6,X1,Z5), (Ra11,Rb6,X1,Z6), (Ra11,Rb6,X1,Z7), (Ra11,Rb6,X1,Z8),(Ra11,Rb6,X1,Z9), (Ra11,Rb6,X1,Z10), (Ra11,Rb6,X1,Z11),(Ra11,Rb6,X1,Z12), (Ra11,Rb6,X1,Z13), (Ra11,Rb6,X1,Z14),(Ra11,Rb6,X1,Z15), (Ra11,Rb6,X1,Z16), (Ra11,Rb6,X1,Z17),(Ra11,Rb6,X1,Z18), (Ra11,Rb6,X1,Z19), (Ra11,Rb6,X1,Z20),(Ra11,Rb6,X1,Z21), (Ra11,Rb6,X1,Z22), (Ra11,Rb6,X1,Z23),(Ra11,Rb6,X1,Z24), (Ra11,Rb8,X1,Z25), (Ra11,Rb8,X1,Z26),(Ra11,Rb6,X1,Z27), (Ra11,Rb6,X1,Z28), (Ra11,Rb6,X1,Z29),(Ra11,Rb6,X1,Z30), (Ra11,Rb6,X1,Z31), (Ra11,Rb6,X1,Z32),(Ra11,Rb6,X1,Z33), (Ra11,Rb6,X1,Z34), (Ra11,Rb6,X1,Z35),(Ra11,Rb6,X1,Z36), (Ra11,Rb6,X1,Z37), (Ra11,Rb6,X1,Z38),(Ra11,Rb6,X1,Z39), (Ra11,Rb6,X2,Z1), (Ra11,Rb6,X2,Z2), (Ra11,Rb6,X2,Z3),(Ra11,Rb6,X2,Z4), (Ra11,Rb6,X2,Z5), (Ra11,Rb6,X2,Z6), (Ra11,Rb6,X2,Z7),(Ra11,Rb6,X2,Z8), (Ra11,Rb6,X2,Z9), (Ra11,Rb6,X2,Z10),(Ra11,Rb6,X2,Z11), (Ra11,Rb6,X2,Z12), (Ra11,Rb6,X2,Z13),(Ra11,Rb6,X2,Z14), (Ra11,Rb6,X2,Z15), (Ra11,Rb6,X2,Z16),(Ra11,Rb6,X2,Z17), (Ra11,Rb6,X2,Z18), (Ra11,Rb6,X2,Z19),(Ra11,Rb6,X2,Z20), (Ra11,Rb6,X2,Z21), (Ra11,Rb6,X2,Z22),(Ra11,Rb6,X2,Z23), (Ra11,Rb6,X2,Z24), (Ra11,Rb6,X2,Z25),(Ra11,Rb6,X2,Z26), (Ra11,Rb6,X2,Z27), (Ra11,Rb6,X2,Z28),(Ra11,Rb6,X2,Z29), (Ra11,Rb6,X2,Z30), (Ra11,Rb6,X2,Z31),(Ra11,Rb6,X2,Z32), (Ra11,Rb6,X2,Z33), (Ra11,Rb6,X2,Z34),(Ra11,Rb6,X2,Z35), (Ra11,Rb6,X2,Z36), (Ra11,Rb6,X2,Z37),(Ra11,Rb6,X2,Z38), (Ra11,Rb6,X2,Z39), (Ra11,Rb7,X1,Z1),(Ra11,Rb7,X1,Z2), (Ra11,Rb7,X1,Z3), (Ra11,Rb7,X1,Z4), (Ra11,Rb7,X1,Z5),(Ra11,Rb7,X1,Z6), (Ra11,Rb7,X1,Z7), (Ra11,Rb7,X1,Z8), (Ra11,Rb7,X1,Z9),(Ra11,Rb7,X1,Z10), (Ra11,Rb7,X1,Z11), (Ra11,Rb7,X1,Z12),(Ra11,Rb7,X1,Z13), (Ra11,Rb7,X1,Z14), (Ra11,Rb7,X1,Z15),(Ra11,Rb7,X1,Z16), (Ra11,Rb7,X1,Z17), (Ra11,Rb7,X1,Z18),(Ra11,Rb7,X1,Z19), (Ra11,Rb7,X1,Z20), (Ra11,Rb7,X1,Z21),(Ra11,Rb7,X1,Z22), (Ra11,Rb7,X1,Z23), (Ra11,Rb7,X1,Z24),(Ra11,Rb7,X1,Z25), (Ra11,Rb7,X1,Z26), (Ra11,Rb7,X1,Z27),(Ra11,Rb7,X1,Z28), (Ra11,Rb7,X1,Z29), (Ra11,Rb7,X1,Z30),(Ra11,Rb7,X1,Z31), (Ra11,Rb7,X1,Z32), (Ra11,Rb7,X1,Z33),(Ra11,Rb7,X1,Z34), (Ra11,Rb7,X1,Z35), (Ra11,Rb7,X1,Z36),(Ra11,Rb7,X1,Z37), (Ra11,Rb7,X1,Z38), (Ra11,Rb7,X1,Z39),(Ra11,Rb7,X2,Z1), (Ra11,Rb7,X2,Z2), (Ra11,Rb7,X2,Z3), (Ra11,Rb7,X2,Z4),(Ra11,Rb7,X2,Z5), (Ra11,Rb7,X2,Z6), (Ra11,Rb7,X2,Z7), (Ra11,Rb7,X2,Z8),(Ra11,Rb7,X2,Z9), (Ra11,Rb7,X2,Z10), (Ra11,Rb7,X2,Z11),(Ra11,Rb7,X2,Z12), (Ra11,Rb7,X2,Z13), (Ra11,Rb7,X2, Z14),(Ra11,Rb7,X2,Z15), (Ra11,Rb7,X2,Z16), (Ra11,Rb7,X2,Z17),(Ra11,Rb7,X2,Z18), (Ra11,Rb7,X2,Z19), (Ra11,Rb7,X2,Z20),(Ra11,Rb7,X2,Z21), (Ra11,Rb7,X2,Z22), (Ra11,Rb7,X2,Z23),(Ra11,Rb7,X2,Z24), (Ra11,Rb7,X2,Z25), (Ra11,Rb7,X2,Z26),(Ra11,Rb7,X2,Z27), (Ra11,Rb7,X2,Z28), (Ra11,Rb7,X2,Z29),(Ra11,Rb7,X2,Z30), (Ra11,Rb7,X2,Z31), (Ra11,Rb7,X2,Z32),(Ra11,Rb7,X2,Z33), (Ra11,Rb7,X2,Z34), (Ra11,Rb7,X2,Z35),(Ra11,Rb7,X2,Z36), (Ra11,Rb7,X2,Z37), (Ra11,Rb7,X2,Z38),(Ra11,Rb7,X2,Z39), (Ra11,Rb8,X1,Z1), (Ra11,Rb8,X1,Z2), (Ra11,Rb8,X1,Z3),(Ra11,Rb8,X1,Z4), (Ra11,Rb8,X1,Z5), (Ra11,Rb8,X1,Z6), (Ra11,Rb8,X1,Z7),(Ra11,Rb8,X1,Z8), (Ra11,Rb8,X1,Z9), (Ra11,Rb8,X1,Z10),(Ra11,Rb8,X1,Z11), (Ra11,Rb8,X1,Z12), (Ra11,Rb8,X1,Z13),(Ra11,Rb8,X1,Z14), (Ra11,Rb8,X1,Z15), (Ra11,Rb8,X1,Z16),(Ra11,Rb8,X1,Z17), (Ra11,Rb8,X1,Z18), (Ra11,Rb8,X1,Z19),(Ra11,Rb8,X1,Z20), (Ra11,Rb8,X1,Z21), (Ra11,Rb8,X1,Z22),(Ra11,Rb8,X1,Z23), (Ra11,Rb8,X1,Z24), (Ra11,Rb8,X1,Z25),(Ra11,Rb8,X1,Z26), (Ra11,Rb8,X1,Z27), (Ra11,Rb8,X1,Z28),(Ra11,Rb8,X1,Z29), (Ra11,Rb8,X1,Z30), (Ra11,Rb8,X1,Z31),(Ra11,Rb8,X1,Z32), (Ra11,Rb8,X1,Z33), (Ra11,Rb8,X1,Z34),(Ra11,Rb8,X1,Z35), (Ra11,Rb8,X1,Z36), (Ra11,Rb8,X1,Z37),(Ra11,Rb8,X1,Z38), (Ra11,Rb8,X1,Z39), (Ra11,Rb8,X2,Z1),(Ra11,Rb8,X2,Z2), (Ra11,Rb8,X2,Z3), (Ra11,Rb8,X2,Z4), (Ra11,Rb8,X2,Z5),(Ra11,Rb8,X2,Z6), (Ra11,Rb8,X2,Z7), (Ra11,Rb8,X2,Z8), (Ra11,Rb8,X2,Z9),(Ra11,Rb8,X2,Z10), (Ra11,Rb8,X2,Z11), (Ra11,Rb8,X2,Z12),(Ra11,Rb8,X2,Z13), (Ra11,Rb8,X2,Z14), (Ra11,Rb8,X2,Z15),(Ra11,Rb8,X2,Z16), (Ra11,Rb8,X2,Z17), (Ra11,Rb8,X2,Z18),(Ra11,Rb8,X2,Z19), (Ra11,Rb8,X2,Z20), (Ra11,Rb8,X2,Z21),(Ra11,Rb8,X2,Z22), (Ra11,Rb8,X2,Z23), (Ra11,Rb8,X2,Z24),(Ra11,Rb8,X2,Z25), (Ra11,Rb8,X2,Z26), (Ra11,Rb8,X2,Z27),(Ra11,Rb8,X2,Z28), (Ra11,Rb8,X2,Z29), (Ra11,Rb8,X2,Z30),(Ra11,Rb8,X2,Z31), (Ra11,Rb8,X2,Z32), (Ra11,Rb8,X2,Z33),(Ra11,Rb8,X2,Z34), (Ra11,Rb8,X2,Z35), (Ra11,Rb8,X2,Z36),(Ra11,Rb8,X2,Z37), (Ra11,Rb8,X2,Z38), (Ra11,Rb8,X2,Z39),(Ra12,Rb1,X1,Z1), (Ra12,Rb1,X1,Z2), (Ra12,Rb1,X1,Z3), (Ra12,Rb1,X1,Z4),(Ra12,Rb1,X1,Z5), (Ra12,Rb1,X1,Z6), (Ra12,Rb1,X1,Z7), (Ra12,Rb1,X1,Z8),(Ra12,Rb1,X1,Z9), (Ra12,Rb1,X1,Z10), (Ra12,Rb1,X1,Z11),(Ra12,Rb1,X1,Z12), (Ra12,Rb1,X1,Z13), (Ra12,Rb1,X1,Z14),(Ra12,Rb1,X1,Z15), (Ra12,Rb1,X1,Z16), (Ra12,Rb1,X1,Z17),(Ra12,Rb1,X1,Z18), (Ra12,Rb1,X1,Z19), (Ra12,Rb1,X1,Z20),(Ra12,Rb1,X1,Z21), (Ra12,Rb1,X1,Z22), (Ra12,Rb1,X1,Z23),(Ra12,Rb1,X1,Z24), (Ra12,Rb1,X1,Z25), (Ra12,Rb1,X1,Z26),(Ra12,Rb1,X1,Z27), (Ra12,Rb1,X1,Z28), (Ra12,Rb1,X1,Z29),(Ra12,Rb1,X1,Z30), (Ra12,Rb1,X1,Z31), (Ra12,Rb1,X1,Z32),(Ra12,Rb1,X1,Z33), (Ra12,Rb1,X1,Z34), (Ra12,Rb1,X1,Z35),(Ra12,Rb1,X1,Z36), (Ra12,Rb1,X1,Z37), (Ra12,Rb1,X1,Z38),(Ra12,Rb1,X1,Z39), (Ra12,Rb1,X2,Z1), (Ra12,Rb1,X2,Z2), (Ra12,Rb1,X2,Z3),(Ra12,Rb1,X2,Z4), (Ra12,Rb1,X2,Z5), (Ra12,Rb1,X2,Z6), (Ra12,Rb1,X2,Z7),(Ra12,Rb1,X2,Z8), (Ra12,Rb1,X2,Z9), (Ra12,Rb1,X2,Z10),(Ra12,Rb1,X2,Z11), (Ra12,Rb1,X2,Z12), (Ra12,Rb1,X2,Z13),(Ra12,Rb1,X2,Z14), (Ra12,Rb1,X2,Z15), (Ra12,Rb1,X2,Z16),(Ra12,Rb1,X2,Z17), (Ra12,Rb1,X2,Z18), (Ra12,Rb1,X2,Z19),(Ra12,Rb1,X2,Z20), (Ra12,Rb1,X2,Z21), (Ra12,Rb1,X2,Z22),(Ra12,Rb1,X2,Z23), (Ra12,Rb1,X2,Z24), (Ra12,Rb1,X2,Z25),(Ra12,Rb1,X2,Z26), (Ra12,Rb1,X2,Z27), (Ra12,Rb1,X2,Z28),(Ra12,Rb1,X2,Z29), (Ra12,Rb1,X2,Z30), (Ra12,Rb1,X2,Z31),(Ra12,Rb1,X2,Z32), (Ra12,Rb1,X2,Z33), (Ra12,Rb1,X2,Z34),(Ra12,Rb1,X2,Z35), (Ra12,Rb1,X2,Z36), (Ra12,Rb1,X2,Z37),(Ra12,Rb1,X2,Z38), (Ra12,Rb1,X2,Z39), (Ra12,Rb2,X1,Z1),(Ra12,Rb2,X1,Z2), (Ra12,Rb2,X1,Z3), (Ra12,Rb2,X1,Z4), (Ra12,Rb2,X1,Z5),(Ra12,Rb2,X1,Z6), (Ra12,Rb2,X1,Z7), (Ra12,Rb2,X1,Z8), (Ra12,Rb2,X1,Z9),(Ra12,Rb2,X1,Z10), (Ra12,Rb2,X1,Z11), (Ra12,Rb2,X1,Z12),(Ra12,Rb2,X1,Z13), (Ra12,Rb2,X1,Z14), (Ra12,Rb2,X1,Z15),(Ra12,Rb2,X1,Z16), (Ra12,Rb2,X1,Z17), (Ra12,Rb2,X1,Z18),(Ra12,Rb2,X1,Z19), (Ra12,Rb2,X1,Z20), (Ra12,Rb2,X1,Z21),(Ra12,Rb2,X1,Z22), (Ra12,Rb2,X1,Z23), (Ra12,Rb2,X1,Z24),(Ra12,Rb2,X1,Z25), (Ra12,Rb2,X1,Z26), (Ra12,Rb2,X1,Z27),(Ra12,Rb2,X1,Z28), (Ra12,Rb2,X1,Z29), (Ra12,Rb2,X1,Z30),(Ra12,Rb2,X1,Z31), (Ra12,Rb2,X1,Z32), (Ra12,Rb2,X1,Z33),(Ra12,Rb2,X1,Z34), (Ra12,Rb2,X1,Z35), (Ra12,Rb2,X1,Z36),(Ra12,Rb2,X1,Z37), (Ra12,Rb2,X1,Z38), (Ra12,Rb2,X1,Z39),(Ra12,Rb2,X2,Z1), (Ra12,Rb2,X2,Z2), (Ra12,Rb2,X2,Z3), (Ra12,Rb2,X2,Z4),(Ra12,Rb2,X2,Z5), (Ra12,Rb2,X2,Z6), (Ra12,Rb2,X2,Z7), (Ra12,Rb2,X2,Z8),(Ra12,Rb2,X2,Z9), (Ra12,Rb2,X2,Z10), (Ra12,Rb2,X2,Z11),(Ra12,Rb2,X2,Z12), (Ra12,Rb2,X2,Z13), (Ra12,Rb2,X2,Z14),(Ra12,Rb2,X2,Z15), (Ra12,Rb2,X2,Z16), (Ra12,Rb2,X2,Z17), (Ra12,Rb2,X2,Z18), (Ra12,Rb2,X2,Z19), (Ra12,Rb2,X2,Z20), (Ra12,Rb2,X2,Z21),(Ra12,Rb2,X2,Z22), (Ra12,Rb2,X2,Z23), (Ra12,Rb2,X2,Z24),(Ra12,Rb2,X2,Z25), (Ra12,Rb2,X2,Z26), (Ra12,Rb2,X2,Z27),(Ra12,Rb2,X2,Z28), (Ra12,Rb2,X2,Z29), (Ra12,Rb2,X2,Z30),(Ra12,Rb2,X2,Z31), (Ra12,Rb2,X2,Z32), (Ra12,Rb2,X2,Z33),(Ra12,Rb2,X2,Z34), (Ra12,Rb2,X2,Z35), (Ra12,Rb2,X2,Z36),(Ra12,Rb2,X2,Z37), (Ra12,Rb2,X2,Z38), (Ra12,Rb2,X2,Z39),(Ra12,Rb3,X1,Z1), (Ra12,Rb3,X1,Z2), (Ra12,Rb3,X1,Z3), (Ra12,Rb3,X1,Z4),(Ra12,Rb3,X1,Z5), (Ra12,Rb3,X1,Z6), (Ra12,Rb3,X1,Z7), (Ra12,Rb3,X1,Z8),(Ra12,Rb3,X1,Z9), (Ra12,Rb3,X1,Z10), (Ra12,Rb3,X1,Z11),(Ra12,Rb3,X1,Z12), (Ra12,Rb3,X1,Z13), (Ra12,Rb3,X1,Z14),(Ra12,Rb3,X1,Z15), (Ra12,Rb3,X1,Z16), (Ra12,Rb3,X1,Z17),(Ra12,Rb3,X1,Z18), (Ra12,Rb3,X1,Z19), (Ra12,Rb3,X1,Z20),(Ra12,Rb3,X1,Z21), (Ra12,Rb3,X1,Z22), (Ra12,Rb3,X1,Z23),(Ra12,Rb3,X1,Z24), (Ra12,Rb3,X1,Z25), (Ra12,Rb3,X1,Z26),(Ra12,Rb3,X1,Z27), (Ra12,Rb3,X1,Z28), (Ra12,Rb3,X1,Z29),(Ra12,Rb3,X1,Z30), (Ra12,Rb3,X1,Z31), (Ra12,Rb3,X1,Z32),(Ra12,Rb3,X1,Z33), (Ra12,Rb3,X1,Z34), (Ra12,Rb3,X1,Z35),(Ra12,Rb3,X1,Z36), (Ra12,Rb3,X1,Z37), (Ra12,Rb3,X1,Z38),(Ra12,Rb3,X1,Z39), (Ra12,Rb3,X2,Z1), (Ra12,Rb3,X2,Z2), (Ra12,Rb3,X2,Z3),(Ra12,Rb3,X2,Z4), (Ra12,Rb3,X2,Z5), (Ra12,Rb3,X2,Z6), (Ra12,Rb3,X2,Z7),(Ra12,Rb3,X2,Z8), (Ra12,Rb3,X2,Z9), (Ra12,Rb3,X2,Z10),(Ra12,Rb3,X2,Z11), (Ra12,Rb3,X2,Z12), (Ra12,Rb3,X2,Z13),(Ra12,Rb3,X2,Z14), (Ra12,Rb3,X2,Z15), (Ra12,Rb3,X2,Z16),(Ra12,Rb3,X2,Z17), (Ra12,Rb3,X2,Z18), (Ra12,Rb3,X2,Z19),(Ra12,Rb3,X2,Z20), (Ra12, Rb3,X2,Z21), (Ra12,Rb3,X2,Z22),(Ra12,Rb3,X2,Z23), (Ra12,Rb3,X2,Z24), (Ra12,Rb3,X2,Z25),(Ra12,Rb3,X2,Z26), (Ra12,Rb3,X2,Z27), (Ra12,Rb3,X2,Z28),(Ra12,Rb3,X2,Z29), (Ra12,Rb3,X2,Z30), (Ra12,Rb3,X2,Z31),(Ra12,Rb3,X2,Z32), (Ra12,Rb3,X2,Z33), (Ra12,Rb3,X2,Z34),(Ra12,Rb3,X2,Z35), (Ra12,Rb3,X2,Z36), (Ra12,Rb3,X2,Z37),(Ra12,Rb3,X2,Z38), (Ra12,Rb3,X2,Z39), (Ra12,Rb4,X1,Z1),(Ra12,Rb4,X1,Z2), (Ra12,Rb4,X1,Z3), (Ra12,Rb4,X1,Z4), (Ra12,Rb4,X1,Z5),(Ra12,Rb4,X1,Z6), (Ra12,Rb4,X1,Z7), (Ra12,Rb4,X1,Z8), (Ra12,Rb4,X1,Z9),(Ra12,Rb4,X1,Z10), (Ra12,Rb4,X1,Z11), (Ra12,Rb4,X1,Z12),(Ra12,Rb4,X1,Z13), (Ra12,Rb4,X1,Z14), (Ra12,Rb4,X1,Z15),(Ra12,Rb4,X1,Z16), (Ra12,Rb4,X1,Z17), (Ra12,Rb4,X1,Z18),(Ra12,Rb4,X1,Z19), (Ra12,Rb4,X1,Z20), (Ra12,Rb4,X1,Z21),(Ra12,Rb4,X1,Z22), (Ra12,Rb4,X1,Z23), (Ra12,Rb4,X1,Z24),(Ra12,Rb4,X1,Z25), (Ra12,Rb4,X1,Z26), (Ra12,Rb4,X1,Z27),(Ra12,Rb4,X1,Z28), (Ra12,Rb4,X1,Z29), (Ra12,Rb4,X1,Z30),(Ra12,Rb4,X1,Z31), (Ra12,Rb4,X1,Z32), (Ra12,Rb4,X1,Z33),(Ra12,Rb4,X1,Z34), (Ra12,Rb4,X1,Z35), (Ra12,Rb4,X1,Z36),(Ra12,Rb4,X1,Z37), (Ra12,Rb4,X1,Z38), (Ra12,Rb4,X1,Z39),(Ra12,Rb4,X2,Z1), (Ra12,Rb4,X2,Z2), (Ra12,Rb4,X2,Z3), (Ra12,Rb4,X2,Z4),(Ra12,Rb4,X2,Z5), (Ra12,Rb4,X2,Z6), (Ra12,Rb4,X2,Z7), (Ra12,Rb4,X2,Z8),(Ra12,Rb4,X2,Z9), (Ra12,Rb4,X2,Z10), (Ra12,Rb4,X2,Z11),(Ra12,Rb4,X2,Z12), (Ra12,Rb4,X2,Z13), (Ra12,Rb4,X2,Z14),(Ra12,Rb4,X2,Z15), (Ra12,Rb4,X2,Z16), (Ra12,Rb4,X2,Z17),(Ra12,Rb4,X2,Z18), (Ra12,Rb4,X2,Z19), (Ra12,Rb4,X2,Z20),(Ra12,Rb4,X2,Z21), (Ra12,Rb4,X2,Z22), (Ra12,Rb4,X2,Z23),(Ra12,Rb4,X2,Z24), (Ra12,Rb4,X2,Z25), (Ra12,Rb4,X2,Z26),(Ra12,Rb4,X2,Z27), (Ra12,Rb4,X2,Z28), (Ra12,Rb4,X2,Z29),(Ra12,Rb4,X2,Z30), (Ra12,Rb4,X2,Z31), (Ra12,Rb4,X2,Z32),(Ra12,Rb4,X2,Z33), (Ra12,Rb4,X2,Z34), (Ra12,Rb4,X2,Z35),(Ra12,Rb4,X2,Z36), (Ra12,Rb4,X2,Z37), (Ra12,Rb4,X2,Z38),(Ra12,Rb4,X2,Z39), (Ra12,Rb5,X1,Z1), (Ra12,Rb5,X1,Z2), (Ra12,Rb5,X1,Z3),(Ra12,Rb5,X1,Z4), (Ra12,Rb5,X1,Z5), (Ra12,Rb5,X1,Z6), (Ra12,Rb5,X1,Z7),(Ra12,Rb5,X1,Z8), (Ra12,Rb5,X1,Z9), (Ra12,Rb5,X1,Z10),(Ra12,Rb5,X1,Z11), (Ra12,Rb5,X1,Z12), (Ra12,Rb5,X1,Z13),(Ra12,Rb5,X1,Z14), (Ra12,Rb5,X1,Z15), (Ra12,Rb5,X1,Z16),(Ra12,Rb5,X1,Z17), (Ra12,Rb5,X1,Z18), (Ra12,Rb5,X1,Z19),(Ra12,Rb5,X1,Z20), (Ra12,Rb5,X1,Z21), (Ra12,Rb5,X1,Z22),(Ra12,Rb5,X1,Z23), (Ra12,Rb5,X1,Z24), (Ra12,Rb5,X1,Z25),(Ra12,Rb5,X1,Z26), (Ra12,Rb5,X1,Z27), (Ra12,Rb5,X1,Z28),(Ra12,Rb5,X1,Z29), (Ra12,Rb5,X1,Z30), (Ra12,Rb5,X1,Z31),(Ra12,Rb5,X1,Z32), (Ra12,Rb5,X1,Z33), (Ra12,Rb5,X1,Z34),(Ra12,Rb5,X1,Z35), (Ra12,Rb5,X1,Z36), (Ra12,Rb5,X1,Z37),(Ra12,Rb5,X1,Z38), (Ra12,Rb5,X1,Z39), (Ra12,Rb5,X2,Z1),(Ra12,Rb5,X2,Z2), (Ra12,Rb5,X2,Z3), (Ra12,Rb5,X2,Z4), (Ra12,Rb5,X2,Z5),(Ra12,Rb5,X2,Z6), (Ra12,Rb5,X2,Z7), (Ra12,Rb5,X2,Z8), (Ra12,Rb5,X2,Z9),(Ra12,Rb5,X2,Z10), (Ra12,Rb5,X2,Z11), (Ra12,Rb5,X2,Z12),(Ra12,Rb5,X2,Z13), (Ra12,Rb5,X2,Z14), (Ra12,Rb5,X2,Z15),(Ra12,Rb5,X2,Z16), (Ra12,Rb5,X2,Z17), (Ra12,Rb5,X2,Z18),(Ra12,Rb5,X2,Z19), (Ra12,Rb5,X2,Z20), (Ra12,Rb5,X2,Z21),(Ra12,Rb5,X2,Z22), (Ra12,Rb5,X2,Z23), (Ra12,Rb5,X2,Z24),(Ra12,Rb5,X2,Z25), (Ra12,Rb5,X2,Z26), (Ra12,Rb5,X2,Z27),(Ra12,Rb5,X2,Z28), (Ra12,Rb5,X2,Z29), (Ra12,Rb5,X2,Z30),(Ra12,Rb5,X2,Z31), (Ra12,Rb5,X2,Z32), (Ra12,Rb5,X2,Z33),(Ra12,Rb5,X2,Z34), (Ra12,Rb5,X2,Z35), (Ra12,Rb5,X2,Z36),(Ra12,Rb5,X2,Z37), (Ra12,Rb5,X2,Z38), (Ra12,Rb5,X2,Z39),(Ra12,Rb6,X1,Z1), (Ra12,Rb6,X1,Z2), (Ra12,Rb6,X1,Z3), (Ra12,Rb6,X1,Z4),(Ra12,Rb6,X1,Z5), (Ra12,Rb6,X1,Z6), (Ra12,Rb6,X1,Z7), (Ra12,Rb6,X1,Z8),(Ra12,Rb6,X1,Z9), (Ra12,Rb6,X1,Z10), (Ra12,Rb6,X1,Z11),(Ra12,Rb6,X1,Z12), (Ra12,Rb6,X1,Z13), (Ra12,Rb6,X1,Z14),(Ra12,Rb6,X1,Z15), (Ra12,Rb6,X1,Z16), (Ra12,Rb6,X1,Z17),(Ra12,Rb6,X1,Z18), (Ra12,Rb6,X1,Z19), (Ra12,Rb6,X1,Z20),(Ra12,Rb6,X1,Z21), (Ra12,Rb6,X1,Z22), (Ra12,Rb6,X1,Z23),(Ra12,Rb6,X1,Z24), (Ra12,Rb6,X1,Z25), (Ra12,Rb6,X1,Z26),(Ra12,Rb6,X1,Z27), (Ra12,Rb6,X1,Z28), (Ra12,Rb6,X1,Z29),(Ra12,Rb6,X1,Z30), (Ra12,Rb6,X1,Z31), (Ra12,Rb6,X1,Z32),(Ra12,Rb6,X1,Z33), (Ra12,Rb6,X1,Z34), (Ra12,Rb6,X1,Z35),(Ra12,Rb6,X1,Z36), (Ra12,Rb6,X1,Z37), (Ra12,Rb6,X1,Z38),(Ra12,Rb6,X1,Z39), (Ra12,Rb6,X2,Z1), (Ra12,Rb6,X2,Z2), (Ra12,Rb6,X2,Z3),(Ra12,Rb6,X2,Z4), (Ra12,Rb6,X2,Z5), (Ra12,Rb6,X2,Z6), (Ra12,Rb6,X2,Z7),(Ra12,Rb6,X2,Z8), (Ra12,Rb6,X2,Z9), (Ra12,Rb6,X2,Z10),(Ra12,Rb6,X2,Z11), (Ra12,Rb6,X2,Z12), (Ra12,Rb6,X2,Z13),(Ra12,Rb6,X2,Z14), (Ra12,Rb6,X2,Z15), (Ra12,Rb6,X2,Z16),(Ra12,Rb6,X2,Z17), (Ra12,Rb6,X2,Z18), (Ra12,Rb6,X2,Z19),(Ra12,Rb6,X2,Z20), (Ra12,Rb6,X2,Z21), (Ra12,Rb6,X2,Z22),(Ra12,Rb6,X2,Z23), (Ra12,Rb6,X2,Z24), (Ra12,Rb6,X2,Z25),(Ra12,Rb6,X2,Z26), (Ra12,Rb6,X2,Z27), (Ra12,Rb6,X2,Z28),(Ra12,Rb6,X2,Z29), (Ra12,Rb6,X2,Z30), (Ra12,Rb6,X2,Z31),(Ra12,Rb6,X2,Z32), (Ra12,Rb6,X2,Z33), (Ra12,Rb6,X2,Z34),(Ra12,Rb6,X2,Z35), (Ra12,Rb6,X2,Z36), (Ra12,Rb6,X2,Z37),(Ra12,Rb6,X2,Z38), (Ra12,Rb6,X2,Z39), (Ra12,Rb7,X1,Z1),(Ra12,Rb7,X1,Z2), (Ra12,Rb7,X1,Z3), (Ra12,Rb7,X1,Z4), (Ra12,Rb7,X1,Z5),(Ra12,Rb7,X1,Z6), (Ra12,Rb7,X1,Z7), (Ra12,Rb7,X1,Z8), (Ra12,Rb7,X1,Z9),(Ra12,Rb7,X1,Z10), (Ra12,Rb7,X1,Z11), (Ra12,Rb7,X1,Z12),(Ra12,Rb7,X1,Z13), (Ra12,Rb7,X1,Z14), (Ra12,Rb7,X1,Z15),(Ra12,Rb7,X1,Z16), (Ra12,Rb7,X1,Z17), (Ra12,Rb7,X1,Z18),(Ra12,Rb7,X1,Z19), (Ra12,Rb7,X1,Z20), (Ra12,Rb7,X1,Z21),(Ra12,Rb7,X1,Z22), (Ra12,Rb7,X1,Z23), (Ra12,Rb7,X1,Z24),(Ra12,Rb7,X1,Z25), (Ra12,Rb7,X1,Z26), (Ra12,Rb7,X1,Z27),(Ra12,Rb7,X1,Z28), (Ra12,Rb7,X1,Z29), (Ra12,Rb7,X1,Z30),(Ra12,Rb7,X1,Z31), (Ra12,Rb7,X1,Z32), (Ra12,Rb7,X1,Z33),(Ra12,Rb7,X1,Z34), (Ra12,Rb7,X1,Z35), (Ra12,Rb7,X1,Z36),(Ra12,Rb7,X1,Z37), (Ra12,Rb7,X1,Z38), (Ra12,Rb7,X1,Z39),(Ra12,Rb7,X2,Z1), (Ra12,Rb7,X2,Z2), (Ra12,Rb7,X2,Z3), (Ra12,Rb7,X2,Z4),(Ra12,Rb7,X2,Z5), (Ra12,Rb7,X2,Z6), (Ra12,Rb7,X2,Z7), (Ra12,Rb7,X2,Z8),(Ra12,Rb7,X2,Z9), (Ra12,Rb7,X2,Z10), (Ra12,Rb7,X2,Z11),(Ra12,Rb7,X2,Z12), (Ra12,Rb7,X2,Z13), (Ra12,Rb7,X2,Z14),(Ra12,Rb7,X2,Z15), (Ra12,Rb7,X2,Z16), (Ra12,Rb7,X2,Z17),(Ra12,Rb7,X2,Z18), (Ra12,Rb7,X2,Z19), (Ra12,Rb7,X2,Z20),(Ra12,Rb7,X2,Z21), (Ra12,Rb7,X2,Z22), (Ra12,Rb7,X2,Z23),(Ra12,Rb7,X2,Z24), (Ra12,Rb7,X2,Z25), (Ra12,Rb7,X2,Z26),(Ra12,Rb7,X2,Z27), (Ra12,Rb7,X2,Z28), (Ra12,Rb7,X2,Z29),(Ra12,Rb7,X2,Z30), (Ra12,Rb7,X2,Z31), (Ra12,Rb7,X2,Z32),(Ra12,Rb7,X2,Z33), (Ra12,Rb7,X2,Z34), (Ra12,Rb7,X2,Z35),(Ra12,Rb7,X2,Z36), (Ra12,Rb7,X2,Z37), (Ra12,Rb7,X2,Z38),(Ra12,Rb7,X2,Z39), (Ra12,Rb8,X1,Z1), (Ra12,Rb8,X1,Z2), (Ra12,Rb8,X1,Z3),(Ra12,Rb8,X1,Z4), (Ra12,Rb8,X1,Z5), (Ra12,Rb8,X1,Z6), (Ra12,Rb8,X1,Z7),(Ra12,Rb8,X1,Z8), (Ra12,Rb8,X1,Z9), (Ra12,Rb8,X1,Z10),(Ra12,Rb8,X1,Z11), (Ra12,Rb8,X1,Z12), (Ra12,Rb8,X1,Z13),(Ra12,Rb8,X1,Z14), (Ra12,Rb8,X1,Z15), (Ra12,Rb8,X1,Z16),(Ra12,Rb8,X1,Z17), (Ra12,Rb8,X1,Z18), (Ra12,Rb8,X1,Z19),(Ra12,Rb8,X1,Z20), (Ra12,Rb8,X1,Z21), (Ra12,Rb8,X1,Z22),(Ra12,Rb8,X1,Z23), (Ra12,Rb8,X1,Z24), (Ra12,Rb8,X1,Z25),(Ra12,Rb8,X1,Z26), (Ra12,Rb8,X1,Z27), (Ra12,Rb8,X1,Z28),(Ra12,Rb8,X1,Z29), (Ra12,Rb8,X1,Z30), (Ra12,Rb8,X1,Z31),(Ra12,Rb8,X1,Z32), (Ra12,Rb8,X1,Z33), (Ra12,Rb8,X1,Z34),(Ra12,Rb8,X1,Z35), (Ra12,Rb8,X1,Z36), (Ra12,Rb8,X1,Z37),(Ra12,Rb8,X1,Z38), (Ra12,Rb8,X1,Z39), (Ra12,Rb8,X2,Z1),(Ra12,Rb8,X2,Z2), (Ra12,Rb8,X2,Z3), (Ra12,Rb8,X2,Z4), (Ra12,Rb8,X2,Z5),(Ra12,Rb8,X2,Z6), (Ra12,Rb8,X2,Z7), (Ra12,Rb8,X2,Z8), (Ra12,Rb8,X2,Z9),(Ra12,Rb8,X2,Z10), (Ra12,Rb8,X2,Z11), (Ra12,Rb8,X2,Z12),(Ra12,Rb8,X2,Z13), (Ra12,Rb8,X2,Z14), (Ra12,Rb8,X2,Z15),(Ra12,Rb8,X2,Z16), (Ra12,Rb8,X2,Z17), (Ra12,Rb8,X2,Z18),(Ra12,Rb8,X2,Z19), (Ra12,Rb8,X2,Z20), (Ra12,Rb8,X2,Z21),(Ra12,Rb8,X2,Z22), (Ra12,Rb8,X2,Z23), (Ra12,Rb8,X2,Z24),(Ra12,Rb8,X2,Z25), (Ra12,Rb8,X2,Z26), (Ra12,Rb8,X2,Z27),(Ra12,Rb8,X2,Z28), (Ra12,Rb8,X2,Z29), (Ra12,Rb8,X2,Z30),(Ra12,Rb8,X2,Z31), (Ra12,Rb8,X2,Z32), (Ra12,Rb8,X2,Z33),(Ra12,Rb8,X2,Z34), (Ra12,Rb8,X2,Z35), (Ra12,Rb8,X2,Z36),(Ra12,Rb8,X2,Z37), (Ra12,Rb8,X2,Z38), (Ra12,Rb8,X2,Z39),(Ra13,Rb1,X1,Z1), (Ra13,Rb1,X1,Z2), (Ra13,Rb1,X1,Z3), (Ra13,Rb1,X1,Z4),(Ra13,Rb1,X1,Z5), (Ra13,Rb1,X1,Z6), (Ra13,Rb1,X1,Z7), (Ra13,Rb1,X1,Z8),(Ra13,Rb1,X1,Z9), (Ra13,Rb1,X1,Z10), (Ra13,Rb1,X1,Z11),(Ra13,Rb1,X1,Z12), (Ra13,Rb1,X1,Z13), (Ra13,Rb1,X1,Z14),(Ra13,Rb1,X1,Z15), (Ra13,Rb1,X1,Z16), (Ra13,Rb1,X1,Z17),(Ra13,Rb1,X1,Z18), (Ra13,Rb1,X1,Z19), (Ra13,Rb1,X1,Z20),(Ra13,Rb1,X1,Z21), (Ra13,Rb1,X1,Z22), (Ra13,Rb1,X1,Z23),(Ra13,Rb1,X1,Z24), (Ra13,Rb1,X1,Z25), (Ra13,Rb1,X1,Z26),(Ra13,Rb1,X1,Z27), (Ra13,Rb1,X1,Z28), (Ra13,Rb1,X1,Z29),(Ra13,Rb1,X1,Z30), (Ra13,Rb1,X1,Z31), (Ra13,Rb1,X1,Z32),(Ra13,Rb1,X1,Z33), (Ra13,Rb1,X1,Z34), (Ra13,Rb1,X1,Z35),(Ra13,Rb1,X1,Z36), (Ra13,Rb1,X1,Z37), (Ra13,Rb1,X1,Z38),(Ra13,Rb1,X1,Z39), (Ra13,Rb1,X2,Z1), (Ra13,Rb1,X2,Z2), (Ra13,Rb1,X2,Z3),(Ra13,Rb1,X2,Z4), (Ra13,Rb1,X2,Z5), (Ra13,Rb1,X2,Z6), (Ra13,Rb1,X2,Z7),(Ra13,Rb1,X2,Z8), (Ra13,Rb1,X2,Z9), (Ra13,Rb1,X2,Z10),(Ra13,Rb1,X2,Z11), (Ra13,Rb1,X2,Z12), (Ra13,Rb1,X2,Z13),(Ra13,Rb1,X2,Z14), (Ra13,Rb1,X2,Z15), (Ra13,Rb1,X2,Z16),(Ra13,Rb1,X2,Z17), (Ra13,Rb1,X2,Z18), (Ra13,Rb1,X2,Z19),(Ra13,Rb1,X2,Z20), (Ra13,Rb1,X2,Z21), (Ra13,Rb1,X2,Z22),(Ra13,Rb1,X2,Z23), (Ra13,Rb1,X2,Z24), (Ra13,Rb1,X2,Z25),(Ra13,Rb1,X2,Z26), (Ra13,Rb1,X2,Z27), (Ra13,Rb1,X2,Z28),(Ra13,Rb1,X2,Z29), (Ra13,Rb1,X2,Z30), (Ra13,Rb1,X2,Z31),(Ra13,Rb1,X2,Z32), (Ra13,Rb1,X2,Z33), (Ra13,Rb1,X2,Z34),(Ra13,Rb1,X2,Z35), (Ra13,Rb1,X2,Z36), (Ra13,Rb1,X2,Z37),(Ra13,Rb1,X2,Z38), (Ra13,Rb1,X2,Z39), (Ra13,Rb2,X1,Z1),(Ra13,Rb2,X1,Z2), (Ra13,Rb2,X1,Z3), (Ra13,Rb2,X1,Z4), (Ra13,Rb2,X1,Z5),(Ra13,Rb2,X1,Z6), (Ra13,Rb2,X1,Z7), (Ra13,Rb2,X1,Z8), (Ra13,Rb2,X1,Z9),(Ra13,Rb2,X1,Z10), (Ra13,Rb2,X1,Z11), (Ra13,Rb2,X1,Z12),(Ra13,Rb2,X1,Z13), (Ra13,Rb2,X1,Z14), (Ra13,Rb2,X1,Z15),(Ra13,Rb2,X1,Z16), (Ra13,Rb2,X1,Z17), (Ra13,Rb2,X1,Z18),(Ra13,Rb2,X1,Z19), (Ra13,Rb2,X1,Z20), (Ra13,Rb2,X1,Z21),(Ra13,Rb2,X1,Z22), (Ra13,Rb2,X1,Z23), (Ra13,Rb2,X1,Z24),(Ra13,Rb2,X1,Z25), (Ra13,Rb2,X1,Z26), (Ra13,Rb2,X1,Z27),(Ra13,Rb2,X1,Z28), (Ra13,Rb2,X1,Z29), (Ra13,Rb2,X1,Z30),(Ra13,Rb2,X1,Z31), (Ra13,Rb2,X1,Z32), (Ra13,Rb2,X1,Z33),(Ra13,Rb2,X1,Z34), (Ra13,Rb2,X1,Z35), (Ra13,Rb2,X1,Z36),(Ra13,Rb2,X1,Z37), (Ra13,Rb2,X1,Z38), (Ra13,Rb2,X1,Z39),(Ra13,Rb2,X2,Z1), (Ra13,Rb2,X2,Z2), (Ra13,Rb2,X2,Z3), (Ra13,Rb2,X2,Z4),(Ra13,Rb2,X2,Z5), (Ra13,Rb2,X2,Z6), (Ra13,Rb2,X2,Z7), (Ra13,Rb2,X2,Z8),(Ra13,Rb2,X2,Z9), (Ra13,Rb2,X2,Z10), (Ra13,Rb2,X2,Z11),(Ra13,Rb2,X2,Z12), (Ra13,Rb2,X2,Z13), (Ra13,Rb2,X2,Z14),(Ra13,Rb2,X2,Z15), (Ra13,Rb2,X2,Z16), (Ra13,Rb2,X2,Z17),(Ra13,Rb2,X2,Z18), (Ra13,Rb2,X2,Z19), (Ra13,Rb2,X2,Z20),(Ra13,Rb2,X2,Z21), (Ra13,Rb2,X2,Z22), (Ra13,Rb2,X2,Z23),(Ra13,Rb2,X2,Z24), (Ra13,Rb2,X2,Z25), (Ra13,Rb2,X2,Z26),(Ra13,Rb2,X2,Z27), (Ra13,Rb2,X2,Z28), (Ra13,Rb2,X2,Z29),(Ra13,Rb2,X2,Z30), (Ra13,Rb2,X2,Z31), (Ra13,Rb2,X2,Z32),(Ra13,Rb2,X2,Z33), (Ra13,Rb2,X2,Z34), (Ra13,Rb2,X2,Z35),(Ra13,Rb2,X2,Z36), (Ra13,Rb2,X2,Z37), (Ra13,Rb2,X2,Z38),(Ra13,Rb2,X2,Z39), (Ra13,Rb3,X1,Z1), (Ra13,Rb3,X1,Z2), (Ra13,Rb3,X1,Z3),(Ra13,Rb3,X1,Z4), (Ra13,Rb3,X1,Z5), (Ra13,Rb3,X1,Z6), (Ra13,Rb3,X1,Z7),(Ra13,Rb3,X1,Z8), (Ra13,Rb3,X1,Z9), (Ra13,Rb3,X1,Z10),(Ra13,Rb3,X1,Z11), (Ra13,Rb3,X1,Z12), (Ra13,Rb3,X1,Z13),(Ra13,Rb3,X1,Z14), (Ra13,Rb3,X1,Z15), (Ra13,Rb3,X1,Z16),(Ra13,Rb3,X1,Z17), (Ra13,Rb3,X1,Z18), (Ra13,Rb3,X1,Z19),(Ra13,Rb3,X1,Z20), (Ra13,Rb3,X1,Z21), (Ra13,Rb3,X1,Z22),(Ra13,Rb3,X1,Z23), (Ra13,Rb3,X1,Z24), (Ra13,Rb3,X1,Z25),(Ra13,Rb3,X1,Z26), (Ra13,Rb3,X1,Z27), (Ra13,Rb3,X1,Z28),(Ra13,Rb3,X1,Z29), (Ra13,Rb3,X1,Z30), (Ra13,Rb3,X1,Z31),(Ra13,Rb3,X1,Z32), (Ra13,Rb3,X1,Z33), (Ra13,Rb3,X1,Z34),(Ra13,Rb3,X1,Z35), (Ra13,Rb3,X1,Z36), (Ra13,Rb3,X1,Z37),(Ra13,Rb3,X1,Z38), (Ra13,Rb3,X1,Z39), (Ra13,Rb3,X2,Z1),(Ra13,Rb3,X2,Z2), (Ra13,Rb3,X2,Z3), (Ra13,Rb3,X2,Z4), (Ra13,Rb3,X2,Z5),(Ra13,Rb3,X2,Z6), (Ra13,Rb3,X2,Z7), (Ra13,Rb3,X2,Z8), (Ra13,Rb3,X2,Z9),(Ra13,Rb3,X2,Z10), (Ra13,Rb3,X2,Z11), (Ra13,Rb3,X2,Z12),(Ra13,Rb3,X2,Z13), (Ra13,Rb3,X2,Z14), (Ra13,Rb3,X2,Z15),(Ra13,Rb3,X2,Z16), (Ra13,Rb3,X2,Z17), (Ra13,Rb3,X2,Z18),(Ra13,Rb3,X2,Z19), (Ra13,Rb3,X2,Z20), (Ra13,Rb3,X2,Z21),(Ra13,Rb3,X2,Z22), (Ra13,Rb3,X2,Z23), (Ra13,Rb3,X2,Z24),(Ra13,Rb3,X2,Z25), (Ra13,Rb3,X2,Z26), (Ra13,Rb3,X2,Z27),(Ra13,Rb3,X2,Z28), (Ra13,Rb3,X2,Z29), (Ra13,Rb3,X2,Z30),(Ra13,Rb3,X2,Z31), (Ra13,Rb3,X2,Z32), (Ra13,Rb3,X2,Z33),(Ra13,Rb3,X2,Z34), (Ra13,Rb3,X2,Z35), (Ra13,Rb3,X2,Z36),(Ra13,Rb3,X2,Z37), (Ra13,Rb3,X2,Z38), (Ra13,Rb3,X2,Z39),(Ra13,Rb4,X1,Z1), (Ra13,Rb4,X1,Z2), (Ra13,Rb4,X1,Z3), (Ra13,Rb4,X1,Z4),(Ra13,Rb4,X1,Z5), (Ra13,Rb4,X1,Z6), (Ra13,Rb4,X1,Z7), (Ra13,Rb4,X1,Z8),(Ra13,Rb4,X1,Z9), (Ra13,Rb4,X1,Z10), (Ra13,Rb4,X1,Z11),(Ra13,Rb4,X1,Z12), (Ra13,Rb4,X1,Z13), (Ra13,Rb4,X1,Z14),(Ra13,Rb4,X1,Z15), (Ra13,Rb4,X1,Z16), (Ra13,Rb4,X1,Z17),(Ra13,Rb4,X1,Z18), (Ra13,Rb4,X1,Z19), (Ra13,Rb4,X1,Z20),(Ra13,Rb4,X1,Z21), (Ra13,Rb4,X1,Z22), (Ra13,Rb4,X1,Z23),(Ra13,Rb4,X1,Z24), (Ra13,Rb4,X1,Z25), (Ra13,Rb4,X1,Z26),(Ra13,Rb4,X1,Z27), (Ra13,Rb4,X1,Z28), (Ra13,Rb4,X1,Z29),(Ra13,Rb4,X1,Z30), (Ra13,Rb4,X1,Z31), (Ra13,Rb4,X1,Z32),(Ra13,Rb4,X1,Z33), (Ra13,Rb4,X1,Z34), (Ra13,Rb4,X1,Z35),(Ra13,Rb4,X1,Z36), (Ra13,Rb4,X1,Z37), (Ra13,Rb4,X1,Z38),(Ra13,Rb4,X1,Z39), (Ra13,Rb4,X2,Z1), (Ra13,Rb4,X2,Z2), (Ra13,Rb4,X2,Z3),(Ra13,Rb4,X2,Z4), (Ra13,Rb4,X2,Z5), (Ra13,Rb4,X2,Z6), (Ra13,Rb4,X2,Z7),(Ra13,Rb4,X2,Z8), (Ra13,Rb4,X2,Z9), (Ra13,Rb4,X2,Z10),(Ra13,Rb4,X2,Z11), (Ra13,Rb4,X2,Z12), (Ra13,Rb4,X2,Z13),(Ra13,Rb4,X2,Z14), (Ra13,Rb4,X2,Z15), (Ra13,Rb4,X2,Z16),(Ra13,Rb4,X2,Z17), (Ra13,Rb4,X2,Z18), (Ra13,Rb4,X2,Z19),(Ra13,Rb4,X2,Z20), (Ra13,Rb4,X2,Z21), (Ra13,Rb4,X2,Z22),(Ra13,Rb4,X2,Z23), (Ra13,Rb4,X2,Z24), (Ra13,Rb4,X2,Z25),(Ra13,Rb4,X2,Z26), (Ra13,Rb4,X2,Z27), (Ra13,Rb4,X2,Z28),(Ra13,Rb4,X2,Z29), (Ra13,Rb4,X2,Z30), (Ra13,Rb4,X2,Z31),(Ra13,Rb4,X2,Z32), (Ra13,Rb4,X2,Z33), (Ra13,Rb4,X2,Z34),(Ra13,Rb4,X2,Z35), (Ra13,Rb4,X2,Z36), (Ra13,Rb4,X2,Z37),(Ra13,Rb4,X2,Z38), (Ra13,Rb4,X2,Z39), (Ra13,Rb5,X1,Z1),(Ra13,Rb5,X1,Z2), (Ra13,Rb5,X1,Z3), (Ra13,Rb5,X1,Z4), (Ra13,Rb5,X1,Z5),(Ra13,Rb5,X1,Z6), (Ra13,Rb5,X1,Z7), (Ra13,Rb5,X1,Z8), (Ra13,Rb5,X1,Z9),(Ra13,Rb5,X1,Z10), (Ra13,Rb5,X1,Z11), (Ra13,Rb5,X1,Z12),(Ra13,Rb5,X1,Z13), (Ra13,Rb5,X1,Z14), (Ra13,Rb5,X1,Z15),(Ra13,Rb5,X1,Z16), (Ra13,Rb5,X1,Z17), (Ra13,Rb5,X1,Z18),(Ra13,Rb5,X1,Z19), (Ra13,Rb5,X1,Z20), (Ra13,Rb5,X1,Z21),(Ra13,Rb5,X1,Z22), (Ra13,Rb5,X1,Z23), (Ra13,Rb5,X1,Z24),(Ra13,Rb5,X1,Z25), (Ra13,Rb5,X1,Z26), (Ra13,Rb5,X1,Z27),(Ra13,Rb5,X1,Z28), (Ra13,Rb5,X1,Z29), (Ra13,Rb5,X1,Z30),(Ra13,Rb5,X1,Z31), (Ra13,Rb5,X1,Z32), (Ra13,Rb5,X1,Z33),(Ra13,Rb5,X1,Z34), (Ra13,Rb5,X1,Z35), (Ra13,Rb5,X1,Z36),(Ra13,Rb5,X1,Z37), (Ra13,Rb5,X1,Z38), (Ra13,Rb5,X1,Z39),(Ra13,Rb5,X2,Z1), (Ra13,Rb5,X2,Z2), (Ra13,Rb5,X2,Z3), (Ra13,Rb5,X2,Z4),(Ra13,Rb5,X2,Z5), (Ra13,Rb5,X2,Z6), (Ra13,Rb5,X2,Z7), (Ra13,Rb5,X2,Z8),(Ra13,Rb5,X2,Z9), (Ra13,Rb5,X2,Z10), (Ra13,Rb5,X2,Z11),(Ra13,Rb5,X2,Z12), (Ra13,Rb5,X2,Z13), (Ra13,Rb5,X2,Z14),(Ra13,Rb5,X2,Z15), (Ra13,Rb5,X2,Z16), (Ra13,Rb5,X2,Z17),(Ra13,Rb5,X2,Z18), (Ra13,Rb5,X2,Z19), (Ra13,Rb5,X2,Z20),(Ra13,Rb5,X2,Z21), (Ra13,Rb5,X2,Z22), (Ra13,Rb5,X2,Z23),(Ra13,Rb5,X2,Z24), (Ra13,Rb5,X2,Z25), (Ra13,Rb5,X2,Z26),(Ra13,Rb5,X2,Z27), (Ra13,Rb5,X2,Z28), (Ra13,Rb5,X2,Z29),(Ra13,Rb5,X2,Z30), (Ra13,Rb5,X2,Z31), (Ra13,Rb5,X2,Z32),(Ra13,Rb5,X2,Z33), (Ra13,Rb5,X2,Z34), (Ra13,Rb5,X2,Z35),(Ra13,Rb5,X2,Z36), (Ra13,Rb5,X2,Z37), (Ra13,Rb5,X2,Z38),(Ra13,Rb5,X2,Z39), (Ra13,Rb6,X1,Z1), (Ra13,Rb6,X1,Z2), (Ra13,Rb6,X1,Z3),(Ra13,Rb6,X1,Z4), (Ra13,Rb6,X1,Z5), (Ra13,Rb6,X1,Z6), (Ra13,Rb6,X1,Z7),(Ra13,Rb6,X1,Z8), (Ra13,Rb6,X1,Z9), (Ra13,Rb6,X1,Z10),(Ra13,Rb6,X1,Z11), (Ra13,Rb6,X1,Z12), (Ra13,Rb6,X1,Z13),(Ra13,Rb6,X1,Z14), (Ra13,Rb6,X1,Z15), (Ra13,Rb6,X1,Z16),(Ra13,Rb6,X1,Z17), (Ra13,Rb6,X1,Z18), (Ra13,Rb6,X1,Z19),(Ra13,Rb6,X1,Z20), (Ra13,Rb6,X1,Z21), (Ra13,Rb6,X1,Z22),(Ra13,Rb6,X1,Z23), (Ra13,Rb6,X1,Z24), (Ra13,Rb6,X1,Z25),(Ra13,Rb6,X1,Z26), (Ra13,Rb6,X1,Z27), (Ra13,Rb6,X1,Z28),(Ra13,Rb6,X1,Z29), (Ra13,Rb6,X1,Z30), (Ra13,Rb6,X1,Z31),(Ra13,Rb6,X1,Z32), (Ra13,Rb6,X1,Z33), (Ra13,Rb6,X1,Z34),(Ra13,Rb6,X1,Z35), (Ra13,Rb6,X1,Z36), (Ra13,Rb6,X1,Z37),(Ra13,Rb6,X1,Z38), (Ra13,Rb6,X1,Z39), (Ra13,Rb6,X2,Z1),(Ra13,Rb6,X2,Z2), (Ra13,Rb6,X2,Z3), (Ra13,Rb6,X2,Z4), (Ra13,Rb6,X2,Z5),(Ra13,Rb6,X2,Z6), (Ra13,Rb6,X2,Z7), (Ra13,Rb6,X2,Z8), (Ra13,Rb6,X2,Z9),(Ra13,Rb6,X2,Z10), (Ra13,Rb6,X2,Z11), (Ra13,Rb6,X2,Z12),(Ra13,Rb6,X2,Z13), (Ra13,Rb6,X2,Z14), (Ra13,Rb6,X2,Z15),(Ra13,Rb6,X2,Z16), (Ra13,Rb6,X2,Z17), (Ra13,Rb6,X2,Z18),(Ra13,Rb6,X2,Z19), (Ra13,Rb6,X2,Z20), (Ra13,Rb6,X2,Z21),(Ra13,Rb6,X2,Z22), (Ra13,Rb6,X2,Z23), (Ra13,Rb6,X2,Z24),(Ra13,Rb6,X2,Z25), (Ra13,Rb6,X2,Z26), (Ra13,Rb6,X2,Z27),(Ra13,Rb6,X2,Z28), (Ra13,Rb6,X2,Z29), (Ra13,Rb6,X2,Z30),(Ra13,Rb6,X2,Z31), (Ra13,Rb6,X2,Z32), (Ra13,Rb6,X2,Z33),(Ra13,Rb6,X2,Z34), (Ra13,Rb6,X2,Z35), (Ra13,Rb6,X2,Z36),(Ra13,Rb6,X2,Z37), (Ra13,Rb6,X2,Z38), (Ra13,Rb6,X2,Z39),(Ra13,Rb7,X1,Z1), (Ra13,Rb7,X1,Z2), (Ra13,Rb7,X1,Z3), (Ra13,Rb7,X1,Z4),(Ra13,Rb7,X1,Z5), (Ra13,Rb7,X1,Z6), (Ra13,Rb7,X1,Z7), (Ra13,Rb7,X1,Z8),(Ra13,Rb7,X1,Z9), (Ra13,Rb7,X1,Z10), (Ra13,Rb7,X1,Z11),(Ra13,Rb7,X1,Z12), (Ra13,Rb7,X1,Z13), (Ra13,Rb7,X1,Z14),(Ra13,Rb7,X1,Z15), (Ra13,Rb7,X1,Z16), (Ra13,Rb7,X1,Z17),(Ra13,Rb7,X1,Z18), (Ra13,Rb7,X1,Z19), (Ra13,Rb7,X1,Z20),(Ra13,Rb7,X1,Z21), (Ra13,Rb7,X1,Z22), (Ra13,Rb7,X1,Z23),(Ra13,Rb7,X1,Z24), (Ra13,Rb7,X1,Z25), (Ra13,Rb7,X1,Z26),(Ra13,Rb7,X1,Z27), (Ra13,Rb7,X1,Z28), (Ra13,Rb7,X1,Z29),(Ra13,Rb7,X1,Z30), (Ra13,Rb7,X1,Z31), (Ra13,Rb7,X1,Z32),(Ra13,Rb7,X1,Z33), (Ra13,Rb7,X1,Z34), (Ra13,Rb7,X1,Z35),(Ra13,Rb7,X1,Z36), (Ra13,Rb7,X1,Z37), (Ra13,Rb7,X1,Z38),(Ra13,Rb7,X1,Z39), (Ra13,Rb7,X2,Z1), (Ra13,Rb7,X2,Z2), (Ra13,Rb7,X2,Z3),(Ra13,Rb7,X2,Z4), (Ra13,Rb7,X2,Z5), (Ra13,Rb7,X2,Z6), (Ra13,Rb7,X2,Z7),(Ra13,Rb7,X2,Z8), (Ra13,Rb7,X2,Z9), (Ra13,Rb7,X2,Z10),(Ra13,Rb7,X2,Z11), (Ra13,Rb7,X2,Z12), (Ra13,Rb7,X2,Z13),(Ra13,Rb7,X2,Z14), (Ra13,Rb7,X2,Z15), (Ra13,Rb7,X2,Z16),(Ra13,Rb7,X2,Z17), (Ra13,Rb7,X2,Z18), (Ra13,Rb7,X2,Z19),(Ra13,Rb7,X2,Z20), (Ra13,Rb7,X2,Z21), (Ra13,Rb7,X2,Z22),(Ra13,Rb7,X2,Z23), (Ra13,Rb7,X2,Z24), (Ra13,Rb7,X2,Z25),(Ra13,Rb7,X2,Z26), (Ra13,Rb7,X2,Z27), (Ra13,Rb7,X2,Z28),(Ra13,Rb7,X2,Z29), (Ra13,Rb7,X2,Z30), (Ra13,Rb7,X2,Z31),(Ra13,Rb7,X2,Z32), (Ra13,Rb7,X2,Z33), (Ra13,Rb7,X2,Z34),(Ra13,Rb7,X2,Z35), (Ra13,Rb7,X2,Z36), (Ra13,Rb7,X2,Z37),(Ra13,Rb7,X2,Z38), (Ra13,Rb7,X2,Z39), (Ra13,Rb8,X1,Z1),(Ra13,Rb8,X1,Z2), (Ra13,Rb8,X1,Z3), (Ra13,Rb8,X1,Z4), (Ra13,Rb8,X1,Z5),(Ra13,Rb8,X1,Z6), (Ra13,Rb8,X1,Z7), (Ra13,Rb8,X1,Z8), (Ra13,Rb8,X1,Z9),(Ra13,Rb8,X1,Z10), (Ra13,Rb8,X1,Z11), (Ra13,Rb8,X1,Z12),(Ra13,Rb8,X1,Z13), (Ra13,Rb8,X1,Z14), (Ra13,Rb8,X1,Z15), (Ra13,Rb8,X1,Z(Ra13,Rb8,X1,Z17), (Ra13,Rb8,X1,Z18), (Ra13,Rb8,X1,Z19),(Ra13,Rb8,X1,Z20), (Ra13,Rb8,X1,Z21), (Ra13,Rb8,X1,Z22),(Ra13,Rb8,X1,Z23), (Ra13,Rb8,X1,Z24), (Ra13,Rb8,X1,Z25),(Ra13,Rb8,X1,Z26), (Ra13,Rb8,X1,Z27), (Ra13,Rb8,X1,Z28),(Ra13,Rb8,X1,Z29), (Ra13,Rb8,X1,Z30), (Ra13,Rb8,X1,Z31),(Ra13,Rb8,X1,Z32), (Ra13,Rb8,X1,Z33), (Ra13,Rb8,X1,Z34),(Ra13,Rb8,X1,Z35), (Ra13,Rb8,X1,Z36), (Ra13,Rb8,X1,Z37),(Ra13,Rb8,X1,Z38), (Ra13,Rb8,X1,Z39), (Ra13,Rb8,X2,Z1),(Ra13,Rb8,X2,Z2), (Ra13,Rb8,X2,Z3), (Ra13,Rb8,X2,Z4), (Ra13,Rb8,X2,Z5),(Ra13,Rb8,X2,Z6), (Ra13,Rb8,X2,Z7), (Ra13,Rb8,X2,Z8), (Ra13,Rb8,X2,Z9),(Ra13,Rb8,X2,Z10), (Ra13,Rb8,X2,Z11), (Ra13,Rb8,X2,Z12),(Ra13,Rb8,X2,Z13), (Ra13,Rb8,X2,Z14), (Ra13,Rb8,X2,Z15),(Ra13,Rb8,X2,Z16), (Ra13,Rb8,X2,Z17), (Ra13,Rb8,X2,Z18),(Ra13,Rb8,X2,Z19), (Ra13,Rb8,X2,Z20), (Ra13,Rb8,X2,Z21),(Ra13,Rb8,X2,Z22), (Ra13,Rb8,X2,Z23), (Ra13,Rb8,X2,Z24),(Ra13,Rb8,X2,Z25), (Ra13,Rb8,X2,Z26), (Ra13,Rb8,X2,Z27),(Ra13,Rb8,X2,Z28), (Ra13,Rb8,X2,Z29), (Ra13,Rb8,X2,Z30),(Ra13,Rb8,X2,Z31), (Ra13,Rb8,X2,Z32), (Ra13,Rb8,X2,Z33),(Ra13,Rb8,X2,Z34), (Ra13,Rb8,X2,Z35), (Ra13,Rb8,X2,Z36),(Ra13,Rb8,X2,Z37), (Ra13,Rb8,X2,Z38), (Ra13,Rb8,X2,Z39),(Ra14,Rb1,X1,Z1), (Ra14,Rb1,X1,Z2), (Ra14,Rb1,X1,Z3), (Ra14,Rb1,X1,Z4),(Ra14,Rb1,X1,Z5), (Ra14,Rb1,X1,Z6), (Ra14,Rb1,X1,Z7), (Ra14,Rb1,X1,Z8),(Ra14,Rb1,X1,Z9), (Ra14,Rb1,X1,Z10), (Ra14,Rb1,X1,Z11),(Ra14,Rb1,X1,Z12), (Ra14,Rb1,X1,Z13), (Ra14,Rb1,X1,Z14),(Ra14,Rb1,X1,Z15), (Ra14,Rb1,X1,Z16), (Ra14,Rb1,X1,Z17),(Ra14,Rb1,X1,Z18), (Ra14,Rb1,X1,Z19), (Ra14,Rb1,X1,Z20),(Ra14,Rb1,X1,Z21), (Ra14,Rb1,X1,Z22), (Ra14,Rb1,X1,Z23),(Ra14,Rb1,X1,Z24), (Ra14,Rb1,X1,Z25), (Ra14,Rb1,X1,Z26),(Ra14,Rb1,X1,Z27), (Ra14,Rb1,X1,Z28), (Ra14,Rb1,X1,Z29),(Ra14,Rb1,X1,Z30), (Ra14,Rb1,X1,Z31), (Ra14,Rb1,X1,Z32),(Ra14,Rb1,X1,Z33), (Ra14,Rb1,X1,Z34), (Ra14,Rb1,X1,Z35),(Ra14,Rb1,X1,Z36), (Ra14,Rb1,X1,Z37), (Ra14,Rb1,X1,Z38),(Ra14,Rb1,X1,Z39), (Ra14,Rb1,X2,Z1), (Ra14,Rb1,X2,Z2), (Ra14,Rb1,X2,Z3),(Ra14,Rb1,X2,Z4), (Ra14,Rb1,X2,Z5), (Ra14,Rb1,X2,Z6), (Ra14,Rb1,X2,Z7),(Ra14,Rb1,X2,Z8), (Ra14,Rb1,X2,Z9), (Ra14,Rb1,X2,Z10),(Ra14,Rb1,X2,Z11), (Ra14,Rb1,X2,Z12), (Ra14,Rb1,X2,Z13),(Ra14,Rb1,X2,Z14), (Ra14,Rb1,X2,Z15), (Ra14,Rb1,X2,Z16),(Ra14,Rb1,X2,Z17), (Ra14,Rb1,X2,Z18), (Ra14,Rb1,X2,Z19),(Ra14,Rb1,X2,Z20), (Ra14,Rb1,X2,Z21), (Ra14,Rb1,X2,Z22),(Ra14,Rb1,X2,Z23), (Ra14,Rb1,X2,Z24), (Ra14,Rb1,X2,Z25),(Ra14,Rb1,X2,Z26), (Ra14,Rb1,X2,Z27), (Ra14,Rb1,X2,Z28),(Ra14,Rb1,X2,Z29), (Ra14,Rb1,X2,Z30), (Ra14,Rb1,X2,Z31),(Ra14,Rb1,X2,Z32), (Ra14,Rb1,X2,Z33), (Ra14,Rb1,X2,Z34),(Ra14,Rb1,X2,Z35), (Ra14,Rb1,X2,Z36), (Ra14,Rb1,X2,Z37),(Ra14,Rb1,X2,Z38), (Ra14,Rb1,X2,Z39), (Ra14,Rb2,X1,Z1),(Ra14,Rb2,X1,Z2), (Ra14,Rb2,X1,Z3), (Ra14,Rb2,X1,Z4), (Ra14,Rb2,X1,Z5),(Ra14,Rb2,X1,Z6), (Ra14,Rb2,X1,Z7), (Ra14,Rb2,X1,Z8), (Ra14,Rb2,X1,Z9),(Ra14,Rb2,X1,Z10), (Ra14,Rb2,X1,Z11), (Ra14,Rb2,X1,Z12),(Ra14,Rb2,X1,Z13), (Ra14,Rb2,X1,Z14), (Ra14,Rb2,X1,Z15),(Ra14,Rb2,X1,Z16), (Ra14,Rb2,X1,Z17), (Ra14,Rb2,X1,Z18),(Ra14,Rb2,X1,Z19), (Ra14,Rb2,X1,Z20), (Ra14,Rb2,X1,Z21),(Ra14,Rb2,X1,Z22), (Ra14,Rb2,X1,Z23), (Ra14,Rb2,X1,Z24),(Ra14,Rb2,X1,Z25), (Ra14,Rb2,X1,Z26), (Ra14,Rb2,X1,Z27),(Ra14,Rb2,X1,Z28), (Ra14,Rb2,X1,Z29), (Ra14,Rb2,X1,Z30),(Ra14,Rb2,X1,Z31), (Ra14,Rb2,X1,Z32), (Ra14,Rb2,X1,Z33),(Ra14,Rb2,X1,Z34), (Ra14,Rb2,X1,Z35), (Ra14,Rb2,X1,Z36),(Ra14,Rb2,X1,Z37), (Ra14,Rb2,X1,Z38), (Ra14,Rb2,X1,Z39),(Ra14,Rb2,X2,Z1), (Ra14,Rb2,X2,Z2), (Ra14,Rb2,X2,Z3), (Ra14,Rb2,X2,Z4),(Ra14,Rb2,X2,Z5), (Ra14,Rb2,X2,Z6), (Ra14,Rb2,X2,Z7), (Ra14,Rb2,X2,Z8),(Ra14,Rb2,X2,Z9), (Ra14,Rb2,X2,Z10), (Ra14,Rb2,X2,Z11),(Ra14,Rb2,X2,Z12), (Ra14,Rb2,X2,Z13), (Ra14,Rb2,X2,Z14),(Ra14,Rb2,X2,Z15), (Ra14,Rb2,X2,Z16), (Ra14,Rb2,X2,Z17),(Ra14,Rb2,X2,Z18), (Ra14,Rb2,X2,Z19), (Ra14,Rb2,X2,Z20),(Ra14,Rb2,X2,Z21), (Ra14,Rb2,X2,Z22), (Ra14,Rb2,X2,Z23),(Ra14,Rb2,X2,Z24), (Ra14,Rb2,X2,Z25), (Ra14,Rb2,X2,Z26),(Ra14,Rb2,X2,Z27), (Ra14,Rb2,X2,Z28), (Ra14,Rb2,X2,Z29),(Ra14,Rb2,X2,Z30), (Ra14,Rb2,X2,Z31), (Ra14,Rb2,X2,Z32),(Ra14,Rb2,X2,Z33), (Ra14,Rb2,X2,Z34), (Ra14,Rb2,X2,Z35),(Ra14,Rb2,X2,Z36), (Ra14,Rb2,X2,Z37), (Ra14,Rb2,X2,Z38),(Ra14,Rb2,X2,Z39), (Ra14,Rb3,X1,Z1), (Ra14,Rb3,X1,Z2), (Ra14,Rb3,X1,Z3),(Ra14,Rb3,X1,Z4), (Ra14,Rb3,X1,Z5), (Ra14,Rb3,X1,Z6), (Ra14,Rb3,X1,Z7),(Ra14,Rb3,X1,Z8), (Ra14,Rb3,X1,Z9), (Ra14,Rb3,X1,Z10),(Ra14,Rb3,X1,Z11), (Ra14,Rb3,X1,Z12), (Ra14,Rb3,X1,Z13),(Ra14,Rb3,X1,Z14), (Ra14,Rb3,X1,Z15), (Ra14,Rb3,X1, Z16),(Ra14,Rb3,X1,Z17), (Ra14,Rb3,X1,Z18), (Ra14,Rb3,X1,Z19),(Ra14,Rb3,X1,Z20), (Ra14,Rb3,X1,Z21), (Ra14,Rb3,X1,Z22),(Ra14,Rb3,X1,Z23), (Ra14,Rb3,X1,Z24), (Ra14,Rb3,X1,Z25),(Ra14,Rb3,X1,Z26), (Ra14,Rb3,X1,Z27), (Ra14,Rb3,X1,Z28),(Ra14,Rb3,X1,Z29), (Ra14,Rb3,X1,Z30), (Ra14,Rb3,X1,Z31),(Ra14,Rb3,X1,Z32), (Ra14,Rb3,X1,Z33), (Ra14,Rb3,X1,Z34),(Ra14,Rb3,X1,Z35), (Ra14,Rb3,X1,Z36), (Ra14,Rb3,X1,Z37),(Ra14,Rb3,X1,Z38), (Ra14,Rb3,X1,Z39), (Ra14,Rb3,X2,Z1),(Ra14,Rb3,X2,Z2), (Ra14,Rb3,X2,Z3), (Ra14,Rb3,X2,Z4), (Ra14,Rb3,X2,Z5),(Ra14,Rb3,X2,Z6), (Ra14,Rb3,X2,Z7), (Ra14,Rb3,X2,Z8), (Ra14,Rb3,X2,Z9),(Ra14,Rb3,X2,Z10), (Ra14,Rb3,X2,Z11), (Ra14,Rb3,X2,Z12),(Ra14,Rb3,X2,Z13), (Ra14,Rb3,X2,Z14), (Ra14,Rb3,X2,Z15),(Ra14,Rb3,X2,Z16), (Ra14,Rb3,X2,Z17), (Ra14,Rb3,X2,Z18),(Ra14,Rb3,X2,Z19), (Ra14,Rb3,X2,Z20), (Ra14,Rb3,X2,Z21),(Ra14,Rb3,X2,Z22), (Ra14,Rb3,X2,Z23), (Ra14,Rb3,X2,Z24),(Ra14,Rb3,X2,Z25), (Ra14,Rb3,X2,Z26), (Ra14,Rb3,X2,Z27),(Ra14,Rb3,X2,Z28), (Ra14,Rb3,X2,Z29), (Ra14,Rb3,X2,Z30),(Ra14,Rb3,X2,Z31), (Ra14,Rb3,X2,Z32), (Ra14,Rb3,X2,Z33),(Ra14,Rb3,X2,Z34), (Ra14,Rb3,X2,Z35), (Ra14,Rb3,X2,Z36),(Ra14,Rb3,X2,Z37), (Ra14,Rb3,X2,Z38), (Ra14,Rb3,X2,Z39),(Ra14,Rb4,X1,Z1), (Ra14,Rb4,X1,Z2), (Ra14,Rb4,X1,Z3), (Ra14,Rb4,X1,Z4),(Ra14,Rb4,X1,Z5), (Ra14,Rb4,X1,Z6), (Ra14,Rb4,X1,Z7), (Ra14,Rb4,X1,Z8),(Ra14,Rb4,X1,Z9), (Ra14,Rb4,X1,Z10), (Ra14,Rb4,X1,Z11),(Ra14,Rb4,X1,Z12), (Ra14,Rb4,X1,Z13), (Ra14,Rb4,X1,Z14),(Ra14,Rb4,X1,Z15), (Ra14,Rb4,X1,Z16), (Ra14,Rb4,X1,Z17),(Ra14,Rb4,X1,Z18), (Ra14,Rb4,X1,Z19), (Ra14,Rb4,X1,Z20),(Ra14,Rb4,X1,Z21), (Ra14,Rb4,X1,Z22), (Ra14,Rb4,X1,Z23),(Ra14,Rb4,X1,Z24), (Ra14,Rb4,X1,Z25), (Ra14,Rb4,X1,Z26),(Ra14,Rb4,X1,Z27), (Ra14,Rb4,X1,Z28), (Ra14,Rb4,X1,Z29),(Ra14,Rb4,X1,Z30), (Ra14,Rb4,X1,Z31), (Ra14,Rb4,X1,Z32),(Ra14,Rb4,X1,Z33), (Ra14,Rb4,X1,Z34), (Ra14,Rb4,X1,Z35),(Ra14,Rb4,X1,Z36), (Ra14,Rb4,X1,Z37), (Ra14,Rb4,X1,Z38),(Ra14,Rb4,X1,Z39), (Ra14,Rb4,X2,Z1), (Ra14,Rb4,X2,Z2), (Ra14,Rb4,X2,Z3),(Ra14,Rb4,X2,Z4), (Ra14,Rb4,X2,Z5), (Ra14,Rb4,X2,Z6), (Ra14,Rb4,X2,Z7),(Ra14,Rb4,X2,Z8), (Ra14,Rb4,X2,Z9), (Ra14,Rb4,X2,Z10),(Ra14,Rb4,X2,Z11), (Ra14,Rb4,X2,Z12), (Ra14,Rb4,X2,Z13),(Ra14,Rb4,X2,Z14), (Ra14,Rb4,X2,Z15), (Ra14,Rb4,X2,Z16),(Ra14,Rb4,X2,Z17), (Ra14,Rb4,X2,Z18), (Ra14,Rb4,X2,Z19),(Ra14,Rb4,X2,Z20), (Ra14,Rb4,X2,Z21), (Ra14,Rb4,X2,Z22),(Ra14,Rb4,X2,Z23), (Ra14,Rb4,X2,Z24), (Ra14,Rb4,X2,Z25),(Ra14,Rb4,X2,Z26), (Ra14,Rb4,X2,Z27), (Ra14,Rb4,X2,Z28),(Ra14,Rb4,X2,Z29), (Ra14,Rb4,X2,Z30), (Ra14,Rb4,X2,Z31),(Ra14,Rb4,X2,Z32), (Ra14,Rb4,X2,Z33), (Ra14,Rb4,X2,Z34),(Ra14,Rb4,X2,Z35), (Ra14,Rb4,X2,Z36), (Ra14,Rb4,X2,Z37),(Ra14,Rb4,X2,Z38), (Ra14,Rb4,X2,Z39), (Ra14,Rb5,X1,Z1),(Ra14,Rb5,X1,Z2), (Ra14,Rb5,X1,Z3), (Ra14,Rb5,X1,Z4), (Ra14,Rb5,X1,Z5),(Ra14,Rb5,X1,Z6), (Ra14,Rb5,X1,Z7), (Ra14,Rb5,X1,Z8), (Ra14,Rb5,X1,Z9),(Ra14,Rb5,X1,Z10), (Ra14,Rb5,X1,Z11), (Ra14,Rb5,X1,Z12),(Ra14,Rb5,X1,Z13), (Ra14,Rb5,X1,Z14), (Ra14,Rb5,X1,Z15),(Ra14,Rb5,X1,Z16), (Ra14,Rb5,X1,Z17), (Ra14,Rb5,X1,Z18),(Ra14,Rb5,X1,Z19), (Ra14,Rb5,X1,Z20), (Ra14,Rb5,X1,Z21),(Ra14,Rb5,X1,Z22), (Ra14,Rb5,X1,Z23), (Ra14,Rb5,X1,Z24),(Ra14,Rb5,X1,Z25), (Ra14,Rb5,X1,Z26), (Ra14,Rb5,X1,Z27),(Ra14,Rb5,X1,Z28), (Ra14,Rb5,X1,Z29), (Ra14,Rb5,X1,Z30),(Ra14,Rb5,X1,Z31), (Ra14,Rb5,X1,Z32), (Ra14,Rb5,X1,Z33),(Ra14,Rb5,X1,Z34), (Ra14,Rb5,X1,Z35), (Ra14,Rb5,X1,Z36),(Ra14,Rb5,X1,Z37), (Ra14,Rb5,X1,Z38), (Ra14,Rb5,X1,Z39),(Ra14,Rb5,X2,Z1), (Ra14,Rb5,X2,Z2), (Ra14,Rb5,X2,Z3), (Ra14,Rb5,X2,Z4),(Ra14,Rb5,X2,Z5), (Ra14,Rb5,X2,Z6), (Ra14,Rb5,X2,Z7), (Ra14,Rb5,X2,Z8),(Ra14,Rb5,X2,Z9), (Ra14,Rb5,X2,Z10), (Ra14,Rb5,X2,Z11),(Ra14,Rb5,X2,Z12), (Ra14,Rb5,X2,Z13), (Ra14,Rb5,X2,Z14),(Ra14,Rb5,X2,Z15), (Ra14,Rb5,X2,Z16), (Ra14,Rb5,X2,Z17),(Ra14,Rb5,X2,Z18), (Ra14,Rb5,X2,Z19), (Ra14,Rb5,X2,Z20),(Ra14,Rb5,X2,Z21), (Ra14,Rb5,X2,Z22), (Ra14,Rb5,X2,Z23),(Ra14,Rb5,X2,Z24), (Ra14,Rb5,X2,Z25), (Ra14,Rb5,X2,Z26),(Ra14,Rb5,X2,Z27), (Ra14,Rb5,X2,Z28), (Ra14,Rb5,X2,Z29),(Ra14,Rb5,X2,Z30), (Ra14,Rb5,X2,Z31), (Ra14,Rb5,X2,Z32),(Ra14,Rb5,X2,Z33), (Ra14,Rb5,X2,Z34), (Ra14,Rb5,X2,Z35),(Ra14,Rb5,X2,Z36), (Ra14,Rb5,X2,Z37), (Ra14,Rb5,X2,Z38),(Ra14,Rb5,X2,Z39), (Ra14,Rb6,X1,Z1), (Ra14,Rb6,X1,Z2), (Ra14,Rb6,X1,Z3),(Ra14,Rb6,X1,Z4), (Ra14,Rb6,X1,Z5), (Ra14,Rb6,X1,Z6), (Ra14,Rb6,X1,Z7),(Ra14,Rb6,X1,Z8), (Ra14,Rb6,X1,Z9), (Ra14,Rb6,X1,Z10),(Ra14,Rb6,X1,Z11), (Ra14,Rb6,X1,Z12), (Ra14,Rb6,X1,Z13),(Ra14,Rb6,X1,Z14), (Ra14,Rb6,X1,Z15), (Ra14,Rb6,X1,Z16),(Ra14,Rb6,X1,Z17), (Ra14,Rb6,X1,Z18), (Ra14,Rb6,X1,Z19),(Ra14,Rb6,X1,Z20), (Ra14,Rb6,X1,Z21), (Ra14,Rb6,X1,Z22),(Ra14,Rb6,X1,Z23), (Ra14,Rb6,X1,Z24), (Ra14,Rb6,X1,Z25),(Ra14,Rb6,X1,Z26), (Ra14,Rb6,X1,Z27), (Ra14,Rb6,X1,Z28),(Ra14,Rb6,X1,Z29), (Ra14,Rb6,X1,Z30), (Ra14,Rb6,X1,Z31),(Ra14,Rb6,X1,Z32), (Ra14,Rb6,X1,Z33), (Ra14,Rb6,X1,Z34),(Ra14,Rb6,X1,Z35), (Ra14,Rb6,X1,Z36), (Ra14,Rb6,X1,Z37),(Ra14,Rb6,X1,Z38), (Ra14,Rb6,X1,Z39), (Ra14,Rb6,X2,Z1),(Ra14,Rb6,X2,Z2), (Ra14,Rb6,X2,Z3), (Ra14,Rb6,X2,Z4), (Ra14,Rb6,X2,Z5),(Ra14,Rb6,X2,Z6), (Ra14,Rb6,X2,Z7), (Ra14,Rb6,X2,Z8), (Ra14,Rb6,X2,Z9),(Ra14,Rb6,X2,Z10), (Ra14,Rb6,X2,Z11), (Ra14,Rb6,X2,Z12),(Ra14,Rb6,X2,Z13), (Ra14,Rb6,X2,Z14), (Ra14,Rb6,X2,Z15),(Ra14,Rb6,X2,Z16), (Ra14,Rb6,X2,Z17), (Ra14,Rb6,X2,Z18),(Ra14,Rb6,X2,Z19), (Ra14,Rb6,X2,Z20), (Ra14,Rb6,X2,Z21),(Ra14,Rb6,X2,Z22), (Ra14,Rb6,X2,Z23), (Ra14,Rb6,X2,Z24),(Ra14,Rb6,X2,Z25), (Ra14,Rb6,X2,Z26), (Ra14,Rb6,X2,Z27),(Ra14,Rb6,X2,Z28), (Ra14,Rb6,X2,Z29), (Ra14,Rb6,X2,Z30),(Ra14,Rb6,X2,Z31), (Ra14,Rb6,X2,Z32), (Ra14,Rb6,X2,Z33),(Ra14,Rb6,X2,Z34), (Ra14,Rb6,X2,Z35), (Ra14,Rb6,X2,Z36),(Ra14,Rb6,X2,Z37), (Ra14,Rb6,X2,Z38), (Ra14,Rb6,X2,Z39),(Ra14,Rb7,X1,Z1), (Ra14,Rb7,X1,Z2), (Ra14,Rb7,X1,Z3), (Ra14,Rb7,X1,Z4),(Ra14,Rb7,X1,Z5), (Ra14,Rb7,X1,Z6), (Ra14,Rb7,X1,Z7), (Ra14,Rb7,X1,Z8),(Ra14,Rb7,X1,Z9), (Ra14,Rb7,X1,Z10), (Ra14,Rb7,X1,Z11),(Ra14,Rb7,X1,Z12), (Ra14,Rb7,X1,Z13), (Ra14,Rb7,X1,Z14),(Ra14,Rb7,X1,Z15), (Ra14,Rb7,X1,Z16), (Ra14,Rb7,X1,Z17),(Ra14,Rb7,X1,Z18), (Ra14,Rb7,X1,Z19), (Ra14,Rb7,X1,Z20),(Ra14,Rb7,X1,Z21), (Ra14,Rb7,X1,Z22), (Ra14,Rb7,X1,Z23),(Ra14,Rb7,X1,Z24), (Ra14,Rb7,X1,Z25), (Ra14,Rb7,X1,Z26),(Ra14,Rb7,X1,Z27), (Ra14,Rb7,X1,Z28), (Ra14,Rb7,X1,Z29),(Ra14,Rb7,X1,Z30), (Ra14,Rb7,X1,Z31), (Ra14,Rb7,X1,Z32),(Ra14,Rb7,X1,Z33), (Ra14,Rb7,X1,Z34), (Ra14,Rb7,X1,Z35),(Ra14,Rb7,X1,Z36), (Ra14,Rb7,X1,Z37), (Ra14,Rb7,X1,Z38),(Ra14,Rb7,X1,Z39), (Ra14,Rb7,X2,Z1), (Ra14,Rb7,X2,Z2), (Ra14,Rb7,X2,Z3),(Ra14,Rb7,X2,Z4), (Ra14,Rb7,X2,Z5), (Ra14,Rb7,X2,Z6), (Ra14,Rb7,X2,Z7),(Ra14,Rb7,X2,Z8), (Ra14,Rb7,X2,Z9), (Ra14,Rb7,X2,Z10),(Ra14,Rb7,X2,Z11), (Ra14,Rb7,X2,Z12), (Ra14,Rb7,X2,Z13),(Ra14,Rb7,X2,Z14), (Ra14,Rb7,X2,Z15), (Ra14,Rb7,X2,Z16),(Ra14,Rb7,X2,Z17), (Ra14,Rb7,X2,Z18), (Ra14,Rb7,X2,Z19),(Ra14,Rb7,X2,Z20), (Ra14,Rb7,X2,Z21), (Ra14,Rb7,X2,Z22),(Ra14,Rb7,X2,Z23), (Ra14,Rb7,X2,Z24), (Ra14,Rb7,X2,Z25),(Ra14,Rb7,X2,Z26), (Ra14,Rb7,X2,Z27), (Ra14,Rb7,X2,Z28),(Ra14,Rb7,X2,Z29), (Ra14,Rb7,X2,Z30), (Ra14,Rb7,X2,Z31),(Ra14,Rb7,X2,Z32), (Ra14,Rb7,X2,Z33), (Ra14,Rb7,X2,Z34),(Ra14,Rb7,X2,Z35), (Ra14,Rb7,X2,Z36), (Ra14,Rb7,X2,Z37),(Ra14,Rb7,X2,Z38), (Ra14,Rb7,X2,Z39), (Ra14,Rb8,X1,Z1),(Ra14,Rb8,X1,Z2), (Ra14,Rb8,X1,Z3), (Ra14,Rb8,X1,Z4), (Ra14,Rb8,X1,Z5),(Ra14,Rb8,X1,Z6), (Ra14,Rb8,X1,Z7), (Ra14,Rb8,X1,Z8), (Ra14,Rb8,X1,Z9),(Ra14,Rb8,X1,Z10), (Ra14,Rb8,X1,Z11), (Ra14,Rb8,X1,Z12),(Ra14,Rb8,X1,Z13), (Ra14,Rb8,X1,Z14), (Ra14,Rb8,X1,Z15),(Ra14,Rb8,X1,Z16), (Ra14,Rb8,X1,Z17), (Ra14,Rb8,X1,Z18),(Ra14,Rb8,X1,Z19), (Ra14,Rb8,X1,Z20), (Ra14,Rb8,X1,Z21),(Ra14,Rb8,X1,Z22), (Ra14,Rb8,X1,Z23), (Ra14,Rb8,X1,Z24),(Ra14,Rb8,X1,Z25), (Ra14,Rb8,X1,Z26), (Ra14,Rb8,X1,Z27),(Ra14,Rb8,X1,Z28), (Ra14,Rb8,X1,Z29), (Ra14,Rb8,X1,Z30),(Ra14,Rb8,X1,Z31), (Ra14,Rb8,X1,Z32), (Ra14,Rb8,X1,Z33),(Ra14,Rb8,X1,Z34), (Ra14,Rb8,X1,Z35), (Ra14,Rb8,X1,Z36),(Ra14,Rb8,X1,Z37), (Ra14,Rb8,X1,Z38), (Ra14,Rb8,X1,Z39),(Ra14,Rb8,X2,Z1), (Ra14,Rb8,X2,Z2), (Ra14,Rb8,X2,Z3), (Ra14,Rb8,X2,Z4),(Ra14,Rb8, X2,Z5), (Ra14,Rb8,X2,Z6), (Ra14,Rb8,X2,Z7), (Ra14,Rb8,X2,Z8),(Ra14,Rb8,X2,Z9), (Ra14,Rb8,X2,Z10), (Ra14,Rb8,X2,Z11),(Ra14,Rb8,X2,Z12), (Ra14,Rb8,X2,Z13), (Ra14,Rb8,X2,Z14),(Ra14,Rb8,X2,Z15), (Ra14,Rb8,X2,Z16), (Ra14,Rb8,X2,Z17),(Ra14,Rb8,X2,Z18), (Ra14,Rb8,X2,Z19), (Ra14,Rb8,X2,Z20),(Ra14,Rb8,X2,Z21), (Ra14,Rb8,X2,Z22), (Ra14,Rb8,X2,Z23),(Ra14,Rb8,X2,Z24), (Ra14,Rb8,X2,Z25), (Ra14,Rb8,X2,Z26),(Ra14,Rb8,X2,Z27), (Ra14,Rb8,X2,Z28), (Ra14,Rb8,X2,Z29),(Ra14,Rb8,X2,Z30), (Ra14,Rb8,X2,Z31), (Ra14,Rb8,X2,Z32),(Ra14,Rb8,X2,Z33), (Ra14,Rb8,X2,Z34), (Ra14,Rb8,X2,Z35),(Ra14,Rb8,X2,Z36), (Ra14,Rb8,X2,Z37), (Ra14,Rb8,X2,Z38),(Ra14,Rb8,X2,Z39), (Ra15,Rb1,X1,Z1), (Ra15,Rb1,X1,Z2), (Ra15,Rb1,X1,Z3),(Ra15,Rb1,X1,Z4), (Ra15,Rb1,X1,Z5), (Ra15,Rb1,X1,Z6), (Ra15,Rb1,X1,Z7),(Ra15,Rb1,X1,Z8), (Ra15,Rb1,X1,Z9), (Ra15,Rb1,X1,Z10),(Ra15,Rb1,X1,Z11), (Ra15,Rb1,X1,Z12), (Ra15,Rb1,X1,Z13),(Ra15,Rb1,X1,Z14), (Ra15,Rb1,X1,Z15), (Ra15,Rb1,X1,Z16),(Ra15,Rb1,X1,Z17), (Ra15,Rb1,X1,Z18), (Ra15,Rb1,X1,Z19),(Ra15,Rb1,X1,Z20), (Ra15,Rb1,X1,Z21), (Ra15,Rb1,X1,Z22),(Ra15,Rb1,X1,Z23), (Ra15,Rb1,X1,Z24), (Ra15,Rb1,X1,Z25),(Ra15,Rb1,X1,Z26), (Ra15,Rb1,X1,Z27), (Ra15,Rb1,X1,Z28),(Ra15,Rb1,X1,Z29), (Ra15,Rb1,X1,Z30), (Ra15,Rb1,X1,Z31),(Ra15,Rb1,X1,Z32), (Ra15,Rb1,X1,Z33), (Ra15,Rb1,X1,Z34),(Ra15,Rb1,X1,Z35), (Ra15,Rb1,X1,Z36), (Ra15,Rb1,X1,Z37),(Ra15,Rb1,X1,Z38), (Ra15,Rb1,X1,Z39), (Ra15,Rb1,X2,Z1),(Ra15,Rb1,X2,Z2), (Ra15,Rb1,X2,Z3), (Ra15,Rb1,X2,Z4), (Ra15,Rb1,X2,Z5),(Ra15,Rb1,X2,Z6), (Ra15,Rb1,X2,Z7), (Ra15,Rb1,X2,Z8), (Ra15,Rb1,X2,Z9),(Ra15,Rb1,X2,Z10), (Ra15,Rb1,X2,Z11), (Ra15,Rb1,X2,Z12),(Ra15,Rb1,X2,Z13), (Ra15,Rb1,X2,Z14), (Ra15,Rb1,X2,Z15),(Ra15,Rb1,X2,Z16), (Ra15,Rb1,X2,Z17), (Ra15,Rb1,X2,Z18),(Ra15,Rb1,X2,Z19), (Ra15,Rb1,X2,Z20), (Ra15,Rb1,X2,Z21),(Ra15,Rb1,X2,Z22), (Ra15,Rb1,X2,Z23), (Ra15,Rb1,X2,Z24),(Ra15,Rb1,X2,Z25), (Ra15,Rb1,X2,Z26), (Ra15,Rb1,X2,Z27),(Ra15,Rb1,X2,Z28), (Ra15,Rb1,X2,Z29), (Ra15,Rb1,X2,Z30),(Ra15,Rb1,X2,Z31), (Ra15,Rb1,X2,Z32), (Ra15,Rb1,X2,Z33),(Ra15,Rb1,X2,Z34), (Ra15,Rb1,X2,Z35), (Ra15,Rb1,X2,Z36),(Ra15,Rb1,X2,Z37), (Ra15,Rb1,X2,Z38), (Ra15,Rb1,X2,Z39),(Ra15,Rb2,X1,Z1), (Ra15,Rb2,X1,Z2), (Ra15,Rb2,X1,Z3), (Ra15,Rb2,X1,Z4),(Ra15,Rb2,X1,Z5), (Ra15,Rb2,X1,Z6), (Ra15,Rb2,X1,Z7), (Ra15,Rb2,X1,Z8),(Ra15,Rb2,X1,Z9), (Ra15,Rb2,X1,Z10), (Ra15,Rb2,X1,Z11),(Ra15,Rb2,X1,Z12), (Ra15,Rb2,X1,Z13), (Ra15,Rb2,X1,Z14),(Ra15,Rb2,X1,Z15), (Ra15,Rb2,X1,Z16), (Ra15,Rb2,X1,Z17),(Ra15,Rb2,X1,Z18), (Ra15,Rb2,X1,Z19), (Ra15,Rb2,X1,Z20),(Ra15,Rb2,X1,Z21), (Ra15,Rb2,X1,Z22), (Ra15,Rb2,X1,Z23),(Ra15,Rb2,X1,Z24), (Ra15,Rb2,X1,Z25), (Ra15,Rb2,X1,Z26),(Ra15,Rb2,X1,Z27), (Ra15,Rb2,X1,Z28), (Ra15,Rb2,X1,Z29),(Ra15,Rb2,X1,Z30), (Ra15,Rb2,X1,Z31), (Ra15,Rb2,X1,Z32),(Ra15,Rb2,X1,Z33), (Ra15,Rb2,X1,Z34), (Ra15,Rb2,X1,Z35),(Ra15,Rb2,X1,Z36), (Ra15,Rb2,X1,Z37), (Ra15,Rb2,X1,Z38),(Ra15,Rb2,X1,Z39), (Ra15,Rb2,X2,Z1), (Ra15,Rb2,X2,Z2), (Ra15,Rb2,X2,Z3),(Ra15,Rb2,X2,Z4), (Ra15,Rb2,X2,Z5), (Ra15,Rb2,X2,Z6), (Ra15,Rb2,X2,Z7),(Ra15,Rb2,X2,Z8), (Ra15,Rb2,X2,Z9), (Ra15,Rb2,X2,Z10),(Ra15,Rb2,X2,Z11), (Ra15,Rb2,X2,Z12), (Ra15,Rb2,X2,Z13),(Ra15,Rb2,X2,Z14), (Ra15,Rb2,X2,Z15), (Ra15,Rb2,X2,Z16),(Ra15,Rb2,X2,Z17), (Ra15,Rb2,X2,Z18), (Ra15,Rb2,X2,Z19),(Ra15,Rb2,X2,Z20), (Ra15,Rb2,X2,Z21), (Ra15,Rb2,X2,Z22),(Ra15,Rb2,X2,Z23), (Ra15,Rb2,X2,Z24), (Ra15,Rb2,X2,Z25),(Ra15,Rb2,X2,Z26), (Ra15,Rb2,X2,Z27), (Ra15,Rb2,X2,Z28),(Ra15,Rb2,X2,Z29), (Ra15,Rb2,X2,Z30), (Ra15,Rb2,X2,Z31),(Ra15,Rb2,X2,Z32), (Ra15,Rb2,X2,Z33), (Ra15,Rb2,X2,Z34),(Ra15,Rb2,X2,Z35), (Ra15,Rb2,X2,Z36), (Ra15,Rb2,X2,Z37),(Ra15,Rb2,X2,Z38), (Ra15,Rb2,X2,Z39), (Ra15,Rb3,X1,Z1),(Ra15,Rb3,X1,Z2), (Ra15,Rb3,X1,Z3), (Ra15,Rb3,X1,Z4), (Ra15,Rb3,X1,Z5),(Ra15,Rb3,X1,Z6), (Ra15,Rb3,X1,Z7), (Ra15,Rb3,X1,Z8), (Ra15,Rb3,X1,Z9),(Ra15,Rb3,X1,Z10), (Ra15,Rb3,X1,Z11), (Ra15,Rb3,X1,Z12),(Ra15,Rb3,X1,Z13), (Ra15,Rb3,X1,Z14), (Ra15,Rb3,X1,Z15),(Ra15,Rb3,X1,Z16), (Ra15,Rb3,X1,Z17), (Ra15,Rb3,X1,Z18),(Ra15,Rb3,X1,Z19), (Ra15,Rb3,X1,Z20), (Ra15,Rb3,X1,Z21),(Ra15,Rb3,X1,Z22), (Ra15,Rb3,X1,Z23), (Ra15,Rb3,X1,Z24),(Ra15,Rb3,X1,Z25), (Ra15,Rb3,X1,Z26), (Ra15,Rb3,X1,Z27),(Ra15,Rb3,X1,Z28), (Ra15,Rb3,X1,Z29), (Ra15,Rb3,X1,Z30),(Ra15,Rb3,X1,Z31), (Ra15,Rb3,X1,Z32), (Ra15,Rb3,X1,Z33),(Ra15,Rb3,X1,Z34), (Ra15,Rb3,X1,Z35), (Ra15,Rb3,X1,Z36),(Ra15,Rb3,X1,Z37), (Ra15,Rb3,X1,Z38), (Ra15,Rb3,X1,Z39),(Ra15,Rb3,X2,Z1), (Ra15,Rb3,X2,Z2), (Ra15,Rb3,X2,Z3), (Ra15,Rb3,X2,Z4),(Ra15,Rb3,X2,Z5), (Ra15,Rb3,X2,Z6), (Ra15,Rb3,X2,Z7), (Ra15,Rb3,X2,Z8),(Ra15,Rb3,X2,Z9), (Ra15,Rb3,X2,Z10), (Ra15,Rb3,X2,Z11),(Ra15,Rb3,X2,Z12), (Ra15,Rb3,X2,Z13), (Ra15,Rb3,X2,Z14),(Ra15,Rb3,X2,Z15), (Ra15,Rb3,X2,Z16), (Ra15,Rb3,X2,Z17), (Ra15,Rb3,X2,Z18), (Ra15,Rb3,X2,Z19), (Ra15,Rb3,X2,Z20), (Ra15,Rb3,X2,Z21),(Ra15,Rb3,X2,Z22), (Ra15,Rb3,X2,Z23), (Ra15,Rb3,X2,Z24),(Ra15,Rb3,X2,Z25), (Ra15,Rb3,X2,Z26), (Ra15,Rb3,X2,Z27),(Ra15,Rb3,X2,Z28), (Ra15,Rb3,X2,Z29), (Ra15,Rb3,X2,Z30),(Ra15,Rb3,X2,Z31), (Ra15,Rb3,X2,Z32), (Ra15,Rb3,X2,Z33),(Ra15,Rb3,X2,Z34), (Ra15,Rb3,X2,Z35), (Ra15,Rb3,X2,Z36),(Ra15,Rb3,X2,Z37), (Ra15,Rb3,X2,Z38), (Ra15,Rb3,X2,Z39),(Ra15,Rb4,X1,Z1), (Ra15,Rb4,X1,Z2), (Ra15,Rb4,X1,Z3), (Ra15,Rb4,X1,Z4),(Ra15,Rb4,X1,Z5), (Ra15,Rb4,X1,Z6), (Ra15,Rb4,X1,Z7), (Ra15,Rb4,X1,Z8),(Ra15,Rb4,X1,Z9), (Ra15,Rb4,X1,Z10), (Ra15,Rb4,X1,Z11),(Ra15,Rb4,X1,Z12), (Ra15,Rb4,X1,Z13), (Ra15,Rb4,X1,Z14),(Ra15,Rb4,X1,Z15), (Ra15,Rb4,X1,Z16), (Ra15,Rb4,X1,Z17),(Ra15,Rb4,X1,Z18), (Ra15,Rb4,X1,Z19), (Ra15,Rb4,X1,Z20),(Ra15,Rb4,X1,Z21), (Ra15,Rb4,X1,Z22), (Ra15,Rb4,X1,Z23),(Ra15,Rb4,X1,Z24), (Ra15,Rb4,X1,Z25), (Ra15,Rb4,X1,Z26),(Ra15,Rb4,X1,Z27), (Ra15,Rb4,X1,Z28), (Ra15,Rb4,X1,Z29),(Ra15,Rb4,X1,Z30), (Ra15,Rb4,X1,Z31), (Ra15,Rb4,X1,Z32),(Ra15,Rb4,X1,Z33), (Ra15,Rb4,X1,Z34), (Ra15,Rb4,X1,Z35),(Ra15,Rb4,X1,Z36), (Ra15,Rb4,X1,Z37), (Ra15,Rb4,X1,Z38),(Ra15,Rb4,X1,Z39), (Ra15,Rb4,X2,Z1), (Ra15,Rb4,X2,Z2), (Ra15,Rb4,X2,Z3),(Ra15,Rb4,X2,Z4), (Ra15,Rb4,X2,Z5), (Ra15,Rb4,X2,Z6), (Ra15,Rb4,X2,Z7),(Ra15,Rb4,X2,Z8), (Ra15,Rb4,X2,Z9), (Ra15,Rb4,X2,Z10),(Ra15,Rb4,X2,Z11), (Ra15,Rb4,X2,Z12), (Ra15,Rb4,X2,Z13),(Ra15,Rb4,X2,Z14), (Ra15,Rb4,X2,Z15), (Ra15,Rb4,X2,Z16),(Ra15,Rb4,X2,Z17), (Ra15,Rb4,X2,Z18), (Ra15,Rb4,X2,Z19),(Ra15,Rb4,X2,Z20), (Ra15,Rb4,X2,Z21), (Ra15,Rb4,X2,Z22),(Ra15,Rb4,X2,Z23), (Ra15,Rb4,X2,Z24), (Ra15,Rb4,X2,Z25),(Ra15,Rb4,X2,Z26), (Ra15,Rb4,X2,Z27), (Ra15,Rb4,X2,Z28),(Ra15,Rb4,X2,Z29), (Ra15,Rb4,X2,Z30), (Ra15,Rb4,X2,Z31),(Ra15,Rb4,X2,Z32), (Ra15,Rb4,X2,Z33), (Ra15,Rb4,X2,Z34),(Ra15,Rb4,X2,Z35), (Ra15,Rb4,X2,Z36), (Ra15,Rb4,X2,Z37),(Ra15,Rb4,X2,Z38), (Ra15,Rb4,X2,Z39), (Ra15,Rb5,X1,Z1),(Ra15,Rb5,X1,Z2), (Ra15,Rb5,X1,Z3), (Ra15,Rb5,X1,Z4), (Ra15,Rb5,X1,Z5),(Ra15,Rb5,X1,Z6), (Ra15,Rb5,X1,Z7), (Ra15,Rb5,X1,Z8), (Ra15,Rb5,X1,Z9),(Ra15,Rb5,X1,Z10), (Ra15,Rb5,X1,Z11), (Ra15,Rb5,X1,Z12),(Ra15,Rb5,X1,Z13), (Ra15,Rb5,X1,Z14), (Ra15,Rb5,X1,Z15),(Ra15,Rb5,X1,Z16), (Ra15,Rb5,X1,Z17), (Ra15,Rb5,X1,Z18),(Ra15,Rb5,X1,Z19), (Ra15,Rb5,X1,Z20), (Ra15,Rb5,X1,Z21),(Ra15,Rb5,X1,Z22), (Ra15,Rb5,X1,Z23), (Ra15,Rb5,X1,Z24),(Ra15,Rb5,X1,Z25), (Ra15,Rb5,X1,Z26), (Ra15,Rb5,X1,Z27),(Ra15,Rb5,X1,Z28), (Ra15,Rb5,X1,Z29), (Ra15,Rb5,X1,Z30),(Ra15,Rb5,X1,Z31), (Ra15,Rb5,X1,Z32), (Ra15,Rb5,X1,Z33),(Ra15,Rb5,X1,Z34), (Ra15,Rb5,X1,Z35), (Ra15,Rb5,X1,Z36),(Ra15,Rb5,X1,Z37), (Ra15,Rb5,X1,Z38), (Ra15,Rb5,X1,Z39),(Ra15,Rb5,X2,Z1), (Ra15,Rb5,X2,Z2), (Ra15,Rb5,X2,Z3), (Ra15,Rb5,X2,Z4),(Ra15,Rb5,X2,Z5), (Ra15,Rb5,X2,Z6), (Ra15,Rb5,X2,Z7), (Ra15,Rb5,X2,Z8),(Ra15,Rb5,X2,Z9), (Ra15,Rb5,X2,Z10), (Ra15,Rb5,X2,Z11),(Ra15,Rb5,X2,Z12), (Ra15,Rb5,X2,Z13), (Ra15,Rb5,X2,Z14),(Ra15,Rb5,X2,Z15), (Ra15,Rb5,X2,Z16), (Ra15,Rb5,X2,Z17),(Ra15,Rb5,X2,Z18), (Ra15,Rb5,X2,Z19), (Ra15,Rb5,X2,Z20),(Ra15,Rb5,X2,Z21), (Ra15,Rb5,X2,Z22), (Ra15,Rb5,X2,Z23),(Ra15,Rb5,X2,Z24), (Ra15,Rb5,X2,Z25), (Ra15,Rb5,X2,Z26),(Ra15,Rb5,X2,Z27), (Ra15,Rb5,X2,Z28), (Ra15,Rb5,X2,Z29),(Ra15,Rb5,X2,Z30), (Ra15,Rb5,X2,Z31), (Ra15,Rb5,X2,Z32),(Ra15,Rb5,X2,Z33), (Ra15,Rb5,X2,Z34), (Ra15,Rb5,X2,Z35),(Ra15,Rb5,X2,Z36), (Ra15,Rb5,X2,Z37), (Ra15,Rb5,X2,Z38),(Ra15,Rb5,X2,Z39), (Ra15,Rb6,X1,Z1), (Ra15,Rb6,X1,Z2), (Ra15,Rb6,X1,Z3),(Ra15,Rb6,X1,Z4), (Ra15,Rb6,X1,Z5), (Ra15,Rb6,X1,Z6), (Ra15,Rb6,X1,Z7),(Ra15,Rb6,X1,Z8), (Ra15,Rb6,X1,Z9), (Ra15,Rb6,X1,Z10),(Ra15,Rb6,X1,Z11), (Ra15,Rb6,X1,Z12), (Ra15,Rb6,X1,Z13),(Ra15,Rb6,X1,Z14), (Ra15,Rb6,X1,Z15), (Ra15,Rb6,X1,Z16),(Ra15,Rb6,X1,Z17), (Ra15,Rb6,X1,Z18), (Ra15,Rb6,X1,Z19),(Ra15,Rb6,X1,Z20), (Ra15,Rb6,X1,Z21), (Ra15,Rb6,X1,Z22),(Ra15,Rb6,X1,Z23), (Ra15,Rb6,X1,Z24), (Ra15,Rb6,X1,Z25),(Ra15,Rb6,X1,Z26), (Ra15,Rb6,X1,Z27), (Ra15,Rb6,X1,Z28),(Ra15,Rb6,X1,Z29), (Ra15,Rb6,X1,Z30), (Ra15,Rb6,X1,Z31),(Ra15,Rb6,X1,Z32), (Ra15,Rb6,X1,Z33), (Ra15,Rb6,X1,Z34),(Ra15,Rb6,X1,Z35), (Ra15,Rb6,X1,Z36), (Ra15,Rb6,X1,Z37),(Ra15,Rb6,X1,Z38), (Ra15,Rb6,X1,Z39), (Ra15,Rb6,X2,Z1),(Ra15,Rb6,X2,Z2), (Ra15,Rb6,X2,Z3), (Ra15,Rb6,X2,Z4), (Ra15,Rb6,X2,Z5),(Ra15,Rb6,X2,Z6), (Ra15,Rb6,X2,Z7), (Ra15,Rb6,X2,Z8), (Ra15,Rb6,X2,Z9),(Ra15,Rb6,X2,Z10), (Ra15,Rb6,X2,Z11), (Ra15,Rb6,X2,Z12),(Ra15,Rb6,X2,Z13), (Ra15,Rb6,X2,Z14), (Ra15,Rb6,X2,Z15),(Ra15,Rb6,X2,Z16), (Ra15,Rb6,X2,Z17), (Ra15,Rb6,X2,Z18),(Ra15,Rb6,X2,Z19), (Ra15,Rb6,X2,Z20), (Ra15,Rb6,X2,Z21),(Ra15,Rb6,X2,Z22), (Ra15,Rb6,X2,Z23), (Ra15,Rb6,X2,Z24),(Ra15,Rb6,X2,Z25), (Ra15,Rb6,X2,Z26), (Ra15,Rb6,X2,Z27),(Ra15,Rb6,X2,Z28), (Ra15,Rb6,X2,Z29), (Ra15,Rb6,X2,Z30),(Ra15,Rb6,X2,Z31), (Ra15,Rb6,X2,Z32), (Ra15,Rb6,X2,Z33),(Ra15,Rb6,X2,Z34), (Ra15,Rb6,X2,Z35), (Ra15,Rb6,X2,Z36),(Ra15,Rb6,X2,Z37), (Ra15,Rb6,X2,Z38), (Ra15,Rb6,X2,Z39),(Ra15,Rb7,X1,Z1), (Ra15,Rb7,X1,Z2), (Ra15,Rb7,X1,Z3), (Ra15,Rb7,X1,Z4),(Ra15,Rb7,X1,Z5), (Ra15,Rb7,X1,Z6), (Ra15,Rb7,X1,Z7), (Ra15,Rb7,X1,Z8),(Ra15,Rb7,X1,Z9), (Ra15,Rb7,X1,Z10), (Ra15,Rb7,X1,Z11),(Ra15,Rb7,X1,Z12), (Ra15,Rb7,X1,Z13), (Ra15,Rb7,X1,Z14),(Ra15,Rb7,X1,Z15), (Ra15,Rb7,X1,Z16), (Ra15,Rb7,X1,Z17),(Ra15,Rb7,X1,Z18), (Ra15,Rb7,X1, Z19), (Ra15,Rb7,X1,Z20),(Ra15,Rb7,X1,Z21), (Ra15,Rb7,X1,Z22), (Ra15,Rb7,X1,Z23),(Ra15,Rb7,X1,Z24), (Ra15,Rb7,X1,Z25), (Ra15,Rb7,X1,Z26),(Ra15,Rb7,X1,Z27), (Ra15,Rb7,X1,Z28), (Ra15,Rb7,X1,Z29),(Ra15,Rb7,X1,Z30), (Ra15,Rb7,X1,Z31), (Ra15,Rb7,X1,Z32),(Ra15,Rb7,X1,Z33), (Ra15,Rb7,X1,Z34), (Ra15,Rb7,X1,Z35),(Ra15,Rb7,X1,Z36), (Ra15,Rb7,X1,Z37), (Ra15,Rb7,X1,Z38),(Ra15,Rb7,X1,Z39), (Ra15,Rb7,X2,Z1), (Ra15,Rb7,X2,Z2), (Ra15,Rb7,X2,Z3),(Ra15,Rb7,X2,Z4), (Ra15,Rb7,X2,Z5), (Ra15,Rb7,X2,Z6), (Ra15,Rb7,X2,Z7),(Ra15,Rb7,X2,Z8), (Ra15,Rb7,X2,Z9), (Ra15,Rb7,X2,Z10),(Ra15,Rb7,X2,Z11), (Ra15,Rb7,X2,Z12), (Ra15,Rb7,X2,Z13),(Ra15,Rb7,X2,Z14), (Ra15,Rb7,X2,Z15), (Ra15,Rb7,X2,Z16),(Ra15,Rb7,X2,Z17), (Ra15,Rb7,X2,Z18), (Ra15,Rb7,X2,Z19),(Ra15,Rb7,X2,Z20), (Ra15,Rb7,X2,Z21), (Ra15,Rb7,X2,Z22),(Ra15,Rb7,X2,Z23), (Ra15,Rb7,X2,Z24), (Ra15,Rb7,X2,Z25),(Ra15,Rb7,X2,Z26), (Ra15,Rb7,X2,Z27), (Ra15,Rb7,X2,Z28),(Ra15,Rb7,X2,Z29), (Ra15,Rb7,X2,Z30), (Ra15,Rb7,X2,Z31),(Ra15,Rb7,X2,Z32), (Ra15,Rb7,X2,Z33), (Ra15,Rb7,X2,Z34),(Ra15,Rb7,X2,Z35), (Ra15,Rb7,X2,Z36), (Ra15,Rb7,X2,Z37),(Ra15,Rb7,X2,Z38), (Ra15,Rb7,X2,Z39), (Ra15,Rb8,X1,Z1),(Ra15,Rb8,X1,Z2), (Ra15,Rb8,X1,Z3), (Ra15,Rb8,X1,Z4), (Ra15,Rb8,X1,Z5),(Ra15,Rb8,X1,Z6), (Ra15,Rb8,X1,Z7), (Ra15,Rb8,X1,Z8), (Ra15,Rb8,X1,Z9),(Ra15,Rb8,X1,Z10), (Ra15,Rb8,X1,Z11), (Ra15,Rb8,X1,Z12),(Ra15,Rb8,X1,Z13), (Ra15,Rb8,X1,Z14), (Ra15,Rb8,X1,Z15),(Ra15,Rb8,X1,Z16), (Ra15,Rb8,X1,Z17), (Ra15,Rb8,X1,Z18),(Ra15,Rb8,X1,Z19), (Ra15,Rb8,X1,Z20), (Ra15,Rb8,X1,Z21),(Ra15,Rb8,X1,Z22), (Ra15,Rb8,X1,Z23), (Ra15,Rb8,X1,Z24),(Ra15,Rb8,X1,Z25), (Ra15,Rb8,X1,Z26), (Ra15,Rb8,X1,Z27),(Ra15,Rb8,X1,Z28), (Ra15,Rb8,X1,Z29), (Ra15,Rb8,X1,Z30),(Ra15,Rb8,X1,Z31), (Ra15,Rb8,X1,Z32), (Ra15,Rb8,X1,Z33),(Ra15,Rb8,X1,Z34), (Ra15,Rb8,X1,Z35), (Ra15,Rb8,X1,Z36),(Ra15,Rb8,X1,Z37), (Ra15,Rb8,X1,Z38), (Ra15,Rb8,X1,Z39),(Ra15,Rb8,X2,Z1), (Ra15,Rb8,X2,Z2), (Ra15,Rb8,X2,Z3), (Ra15,Rb8,X2,Z4),(Ra15,Rb8,X2,Z5), (Ra15,Rb8,X2,Z6), (Ra15,Rb8,X2,Z7), (Ra15,Rb8,X2,Z8),(Ra15,Rb8,X2,Z9), (Ra15,Rb8,X2,Z10), (Ra15,Rb8,X2,Z11),(Ra15,Rb8,X2,Z12), (Ra15,Rb8,X2,Z13), (Ra15,Rb8,X2,Z14),(Ra15,Rb8,X2,Z15), (Ra15,Rb8,X2,Z16), (Ra15,Rb8,X2,Z17),(Ra15,Rb8,X2,Z18), (Ra15,Rb8,X2,Z19), (Ra15,Rb8,X2,Z20),(Ra15,Rb8,X2,Z21), (Ra15,Rb8,X2,Z22), (Ra15,Rb8,X2,Z23),(Ra15,Rb8,X2,Z24), (Ra15,Rb8,X2,Z25), (Ra15,Rb8,X2,Z26),(Ra15,Rb8,X2,Z27), (Ra15, Rb8,X2,Z28), (Ra15,Rb8,X2,Z29),(Ra15,Rb8,X2,Z30), (Ra15,Rb8,X2,Z31), (Ra15,Rb8,X2,Z32),(Ra15,Rb8,X2,Z33), (Ra15,Rb8,X2,Z34), (Ra15,Rb8,X2,Z35),(Ra15,Rb8,X2,Z36), (Ra15,Rb8,X2,Z37), (Ra15,Rb8,X2,Z38), and(Ra15,Rb8,X2,Z39)

EXAMPLES

Following examples illustrate the present invention in more detail, butthe present invention is not limited by these examples. The meaning ofeach abbreviation is following.

Me: methyl

Et: ethyl

Bu: butyl

Ac: acetyl

TMS: tetramethylsilane

TMS-Cl: trimethylsilyl chloride

DMSO: dimethyl sulfoxide

DMF: dimethylformamide

THF: tetrahydrofuran

rt: room temperature

Example 1 Preparation of4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxycarbonylmethyloxyphenyl-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one

A mixture of ethyl trimethylacetopyruvate (0.40 g, 2 mmol),4-thiophene-3-ylaniline (0.35 g, 2 mmol),2-(methoxycarbonylmethyloxy)benzaldehyde (0.39, 2 mmol), acetic acid(0.057 mL, 1 mmol) and dioxane (4 mL) was heated at reflux overnight.After the reaction was completed, saturated sodium bicarbonate solutionand brine were poured into the reaction mixture, and the resultingmixture was extracted with ethyl acetate. The extract was dried overanhydrous sodium sulphate, and then concentrated in vacuo. The resultingresidue was purified on a silica gel column chromatography(methanol/chloroform), and the aimed compound was triturated with ethylacetate and diisopropyl ether to give4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxycarbonylmethyloxyphenyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.42 g, yield: 41%) as pale brown solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.10 (9H, s), 3.78 (3H, s), 4.50-4.90 (2H,m), 6.00-6.45 (1H, m), 6.60-7.11 (11H, m).

Example 2 Preparation of5-(2-hydroxycarbonylmethyloxyphenyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one

To a mixture of4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxycarbonylmethyloxyphenyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.172 g, 0.34 mmol), THF (1.72 mL), and methanol (1.72 mL) was added 1mol/L aqueous lithium hydroxide solution (1.02 mL), and the resultingmixture was stirred at room temperature for 1 hour. After the reactionwas completed, 2 mol/L hydrochloric acid (0.52 mL) and water (14 mL)were added to the reaction mixture, and the precipitated aimed compoundwas collected by filtration. The resulting aimed compound was dissolvedin ethyl acetate, and the mixture was dried over anhydrous sodiumsulphate and then concentrated in vacuo. The resulting residue wastriturated with ethyl ether and diisopropyl ether to give5-(2-hydroxycarbonylmethyloxyphenyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.137 g, yield: 82%) as pale yellow solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.10 (9H, s), 4.85 (2H, s), 6.46 (1H, brs),6.76-7.75 (11H, m).

Example 3 Preparation of3-t-butyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxycarbonylmethyloxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

A mixture of4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxycarbonylmethyloxyphenyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.207 g, 0.41 mmol), hydrazine hydrate (0.022 mL, 0.45 mmol) and aceticacid (3.1 mL) was stirred at 95° C. for 1 hour. After the reaction wascompleted, saturated sodium bicarbonate solution was poured into thereaction mixture, and the mixture was extracted with chloroform. Theextract was washed with brine, dried over anhydrous sodium sulphate, andthen concentrated in vacuo. The resulting residue was triturated withethyl ether and diisopropyl ether to give3-t-butyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxycarbonylmethyloxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.191 g, yield: 93%) as pale brown solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.05 (9H, s), 3.78 (3H, s), 4.94 (2H, s),6.70-7.77 (12H, m), 13.4 (1H, brs).

Example 4 Preparation of3-t-butyl-5-(4-thiophene-3-ylphenyl)-4-(2-hydroxycarbonylmethyloxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

To a mixture of3-t-butyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxycarbonylmethyloxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.124 g, 0.25 mmol), THF (1.24 mL) and methanol (1.24 mL) was added 1mol/L aqueous lithium hydroxide solution (0.74 mL), and the resultingmixture was stirred at room temperature for 1.5 hours. After thereaction was completed, 2 mol/L hydrochloric acid (0.38 mL) and water(10 mL) were poured into the reaction mixture, and the precipitatedaimed compound was collected by filtration. The resulting aimed compoundwas dissolved in ethyl acetate, and the solution was dried overanhydrous sodium sulphate and then concentrated in vacuo. The resultingresidue was triturated with ethyl ether and diisopropyl ether to give5-(2-hydroxycarbonylmethyloxyphenyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.104 g, yield: 87%) as pale brown solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.05 (9H, s), 4.78 (2H, s), 6.70-7.80 (12H,m), 13.33 (1H, brs).

Example 5 Preparation of1-(6-furan-3-yl-3-pyridyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxy-3-pyridyl)-1,5-dihydropyrrole-2-one

A mixture of1-(6-bromo-3-pyridyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-5-(2-methoxy-3-pyridyl)-1,5-dihydropyrrole-2-one(0.10 g, 0.22 mmol), furan-3-yl boronic acid (0.038 g, 0.34 mmol),tripotassium phosphate (0.14 mg, 0.67 mmol), 1,2-Dimethoxyethane (3 mL)and water (0.6 mL) was placed in a flask under nitrogen. To the mixturewas added 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethane complex (0.018 g, 0.022 mmol), and the resulting mixturewas heated at reflux for 4 hours. After the reaction was completed,saturated ammonium chloride aqueous solution was poured into the mixtureand the resulting mixture was extracted with ethyl acetate. The extractwas washed with brine, dried over anhydrous sodium sulphate, andconcentrated in vacuo. The resulting residue was purified on a silicagel column chromatography (ethyl acetate/n-hexane) and the aimedcompound was triturated with ethyl acetate and n-hexane to give1-(6-furan-3-yl-3-pyridyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-1-5-(2-methoxy-3-pyridyl)-1,5-dihydropyrrole-2-one(0.045 g, yield: 46%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.11 (9H, s), 3.79 (3H, brs), 6.24 (1H,brs), 6.86 (1H, m), 6.96 (1H, m), 7.64-7.95 (4H, m), 8.23 (1H, s), 8.71(1H, s), 12.31 (1H, brs).

Example 6 Preparation of3-t-butyl-5-(6-thiophene-2-yl-3-pyridyl)-4-(2-methoxy-3-pyridyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

A mixture of5-(6-bromo-3-pyridyl)-3-t-butyl-4-(2-methoxy-3-pyridyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.10 g, 0.23 mmol), thiophene-2-yl boronic acid (0.043 g, 0.34 mmol),tripotassium phosphate (0.14 mg, 0.67 mmol), 1,2-Dimethoxyethane (3 mL)and water (0.6 mL) was placed in a flask under nitrogen. To the mixturewas added 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II) dichloridedichloromethane complex (0.018 g, 0.022 mmol) and the resulting mixturewas heated at reflux for 3 hours. After the reaction was completed,water was added to the mixture, and the resulting mixture was extractedwith ethyl acetate. The extract was dried over anhydrous sodium sulphateand concentrated in vacuo. The resulting residue was purified on asilica gel column chromatography (ethyl acetate/n-hexane). The aimedcompound was triturated with ethyl acetate and n-hexane to give1-(6-furan-3-yl-3-pyridyl)-4-(2,2-dimethylpropionyl)-3-hydroxy-1-5-(2-methoxy-3-pyridyl)-1,5-dihydropyrrole-2-one(0.089 g, yield: 88%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.07 (9H, s), 3.97 (3.55) (3H, s), 6.56-7.28(4H, m), 7.58 (1H, d, J=5.0), 7.69 (1H, d, J=3.7), 7.87-8.10 (3H, m),8.64 (1H, s), 13.36 (1H, m).

Example 7 Preparation of3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxyphenyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

A mixture of methyl5,5-dimethyl-2,4-dioxo-6-(tetrahydro-2H-pyrane-2-yloxy)hexanoate (4.29g, 15 mmol), 4-bromoaniline (2.58 g, 15 mmol), 2-methoxybenzaldehyde(1.812 mL, 15 mmol), acetic acid (0.343 mL, 6 mmol) and dioxane (15 ml)was heated at reflux overnight. After the reaction was completed, themixture was concentrated in vacuo and the resulting residue was purifiedon a silica gel column chromatography (ethyl acetate/n-hexane). Theresulting aimed compound was triturated with ethyl acetate and n-hexaneto give1-(4-bromophenyl)-4-(2,2-dimethyl-3-tetrahydro-2H-pyrane-2-yloxypropionyl)-3-hydroxy-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(2.69 g, yield: 33%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 1.08 (3H, s), 1.13 (3H, s), 1.20-1.40 (6H,m), 3.50-3.90 (7H, m), 4.37 (1H, m), 6.31 (1H, brs), 6.70-7.44 (8H, m),12.23 (1H, brs).

A mixture of1-(4-bromophenyl)-4-(2,2-dimethyl-3-tetrahydro-2H-pyrane-2-yloxypropionyl)-3-hydroxy-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(1.51 g, 2.77 mmol), hydrazine hydrate (0.204 mL, 4.16 mmol) and aceticacid (3 mL) was stirred at 95° C. for 2 hours. After the reaction wascompleted, saturated sodium bicarbonate solution (150 mL) was pouredinto the reaction mixture, and the resulting mixture was extracted withethyl acetate. The extract was washed with saturated sodium bicarbonatesolution, dried over anhydrous sodium sulphate, and concentrated invacuo. The resulting residue was triturated with ethyl acetate to give5-(4-bromophenyl)-3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(1.02 g, yield: 81%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 0.88 (3H, s), 1.00 (3H, s), 3.11 (2H, m),3.87 (3H, s), 4.73 (1H, brs), 6.30-7.50 (9H, m), 13.21 (1H, m).

A mixture of5-(4-bromophenyl)-3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.15 g, 0.33 mmol), thiophene-3-yl boronic acid (0.063. g, 0.49 mmol),tripotassium phosphate (0.21 mg, 0.99 mmol), 1,2-Dimethoxyethane (3 mL)and water (0.6 mL) was placed in a flask under nitrogen. To the mixturewas added 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II) dichloridedichloromethane complex (0.027 mg, 0.033 mmol) and the resulting mixturewas heated at reflux for 5 hours. After the reaction was completed, thereaction mixture was purified on a silica gel column chromatography(ethyl acetate/n-hexane). The resulting aimed compound was trituratedwith ethyl acetate and n-hexane to give3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxyphenyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.038 g, yield: 25%) as colorless solid.

1H-NMR (5 ppm TMS I DMSO-d6): 0.91 (3H, s), 1.04 (3H, s), 3.25 (2H, m),3.91 (3H, s), 4.74 (1H, s), 6.33-7.78 (9H, m), 13.21 (1H, m)

Example 8 Preparation of3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxy-3-pyridyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

A mixture of methyl5,5-dimethyl-2,4-dioxo-6-(tetrahydro-2H-pyrane-2-yloxy)hexanoate (0.29mg, 1.0 mmol), 4-(3-thienyl)aniline (0.18 g, 1.0 mmol),2-methoxynicotinaldehyde (0.14 g, 1.0 mmol), acetic acid (0.043 mL, 0.75mmol) and dioxane (2 ml) was heated at reflux overnight. After thereaction was completed, the reaction mixture was concentrated in vacuo.The resulting residue was purified on a silica gel column chromatography(methanol/chloroform) to give4-(2,2-dimethyl-3-tetrahydro-2H-pyrane-2-yloxypropionyl)-3-hydroxy-5-(2-methoxy-3-pyridyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.30 g, yield: 55%) as pale yellow solid.

To a mixture of4-(2,2-dimethyl-3-tetrahydro-2H-pyrane-2-yloxypropionyl)-3-hydroxy-5-(2-methoxy-3-pyridyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.30 g, 0.55 mmol), methanol (3 mL) and chloroform (3 mL) was addedp-toluenesulfonic acid hydrate (0.158 g, 0.8 mmol), and the resultingmixture was stirred at room temperature for 3 hours. After the reactionwas completed, saturated sodium bicarbonate solution and brine werepoured into the mixture. The resulting mixture was extracted withchloroform. The extract was dried over anhydrous sodium sulphate andconcentrated in vacuo. To the obtained crude4-(2,2-dimethyl-3-hydroxypropionyl)-3-hydroxy-5-(2-methoxy-3-pyridyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.233 g), acetic acid (2 mL) and hydrazine hydrate (0.074 mL, 1.5 mmol)were added, and the resulting mixture was stirred at 50° C. for 1 hour.After the reaction was completed, saturated sodium bicarbonate solutionwas poured into the mixture, and the resulting mixture was extractedwith chloroform. The extract was dried over anhydrous sodium sulphateand concentrated in vacuo. The resulting residue was triturated withethyl acetate to give3-(1-hydroxymethyl-1-methylethyl)-4-(2-methoxy-3-pyridyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.061 g, yield: 26%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 0.95 (3H, s), 1.06 (3H, s), 3.23 (2H, m),4.06 (213, s), 4.78 (1H, brs), 6.43-8.10 (10H, m), 13.40 (1H, m).

Example 9 Preparation of3-(1,1-dihydroxymethylethyl)-4-(2-methoxyphenyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

To a mixture of 3-hydroxy-2-hydroxymethyl-2-methylpropionic acid (6.71g, 50 mmol), dimethoxypropane (7.99 mL, 65 mmol) and acetone (50 mL),p-toluenesulfonic acid hydrate (0.048 g, 0.25 mmol) was added and theresulting mixture was stirred at room temperature for 2.5 hours. Afterthe reaction was completed, sodium bicarbonate (0.1 g) was added to thereaction mixture, and the resulting mixture was stirred at roomtemperature for 5 minutes and concentrated in vacuo. To the resultingresidue was added water and the resulting mixture was extracted withethyl ether. The extract was dried over anhydrous sodium sulphate andconcentrated in vacuo to give 2,2,5-trimethyl-1,3-dioxane5-carboxylicacid (7.87 g, yield: 90%) as colorless oil.

1H-NMR (δ ppm TMS/CDCl3): 1.20 (3H, s), 1.43 (3H, s), 1.46 (3H, s), 3.70(2H, d, J=11.7), 4.16 (2H, d, J=11.7).

To a mixture of 2,2,5-trimethyl-1,3-dioxane5-carboxylic acid (1.0 g,5.74 mmol) and DMF (10 mL) were added N,O-dimethylhydroxylaminehydrochloride (0.84 g, 8.6 mmol), 1-hydroxybenzotriazole hydrate (1.32g, 8.6 mmol), 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloricacid (1.651 g, 8.61 mmol) and triethylamine (2.39 mL, 17.2 mmol) undernitrogen atmosphere, and the resulting mixture was stirred at roomtemperature for 3 hours. After the reaction was completed, water wasadded to the reaction mixture and the resulting mixture was extractedwith ethyl acetate. The extract was washed with brine, dried overanhydrous sodium sulphate, and concentrated in vacuo to giveN-methoxy-N,2,2,5-tetramethyl-1,3-dioxane5-carboxylic acid amid (1.08 g,yield: 86%) as colorless oil.

1H-NMR (δ ppm TMS/CDCl3): 1.38 (3H, s), 1.41 (3H, s), 1.42 (3H, s), 3.18(3H, s), 3.69 (3H, s), 3.76 (2H, d, J=11.7), 4.19 (2H, d, J=11.7).

To a mixture of N-methoxy-N,2,2,5-tetramethyl-1,3-dioxane5-carboxylicacid amid (1.07 g, 4.92 mmol) and THF (10 mL) was gradually added 3mol/L methylmagnesium bromide in THF (2.46 mL, 7.4 mmol) at 0° C. undernitrogen atmosphere, and the resulting mixture was stirred at 0° C. for4 hours. After the reaction was completed, saturated ammonium chlorideaqueous solution was added to the reaction mixture and the resultingmixture was extracted with ethyl acetate. The extract was washed withbrine, dried over anhydrous sodium sulphate, and concentrated in vacuoto give 1-(2,2,5-trimethyl-1,3-dioxane5-yl)ethanone (0.76 g, yield: 90%)as colorless oil.

1H-NMR (δ ppm TMS/CDCl3): 1.03 (3H, s), 1.37 (3H, d, J=0.5), 1.45 (3H,d, J=0.5), 2.28 (3H, s), 3.68 (2H, d, J=12.2), 4.16 (2H, d, J=12.2).

To a mixture of 1-(2,2,5-trimethyl-1,3-dioxane5-yl)ethanone (0.76 g, 4.4mmol) and THF (7.6 mL) was added sodium hydride (0.16 g, 6.6 mmol) undernitrogen atmosphere, and the resulting mixture was stirred at roomtemperature for 0.5 hour. To the resulting reaction mixture was addeddimethyl oxalate (0.78 g, 6.6 mmol) and the mixture was heated at refluxfor 2 hours. After the reaction was completed, saturated ammoniumchloride aqueous solution was added to mixture and the resulting mixturewas extracted with ethyl acetate. The extract was washed with brine,dried over anhydrous sodium sulphate, and concentrated in vacuo. Theresulting residue was purified on a silica gel column chromatography(ethyl acetate/n-hexane) to give methyl2,4-dioxo-4-(2,2,5-trimethyl-1,3-dioxane5-yl)butanoate (1.0 g, yield:88%) as colorless oil.

A mixture of methyl2,4-dioxo-4-(2,2,5-trimethyl-1,3-dioxane5-yl)butanoate (0.26 mg, 1.0mmol), 4-(3-thienyl)aniline (0.18 g, 1.0 mmol), 2-methooxybenzaldehyde(0.12 mL, 1.0 mmol), acetic acid (0.023 mL, 0.40 mmol) and dioxane (2ml) was heated at reflux overnight. After the reaction was completed,the mixture was concentrated in vacuo. To the residue was addeddiisopropyl ether, and the resulting mixture was stirred underice-cooling. The precipitated aimed compound was collected by filtrationto give3-hydroxy-4-(2,2,5-trimethyl-1,3-dioxane5-yl)carbonyl-5-(2-methoxyphenyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.29 g, yield: 56%) as pale yellow solid.

1H-NMR (δ ppm TMS/CDCl3): 0.99 (3H, s), 1.12 (3H, s), 1.40 (3H, s),3.63-3.76 (2H, m), 3.89 (3H, brs), 4.20-4.37 (2H, m), 6.50-7.58 (12H,m), 9.00 (1H, brs).

A mixture of3-hydroxy-4-(2,2,5-trimethyl-1,3-dioxane5-yl)carbonyl-5-(2-methoxyphenyl)-1-(4-thiophene-3-ylphenyl)-1,5-dihydropyrrole-2-one(0.15 g, 0.3 mmol), hydrazine hydrate (0.07 mL, 1.4 mmol) and aceticacid (1 mL) was heated at reflux overnight. After the reaction mixturewas concentrated in vacuo, to the resulting residue was added 2 mol/Lhydrochloric acid/methanol solution (2.89 mL, 5.8 mmol) and theresulting mixture was heated at reflux for 6 hours. After the reactionmixture was concentrated in vacuo, saturated sodium bicarbonate solutionwas added to the residue and the mixture was extracted with chloroform.The extract was dried over anhydrous magnesium sulfate and concentratedin vacuo. The resulting residue was purified on a silica gel columnchromatography (methanol/chloroform). The resulting compound wastriturated with ethyl acetate and n-hexane to give3-(1,1-dihydroxymethylethyl)4-(2-methoxyphenyl)-5-(4-thiophene-3-ylphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.105 g, yield: 77%) as colorless solid.

1H-NMR (δ ppm TMS/DMSO-d6): 0.95 (3H, s), 3.91 (2H, m), 4.57 (2H, m),6.29-7.78 (12H, m), 12.97 (1H, m).

Example 10 Preparation of 3-(1-hydroxycarbonyl-1-methylethyl)-5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

To a solution of periodic acid (0.32 mg, 1.4 mmol) in acetonitrile (15mL), a solution of3-(1-hydroxymethyl-1-methylethyl)-5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.206 g, 0.463 mmol) in dichloromethane (15 mL) andpyridiniumchlorochromate (0.01 g, 0.046 mmol) were added, and theresulting mixture was stirred at room temperature for 4 hours. After thereaction was completed, water was added to the reaction mixture, and theresulting mixture was extracted with ethyl acetate. The extract waswashed with brine, and dried over anhydrous sodium sulphate, and thenconcentrated in vacuo. To the resulting residue was addeddichloromethane, and the precipitated compound was collected byfiltration to give 3-(1-hydroxycarbonyl-1-methylethyl)-5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.11 g, yield: 49%) as pale yellow solid.

1H-NMR (8 ppm TMS/DMSO-d6): 1.19 (3H, s), 1.30 (3H, s), 3.91 (3H, brs),6.40-7.19 (6H, m), 7.66-7.80 (4H, m), 8.94 (1H, d, J=1.7), 12.50 (1H,brs), 13.55 (1H, brs).

Example 11 Preparation of5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-3-[1-(N-methylcarbamoyl)-1-methylethyl]-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one

To a mixture of 3-(1-hydroxycarbonyl-1-methylethyl)-5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.05 g, 0.11 mmol) and DMF (2 mL) were added methylamine hydrochloride(0.013 g, 0.19 mmol), 1-hydroxybenzotriazole (0.039 g, 0.29 mmol),4-dimethylaminopyridine (0.005 g, 0.04 mmol),1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloric acid (0.058g, 0.3 mmol) and triethylamine (0.040 mL, 0.29 mmol), and the resultingmixture was stirred at room temperature for 2 hours. After the reactionwas completed, water (2 mL) was added to the reaction mixture, and theresulting mixture was stirred under ice-cooling for a while. Theprecipitated compound was filtered off, and the residue was purified ona silica gel column chromatography (ethyl acetate/n-hexane) to give5-(4-isoxazolyl-3-ylphenyl)-4-(2-methoxyphenyl)-3-[1-(N-methylcarbamoyl)-1-methylethyl]-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.036 g, yield: 40%) as pale brown solid.

1H-NMR (δ ppm TMS/DMSO-d6) 1.12 (3H, s), 1.29 (3H, s), 2.43 (3H, brs),3.91 (3H, brs), 6.63-7.20 (7H, m), 7.67-7.82 (4H, m), 8.95 (1H, d,J=1.7), 13.43 (1H, brs).

Example 12 Preparation of(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-bromophenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one

To a mixture of4-(2-methylpropionyl)-3-hydroxy-1-(4-bromophenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(2.15 g, 5 mmol), (R)-methyl 2-hydroxy-2-phenylacetate (1.00 g, 6.0mmol), triphenylphosphine (1.44 g, 5.5 mmol) and dioxane (15 mL) wasadded dimethoxyethyl azodicarboxylate (1.29 g, 5.5 mmol) at roomtemperature over 1 minute, and the resulting mixture was stirred at roomtemperature for 6 hours. To the reaction mixture was added water (200mL) and the resulting mixture was extracted with ethyl acetate (200 mL).The extract was washed with brine (200 mL), dried over anhydrousmagnesium sulfate, and concentrated in vacuo. The resulting residue waspurified on a silica gel column chromatography (ethyl acetate/n-hexane).The resulting mixture of diastereomers was recrystallized (ethylacetate/n-hexane) to give the diastereomer (0.80 g, yield: 28%) as paleyellow crystalline.

A mixture of the resulting diastereomer (0.59 g, 1 mmol), lithiumchloride (0.127 g, 3 mmol) and 1,3-dimethyl-2-imidazolidinone (3 mL) wasstirred at 80° C. for 6 hours. To the reaction mixture were added water(200 mL) and 1 mol/L hydrochloric acid (3 mL), and the resulting mixturewas extracted with toluene (200 mL). The extract was washed with brine(200 mL), dried over anhydrous magnesium sulfate, and concentrated invacuo. The resulting residue was purified on a silica gel columnchromatography (ethyl acetate/n-hexane). The resulting compound wasrecrystallized (ethyl acetate/n-hexane) to give(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-bromophenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(0.40 g, yield: 93%) as pale yellow crystalline.

[α]_(D): −142.2±3.6° (in CHCl3),

1H-NMR (δ ppm TMS/DMSO-d6) 0.88 (3H, d, J=6.9), 0.91 (3H, d, J=6.9),3.33 (1H, sept, J=6.9), 3.81 (3H, brs), 6.23 (1H, brs), 6.75-7.15 (4H,m), 7.45-7.53 (4H, m), 12.00 (1H, brs).

Example 13 Preparation of(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one

After a mixture of(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-bromophenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(0.10 g, 0.23 mmol), 3-thiophene-boronic acid (0.045 g, 0.35 mmol),tripotassium phosphate (0.148 g, 0.7 mmol), 1,2-dimethoxyethane (3 mL)and water (3 mL) was placed in a flask under nitrogen,1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethane complex (0.019 g, 0.023 mmol) was added to the mixture,and the resulting mixture was stirred at reflux for 3 hours. To thereaction mixture was added water (50 mL), and the resulting mixture wasextracted with dichloromethane (50 mL). The extract was washed withbrine (50 mL), dried over anhydrous magnesium sulfate, and concentratedin vacuo. The resulting residue was purified on a silica gel columnchromatography (methanol/chloroform). The resulting compound wastriturated with ethyl acetate/n-hexane to give(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(0.029 g, yield: 29%) as pale brown powder.

[α]_(D): −57.4+1.9° (in CHCl3),

1H-NMR (δ ppm TMS/DMSO-d6) 0.89 (3H, d, J=6.9), 0.92 (3H, d, J=6.9),3.34 (1H, sept, J=6.9), 3.87 (3H, brs), 6.32 (1H, brs), 6.75-7.15 (5H,m), 7.51 (1H, d, J=1.1), 7.58-7.63 (4H, m), 7.81 (1H, m), 12.00 (1H,brs).

Example 14 Preparation of3-i-prppyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxyphenyl)-1,4,5,6-tetrahydro-1H-pyrrolo[3,4-c]pyrazole

To a mixture of3-i-propyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxyphenyl)-4,5-dihydro-1H-pyrrolo[3,4-c]pyrazole-6-one(0.72 g, 1.65 mmol) and dioxane (40 mL), lithium aluminum hydride (0.19g, 5 mmol) was added and the resulting mixture was heated at reflux for2 hours. The reaction mixture was added to a mixture of ice-water (100mL) and 2 mol/L hydrochloric acid (10 mL), and the resulting mixture wasextracted with chloroform (100 mL). The extract was washed with brine(100 mL), and dried over anhydrous sodium sulphate, and concentrated invacuo. The resulting residue was purified on a silica gel columnchromatography (methanol/chloroform). The resulting compound wastriturated with ether to give3-i-propyl-5-(4-thiophene-3-ylphenyl)-4-(2-methoxyphenyl)-1,4,5,6-tetrahydro-1H-pyrrolo[3,4-c]pyrazole(0.029 g, yield: 29%) as pale brown powder.

1H-NMR (δ ppm TMS/DMSO-d6) 0.86 (3H, d, J=7.0), 0.97 (3H, d, J=7.0),2.78 (1H, sept, J=7.0), 3.94 (3H, s), 4.42 (1H, d, J=12.6), 4.77 (1H, d,J=12.6), 6.11 (1H, d, J=2.0), 6.55-7.53 (11H, m), 12.32 (1H, s).

Example 15 Preparation of(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyethoxyphenyl)-1,5-dihydropyrrole-2-one

To a mixture of4-(2-methylpropionyl)-3-hydroxy-1-(4-bromophenyl)-5-(2-methoxymethylphenyl)-1,5-dihydropyrrole-2-one(11.0 g, 23.7 mmol), (R)-methyl 2-hydroxy-2-phenylacetate (4.73 g, 28.5mmol), triphenylphosphine (7.47 g, 28.5 mmol) and THF (150 mL) was addeddimethoxyethyl azodicarboxylate (6.67 g, 28.5 mmol) at room temperatureover 2 minutes, and the resulting mixture was stirred at roomtemperature overnight. To the reaction mixture was added water (200 mL),and the resulting mixture was extracted with toluene (200 mL). Theextract was washed with brine (200 mL), dried over anhydrous magnesiumsulfate, and concentrated in vacuo. The resulting residue was purifiedon a silica gel column chromatography (ethyl acetate/n-hexane). Theresulting mixture of diastereomers was recrystallized by ethylacetate/n-hexane to give diastereomer A (4.98 g, yield: 34%) as paleyellow crystalline.

1H-NMR (δ ppm TMS/CDCl3) 0.85 (3H, d, J=7.0), 1.15 (3H, d, J=7.0), 3.49sept, J=7.0), 3.57 (3H, brs), 3.73 (3H, s), 5.25 (2H, brs), 6.40-6.80(2H, m), 7.05-7.63 (16H, m).

To a solution of Diastereomer A (4.0 g, 6.5 mmol) in ethyl acetate (33mL) was added 2 mol/l hydrochloric acid/methanol solution (32.7 mL), andthe resulting mixture was stirred at 60° C. for 1 hour. To the reactionmixture was added water (200 mL), the resulting mixture was extractedwith ethyl acetate (200 mL). The extract was washed with brine (200 mL),dried over anhydrous magnesium sulfate, and concentrated in vacuo. Theresulting residue was purified on a silica gel column chromatography(ethyl acetate/n-hexane). The resulting mixture of diastereomers wastriturated with ethyl acetate/n-hexane to give diastereomer B (2.93 g,yield: 79%) as yellow powder.

1H-NMR (δ ppm TMS/CDCl3) 0.90 (3H, d, J=6.9), 1.24 (3H, d, J=6.9), 3.52(1H, sept, J=6.9), 3.75 (3H, s), 6.22 (1H, s), 6.68-6.75 (2H, m),6.97-7.56 (15H, m), 7.95 (1H, s).

To a mixture of Diastereomer B (2.65 g, 4.7 mmol), 2-methoxyethanol(0.71 g, 9.3 mmol), triphenylphosphine (1.84 g, 7.0 mmol) and THF (50mL) was added dimethoxyethyl azodicarboxylate (1.64 g, 7.0 mmol) at roomtemperature over 2 minutes, and the resulting mixture was stirred atroom temperature overnight. To the reaction mixture was added water (200mL), and the resulting mixture was extracted with toluene (200 mL). Theextract was washed with brine (200 mL), dried over anhydrous magnesiumsulfate, and concentrated in vacuo. The resulting residue was purifiedon a silica gel column chromatography (ethyl acetate/n-hexane) to givediastereomer C (2.44 g, yield: 84%) as yellow amorphous.

A mixture of the obtained diastereomer C (2.25 g, 3.6 mmol), lithiumchloride (0.46 g, 10.8 mmol) and 1,3-dimethyl-2-imidazolidinone (45 mL)was stirred at 100° C. for 16 hours. To the reaction mixture were addedwater (200 mL) and 2 mol/L hydrochloric acid (15 mL), and the resultingmixture was extracted with toluene (200 mL). The extract was washed withbrine (200 mL), dried over anhydrous magnesium sulfate, and concentratedin vacuo. The resulting residue was purified on a silica gel columnchromatography (methanol/chloroform). The resulting compound wastriturated with ethyl acetate/n-hexane to give(−)-4-(2-methylpropionyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyethoxyphenyl)-1,5-dihydropyrrole-2-one(1.01 g, yield: 59%) as pale yellow powder.

[α]_(D): −39.3±1.6° (in CHCl3),

1H-NMR (δ ppm TMS/DMSO-d6) 0.89 (3H, d, J=7.0), 0.93 (3H, d, J=7.0),3.44 (3H, s), 3.57 (2H, brs), 3.83 (3H, s), 4.15 (1H, m), 4.29 (1H, m),6.01 (1H, s), 6.38 (1H, s), 6.63-7.13 (4H, m), 7.40-7.76 (7H, m), 7.78(1H, m), 12.5 (1H, brs)

Example 16 Preparation of4-(i-propylsulfonyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one

To a mixture of i-propylmethylsulfone (5.17 g, 42.3 mmol) and THF (20mL) was added 28% sodium methoxide methanol solution (8.58 g, 44.5 mmol)at room temperature, and then methyl oxalate (5.0 g, 42.3 mmol) wasgradually added to the mixture at room temperature. The resultingmixture was stirred at room temperature overnight. To the reactionmixture was added ice-water (200 mL), and the pH of the resultingmixture was adjusted pH3 or less than pH3 with 2 mol/L hydrochloricacid. The mixture was extracted with ethyl acetate (200 mL). The extractwas washed with brine (200 mL), dried over anhydrous sodium sulphate,and concentrated in vacuo. The resulting residue was purified on asilica gel column chromatography (ethyl acetate/n-hexane) to give methyl3-(i-propylsulfonyl)-2-oxopropanoate (2.7 g, yield: 28%) as colorlessoil.

1H-NMR (δ ppm TMS/DMSO-d6) 1.26 (6H, d, J=6.7), 3.46 (1H, sept, J=6.7),3.81 (3H, s), 4.74 (2H, s).

A mixture of methyl 3-(i-propylsulfonyl)-2-oxopropanoate (0.23 g, 1mmol), 4-thiophene-3-ylaniline (0.18 g, 1 mmol), 2-methoxybenzaldehyde(0.14, 1 mmol), acetic acid (0.023 mL, 0.4 mmol) and toluene (3 mL) washeated at reflux overnight. After the reaction was completed, thereaction mixture was allowed to cool to room temperature. To the mixturewas added ether and precipitated compound was collected by filtration.The resulting aimed compound was washed with ether/n-hexane solution togive4-(i-propylsulfonyl)-3-hydroxy-1-(4-thiophene-3-ylphenyl)-5-(2-methoxyphenyl)-1,5-dihydropyrrole-2-one(0.37 g, yield: 79%) as pale brown solid.

1H-NMR (δ ppm TMS/DMSO-d6): 0.97-1.15 (6H, m), 3.62 (3.87) (3H, s), 6.13(6.50) (1H, s), 6.82-7.27 (3H, m), 7.48-7.81 (8H, m), 12.20 (1H, brs).

The following compounds were synthesized in a manner similar to thosedescribed in the above synthetic scheme, general, general procedures forthe synthesis of the compound of the invention, and Examples. Thechemical structure of the compounds and the physical properties of themare described below.

(Method of Identification for the Compound)

LC/MS data of compound of the present invention were measured under anyone of the following 2 conditions (Method 1 to 3), and a retention timeand [M+H]⁺ are shown.

(Method 1)

Column: Xbridge C18(5 μm, i.d. 4.6×50 mm) (Waters)

Flow rate: 3 mL/min

UV detection wavelength: 254 nm

Mobile phase: [A] is 0.1% formic acid-containing aqueous solution, and[B] is 0.1% formic acid-containing acetonitrile solution

Gradient: Linear gradient of 10% to 100% solvent[B] for 3 minutes wasperformed, and 100% solvent [B] was maintained for 1 minute.

(Method 2)

Column: Shim-pack XR-ODS (2.2 μm, i.d. 50×3.0 mm) (Shimadzu)

Flow rate: 1.6 mL/min

UV detection wavelength: 254 nm

Mobile phase: [A] is 0.1% formic acid-containing aqueous solution, and[B] is 0.1% formic acid-containing acetonitrile solution

Gradient: Linear gradient of 10% to 100% solvent[B] for 3 minutes wasperformed, and 100% solvent [B] was maintained for 1 minute.

(Method 3)

Column: Gemini-NX (5 μm, i.d. 4.6×50 mm) (Phenomenex)

Flow rate: 3 mL/min

UV detection wavelength: 254 nm

Mobile phase: [A] is 0.1% formic acid-containing aqueous solution, and[B] is 0.1% formic acid-containing acetonitrile solution

Gradient: Linear gradient of 10% to 100% solvent[B] for 3.5 minutes wasperformed, and 100% solvent [B] was maintained for 0.5 minute.

TABLE 10 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-001 438 2 2.49

I-002 503 2 2.30

I-003 488 2 2.17

I-004 488 2 2.20

I-005 420 2 1.60

TABLE 11 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-006 475 2 2.36

I-007 503 2 2.61

I-008 504 2 1.90

I-009 479 2 2.80

I-010 445 2 2.09

TABLE 12 Compound MS LC LC/MS retention Chemical Structure No. [M + H]⁺method time (min)

I-011 451 2 2.34

I-012 431 2 2.26

I-013 463 2 2.26

I-014 471 2 2.70

I-015 458 2 2.80

TABLE 13 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-016 507 2 2.77

I-017 452 2 2.03

I-018 448 2 2.23

I-019 487 2 2.47

I-020 474 2 2.55

TABLE 14 Compound MS LC LC/MS retention Chemical Structure No. [M + H]⁺method time (min)

I-021 451 2 2.31

I-022 450 2 2.22

I-023 449 2 2.19

I-024 449 2 2.23

I-025 451 2 2.25

TABLE 15 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-026 513 2 2.73

I-027 497 2 2.10

I-028 501 2 2.00

I-029 499 2 2.20

I-030 498 2 2.10

TABLE 16 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-031 489 2 2.08

I-032 498 2 2.10

I-033 498 2 1.90

I-034 493 2 1.60

I-035 470 2 1.52

TABLE 17 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-036 380 2 2.46

I-037 408 2 2.69

I-038 453 2 2.50

I-039 458 2 2.60

I-040 478 2 2.11

TABLE 18 Compound MS LC/MS Chemical Structure No. {M + H]⁺ LC methodretention time (min)

I-041 523 2 2.41

I-042 495 2 2.52

I-043 411 2 2.28

I-044 408 1 2.50

I-045 424 1 2.30

TABLE 19 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-046 422 1 2.50

I-047 466 1 2.50

I-048 433 1 2.40

I-049 449 1 2.40

I-050 461 2 2.53

TABLE 20 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-051 462 2 2.49

I-052 412 1 2.26

I-053 409 2 2.23

I-054 396 1 2.10

I-055 447 1 2.00

TABLE 21 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-056 463 1 2.10

I-057 449 1 2.20

I-058 463 1 1.80

I-059 447 1 2.20

I-060 395 2 1.51

TABLE 22 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

I-061 395 2 1.43

I-062 461 1 1.90

I-063 445 2 2.52

I-064 469 1 2.20

I-065 384 2 2.40

TABLE 23 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

I-066 413 1 2.10

I-067 410 1 1.80

I-068 428 1 1.80

I-069 400 2 2.50

I-070 446 1 2.00

TABLE 24 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-071 499 1 1.90

I-072 447 1 2.20

I-073 434 2 2.20

I-074 378 2 2.00

I-075 478 1 2.10

TABLE 25 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-076 461 2 2.27

I-077 432 2 2.54

I-078 448 2 2.65

I-079 448 2 2.69

I-080 478 1 2.10

TABLE 26 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-081 442 1 2.00

I-082 479 1 1.90

I-083 445 2 2.36

I-084 385 1 1.91

I-085 462 1 2.10

TABLE 27 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-086 2 2.05

I-087 460 2 2.40

I-088 478 1 1.90

I-089 478 1 1.80

I-090 477 1 1.90

TABLE 28 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

I-091 431 1 2.30

I-092 432 2 2.61

I-093 433 2 1.19

I-094 431 2 1.17

I-095 465 2 2.14

TABLE 29 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-096 419 1 1.90

I-097 448 2 2.20

I-098 477 1 2.10

I-099 465 2 1.80

I-100 465 2 1.90

TABLE 30 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

I-101 446 2 2.42

I-102 432 2 1.98

I-103 458 1 1.90

I-104 435 2 1.96

I-105 461 1 2.30

TABLE 31 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-106 459 2 2.70

I-107 446 2 2.21

I-108 450 2 2.30

I-109 434 2 2.16

I-110 433 1 1.80

TABLE 32 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-111 481 1 1.90

I-112 435 2 2.00

I-113 506 1 2.30

I-114 506 1 2.30

I-115 449 1 2.30

TABLE 33 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-116 449 1 2.20

I-117 433 1 2.20

I-118 433 1 2.10

I-119 492 1 2.10

I-120 492 1 2.00

TABLE 34 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-121 434 2 2.19

I-122 450 2 2.36

I-123 492 1 2.40

I-124 492 1 2.30

I-125 533 1 1.90

TABLE 35 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-126 533 1 1.90

I-127 513 1 1.70

I-128 492 1 2.10

I-129 492 1 2.10

I-130 456 1 2.20

TABLE 36 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-131 561 2 2.40

I-132 476 1 2.30

I-133 491 1 2.00

I-134 477 1 1.80

I-135 505 1 1.50

TABLE 37 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-136 505 1 1.90

I-137 490 1 1.30

I-138 493 1 2.20

I-139 478 1 1.90

I-140 418 1 1.20

TABLE 38 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-141 433 1 1.50

I-142 417 1 1.40

I-143 433 1 1.40

I-144 476 1 1.67

I-145 524 1 1.91

TABLE 39 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-146 490 1 1.81

I-147 505 2 2.36

I-148 519 2 2.39

I-149 493 1 2.30

I-150 457 1 2.10

TABLE 40 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-151 491 2 2.22

I-152 509 2 1.94

I-153 475 2 1.76

I-154 461 2 2.10

I-155 462 1 1.90

TABLE 41 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-156 476 1 2.20

I-157 491 1 1.50

I-158 491 1 1.55

I-159 434 1 2.20

I-160 464 2 2.27

TABLE 42 Compound MS LC/MS Chemical Structure No. [M + H] LC methodretention time (min)

I-161 478 2 2.56

I-162 463 1 1.70

I-163 464 1 1.60

I-164 477 1 2.10

I-165 463 1 1.80

TABLE 43 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-166 479 1 2.00

I-167 510 1 1.79

I-168 507 1 1.65

I-169 479 2 2.45

I-170 464 2 2.11

TABLE 44 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-171 443 1 1.80

I-172 479 1 2.00

I-173 463 1 1.90

I-174 479 2 2.15

I-175 479 2 2.18

TABLE 45 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-176 465 1 1.80

I-177 465 1 1.60

I-178 465 1 1.50

I-179 450 1 1.50

I-180 473 2 2.52

TABLE 46 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-181 521 1 1.79

I-182 507 1 1.51

I-183 459 1 2.11

I-184 462 1 2.05

I-185 478 1 1.90

TABLE 47 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-186 448 2 2.56

I-187 435 1 2.10

I-188 491 1 2.00

I-189 477 1 1.80

I-190 448 2 2.15

TABLE 48 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-191 449 2 1.87

I-192 482 2 2.84

I-193 462 2 2.80

I-194 449 1 1.53

I-195 479 1 1.80

TABLE 49 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-196 476 2 2.52

I-197 462 2 2.83

I-198 418 1 2.16

I-199 492 1 1.90

I-200 478 1 1.80

TABLE 50 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-201 462 1 2.14

I-202 418 1 2.17

I-203 418 1 2.17

I-204 432 2 2.45

I-205 431 2 2.48

TABLE 51 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-206 434 2 2.58

I-207 434 2 2.58

I-208 462 1 2.14

I-209 462 1 2.14

I-210 462 2 2.87

TABLE 52 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-211 458 2 2.38

I-212 475 1 1.90

I-213 464 1 2.29

I-214 434 2 2.57

I-215 448 2 2.59

TABLE 53 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-216 400 2 2.47

I-217 502 2 2.22

I-218 432 1 2.20

I-219 405 2 2.28

I-220 492 2 1.84

TABLE 54 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-221 464 2 2.61

I-222 478 1 2.26

I-223 464 1 2.04

I-224 418 2 2.51

I-225 448 2 2.21

TABLE 55 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-226 478 1 2.29

I-227 464 1 2.32

I-228 479 1 2.15

I-229 465 1 1.87

I-230 448 2 2.51

TABLE 56 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-231 462 2 2.47

I-232 448 1 2.18

I-233 449 2 2.00

I-234 462 1 1.99

I-235 452 2 2.67

TABLE 57 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-236 448 2 2.66

I-237 449 2 2.38

I-238 492 2 2.51

I-239 448 1 2.37

I-240 450 1 2.09

TABLE 58 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-241 464 1 2.03

I-242 477 1 2.39

I-243 477 2 2.05

I-244 428 1 2.12

I-245 475 1 2.10

TABLE 59 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-246 421 2 1.87

I-247 462 1 2.28

I-248 493 1 2.19

I-249 478 1 2.38

I-250 478 1 2.09

TABLE 60 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-251 492 1 2.37

I-252 462 1 2.39

I-253 434 1 1.41

I-254 448 2 2.59

I-255 448 2 2.59

TABLE 61 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-256 478 1 2.14

I-257 448 1 2.39

I-258 478 1 2.16

I-259 448 1 2.42

I-260 438 2 2.33

TABLE 62 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-261 492 2 2.70

I-262 478 2 2.71

I-263 492 2 2.73

I-264 478 2 2.75

I-265 462 2 2.73

TABLE 63 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-266 462 2 2.76

I-267 493 2 2.60

I-268 493 2 2.56

I-269 408 2 2.42

I-270 431 2 2.49

TABLE 64 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-271 478 1 2.02

I-272 464 1 1.73

I-273 492 1 2.15

I-274 478 1 1.85

I-275 478 1 1.97

TABLE 65 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-276 492 1 2.12

I-277 464 1 1.72

I-278 478 1 1.86

I-279 448 2 2.68

I-280 448 2 2.67

TABLE 66 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-281 492 1 2.30

I-282 442 1 2.37

I-283 448 1 2.40

I-284 434 2 2.50

I-285 434 2 2.50

TABLE 67 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-286 478 2 2.45

I-287 442 1 2.10

I-288 507 1 2.04

I-289 488 2 2.63

I-290 484 1 2.44

TABLE 68 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-291 449 2 2.51

I-292 486 2 2.72

I-293 476 2 2.87

I-294 434 1 1.99

I-295 477 1 2.18

TABLE 69 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-296 430 1 2.07

I-297 473 1 2.11

I-298 463 1 1.96

I-299 462 1 2.48

I-300 472 1 2.33

TABLE 70 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-301 470 1 2.35

I-302 488 1 2.39

I-303 476 1 2.54

I-304 506 1 2.53

I-305 492 1 2.51

TABLE 71 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-306 461 1 2.27

I-307 469 1 2.17

I-308 487 1 2.21

I-309 477 1 2.09

I-310 448 2 2.29

TABLE 72 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-311 464 2 2.28

I-312 462 2 2.49

I-313 470 2 2.34

I-314 488 2 2.43

I-315 462 2 2.42

TABLE 73 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-316 478 2 2.40

I-317 476 2 2.61

I-318 484 2 2.45

I-319 502 2 2.54

I-320 449 2 2.53

TABLE 74 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-321 484 2 2.73

I-322 502 2 2.80

I-323 463 1 1.83

I-324 463 1 1.69

I-325 452 1 2.27

TABLE 75 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-326 466 1 2.40

I-327 462 1 2.52

I-328 492 1 2.27

I-329 476 1 2.74

I-330 502 1 2.51

TABLE 76 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-331 488 2 2.61

I-332 449 1 2.26

I-333 484 1 2.50

I-334 502 1 2.55

I-335 512 2 2.36

TABLE 77 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-336 463 1 2.40

I-337 498 1 2.56

I-338 516 1 2.67

I-339 447 2 2.47

I-340 433 1 2.10

TABLE 78 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-341 483 2 2.53

I-342 468 1 2.30

I-343 486 1 2.40

I-344 501 2 2.59

I-345 477 2 2.19

TABLE 79 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-346 491 2 2.46

I-347 446 1 2.25

I-348 476 1 2.21

I-349 462 1 2.26

I-350 462 1 1.98

TABLE 80 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-351 432 1 2.27

I-352 437 1 1.92

I-353 433 1 2.09

I-354 432 2 2.53

I-355 446 2 2.64

TABLE 81 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-356 462 2 2.67

I-357 477 1 2.16

I-358 468 1 2.41

I-359 486 1 2.46

I-360 491 1 2.29

TABLE 82 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-361 482 1 2.47

I-362 500 1 2.56

I-363 496 1 2.26

I-364 510 1 2.39

I-365 510 1 2.11

TABLE 83 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-366 492 1 2.12

I-367 480 1 2.15

I-368 494 1 2.27

I-369 496 1 2.00

I-370 475 1 2.38

TABLE 84 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-371 463 2 2.67

I-372 492 2 2.81

I-373 490 2 2.97

I-374 492 2 2.51

I-375 506 2 2.79

TABLE 85 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-376 476 2 2.83

I-377 498 1 2.52

I-378 516 1 2.61

I-379 462 1 2.52

I-380 460 1 2.48

TABLE 86 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-381 490 1 2.40

I-382 476 1 2.45

I-383 446 1 2.43

I-384 476 1 2.18

I-385 437 1 1.91

TABLE 87 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-386 476 2 2.32

I-387 433 2 2.18

I-388 477 2 2.17

I-389 447 2 2.19

I-390 447 2 2.30

TABLE 88 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-391 491 2 2.32

I-392 461 2 2.35

I-393 462 1 2.47

I-394 448 1 2.29

I-395 479 1 2.11

TABLE 89 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-396 460 1 2.52

I-397 473 1 2.17

I-398 474 1 2.65

I-399 487 1 2.25

I-400 476 1 2.61

TABLE 90 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-401 489 1 2.27

I-402 490 1 2.70

I-403 513 2 2.00

I-404 503 2 2.64

I-405 489 2 2.51

TABLE 91 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-406 503 1 2.38

I-407 476 2 2.67

I-408 460 1 2.44

I-409 489 2 2.53

I-410 495 1 1.97

TABLE 92 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-411 476 1 2.09

I-412 451 1 2.00

I-413 479 1 2.21

I-414 465 1 2.02

I-415 545 1 2.58

TABLE 93 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-416 435 2 2.27

I-417 479 2 2.27

I-418 449 2 2.28

I-419 476 2 2.89

I-420 449 2 2.39

TABLE 94 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-421 493 2 2.40

I-422 463 2 2.41

I-423 449 2 2.41

I-424 493 2 2.39

I-425 463 2 2.42

TABLE 95 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-426 463 2 2.53

I-427 507 2 2.52

I-428 477 2 2.55

I-429 478 1 2.00

I-430 473 1 2.08

TABLE 96 LC/MS Chemical Compound MS LC retention Structure No. [M + H]⁺method time (min)

I-431 462 1 2.26

I-432 462 1 1.97

I-433 479 1 2.08

I-434 413 2 2.52

I-435 456 2 2.48

TABLE 97 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-436 440 2 2.71

I-437 426 2 2.55

I-438 450 2 2.91

I-439 488 2 2.85

I-440 463 1 2.32

TABLE 98 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-441 449 1 2.18

I-442 503 1 2.37

I-443 489 1 2.26

I-444 478 1 1.75

I-445 492 1 1.84

TABLE 99 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-446 510 1 2.50

I-447 494 1 2.69

I-448 480 1 2.51

I-449 476 1 2.62

I-450 461 1 2.31

TABLE 100 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-451 476 1 2.38

I-452 452 1 2.23

I-453 466 1 2.41

I-454 450 1 2.30

I-455 462 2 2.72

TABLE 101 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-456 508 2 2.12

I-457 433 2 2.36

I-458 447 2 2.39

I-459 449 1 2.44

I-460 469 2 2.04

TABLE 102 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-461 483 2 2.04

I-462 463 2 2.61

I-463 507 2 2.64

I-464 449 1 2.19

I-465 492 2 2.73

TABLE 103 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-466 503 2 2.61

I-467 468 2 2.38

I-468 440 2 2.23

I-469 497 2 2.88

I-470 520 2 2.70

TABLE 104 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-471 491 1 2.24

I-472 493 2 2.60

I-473 398 2 2.38

I-474 426 2 2.61

I-475 442 2 2.36

TABLE 105 LC/MS Compound MS LC retention Chemical Structure No. [M + H]⁺method time (min)

I-476 442 2 2.12

I-477 412 2 2.39

I-478 477 1 1.89

I-479 461 1 2.39

I-480 497 2 2.32

TABLE 106 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-481 477 2 2.35

I-482 465 2 2.41

I-483 463 1 1.89

I-484 456 2 2.47

I-485 443 2 2.24

TABLE 107 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-486 487 1 2.28

I-487 489 1 1.97

I-488 503 1 2.07

I-489 492 1 2.32

I-490 506 1 2.39

TABLE 108 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-491 492 1 2.06

I-492 506 1 2.15

I-493 487 1 1.98

I-494 503 2 2.65

I-495 487 2 2.59

TABLE 109 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-496 531 2 2.63

I-497 547 2 2.70

I-498 522 2 2.23

I-499 480 2 2.44

I-500 520 2 2.63

TABLE 110 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-501 506 2 2.24

I-502 504 1 1.96

I-503 487 1 2.34

I-504 519 1 2.39

I-505 545 2 2.61

TABLE 111 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-506 529 2 2.55

I-507 496 2 2.45

I-508 459 2 2.11

I-509 423 2 2.20

I-510 474 2 2.21

TABLE 112 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-511 437 2 2.29

I-512 473 1 2.36

I-513 487 1 2.49

I-514 501 1 2.24

I-515 475 1 2.38

TABLE 113 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-516 474 1 2.43

I-517 505 1 2.26

I-518 488 1 2.39

I-519 502 1 2.55

I-520 476 1 1.70

TABLE 114 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-521 490 1 1.96

I-522 491 1 1.71

I-523 505 1 1.98

I-524 490 1 1.65

I-525 490 1 1.91

TABLE 115 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-526 529 2 2.43

I-527 432 1 2.46

I-528 434 1 2.50

I-529 477 1 1.76

I-530 504 1 2.30

TABLE 116 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-531 436 2 2.28

I-532 480 2 2.25

I-533 464 2 2.51

I-534 515 1 1.75

I-535 487 1 1.89

TABLE 117 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-536 473 1 1.80

I-537 501 2 2.25

I-538 515 2 2.31

I-539 476 1 2.27

I-540 461 1 2.23

TABLE 118 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-541 476 1 2.51

I-542 478 1 2.12

I-543 463 1 2.09

I-544 478 1 2.37

I-545 478 1 2.14

TABLE 119 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-546 531 2 2.52

I-547 533 2 2.53

I-548 480 2 2.38

I-549 515 2 2.44

I-550 457 2 2.22

TABLE 120 Compound MS LC LC/MS Chemical Structure No. [M + H]⁺ methodretention time (min)

I-551 506 2 2.39

I-552 476 1 2.32

I-553 471 2 2.37

I-554 418 2 2.08

I-555 433 2 2.11

TABLE 121 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-556 506 2 2.43

I-557 492 2 2.19

I-558 450 2 2.53

I-559 464 2 2.65

I-560 510 2 2.35

TABLE 122 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-561 495 2 2.31

I-562 479 2 2.19

I-563 514 2 2.20

I-564 479 1 1.83

I-565 493 1 2.14

TABLE 123 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-566 463 1 1.72

I-567 477 1 2.02

I-568 493 2 2.21

I-569 507 2 2.54

I-570 493 2 2.19

TABLE 124 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-571 507 2 2.51

I-572 476 3 3.28

I-573 490 3 3.35

I-574 504 3 3.32

I-575 518 3 3.41

TABLE 125 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-576 519 3 3.40

I-577 515 3 3.24

I-578 518 3 3.68

I-579 530 3 3.45

I-580 546 3 3.40

TABLE 126 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-581 534 3 3.50

I-582 548 3 3.37

I-583 547 3 2.43

I-584 519 2 2.17

I-585 503 2 2.10

TABLE 127 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-586 517 2 2.39

I-587 487 2 2.24

I-588 459 1 2.20

I-589 438 1 2.34

I-590 503 1 2.01

TABLE 128 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-591 482 1 2.15

I-592 475 1 1.52

I-593 489 1 1.60

I-594 517 1 1.83

I-595 503 1 1.75

TABLE 129 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

I-596 487 2 1.82

I-598 501 2 2.27

I-598 501 2 2.27

TABLE 130 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-001 404 1 2.30

II-002 420 1 2.10

II-003 418 1 2.40

II-004 462 1 2.40

II-005 459 1 1.90

TABLE 131 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-006 443 1 1.80

II-007 409 1 1.90

II-008 406 1 1.50

II-009 424 1 1.70

II-010 466 1 1.90

TABLE 132 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-011 421 1 1.30

II-012 474 1 2.00

II-013 438 1 1.80

II-014 475 1 1.70

II-015 473 1 1.70

TABLE 133 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-016 474 1 1.70

II-017 474 1 1.70

II-018 473 1 1.90

II-019 457 1 2.10

II-020 502 1 2.10

TABLE 134 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-021 502 1 2.10

II-022 488 1 1.80

II-023 488 1 1.80

II-024 488 1 1.90

II-025 488 1 1.90

TABLE 135 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-026 452 1 2.00

II-027 472 1 2.10

II-028 487 1 1.80

II-029 473 1 1.60

II-030 486 1 1.20

TABLE 136 LC/MS Com- MS LC retention pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-031 501 1 1.50

II-032 489 1 2.00

II-033 474 1 1.70

II-034 453 1 1.80

II-035 489 1 2.10

TABLE 137 LC/MS Com- MS LC retention pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-036 460 1 1.50

II-037 473 1 2.00

II-038 473 1 1.90

II-039 475 1 1.80

II-040 439 1 1.60

Table 138 LC/MS reten- Com- MS LC tion pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-041 459 1 1.70

II-042 475 1 1.80

II-043 459 1 1.70

II-044 446 1 1.40

II-045 461 1 1.70

TABLE 139 LC/MS reten- Com- MS LC tion pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-046 461 1 1.40

II-047 474 1 1.80

II-048 431 1 2.00

II-049 487 1 1.80

II-050 473 1 1.70

TABLE 140 LC/MS Com- MS LC retention pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-051 488 1 1.60

II-052 475 1 1.70

II-053 488 1 1.70

II-054 474 1 1.60

II-055 427 2 2.13

TABLE 141 LC/MS Com- MS LC retention pound [M + meth- time ChemicalStructure No. H]⁺ od (min)

II-056 509 1 2.43

II-057 434 1 2.09

II-058 416 1 1.23

II-059 447 1 1.93

II-060 459 2 2.07

TABLE 142 LC/MS reten- Com- LC tion pound MS meth- time ChemicalStructure No. [M + H]⁺ od (min)

II-061 483 2 2.23

II-062 447 2 2.08

II-063 447 1 1.9 

II-064 485 1 1.76

II-065 466 1 1.36

TABLE 143 LC/MS Com- retention pound MS LC time Chemical Structure No.[M + H]⁺ method (min)

II-066 426 1 2.47

II-067 416 1 2.43

II-068 457 1 1.93

II-069 458 1 1.88

II-070 440 1 1.68

TABLE 144 LC/MS Com- retention pound MS LC time Chemical Structure No.[M + H]⁺ method (min)

II-071 424 1 1.49

II-072 419 1 1.25

II-073 443 1 2.03

II-074 431 1 1.55

II-075 472 1 1.48

TABLE 145 LC/MS Com- reten- pound MS LC tion Chemical Structure No. [M +H]⁺ method time (min)

II-076 520 1 1.76

II-077 486 1 1.55

II-078 487 1 1.39

II-079 430 1 1.91

II-080 506 1 1.69

TABLE 146 LC/MS Com- retention pound MS LC time Chemical Structure No.[M + H]⁺ method (min)

II-081 415 1 1.96

II-082 471 1 1.78

II-083 428 1 2.09

II-084 457 1 1.23

II-085 457 1 1.72

TABLE 147 LC/MS Com- retention pound MS LC time Chemical Structure No.[M + H]⁺ method (min)

II-086 430 1 1.79

II-087 458 1 1.58

II-088 493 1 1.76

II-089 444 1 1.77

II-090 443 1 1.62

TABLE 148 LC/MS Com- retention pound MS LC time Chemical Structure No.[M + H]⁺ method (min)

II-091 487 1 1.55

II-092 457 1 1.74

II-093 471 1 1.86

II-094 458 1 1.75

II-095 473 1 1.87

TABLE 149 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-096 425 1 2.30

II-097 446 1 2.20

II-098 392 1 1.90

II-099 445 1 2.00

II-100 459 1 1.60

TABLE 150 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-101 443 1 2.00

II-102 465 1 1.90

II-103 495 1 1.60

II-104 474 1 1.90

II-105 458 1 1.90

TABLE 151 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-106 427 1 2.40

II-107 415 1 1.60

II-108 454 1 1.70

II-109 461 1 1.70

II-110 461 1 1.80

TABLE 152 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-111 445 1 1.70

II-112 477 1 1.60

II-113 429 1 1.60

II-114 488 1 2.20

II-115 488 1 2.20

TABLE 153 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-116 509 1 1.70

II-117 529 1 1.90

II-118 529 1 2.00

II-119 442 1 2.00

II-120 414 1 1.10

TABLE 154 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-121 429 1 1.50

II-122 413 1 1.40

II-123 429 1 1.50

II-124 458 1 1.60

II-125 472 1 1.80

TABLE 155 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-126 459 1 1.70

II-127 455 1 1.95

II-128 517 1 1.72

II-129 503 1 1.48

II-130 504 1 1.88

TABLE 156 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-131 458 1 1.81

II-132 489 1 1.56

II-133 445 1 1.67

II-134 391 2 1.37

II-135 391 2 1.31

TABLE 157 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-136 459 2 1.90

II-137 460 2 1.90

II-138 460 2 1.90

II-139 435 2 2.20

II-140 465 2 2.10

TABLE 158 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

II-141 461 2 1.90

II-142 465 2 2.20

II-143 419 2 2.10

II-144 432 2 1.90

II-145 473 2 1.70

TABLE 159 Com- MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

II-146 458 2 1.98

II-147 486 2 1.96

II-148 441 2 2.07

II-149 413 2 1.85

II-150 406 2 1.88

TABLE 160 Com- LC/MS pound MS LC retention Chemical Structure No. [M +H]⁺ method time (min)

II-151 420 2 2.03

II-152 433 2 1.97

II-153 419 2 1.79

II-154 449 2 1.97

II-155 404 2 2.07

TABLE 161 Com MS LC/MS pound [M + LC retention Chemical Structure No.H]⁺ method time (min)

II-156 433 2 2.40

II-157 458 2 1.77

II-158 486 2 1.21

II-159 472 2 1.20

II-160 420 2 2.41

TABLE 162 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-161 449 2 1.88

II-162 406 2 1.57

II-163 474 2 2.16

II-164 431 2 1.86

II-165 474 2 2.13

TABLE 163 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-166 515 2 2.19

II-167 501 2 2.12

II-168 505 2 1.76

II-169 487 2 2.03

II-170 487 2 2.06

TABLE 164 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-171 551 2 2.23

II-172 501 2 2.19

II-173 469 2 2.39

II-174 512 2 2.40

II-175 498 2 2.05

TABLE 165 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-176 501 2 2.10

II-177 428 2 1.97

II-178 454 2 2.42

II-179 432 2 2.10

II-180 459 2 2.15

TABLE 166 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-181 445 2 2.14

II-182 418 2 2.13

II-183 396 2 2.30

II-184 488 2 2.27

II-185 488 2 1.79

TABLE 167 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-186 473 2 2.23

II-187 421 2 1.92

II-188 430 2 2.25

II-189 459 2 2.40

II-190 413 2 2.70

TABLE 168 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-191 444 2 2.06

II-192 448 2 1.83

II-193 446 2 2.06

II-194 445 2 2.04

II-195 445 2 2.08

TABLE 169 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-196 376 2 2.17

II-197 404 2 2.43

II-198 519 2 2.34

II-199 491 2 2.37

II-200 407 2 2.22

TABLE 170 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-201 408 2 2.35

II-202 405 2 1.94

II-203 428 2 2.40

II-204 444 2 2.50

II-205 441 2 2.40

TABLE 171 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-206 442 2 2.00

II-207 583 2 3.30

II-208 438 2 2.50

II-209 429 2 2.10

II-210 442 2 2.30

TABLE 172 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-211 540 2 3.10

II-212 441 2 2.40

II-213 444 2 2.60

II-214 362 2 2.20

II-215 444 2 2.10

TABLE 173 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-216 457 2 2.10

II-217 460 2 2.20

II-218 460 2 2.20

II-219 444 2 2.00

II-220 429 2 2.20

TABLE 174 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-221 380 2 2.20

II-222 396 2 2.30

II-223 445 2 2.40

II-224 445 2 2.40

II-225 430 2 2.20

TABLE 175 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-226 445 2 1.80

II-227 445 2 1.80

II-228 483 2 2.40

II-229 498 2 2.20

II-230 524 2 1.40

TABLE 176 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-231 444 2 2.00

II-232 443 2 1.70

II-233 401 2 2.12

II-234 431 2 1.85

II-235 460 2 2.50

TABLE 177 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-236 490 2 1.88

II-237 487 2 2.07

II-238 448 2 2.56

II-239 444 2 2.55

II-240 445 2 2.24

TABLE 178 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-241 488 2 2.39

II-242 473 2 1.93

II-243 460 2 2.18

II-244 473 2 2.51

II-245 522 2 2.12

TABLE 179 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-246 441 2 2.46

II-247 429 2 2.37

II-248 445 2 2.52

II-249 457 2 2.09

II-250 445 2 1.98

TABLE 180 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-251 461 2 1.18

II-252 441 2 2.20

II-253 429 2 1.90

II-254 445 2 2.06

II-255 445 2 2.13

TABLE 181 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-256 445 2 2.55

II-257 429 2 2.44

II-258 461 2 1.56

II-259 442 2 2.39

II-260 446 2 2.47

TABLE 182 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-261 430 2 2.25

II-262 446 2 2.41

II-263 430 2 2.36

II-264 461 2 2.20

II-265 445 2 2.09

TABLE 183 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-266 476 2 1.93

II-267 442 2 2.05

II-268 446 2 2.09

II-269 430 2 1.94

II-270 446 2 2.20

TABLE 184 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-271 430 2 2.03

II-272 478 2 2.70

II-273 458 2 2.65

II-274 458 2 2.68

II-275 458 2 2.74

TABLE 185 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-276 461 2 1.60

II-277 503 2 1.98

II-278 475 2 2.29

II-279 460 2 1.94

II-280 475 2 1.98

TABLE 186 Compound MS LC/MS Chemical Structure No. [M + H]⁺ LC methodretention time (min)

II-281 475 2 2.03

Test Examples

Stably expressing cell line (C6BU-1 cell transfected with human P2X₃receptor gene (GenBank accession number Y07683)) was used. The cellswere seeded in a 96-well microtiter plate at a concentration of 8000cells/well and cultured in the medium (8.3% fetal bovine serum, 8.3%horse serum, 1% antibiotic and antifungal in DMEM) for one day at 37° C.under 5% carbon dioxide atmosphere. The medium was replaced with 4 μMFluo-3-AM solution (pH7.5) containing 20 mM HEPES, 137 mM NaCl, 2.7 mMKCl, 0.9 mM MgCl₂, 5.0 mM CaCl₂, 5.6 mM D-glucose, 2.5 mM probenecid,10% BSA, and 0.08% Pluronic F-127, and incubated at 37° C. under 5%dioxide carbon atmosphere for one hour. The plate was washed withwashing buffer (20 mM HEPES, 137 mM NaCl, 2.7 mM KCl, 0.9 mM MgCl₂, 5.0mM CaCl₂, 5.6 mM D-glucose, 2.5 mM probenecid, pH7.5), and each well wasadded with 40 μL of this buffer. The plate was placed in High-ThroughputScreening System FDSS 3000 (Hamamatsu Photonics K.K.). Measurement offluorescence intensity by FDSS 3000 was started, and 40 p. 1.4 of DMSOsolutions containing different concentrations of the test compound asprepared by dilution with dilution buffer (20 mM HEPES, 137 mM NaCl, 2.7mM KCl, 0.9 mM MgCl₂, 5.0 mM CaCl₂, 5.6 mM D-glucose, 2.5 mM probenecid,0.1% Pluronic F-127, pH7.5) were dispensed to each well through thebuilt-in automatic dispenser. Five minutes after, 40 nM ATP solution (50μL) prepared by dilution with the dilution buffer was dispensed throughthe built-in automatic dispenser, and the measurement of fluorescenceintensity was continued for 3 min. For each well, the specific maximumfluorescence intensity was calculated as the ratio of the maximumfluorescence intensity after addition of the ATP solution to thefluorescence intensity at the starting of the measurement. The 50%inhibitory concentration (IC₅₀) was calculated under the assumption thatthe specific maximum fluorescence intensity without test compound is 0%inhibition and that the specific maximum fluorescence intensity when thedilution buffer was added in place of ATP solution is 100% inhibition,to evaluate the inhibitory activity of the test compound. FDSS software(Hamamatsu Photonics K.K.) was used for calculation of the specificmaximum fluorescence intensity. 1050 was calculated using Microsoft™Excel™ (Microsoft Corporation) and XLfit™ (ID Business Solutions Ltd.).

The results of the compounds of the invention are shown in the followingtables.

TABLE 187 Compound P2X3 No. IC50 (μM) I-001 0.032 I-002 0.024 I-0030.040 I-004 0.012 I-005 0.247 I-006 0.027 I-007 0.100 I-008 0.014 I-0090.014 I-010 0.595 I-011 0.270 I-012 0.340 I-014 0.134 I-015 0.012 I-0160.079 I-019 0.132 I-020 0.021 I-021 0.382 I-026 0.339 I-027 0.040 I-0280.075 I-029 0.160 I-030 0.053 I-031 0.700 I-032 0.160 I-033 0.053 I-0340.700 I-037 0.954 I-038 0.926 I-039 0.012 I-044 0.468 I-046 0.580 I-0470.221 I-048 0.752 I-050 0.642 I-051 0.277 I-052 0.187 I-055 0.596 I-0570.159 I-058 0.082 I-059 0.260 I-064 0.137 I-066 0.434 I-068 0.305 I-0700.519 I-072 0.352 I-075 0.013 I-077 0.048 I-078 0.016 I-225 0.065 I-2260.012 I-227 0.008 I-228 0.015 I-229 0.029 I-230 0.018 I-231 0.023 I-2320.024 I-233 0.124 I-234 0.056 I-235 0.035 I-236 0.431 I-237 0.705 I-2390.035 I-240 0.185 I-241 0.822 I-242 0.357 I-244 0.027 I-245 0.047 I-2470.015 I-248 0.030 I-249 0.010 I-250 0.029 I-251 0.017 I-252 0.010 I-2530.193 I-254 0.511 I-255 0.008 I-256 0.023 I-257 0.037 I-258 0.024 I-2590.030 I-260 0.331 I-261 0.019 I-262 0.016 I-263 0.008 I-264 0.014 I-2650.028 I-266 0.025 I-267 0.014 I-268 0.032 I-269 0.347 I-271 0.542 I-2730.491 I-275 0.172 I-276 0.117 I-277 0.342 I-278 0.366 I-279 0.016 I-4160.322 I-417 0.181 I-418 0.593 I-419 0.032 I-420 0.257 I-421 0.191 I-4220.361 I-424 0.519 I-425 0.697 I-427 0.331 I-428 0.399 I-429 0.007 I-4300.153 I-431 0.232 I-433 0.425 I-434 0.125 I-435 0.082 I-436 0.042 I-4370.111 I-438 0.490 I-439 0.116 I-440 0.035 I-441 0.013 I-442 0.005 I-4430.006 I-444 0.172 I-445 0.152 I-446 0.338 I-447 0.128 I-448 0.246 I-4490.013 I-450 0.036 I-451 0.019 I-452 0.026 I-453 0.041 I-454 0.036 I-4550.014 I-456 0.006 I-457 0.488 I-458 0.699 I-459 0.026 I-460 0.103 I-4610.036 I-462 0.427 I-463 0.127 I-464 0.453 I-465 0.007 I-466 0.260 I-4670.286

TABLE 188 Compound P2X3 No. IC50 (μM) I-079 0.023 I-080 0.016 I-0810.151 I-082 0.650 I-085 0.048 I-089 0.700 I-090 0.555 I-091 0.341 I-0920.092 I-093 0.756 I-094 0.301 I-095 0.195 I-098 0.370 I-102 0.134 I-1030.355 I-104 0.424 I-105 0.097 I-108 0.192 I-111 0.624 I-112 0.388 I-1130.012 I-114 0.012 I-115 0.108 I-116 0.077 I-117 0.383 I-118 0.282 I-1190.098 I-120 0.074 I-122 0.342 I-123 0.013 I-124 0.011 I-125 0.110 I-1260.015 I-127 0.049 I-128 0.155 I-129 0.091 I-130 0.476 I-131 0.251 I-1320.043 I-133 0.367 I-134 0.776 I-135 0.015 I-136 0.015 I-137 0.615 I-1380.016 I-139 0.930 I-141 0.346 I-142 0.315 I-143 0.331 I-280 0.477 I-2810.637 I-282 0.472 I-283 0.144 I-284 0.300 I-285 0.648 I-286 0.669 I-2880.036 I-290 0.051 I-291 0.130 I-292 0.127 I-293 0.012 I-295 0.054 I-2960.244 I-297 0.220 I-298 0.269 I-299 0.008 I-300 0.114 I-301 0.018 I-3020.034 I-303 0.031 I-304 0.021 I-305 0.020 I-306 0.054 I-307 0.158 I-3080.193 I-309 0.182 I-310 0.337 I-311 0.121 I-312 0.054 I-313 0.320 I-3140.329 I-315 0.252 I-316 0.130 I-317 0.073 I-318 0.328 I-319 0.222 I-3200.274 I-321 0.070 I-322 0.102 I-323 0.310 I-324 0.109 I-325 0.018 I-3260.027 I-327 0.093 I-328 0.065 I-329 0.578 I-330 0.070 I-331 0.722 I-4680.467 I-469 0.646 I-470 0.972 I-471 0.019 I-472 0.007 I-473 0.182 I-4740.071 I-475 0.181 I-476 0.051 I-477 0.477 I-478 0.034 I-479 0.010 I-4800.042 I-481 0.378 I-482 0.333 I-483 0.089 I-484 0.091 I-485 0.218 I-4860.004 I-487 0.167 I-488 0.067 I-489 0.006 I-490 0.017 I-491 0.155 I-4920.104 I-493 0.105 I-494 0.053 I-495 0.059 I-496 0.055 I-497 0.036 I-4980.008 I-499 0.398 I-500 0.012 I-501 0.052 I-502 0.067 I-503 0.017 I-5040.238 I-505 0.168 I-506 0.112 I-507 0.101 I-508 0.133 I-509 0.247 I-5100.174 I-511 0.117 I-512 0.062 I-513 0.065 I-514 0.138 I-515 0.037 I-5160.033

TABLE 189 Compound P2X3 No. IC50 (μM) I-144 0.365 I-145 0.016 I-1460.727 I-147 0.017 I-148 0.073 I-149 0.015 I-150 0.415 I-151 0.008 I-1520.219 I-153 0.216 I-154 0.192 I-155 0.035 I-156 0.032 I-157 0.025 I-1580.023 I-159 0.016 I-160 0.013 I-161 0.007 I-162 0.041 I-164 0.074 I-1650.095 I-166 0.019 I-167 0.013 I-168 0.120 I-169 0.019 I-171 0.610 I-1720.024 I-173 0.137 I-174 0.572 I-176 0.046 I-178 0.374 I-179 0.659 I-1800.005 I-181 0.114 I-183 0.004 I-184 0.163 I-185 0.111 I-186 0.013 I-1870.086 I-188 0.022 I-189 0.014 I-190 0.040 I-191 0.279 I-192 0.612 I-1930.994 I-194 0.063 I-195 0.235 I-197 0.036 I-198 0.064 I-332 0.281 I-3330.058 I-334 0.078 I-336 0.351 I-337 0.103 I-338 0.147 I-339 0.892 I-3400.336 I-341 0.508 I-342 0.067 I-343 0.078 I-344 0.594 I-345 0.999 I-3460.677 I-347 0.047 I-348 0.055 I-349 0.037 I-350 0.066 I-351 0.101 I-3530.210 I-354 0.057 I-355 0.044 I-356 0.007 I-357 0.020 I-358 0.025 I-3590.024 I-360 0.021 I-361 0.048 I-362 0.040 I-363 0.007 I-364 0.009 I-3650.082 I-366 0.013 I-367 0.019 I-368 0.016 I-369 0.091 I-370 0.194 I-3710.447 I-372 0.035 I-373 0.051 I-374 0.040 I-375 0.030 I-376 0.025 I-3770.148 I-378 0.192 I-379 0.118 I-380 0.007 I-381 0.007 I-382 0.006 I-5170.026 I-518 0.087 I-519 0.033 I-521 0.554 I-523 0.351 I-524 0.696 I-5250.018 I-526 0.219 I-527 0.039 I-528 0.070 I-530 0.237 I-531 0.286 I-5320.204 I-533 0.033 I-535 0.049 I-536 0.032 I-537 0.083 I-538 0.119 I-5390.062 I-540 0.496 I-541 0.010 I-542 0.058 I-543 0.240 I-544 0.008 I-5450.142 I-546 0.395 I-547 0.217 I-548 0.077 I-549 0.213 I-550 0.254 I-5510.005 I-552 0.186 I-553 0.337 I-555 0.579 I-556 0.032 I-557 0.444 I-5580.008 I-559 0.040 I-560 0.275 I-562 0.101 I-563 0.042 I-564 0.018 I-5650.013 I-566 0.061 I-567 0.057 I-568 0.066 I-569 0.035 I-570 0.070 I-5710.060

TABLE 190 Compound P2X3 No. IC50 (μM) I-199 0.019 I-200 0.014 I-2010.039 I-202 0.040 I-204 0.043 I-206 0.630 I-207 0.008 I-208 0.014 I-2090.234 I-210 0.047 I-211 0.157 I-212 0.092 I-213 0.006 I-214 0.022 I-2150.013 I-216 0.679 I-217 0.012 I-218 0.073 I-219 0.324 I-220 0.005 I-2210.081 I-222 0.006 I-223 0.012 I-224 0.073 I-383 0.036 I-384 0.019 I-3850.227 I-391 0.684 I-392 0.946 I-393 0.015 I-394 0.011 I-395 0.006 I-3960.007 I-397 0.122 I-398 0.014 I-399 0.044 I-400 0.022 I-401 0.079 I-4020.080 I-404 0.071 I-405 0.031 I-406 0.029 I-408 0.018 I-409 0.177 I-4100.151 I-412 0.310 I-413 0.042 I-414 0.268 I-572 0.171 I-573 0.123 I-5740.280 I-575 0.252 I-576 0.237 I-577 0.047 I-578 0.386 I-579 0.429 I-5810.466 I-582 0.359 I-583 0.010 I-584 0.167 I-585 0.157 I-586 0.254 I-5870.374 I-588 0.029 I-589 0.032 I-590 0.028 I-591 0.031 I-592 0.827 I-5930.811 I-594 0.715 I-597 0.668 I-598 0.785

TABLE 191 Compound P2X3 No. IC50 (μM) II-001 0.104 II-002 0.217 II-0030.140 II-004 0.378 II-006 0.245 II-007 0.062 II-008 0.505 II-009 0.054II-010 0.134 II-011 0.319 II-012 0.004 II-013 0.019 II-014 0.017 II-0150.087 II-016 0.158 II-017 0.054 II-018 0.022 II-019 0.021 II-020 0.008II-021 0.009 II-022 0.004 II-023 0.004 II-024 0.062 II-025 0.015 II-0260.023 II-027 0.008 II-028 0.014 II-029 0.090 II-030 0.128 II-031 0.018II-032 0.006 II-033 0.117 II-034 0.046 II-035 0.006 II-036 0.231 II-0370.008 II-038 0.014 II-039 0.005 II-040 0.070 II-041 0.027 II-042 0.010II-043 0.017 II-044 0.582 II-045 0.016 II-046 0.861 II-047 0.011 II-0480.057 II-049 0.011 II-050 0.007 II-088 0.004 II-089 0.107 II-090 0.002II-091 0.002 II-092 0.002 II-093 0.002 II-094 0.065 II-095 0.012 II-0960.223 II-097 0.358 II-098 0.761 II-099 0.046 II-100 0.031 II-101 0.027II-102 0.076 II-104 0.003 II-105 0.013 II-106 0.226 II-107 0.114 II-1080.015 II-109 0.021 II-110 0.024 II-111 0.091 II-112 0.389 II-113 0.838II-114 0.012 II-115 0.011 II-117 0.348 II-118 0.429 II-119 0.137 II-1210.464 II-123 0.431 II-124 0.008 II-125 0.010 II-126 0.221 II-127 0.004II-128 0.216 II-130 0.004 II-131 0.088 II-132 0.141 II-133 0.116 II-1360.055 II-137 0.148 II-138 0.044 II-139 0.332 II-141 0.022 II-142 0.104II-145 0.033 II-146 0.416 II-189 0.897 II-191 0.322 II-192 0.222 II-1930.195 II-194 0.392 II-195 0.944 II-196 0.783 II-197 0.106 II-198 0.123II-199 0.113 II-200 0.448 II-201 0.033 II-202 0.076 II-203 0.028 II-2040.017 II-205 0.811 II-208 0.112 II-209 0.087 II-210 0.811 II-211 0.135II-212 0.238 II-213 0.011 II-215 0.015 II-216 0.473 II-217 0.003 II-2180.005 II-219 0.014 II-220 0.069 II-223 0.023 II-224 0.031 II-225 0.979II-227 0.034 II-229 0.082 II-231 0.344 II-232 0.016 II-233 0.092 II-2340.130 II-235 0.017 II-236 0.005 II-237 0.853 II-238 0.019 II-239 0.205II-240 0.116 II-241 0.213 II-242 0.152 II-243 0.138 II-244 0.144 II-2450.006 II-246 0.871

TABLE 192 Compound P2X3 No. IC50 (μM) II-051 0.005 II-052 0.033 II-0530.035 II-054 0.026 II-055 0.548 II-057 0.017 II-058 0.494 II-059 0.046II-060 0.538 II-061 0.166 II-062 0.112 II-064 0.075 II-067 0.153 II-0680.508 II-069 0.414 II-072 0.739 II-073 0.105 II-074 0.032 II-075 0.153II-076 0.012 II-077 0.237 II-078 0.016 II-079 0.011 II-080 0.011 II-0810.189 II-082 0.044 II-083 0.024 II-084 0.018 II-085 0.023 II-086 0.032II-087 0.009 II-147 0.977 II-148 0.311 II-149 0.377 II-151 0.650 II-1550.322 II-156 0.412 II-157 0.524 II-158 0.650 II-159 0.360 II-163 0.034II-164 0.036 II-165 0.041 II-166 0.007 II-167 0.005 II-168 0.101 II-1690.004 II-170 0.034 II-171 0.007 II-172 0.011 II-173 0.004 II-174 0.003II-175 0.003 II-176 0.010 II-178 0.149 II-180 0.262 II-181 0.301 II-1820.060 II-183 0.460 II-184 0.012 II-185 0.011 II-188 0.156 II-247 0.033II-248 0.013 II-250 0.043 II-251 0.008 II-253 0.020 II-254 0.002 II-2550.003 II-256 0.018 II-257 0.033 II-258 0.304 II-259 0.410 II-260 0.036II-261 0.140 II-262 0.039 II-263 0.108 II-264 0.011 II-265 0.031 II-2660.007 II-268 0.024 II-269 0.363 II-270 0.025 II-271 0.153 II-272 0.392II-274 0.019 II-275 0.027 II-277 0.274 II-278 0.013 II-279 0.378 II-2800.244 II-281 0.664

As shown, the compounds of the invention showed inhibiting activity onP2X₃ receptor. Furthermore, as the compounds of the invention areeffective to P2X₃ subtype, the compounds also have inhibiting activityon P2X₂/₃ receptor, which comprises P2X₃ subtype.

(CYP3A4 Fluorescent MBI Test)

The CYP3A4 fluorescent MBI test is a test of investigating enhancementof CYP3A4 inhibition of a compound by a metabolism reaction, and thetest was performed using, as CYP3A4 enzyme expressed in Escherichia coliand employing, as an index, a reaction in which7-benzyloxytrifluoromethylchmarin (7-BFC) is debenzylated by the CYP3A4enzyme to produce a metabolite, 7-hydroxytrifluoromethylchmarin (HFC)emitting fluorescent light.

The reaction conditions were as follows: substrate, 5.6 μmol/L 7-BFC;pre-reaction time, 0 or 30 minutes; reaction time, 15 minutes; reactiontemperature, 25° C. (room temperature); CYP3A4 content (expressed inEscherichia cob), at pre-reaction 62.5 μmol/mL, at reaction 6.25 pmol/mL(at 10-fold dilution); test drug concentration, 0.625, 1.25, 2.5, 5, 10,20 μmol/L (six points).

An enzyme in a K-Pi buffer (pH 7.4) and a test drug solution as apre-reaction solution were added to a 96-well plate at the compositionof the pre-reaction, a part of it was transferred to another 96-wellplate so that it was 1/10 diluted by a substrate in a K-Pi buffer, NADPHas a co-factor was added to initiate a reaction as an index (withoutpreincubation) and, after a predetermined time of a reaction,acetonitrile/0.5 mol/L Tris (trishydroxyaminomethane)=4/1 was added tostop the reaction. In addition, NADPH was added to a remainingpreincubation solution to initiate a preincubation (with preincubation)and, after a predetermined time of a preincubation, a part wastransferred to another plate so that it was 1/10 diluted with asubstrate and a K-Pi buffer to initiate a reaction as an index. After apredetermined time of a reaction, acetonitrile/0.5 mol/L Tris(trishydroxyaminomethane)=4/1 was added to stop the reaction. For theplate on which each index reaction had been performed, a fluorescentvalue of 7-HFC which is a metabolite was measured with a fluorescentplate reader. (Ex=420 nm, Em=535 nm).

Addition of only DMSO which is a solvent dissolving a drug to a reactionsystem was adopted as a control (100%), remaining activity (%) wascalculated at each concentration of a test drug added as the solution,and IC₅₀ was calculated by reverse-presumption by a logistic model usinga concentration and an inhibition rate. When a difference between IC₅₀values is 5 μM or more, this was defined as (+) and, when the differenceis 3 μM or less, this was defined as (−).

(CYP Inhibition Test)

Using commercially available pooled human hepatic microsome, andemploying, as markers, 7-ethoxyresorufin O-deethylation (CYP1A2),tolbutamide methyl-hydroxylation (CYP2C9), mephenyloin 4′-hydroxylation(CYP2C19), dextromethorphan O-demethylation (CYP2D6), and terfenedinehydroxylation as typical substrate metabolism reactions of human mainfive CYP enzyme forms (CYP1A2, 2C9, 2C19, 2D6, 3A4), an inhibitorydegree of each metabolite production amount by a test compound wasassessed.

The reaction conditions were as follows: substrate, 0.5 μmol/Lethoxyresorufin (CYP1A2), 100 μmol/L tolbutamide (CYP2C9), 50 μmol/LS-mephenitoin (CYP2C19), 5 μmol/L dextromethorphan (CYP2D6), 1terfenedine (CYP3A4); reaction time, 15 minutes; reaction temperature,37° C.; enzyme, pooled human hepatic microsome 0.2 mg protein/mL; testdrug concentration, 1, 5, 10, 20 μmol/L (four points).

Each five kinds of substrates, human hepatic microsome, or a test drugin 50 mM Hepes buffer as a reaction solution was added to a 96-wellplate at the composition as described above, NADPH, as a cofactor wasadded to initiate metabolism reactions as markers and, after theincubation at 37° C. for 15 minutes, a methanol/acetonitrile=1/1 (v/v)solution was added to stop the reaction. After the centrifugation at3000 rpm for 15 minutes, resorufin (CYP1A2 metabolite) in thesupernatant was quantified by a fluorescent multilabel counter andtributamide hydroxide (CYP2CP metabolite), mephenyloin 4′ hydroxide(CYP2C19 metabolite), dextromethorphan (CYP2D6 metabolite), andterfenadine alcohol (CYP3A4 metabolite) were quantified by LC/MS/MS.

Addition of only DMSO being a solvent dissolving a drug to a reactionsystem was adopted as a control (100%), remaining activity (%) wascalculated at each concentration of a test drug added as the solutionand IC₅₀ was calculated by reverse presumption by a logistic model usinga concentration and an inhibition rate.

(FAT Test)

20 μl of freezing-stored rat typhoid bacillus (Salmonella typhimuriumTA98 strain, TA100 strain) was inoculated on 10 mL of a liquid nutrientmedium (2.5% Oxoid nutrient broth No. 2), and this was cultured beforeshaking at 37° C. for 10 hours. 9 mL of a bacterial solution of the TA98strain was centrifuged (2000×g, 10 minutes) to remove a culturingsolution, the bacteria was suspended in 9 mL of a Micro F buffer(K₂HPO₄: 3.5 g/L, KH2PO₄: 1 g/L, (NH₄)₂SO₄: 1 g/L, trisodium citratedehydrate: 0.25 g/L, MgSO₄.7H₂O: 0.1 g/L), the suspension was added to110 mL of an Exposure medium (Micro F buffer containing Biotin: 8 μg/mL,histidine: 0.2 μg/mL, glucose: 8 mg/mL), and the TA100 strain was addedto 120 mL of the Exposure medium relative to 3.16 mL of the bacterialsolution to prepare a test bacterial solution. Each 12 μL of a testsubstance DMSO solution (8 stage dilution from maximum dose 50 mg/mL at2-fold ratio), DMSO as a negative control, 50 μg/mL of4-nitroquinoline-1-oxide DMSO solution for the TA98 strain, 0.25 μg/mLof 2-(furyl)-3-(5-nitro-2-furyl)acrylamide DMSO solution for the TA100strain under the non-metabolism activating condition, 40 μg/mL of2-aminoanthracene DMSO solution for the TA98 strain, 20 μg/mL of2-aminoanthracene DMSO solution for the TA100 strain under themetabolism activating condition as a positive control, and 588 μL of thetest bacterial solution (a mixed solution of 498 μl of the testbacterial solution and 90 μL of S9 mix under the metabolism activatingcondition) were mixed, and this was shaking-cultured at 37° C. for 90minutes. 460 μL of the bacterial solution exposed to the test substancewas mixed with 2300 μL of an Indicator medium (Micro F buffer containingbiotin: 8 μg/mL, histidine 0.2 μg/mL, glucose: 8 mg/mL, Bromo CresolPurple: 37.5 μg/mL), each 50 μL was dispensed into microplate 48wells/dose, and this was subjected to stationary culturing at 37° C. for3 days. Since a well containing a bacterium which has obtained theproliferation ability by mutation of an amino acid (histidine)synthesizing enzyme gene turns from purple to yellow due to a pH change,the bacterium proliferation well which has turned to yellow in 48 wellsper dose is counted, and was assessed by comparing with a negativecontrol group. (−) means that mutagenicity is negative and (+) ispositive.

(Solubility Test)

The solubility of a compound is determined under a condition in which 1%DMSO is added. 10 mM compound solution is prepared using DMSO, and then6 μL of the compound solution is added to 594 μL of artificialintestinal juice in pH 6.8 (to 250 mL of 0.2 mol/L potassium dihydrogenphosphate reagent solution is added 118 mL of 0.2 mol/L NaOH reagentsolution and water to provide a final volume of 1000 mL). After standingat 25 degrees Celsius for 16 hours, the mixed solution is filtrated withsuction. The filtrate is diluted twice with methanol/water (1/1), andthen a concentration in the filtration is measured with HPLC or LC/MS/MSby the absolute calibration method.

(Metabolism Stability Test)

Using commercially available pooled human hepatic microsomes, a testcompound was reacted for a constant time, a remaining rate wascalculated by comparing a reacted sample and an unreacted sample,thereby, a degree of metabolism in liver was assessed.

A reaction was performed (oxidative reaction) at 37° C. for 0 minute or30 minutes in the presence of 1 mmol/L NADPH in 0.2 mL of a buffer (50mmol/L Tris-HCl pH 7.4, 150 mmol/L potassium chloride, 10 mmol/Lmagnesium chloride) containing 0.5 mg protein/mL of human livermicrosomes. After the reaction, 50 of the reaction solution was added to100 μl, of a methanol/acetonitrile=1/1 (v/v), mixed and centrifuged at3000 rpm for 15 minutes. The test compound in the supernatant wasquantified by LC/MS/MS, and a remaining amount of the test compoundafter the reaction was calculated, letting a compound amount at 0 minutereaction time to be 100%. Hydrolysis reaction was performed in theabsence of NADPH and glucuronidation reaction was in the presence of 5mM UDP-glucuronic acid in place of NADPH, followed by similaroperations.

(hERG Test)

For the purpose of assessing risk of an electrocardiogram QT intervalprolongation, effects on delayed rectifier K+ current (I_(Kr)), whichplays an important role in the ventricular repolarization process, wasstudied using HEK293 cells expressing human ether-a-go-go related gene(hERG) channel.

After a cell was retained at a membrane potential of −80 mV by wholecell patch clamp method using an automated patch clamp system(PatchXpress 7000A, Axon Instruments Inc.), I_(Kr) induced bydepolarization pulse stimulation at +40 mV for 2 seconds and, further,repolarization pulse stimulation at −50 mV for 2 seconds was recorded.After the generated current was stabilized, extracellular solution(NaCl: 135 mmol/L, KCl: 5.4 mmol/L, NaH₂PO₄: 0.3 mmol/L, CaCl₂.2H₂O: 1.8mmol/L, MgCl₂.6H₂O: 1 mmol/L, glucose: 10 mmol/L, HEPES(4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid): 10 mmol/L, pH=7.4)in which the test compound had been dissolved at an objectiveconcentration was applied to the cell under the room temperaturecondition for 10 minutes. From the recording I_(Kr), an absolute valueof the tail peak current was measured based on the current value at theresting membrane potential using an analysis software (DataXpress ver.1, Molecular Devices Corporation). Further, the % inhibition relative tothe tail peak current before application of the test substance wascalculated, and compared with the vehicle-applied group (0.1% dimethylsulfoxide solution) to assess influence of the test substance on I_(Kr).

(Bioavailability (BA) Test)

Materials and Methods for experiment of BA

(1) Animals:

Male Crl: CD(SD) rats of 6 weeks of age are purchased from Charles RiverLaboratories Japan, Inc., and housed during one week quarantine. Jugularvein c annulation surgery is performed more than 3 days beforeadministration for the rats. The rats are used at 8 weeks of age in theexperiments.

(2) Animal Husbandry:

Animal room is maintained under a 12-hr light (8:00-20:00)/dark(20:00-8:00) cycle and kept temperature (20-26° C.) and relativehumidity (30-70%). Rats have free access to solid food (CRF-1, JapanCharles River Inc.,) and sterilized bottled tap water.

(3) Identification of Rats and Cage:

Each rat is identified by a tail or a back marked with an oil marker penand individually housed in a cage labeled with name of the studydirector, date of receipt, strain, gender and supplier in theexperiment. Five rats are housed in one cage before the experiments. Onerat is housed in one cage in the experiments.

(4) Setting of Dose and Group Compositions:

Group compositions as shown below, are set by Dose of Oral andIntravenous administration, respectively.

Oral: 1 mg/5 mL/kg (n=2)

Intravenous: 0.5 mg/l mL/kg (n=2)

(5) Preparation for Dosing Formulation:

In oral administration study, a test suspension is prepared by using0.5% methylcellulose (MC, 400 cP) as test substance. In intravenousadministration study, a test solution is prepared by usingN,N-dimethylacetoamide (DMA)/propylenglycol (PG)=(1/1) as testsubstance.

(6) Dosing Procedure:

In oral administration study, the test suspension is dosed to thestomach of rats by using a gavage tube at 5 mL/kg In intravenousadministration study, the test solution is dosed to rats via tail veinusing a syringe with a needle.

(7) Evaluation Items:

Blood was collected at each time point and separated plasma. Plasmaconcentration of the test substance is determined by a LC/MS/MS system.

(8) Data Analysis:

Area under the plasma concentration-time curve (AUC) is calculated bymeans of WinNonline® program, respectively. Bioavailability (BA) iscalculated by using AUC values in oral administration study and inintravenous administration study.

Preparation Example 1

A granule containing the following ingredient is prepared.

Ingredient Compound represented by the formula (I)  10 mg Lactose 700 mgCorn starch 274 mg HPC-L  16 mg

The compound represented by the formula (I) and lactose are passedthrough a 60 mesh sieve. Corn starch is passed through a 120 mesh sieve.These are mixed with a V-type mixing machine. An aqueous solution ofHPC-L (low viscosity hydroxypropylcellulose) is added to a mixturepowder, and this is kneaded, granulated (extrusion granulation, porediameter 0.5 to 1 mm), and dried. The resulting dry granule is sievedwith a vibration sieve (12/60 mesh) to obtain a granule.

Preparation Example 2

A powder for filling into a capsule containing the following ingredientsis prepared.

Ingredient Compound represented by the formula (I) 10 mg Lactose 79 mgCorn starch 10 mg Magnesium stearate  1 mg

The compound represented by the formula (I), and lactose are passedthrough a 60 mesh sieve. Corn starch is passed through a 120 mesh sieve.These and magnesium stearate are mixed with a V-type mixing machine. 10trituration 100 mg is filled into a No. 5 hard gelatin capsule.

Preparation Example 3

A tablet containing the following ingredients is prepared.

Ingredient Compound represented by the formula (I) 10 mg Lactose 90 mgMicrocrystaline cellulose 30 mg CMC-Na 15 mg Magnesium stearate  5 mg

The compound represented by the formula (I), lactose, microcrystallinecellulose, CMC-Na (carboxymethylcellulose sodium salt) are passedthrough a 60 mesh sieve, and mixed. Magnesium stearate is mixed into amixture powder to obtain a mixture powder for tabletting. The presentmixed powder is directly compressed to obtain a 150 mg tablet.

Formulation Example 4

The following ingredients are warmed, mixed, and sterilized to obtain aninjectable.

Ingredient Compound represented by the formula (I) 3 mg Nonionicsurfactant 15 mg Purified water for injection 1 ml

Formulation Example 5

A cataplasm containing the following ingredients is prepared.

Ingredient Compound represented by the formula (I)  50 mg aqueous-based(5% ethanol/5% butylene 950 mg glycol/90% purified water) glycerinkaoline aqueous polyvinyl alcohol

The compound represented by the formula (I) is added to aqueous-based.The mixture is irradiated by ultrasonic for 15 minutes and then issufficiently stirred to obtain a solution. 5 part of glycerin, 1 part ofkaoline and 5 part of aqueous polyvinyl alcohol are homogeneously mixedand 1 part of the resulting solution is added to the above solutionincluding the compound represented by the formula (I). The obtainedsolution is mixed and to give a paste form and the resulting paste isapplied to an onwoven fabric. The resulting composition is covered bypolyester film to give a cataplasm.

INDUSTRIAL APPLICABILITY

The compound of the invention has antagonizing effect on P2X₃ and/orP2X₂/₃ receptor and is useful in the treatment of diseases or conditionsassociated with a P2X₃ and/or P2X₂/₃ receptor, such as chronic pain,overactive bladder, etc.

1. A compound represented by the formula (I):

wherein Z¹ is optionally protected hydroxy or optionally protectedmercapto; Z² is —C(═O)—, —C(═S)— or —S(O)v-, or

wherein R^(5a) and R^(5b) are each independently hydrogen or loweralkyl; R⁶ is hydrogen, substituted or unsubstituted lower alkyl,substituted or unsubstituted acyl or substituted or unsubstituted loweralkoxycarbonyl; p is an integer of 0 to 2; v is an integer of 0 to 2;Z^(3a) and Z^(3b) are each independently hydrogen, substituted orunsubstituted lower alkyl, or taken together ═O or ═S; t is an integerof 0 to 4; R^(4a) and R^(4b) are each independently, hydrogen orsubstituted or unsubstituted lower alkyl; m and n are each independentlyan integer of 0 to 2; k is an integer of 0 or 1; Ring A is cycloalkane,cycloalkene, an aromatic carbocyclic ring or a heterocyclic ring; B iscycloalkane-diyl, cycloalkene-diyl, aromatic carbocyclic ring-diyl orheterocyclic ring-diyl; R^(1a) and R^(1b) are each independentlyhalogen, hydroxy, substituted or unsubstituted lower alkyl, substitutedor unsubstituted lower alkenyl, substituted or unsubstituted loweralkynyl, substituted or unsubstituted lower alkoxy, substituted orunsubstituted lower alkylthio, substituted or unsubstituted acyl,carboxy, substituted or unsubstituted lower alkoxycarbonyl, substitutedor unsubstituted carbamoyl, substituted or unsubstituted thiocarbamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl, substituted or unsubstituted sulfamoyl, cyano, nitro or—C(R^(7a))═N—O—R^(7b); R^(7a) and R^(7b) are each independently hydrogenor substituted or unsubstituted lower alkyl; R² is substituted orunsubstituted alkyl, substituted or unsubstituted alkenyl, substitutedor unsubstituted alkynyl, substituted or unsubstituted alkoxy,substituted or unsubstituted aryloxy, hydroxy, substituted orunsubstituted amino, substituted or unsubstituted cycloalkyl,substituted or unsubstituted cycloalkenyl, substituted or unsubstitutedaryl or a substituted or unsubstituted heterocyclic group; R³ issubstituted or unsubstituted alkyl, substituted or unsubstitutedalkoxycarbonyl, substituted or unsubstituted aryloxycarbonyl, carboxy,substituted or unsubstituted carbamoyl, substituted or unsubstitutedcycloalkyl, substituted or unsubstituted cycloalkenyl, substituted orunsubstituted aryl or a substituted or unsubstituted heterocyclic group;provided that a compound of the following (i) to (viii) is excluded: (i)a compound wherein Ring A is thiadiazole, k is 0 and R^(1a) ismethylthio; (ii) a compound wherein Ring A is benzothiophene, k is 0,R^(1a) is methylsulfonyl and R² is substituted or unsubstituted furyl orsubstituted or unsubstituted phenyl; (iii) a compound wherein Ring A isthiazole or 7H-purine, and R² is substituted or unsubstituted furyl;(iv) a compound wherein R³ is a group represented by the formula:

t is an integer of 1 to 2 and Ring A is furan or benzene; (v) a compoundwherein R² is t-butyl or 4-methyloxyphenyl; (vi) a compound wherein R²is substituted or unsubstituted alkyl provided that substituted orunsubstituted i-propyl and substituted or unsubstituted i-butyl areexcluded, R³ is a substituted or unsubstituted carbocyclic ring or asubstituted or unsubstituted heterocyclic ring, and k is 0; (vii) acompound wherein R² is substituted or unsubstituted cycloalkyl,substituted or unsubstituted cycloalkenyl, substituted or unsubstitutedaryl or a substituted or unsubstituted heterocyclic group, and R³ ispentane-3-yl; and (viii) a compound represented by the formula:

or its pharmaceutically acceptable salt, or a solvate thereof.
 2. Thecompound according to claim 1, wherein R² is a group represented by theformula:

wherein Me is methyl, q is an integer of 0 to 4; and R³ is a grouprepresented by the formula:

wherein Y is hydroxy, halogen, cyano, carboxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkoxy,substituted or unsubstituted lower alkoxycarbonyl, substituted orunsubstituted acyl, substituted or unsubstituted carbamoyl, substitutedor unsubstituted thiocarbamoyl, substituted or unsubstituted loweralkylthio, substituted or unsubstituted lower alkylsulfamoyl,substituted or unsubstituted amino, substituted sulfinyl, substitutedsulfonyl or a substituted or unsubstituted heterocyclic group, or Y andR¹⁴ may form a substituted or unsubstituted heterocyclic group withadjacent carbon atom; R¹⁴ is halogen, hydroxy, substituted orunsubstituted lower alkyl, substituted or unsubstituted lower alkenyl,substituted or unsubstituted lower alkynyl, substituted or unsubstitutedlower alkoxy, substituted or unsubstituted lower alkylthio, substitutedor unsubstituted acyl, carboxy, substituted or unsubstituted loweralkoxycarbonyl, substituted or unsubstituted carbamoyl, substituted orunsubstituted amino, substituted or unsubstituted sulfamoyl, cyano ornitro; and r is an integer of 0 to 2, or its pharmaceutically acceptablesalt, or a solvate thereof.
 3. The compound according to claim 2,wherein Z³ and Z^(3b) are take together ═O, or its pharmaceuticallyacceptable salt, or a solvate thereof.
 4. The compound according toclaim 2, wherein t is 0, or its pharmaceutically acceptable salt, or asolvate thereof.
 5. The compound according to claim 2, wherein Z² is—C(═O)—, —C(═S)— or —S(O)₂—, or its pharmaceutically acceptable salt, ora solvate thereof.
 6. The compound according to claim 2, wherein Z² is—C(═O)—, or its pharmaceutically acceptable salt, or a solvate thereof.7. The compound according to claim 2, wherein the group represented bythe formula:

is a group represented by the formula:

or its pharmaceutically acceptable salt, or a solvate thereof.
 8. Thecompound according to claim 2, wherein the group represented by theformula:

is a group represented by the formula:

or its pharmaceutically acceptable salt, or a solvate thereof.
 9. Apharmaceutical composition comprising the compound according to any oneof claims 1 to 8, or its pharmaceutically acceptable salt, or a solvatethereof.
 10. A pharmaceutical composition having an antagonisticactivity for P2X₃ and/or P2X_(2/3) receptor, comprising the compoundaccording to any one of claims 1 to 8, or its pharmaceuticallyacceptable salt, or a solvate thereof.
 11. A method for preventing ortreating a disease related to P2X₃ and/or P2X_(2/3) receptorcharacterized by administration of the compound of any one of claims 1to 8, or its pharmaceutically acceptable salt, or a solvate thereof.12-13. (canceled)